Copper Sulfate Research Articles

Study on the performance of nano boron nitride composite phosphate film modified on carbon steel surface

Purpose The purpose of this paper is to study the effect of nano polypyrrole-modified boron nitride on the performance of phosphate film. Design/methodology/approach By adding polypyrrole-modified boron nitride to the phosphate solution, a phosphate film is formed on the metal surface, improving its corrosion resistance. The effect of different concentrations of polypyrrole-modified boron nitride on the corrosion resistance of Q235 carbon steel surface was studied. The corrosion resistance of the phosphate film was evaluated using the copper sulfate drop test. The electrochemical corrosion performance of the phosphate film was assessed using the weak polarization curve method and electrochemical impedance spectroscopy. The surface of the samples was characterized using scanning electron microscopy and X-ray diffraction analysis. Findings The results show that samples containing polypyrrole-modified boron nitride have a denser and more uniform phosphate film. When the concentration of polypyrrole-modified boron nitride is 0.6 g/L, the drop time of copper sulfate on the formed phosphate film can reach 219 s, which is a 189% increase compared to the performance of the sample without the additive. The current density is 1.06 × 10−6 A/cm2 lower than that of the pure phosphate film, indicating the best corrosion resistance. Polypyrrole-modified boron nitride effectively promotes the formation of the phosphate film. Originality/value This study used the modification of phosphate solution using nanoparticles to investigate the influence of different nanoparticle concentrations on the phosphate film. The corrosion resistance of the phosphate film was enhanced, providing a method and theoretical guidance for the improvement of phosphate solution formulation.

Copper sulfate-induced stress in Spinach: Metabolic pathway disruption and plant response

Copper sulfate (CuSO4) stress profoundly affects plant growth by interfering with key metabolic pathways. This disruption leads to significant alterations in various physiological parameters, ultimately impacting the overall health and productivity of the plant. This study assessed the impact of CuSO4 stress on spinach (Spinacia oleracea L.) through a pot experiment using CuSO4 concentrations of 0, 75, 125, and 175 ppm. We noticed that at 75 ppm, CuSO4 improved plant height and the concentration of soluble sugar and ascorbic acid compared to the control. Additionally, amino acid, phenol, proline, fresh weight, and moisture content peaked at 175 ppm. Conversely, at 125 and 175 ppm, plant height, dry weight, leaf area, and concentrations of ascorbic acid and sugar significantly decreased. Moreover, at 175 ppm, there were substantial decreases in chlorophyll a (14.8%), chlorophyll b (73.6%), carotenoids (15%), and photosynthetic rates compared to the control. However, the chlorophyll a to chlorophyll b ratio increased by 29.53% at 175 ppm. In addition, protein and phenol contents diminished at 75 and 125 ppm. Elevated CuSO4 levels increased non-protein thiol levels while reducing the activities of superoxide dismutase, catalase, ascorbate peroxidase, and glutathione peroxidase. Stress hormones such as abscisic acid, jasmonic acid, and ethylene increased with CuSO4 stress, whereas growth hormones indol-acetic acid and gibberellic acid declined. This study demonstrates that spinach shows improved growth and metabolic function at 75 ppm CuSO4, indicating tolerance to mild stress. However, higher CuSO4 concentrations (125 and 175 ppm) significantly reduce growth parameters, chlorophyll content, and enzyme activities, highlighting the need for careful CuSO4 management in agriculture to avoid adverse effects on plant health and productivity.

Copper requirements of animals and pastures in New Zealand pastoral agriculture - a review

More copper (Cu) is required for the growth of cattle and deer than sheep and pasture. National and regional farm surveys showed that mean pasture Cu concentrations were generally within or above the required range for pasture growth and lambs but below that for cattle and deer. Pasture concentrations of molybdenum (Mo) of up to 7 mg/kg for lambs and 10 mg/kg for deer had no effect on liveweight gain provided that pasture Cu concentrations were 7 to 8 mg/kg or greater. From twenty-one sites, there was a significant response to Cu in animal liveweight gain and wool weight only from lambs injected monthly with Cu and deer grazing pasture top dressed with copper sulphur, both on pasture with high Mo concentrations. Daily drenching of animals with copper sulphate or chelated Cu and the use of Cu capsules or copper oxide (CuO) wire particles was more effective at increasing liver Cu concentration than Cu injections or topdressing with copper sulphate. There was a significant pasture yield response measured on Recent and podzolised soils that had pasture Cu concentrations in the deficient range. There is a need for more research on the response in liveweight gain of cattle and deer from different Cu treatments at varying pasture Mo concentrations.

Role of chemistry in modern world: Boons and banes of chemical coating effects on human health

Water is the principal component of fresh fruits and Vegetable which constitutes between 80 to 90% of a produce's fresh weight. Fruits are covered by a layer of natural wax which acts as a barrier to reduce moisture loss and at the same times give the fruit a shiny surface. Besides orange shellac, other common materials used for these purposes include starch, carrageenan, alginates, wood rosin and various waxes. Panko breadcrumbs are crucial to the vegetables being very crispy. The coatings are typically made from natural materials, such as CHI, cellulose, and pectin that are safe for human consumption. The multilayer coating method has been shown to be effective in extending the shelf life of a variety of fresh fruits and vegetables, including apples, strawberries, tomatoes, and cucumbers. Both natural waxes (carnauba, shellac, beeswax or resin) and petroleum-based waxes (usually proprietary formulae) are used, and often more than one wax is combined to create the desired properties for the fruit or vegetable being treated. However, chemical treatments, such as copper sulfate, rhodamine oxide, malachite green, and deadly carbide, used on green vegetables to enhance coloration and freshness, are often counterproductive to their nutritional value. There is multiple health risks associated with these chemicals. This study reveals that food preservatives have made a big difference in eating food every day. They help keep the food safe because they add these chemicals to prevent spoilage and retard prevent or control undesirable changes in flavor, color, texture, or consistency of food and nutritive value of food which means the Control natural spoilage of food.

Influence of copper and zinc sulfates on in vitro propagation efficiency of orchids (Dendrobium phalaenopsis): A step towards optimizing clonal propagation protocols

Influence of copper and zinc sulfates on in vitro propagation efficiency of orchids (Dendrobium phalaenopsis): A step towards optimizing clonal propagation protocols

Cupric citrate supplementation improves growth performance, nutrient utilization, antioxidant capacity, and intestinal microbiota of broilers.

This study aimed to examine the impact of cupric citrate on broilers and compare it with the copper sulfate groups and a control group. A total of 360 1-day-old Ross 308 broilers were randomly assigned into 5 groups, each with 6 replicates of 12 broilers per treatment. The control group was fed a basal diet without any copper supplementation. In contrast, the other groups received basal diets supplemented with either 50 mg/kg (CS-50) or 100 mg/kg (CS-100) of copper in the form of copper sulfate, or 50 mg/kg (CC-50) or 100 mg/kg (CC-100) of copper in the form of cupric citrate, for a period of 42 days. The results showed that copper supplementation affected the average daily gain from day 1 to 21 (p = 0.026) and day 1 to 42 (p = 0.025) in a source-dependent manner. Copper source also influenced the energy digestibility (p = 0.004), with the CC-100 being the most effective treatment. Notably, birds in the CC-100 groups had significantly reduced concentrations of Escherichia coli (p < 0.05) in the cecum, and the Lactobacillus in the ileum, compared to the control group. Dietary copper supplementation also increased the pH in the duodenum (p < 0.05) irrespective of the sources and levels. In addition, the source of copper affected the activities of ceruloplasmin (p = 0.014) and Cu-Zn superoxide dismutase (p = 0.025) in the serum, with the CC-100 group showing the highest levels of both enzymes. Copper supplementation generally improves the growth, nutrient utilization, intestinal microflora, gastrointestinal pH, and antioxidant defences of broilers. Moreover, cupric citrate is as effective as copper sulfate even at equal or lower concentrations.

CuBe: a geminivirus-based copper-regulated expression system suitable for post-harvest activation.

The growing demand for sustainable platforms for biomolecule manufacturing has fuelled the development of plant-based production systems. Agroinfiltration, the current industry standard, offers several advantages but faces limitations for large-scale production due to high operational costs and batch-to-batch variability. Alternatively, here, we describe the CuBe system, a novel bean yellow dwarf virus (BeYDV)-derived conditional replicative expression platform stably transformed in Nicotiana benthamiana and activated by copper sulphate (CuSO4), an inexpensive and widely used agricultural input. The CuBe system utilizes a synthetic circuit of four genetic modules integrated into the plant genome: (i) a replicative vector harbouring the gene of interest (GOI) flanked by cis-acting elements for geminiviral replication and novelly arranged to enable transgene transcription exclusively upon formation of the circular replicon, (ii) copper-inducible Rep/RepA proteins essential for replicon formation, (iii) the yeast-derived CUP2-Gal4 copper-responsive transcriptional activator for Rep/RepA expression, and (iv) a copper-inducible Flp recombinase to minimize basal Rep/RepA expression. CuSO4 application triggers the activation of the system, leading to the formation of extrachromosomal replicons, expression of the GOI, and accumulation of the desired recombinant protein. We demonstrate the functionality of the CuBe system in N. benthamiana plants expressing high levels of eGFP and an anti-SARS-CoV-2 antibody upon copper treatment. Notably, the system is functional in post-harvest applications, a strategy with high potential impact for large-scale biomanufacturing. This work presents the CuBe system as a promising alternative to agroinfiltration for cost-effective and scalable production of recombinant proteins in plants.

Structural, Morphological, Optical and Vibrational Properties of a Novel Coral-Like Fibrous CuO Nanostructure Synthesized via Dropwise Precipitation for UV-light Induced Photocatalytic Wastewater Remediation on Aqueous R6G Dye

CuO is a well-known monoclinic structure with unique properties that is extensively investigated for sensor, energy storage, and optoelectronic applications. In this work, the CuO nanostructure was synthesized through facile precipitation by mixing the aqueous copper (II) sulfate pentahydrate with sodium hydroxide. The as-synthesized CuO was characterized by scanning electron microscopy (SEM), X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR) and UV–visible spectroscopy. A homogeneous growth of a narrow, fine coral-like fibrous morphology was observed on CuO under SEM imaging. The FTIR spectra reveal the existence of some dominant sharp bands in the lower wavenumber region that represent the Cu-O bonds. The high solubility of CuO in water confirms the formation of particles with nanoscale dimensions. CuO exhibits a strong optical absorption peak at 510 nm, and the band gap determined by Tauc's relation is 2.11 eV. CuO is capable of inducing photocatalytic degradation on R6G dye solutions under low-intensity UVC irradiation, which can serve as a future photocatalyst for wastewater treatment.

Assessing the Comparative Toxicity of Salvia Officinalis Extracts and Copper Sulphate on Melanopsis Nodosa, a Freshwater Snail

This study investigates the molluscicidal properties of Salvia officinalis extracts against Melanopsis nodosa snails, with a focus on environmentally friendly alternatives to traditional chemical molluscicides. Melanopsis nodosa, a common freshwater snail in Iraq, is an intermediate host for diseases affecting humans and animals. Traditional molluscicides, such as copper sulphate, pose environmental and non-target organism risks. S. officinalis, known for various medicinal uses, was explored for its potential molluscicidal activity. Snails were collected from Muhyii Canal, Baghdad, and exposed to different concentrations of S. officinalis extracts and copper sulphate in controlled laboratory conditions. The study evaluated mortality rates at 24-, 48-, 72-, and 96-hours exposure, using the WHO method for molluscicide testing and Probit analysis for mortality calculation. Results showed significant molluscicidal activity of S. officinalis extracts, with the LC50 values of 15.53 ppm (24 hrs), 6.821 ppm (48 hrs), 4.288 ppm (72 hrs), and 0.0735 ppm (96 hrs). Compared to copper sulphate, the extracts were less effective but still significant, indicating the potential of S. officinalis as an environmentally friendly molluscicide. This study contributes to the search for safer molluscicides, highlighting S. officinalis extracts' effectiveness against M. nodosa. These findings could aid in controlling snail populations, thereby reducing the spread of snail-borne diseases, with lower environmental impact compared to traditional chemical molluscicides. Further research is suggested to understand the exact mechanism of snail mortality caused by these extracts.

Optimization of Reactive Ink Formulation for Controlled Additive Manufacturing of Copolymer Membrane Functionalization.

Multifunctional, nanostructured membranes hold immense promise for overcoming permeability-selectivity trade-offs and enhancing membrane durability in challenging molecule separations. Following the fabrication of copolymer membranes, additive manufacturing technologies can introduce reactive inks onto substrates to modify pore wall chemistries. However, large-scale implementation is hindered by a lack of systematic optimization. This study addresses this challenge by elucidating the membrane functionalization mechanisms and optimal manufacturing conditions using a copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) "click" reaction. Leveraging a data science toolkit (e.g., nonlinear regression, uncertainty quantification, identifiability analyses, model selection, and design of experiments), we developed two mathematical models: (1) algebraic equations to predict equilibrium concentrations after preparing reactive inks by mixing copper sulfate, ascorbic acid (AA), and an alkynyl-terminated reactant; and (2) reaction-diffusion partial differential equations (PDEs) to describe the functionalization process. The ink preparation chemistry with side reactions was validated through pH and UV-vis measurements, while the diffusion and kinetic parameters in the PDE model were calibrated using time-series conversion of the azide moieties inferred from Fourier-transform infrared spectroscopy. This modeling framework avoids redundant experimental efforts and offers a functionalization protocol for scaling up designs. Ink optimization problems were proposed to reduce the use of expensive and environmentally insulting ink materials, i.e., Cu(II), while ensuring the desired chemical distributions. With optimal ink formulation Cu(II)/AA/alkyne = 1:1:2 identified, we uncovered trade-offs between Cu(II) usage and functionalization time; for example, in continuous roll-to-roll manufacturing with a conserved functionalization bath setup, our optimal operational conditions to achieve ≥90% functionalization enable at least a 20% reduction in total copper investment compared to previous experimental results. The data science-enabled ink optimization framework is extendable for on-demand multifunctional membranes in numerous future applications such as metal recovery from wastewater and brine.

Discovery of Anti-Inflammatory Alkaloids from Sponge Stylissa massa Suggests New Biosynthetic Pathways for Pyrrole-Imidazole Alkaloids.

Pyrrole-imidazole alkaloids (PIAs) are a class of marine sponge derived natural products which have complex carbon frameworks and broad bioactivities. In this study, four new alkaloids, stylimassalins A-B (1-2), 3, and 5, together with two known compounds (4 and 6), were isolated from Stylissa massa. Compounds 2, 4, and 6 are the C-2 brominated analogues of 1, 3, and 5, respectively. Their structures display three different scaffolds, of which scaffold 1 (compounds 1,2) is new. A new biosynthetic pathway from oroidin, through spongiacidin, to latonduine and scaffold 1 was proposed by our group, in which the C12-N13-cleavaged compounds of spongiacidin (scaffold 2), dubbed seco-spongiacidins (3 and 4), are recognized as a key bridged scaffold, to afford PIA analogues (1,2 and 5,6). An anti-inflammatory evaluation in a zebrafish inflammation model induced by copper sulphate (CuSO4) demonstrated that stylimassalins A and B (1 and 2) could serve as a promising lead scaffold for treating inflammation.

Copper(II)-Catalyzed Amination of Aryl Chlorides in Aqueous Ammonia.

Anilines are ubiquitous in bio-active compounds and their synthesis can be achieved via metal-catalyzed cross-coupling reactions involving aryl halides. We describe an unusual, yet simple, CuII-catalyzed system for the amination of aryl chlorides in pure aqueous ammonia with 2.5 mol % catalyst loading under non-inert conditions. Different from previous systems, the reaction proceeds even without an additional organic solvent. Copper(II) sulfate in combination with 4,7-dimethoxy-1,10-phenanthroline enabled the amination of several aryl chlorides containing electron-neutral, -donating and -withdrawing groups to the corresponding anilines with good to excellent yields. The upscaling potential of the procedure has been shown by the synthesis at 50 mmol scale. The reaction proceeds as one of the rare cases of a CuII-assisted coupling, in contrast to the typical CuI-CuIII intermediates postulated for most Ullmann-type coupling reactions. The copper(II) center allows for a nucleophilic substitution pathway, enabled by the deprotonation of coordinated ammonia.

Effect of different levels of micronutrients on vegetative growth, yield and fruit quality of Mango (Mangifera indica L.)

An experiment was carried out to ascertain the impact of foliar application of certain micro-nutrients on fruit yield and quality of Mango (Mangifera indica L.) cultivars "Dashehari" and "Langra" at Agriculture Research Station, Banswara, Maharana Pratap University of Agriculture and Technology, Udaipur, Rajasthan, during the year 2016-17 on seventeen years old mango trees. The experiment was laid out in One way ANOVA (Randomized Block Design) with eight treatments in thrice replications for combinations with different micronutrients Zinc sulphate, Copper sulphate, Borax, boric acid and IIHR-2 mango special were applied on mango cultivars "Dashehari" and "Langra" at different growth stages. All were fertilized with a recommended dose of NPK (1500:500:1000 g as N, P2O5 and K2O). The spraying was done twice; during mid-October, mid-December, and mid-February before the flowering stage and again in mid-March at the marble stage during both years of study. Foliar sprays, in general, improved fruit yield. Yields were exceptionally higher in response to foliar application of Zinc (Zn), Copper (Cu) and boron (B) compared to other treatments. Result proved that foliar application of mango trees with [(RDF + Zinc sulphate (100 g) + Copper sulphate (50 g) + Boric acid (50 g) as soil + Zinc sulphate (0.2%) + Copper sulphate (0.1%) + Boric acid (0.1%) as foliar (Two sprays before flowering and marble stage)] was the promising treatment for improvement of vegetative growth, yield and fruit quality. This treatment was also found best for maximum total carotenoids, average fruit weight as well as fruit yield.

Alternative products for breaking dormancy in ‘Reubennel’ plum in subtropical regions

Abstract Plum is a temperate fruit tree and thus shows abundant vegetative bud percentage and flowering following extended periods of low winter temperatures. When adequate periods of low temperatures do not occur, it is necessary to apply products to stimulate bud dormancy break and uniform leaf and flower appearance. This application is more frequently needed when plum trees are grown in the tropics. The objective of this study was to evaluate alternative products for breaking dormancy in ‘Reubennel’ plum in subtropical regions. The experiment was conducted at a site located at 22°22’S, 43°77’W and 1,173 m altitude, with a Cwa climate type. The following treatments were applied to eight-year-old ‘Reubennel’ plum trees in the 2018 and 2019 production cycles: 1) a negative standard composed of only water (control), a positive standard composed of 2) 1.5% hydrogen cyanamide (HC) (Dormex® commercial product) plus 4.5% mineral oil, 3) Erger G® organomineral fertilizer supplemented with 3% calcium nitrate, 4) 5% potassium nitrate and 5) 0.3% copper sulfate. Two liters of the treatment solutions were applied per plant with a sprayer. The effect of the tested products on vegetative bud percentage and flowering capacity, production cycle reduction and production and quality of ‘Reubennel’ plums was evaluated. It was concluded that the chemicals used to break dormancy affected only the phenology of plum trees in this subtropical region and that the application of copper sulfate can be used to break dormancy in these trees.

Enhanced biocatalytic laccase production using agricultural waste in solid-state fermentation by Aspergillus oryzae for p-chlorophenol degradation

Agricultural residues are one of the most cost-effective and readily accessible carbon resources for producing commercially significant enzymes. Several enzymes have been used in different industries like pharmaceuticals, foods, textiles, and dyes that can be generated by various species of microbes found in waste from agriculture. The current research investigated laccase production by Aspergillus oryzae utilizing agricultural wastes. Physical and chemical properties, including pH, temperature, sucrose, yeast extract, and copper sulfate levels, were optimized. The utilization of the response surface methodology along with the centralized composite design method, which assesses multiple media parameters and utilizes a two-level experimental approach, aids in determining the variable and its significance in increasing production quality. The centralized composite design enhancement showed that the optimal conditions for highest laccase activity (623.16 U/mL) were pH 7.0, temperature 25 °C, corn cobs as substrate, sucrose (2.0 %), yeast extract (1.0 %), and copper sulfate (0.1 mM) level. The laccase enzyme was optimized using various pH, temperature, metal ions, and inhibitors combinations. The extracted laccase enzyme maximum activity was attained at pH 6.0 and 40 °C. The inclusion of divalent ions can enhance laccase activity, while the use of various inhibitors decreases laccase activity. Under various pH circumstances, the Aspergillus oryzae laccase enzyme can successfully degrade p-chlorophenol. The present study describes statistically validated optimal methodologies for enhancing laccase synthesis, leading to a laccase production technique that is simultaneously highly efficient and economically profitable, with possible use of p-chlorophenol degradation.

Optimization of Progressive Freeze Crystallization Process by Response Surface Methodology for the Treatment of Electroplating Wastewater for Copper (II) Sulphate Recovery

&lt;p style="line-height:200%;text-align:justify;text-indent:0cm;text-justify:inter-ideograph;"&gt;&lt;span style="line-height:200%;" lang="EN-US"&gt;For the copper-containing electroplating wastewater generated by a semiconductor company, the recovery of copper salts by progressive freeze crystallization and its process parameters were experimentally optimized and studied.&amp;nbsp;Based on the results of single-factor experiments, according to the principles of Box-Behnken Design experimental design for response surface methodology to investigate the effects of coolant temperature, agitation rate, and freezing time on salt removal and optimize process parameters. The optimization results of the response surface method showed that the optimal conditions were when the coolant temperature was -8°C, the stirring rate was 264 r&lt;/span&gt;&lt;span style="font-family:Symbol;line-height:200%;" lang="EN-US"&gt;×&lt;/span&gt;&lt;span style="line-height:200%;" lang="EN-US"&gt;min&lt;sup&gt;-1&lt;/sup&gt;, and the freezing time was 78 min.&amp;nbsp;Three validation experiments were conducted under optimum conditions, and salt removal was obtained as 60.13 ± 4.10%, which is more in line with the predicted values.&amp;nbsp;Treatment of copper-containing electroplating wastewater using tertiary freezing under response surface optimized experimental conditions.&amp;nbsp;At this time, the total ice rate of the wastewater was about 65.00%, and the conductivity was also concentrated from 2.17&amp;nbsp;mS&lt;/span&gt;&lt;span style="font-family:Symbol;line-height:200%;" lang="EN-US"&gt;×&lt;/span&gt;&lt;span style="line-height:200%;" lang="EN-US"&gt;cm&lt;sup&gt;-1&lt;/sup&gt; of the raw water to 2.99&amp;nbsp;mS&lt;/span&gt;&lt;span style="font-family:Symbol;line-height:200%;" lang="EN-US"&gt;×&lt;/span&gt;&lt;span style="line-height:200%;" lang="EN-US"&gt;cm&lt;sup&gt;-1&lt;/sup&gt; with a total concentration ratio of 1.38.&amp;nbsp;In addition, a higher concentration of concentrated liquid was obtained in the third freezing, while a crystalline salt precipitated from the bottom of the reactor. The precipitate was analyzed mainly as copper sulfate pentahydrate using XRD, XRF, EDS, and other characterization techniques.&lt;/span&gt;&lt;span lang="EN-US"&gt; Theoretical calculations show that pre-cooling of raw wastewater reduces energy consumption by up to 20.40%.&lt;/span&gt;&lt;/p&gt;

Dispersion Parameters of Copper Sulphate Doped PMMA

Films of PMMA and copper sulphate doped PMMA have been prepared by casting method. Absorbance and transmittance spectra were recorded in the wavelength range (300-900) nm in order to calculate, single oscillator energy, dispersion energy, average oscillator strength, the refractive index at infinite wavelength, M-1 and M -3 moments of the optical spectra, it was found that all these parameters were effected by doping.

Structural characteristics and biological evaluation of copper coating cotton material obtained by chemical reduction method

The article describes the preparation of new cotton materials obtained by chemical deposition of copper sulfide. This two-stage process consists of chelation of copper sulfate on cellulose chains of cotton (COT → COT-CuSO4) with subsequent precipitation of copper in the form of copper sulfide (COT-CuSO4 → COT-CuS) using sodium sulfide. The obtained COT-CuS composites were characterized physicobiologically. Thus, the structural characteristic of the Cotton-CuS material was determined by microscopy analysis (SEM), Atomic Absorption Spectrometry with Flame Excitation (FAAS), specific surface area and total pore volume analysis (BET). The copper functionalized cotton fabric was subjected to microbial activity tests against colonies of Gram-negative (Escherichia coli) and Gram-positive ( Staphylococcus aureus) bacteria and Chaetomium globosum, Aspergillus niger fungal molds species. Biochemical evaluation includes hematological tests of activated partial thromboplastin time (aPTT) and prothrombin time (PT). The substantial antimicrobial properties of the newly synthesized COT-CuS material with the lack of influence on blood coagulation processes offer prospects of a potential use as applications as an antibacterial/antifungal material.

Chitosan-mediated copper nanohybrid attenuates the virulence of a necrotrophic fungal pathogen Macrophomina phaseolina.

This study reported the synthesis and characterization of chitosan-copper nanoparticles (Ch-CuNPs) using a 1% copper sulfate solution in 0.2% w/v chitosan. The Ch-CuNPs, displaying a stable brick-red hue, showed an absorption peak at 572nm, indicative of monodisperse nanoparticle formation and surface plasmon resonance. X-ray diffraction confirmed the face-centered cubic structure with peaks at 36.78°, 43.38°, 50.56°, and 74.26°, and an average particle size of 87-89nm. FTIR analysis showed interactions between chitosan and copper, particularly around 3370 -3226cm⁻¹, 1633cm⁻¹, and 680cm⁻¹. In vitro assays revealed that Ch-CuNPs inhibited Macrophomina phaseolina growth by 18-71% at 0.03-0.09% concentrations, achieving complete inhibition at 0.12-0.15%, with PCA analysis confirming that growth peaked at lower concentrations and sharply declined at higher levels. Ch-CuNPs also altered fungal morphology and enzyme activity, with notable degradation at higher concentrations. The Cu uptake by the fungus peaked at 29.9% with 0.03% Ch-CuNPs and decreased at higher concentrations. FTIR analysis showed shifts and disappearance of peaks in fungal biomass treated with Ch-CuNPs, indicating molecular interactions and potential structural changes. This study underscores the potential of Ch-CuNPs as an effective antifungal agent and elucidates their interaction mechanisms.

Eco-friendly and low-cost phytodyeing for wool, cotton and polyester textile materials using Parthenocissus Quinquefolia L. Fruit Extracts

This study investigates the extraction of natural colorant from fresh fruits of Parthenocissus quinquefolia L. and the application of the extracted dye to wool yarn, cotton, and polyester fabrics in the presence and absence of various mordants. The effect of mordant type on the dyeing quality with different mordanting methods was examined. Iron sulfate, tin chloride, alum, copper sulfate, and potassium dichromate were used as mordant. The effects of these mordants on the color of the dyed samples were investigated in terms of CIELab (L*, a*, b*) and K/S values. The light, washing and rubbing fastness of the dyed samples were evaluated according to ISO standards. While dyeing wool yarn without mordant produces reddish brown, and dyeing with mordant produces a wide range of colors from green to purple, blue and lilac tones are obtained in cotton fabric dyeing, and green, purple and brown tones are obtained in polyester fabric dyeing. While polyester fabrics are dyed with synthetic dyes at 130 oC, in this study they were dyed with natural dyes at 90 oC. As a result of dyeing, colors with high fastness are generally obtained.