Sulfate Minerals Research Articles

Reclamation and Improvement of Saline Soils Using Organo–Mineral–Natural Resources, Treated Saline Water, and Drip Irrigation Technology

Reclamation and management of saline soil in arid regions fundamentally require more consideration to attain sustainable agriculture. Experiments were conducted at Abo-Kalam Farm, South Sinai, Egypt. Split-split-plot design experiments were carried out to study the effect of treatments on saline soil hydrophysical properties, sorghum, and cv. ‘Dorado’ plants during the summer season. Pea cv. ‘Entsar 3’ plants were cultivated during the winter season for the residual effect of treatments. Organo–mineral amendment (rice straw compost + mineral sulfur at different rates) was assigned as the main factor, natural rock or artificial fertilizers were assigned as subfactors, and humic acid at different rates was the sub-subfactor. Results showed that organo–mineral amendments improved the hydrophysical properties of the soil, plant nutrient uptake, crop yield, and crop water productivity; however, it diminished by 10 tons/fed (4200 m2) of compost plus 700 kg/fed of mineral sulfur. Therefore, it is recommended that economically using the combination of applying organic–mineral amendments of 4 tons/fed of compost plus 400 kg/fed of mineral sulfur and 5 kg/fed of humic acid plus natural rock fertilizer is the best safe management for reclamation and improvement of saline soils using partially treated saline irrigation water and natural resources.

Discovery of calcium sulfate at different hydration states on Mars - based on perseverance SHERLOC analysis

Organic matter on planets is often co-deposited with evaporites, and evaporation of lakes in the Jezero region of Mars may have led to the deposition of abundant organic matter and minerals such as sulfates, making sulfates important minerals for preserving the remains of potential life on Mars, especially in different hydration states, will help to invert the variability of the Martian environment and provide guidance for the exploration of life on Mars. Raman spectroscopy can detect the molecular composition of organic matter and acid anion information of the target of interest, thus enabling in situ analysis of life information and its living environment. In order to realize the detection of life remains on Mars, The Perseverance rover is equipped with SHERLOC in situ material detection payload, which adopts a 248.6 nm deep ultraviolet (DUV) laser to simultaneously excite Raman and fluorescence signals of the target. In this paper, five scans in three modes (survey scan, HDR scan and detail scan) from two sites on Mars (Quartier and Bellegarde) were selected for preliminary analysis, and the presence of sulfate minerals at these two sites was confirmed. The detail scans at Quartier were analyzed in depth, and the presence of four calcium sulfate minerals, gypsum (CaSO4∙2 H2O), bassanite (CaSO4∙0.5 H2O), anhydrite (β-CaSO4) and gamma-calcium sulfate (γ-CaSO4)was inferred from the states of ν1 (SO4), ν3 (SO4) and hydrated peaks. The differences in the degree of hydration of calcium sulfate minerals suggest that there may have been active water activity on Mars. By comparing data collected by SHERLOC with spectra from spectral libraries, the composition of small-scale structures on Mars may be assessable. However, due to the complexity of the Martian geology, more accurate water activity will need to be combined with more detailed ions, temperatures, humidity, and other conditions for a more precise analysis.

Hydrochemical Characteristics and Formation Mechanism of Geothermal Fluids in Zuogong County, Southeastern Tibet

Zuogong County is located in the southeast of Tibet, which is rich in hot spring geothermal resources, but its development and utilization degree are low, and the genetic mechanism of the geothermal system is not clear. Hydrogeochemical characteristics of geothermal water are of great significance in elucidating the genesis and evolution of geothermal systems, as well as the sustainable development and utilization of geothermal resources. The hydrogeochemical characteristics and genesis of the geothermal water in Zuogong County were investigated using hydrogeochemical analysis, a stable isotope (δD, δ18O) approach, and an inverse simulation model for water–rock reactions using the PHREEQC. The results indicated that the Zuogong geothermal system is a deep circulation heating type without a magmatic heat source. The chemical types present in the geothermal water from the Zuogong area are HCO3 and HCO3·SO4, and the main cations are Na+ and Ca2+. The groundwater is replenished by atmospheric precipitation and glacier meltwater. The salt content of geothermal water mainly comes from the interaction between water and surrounding rocks during the deep circulation process. The reservoir temperature of geothermal water in Zuogong is 120–176 °C before mixing with non-geothermal water and drops to 62–98 °C after mixing with 58 to 79% of non-geothermal water. According to the proposed conceptual model, geothermal water mainly produces water–rock interaction with aluminosilicate minerals in the deep formation, while in shallow areas it interacts mainly with sulfate minerals. These findings contribute to a better understanding of the geothermal system in Zuogong County, Tibet.

From Ions to Crystals: A Comprehensive View of the Non-Classical Nucleation of Calcium Sulfate.

After years ofintensive research andnumerous important observations, our understanding of the early stages of crystallization is still limited due to the complexity of the underlying processes and their elusive character. In the present work, we provide a detailed view on the nucleation of calcium sulfate mineralization - an abundant mineral with broad use in construction industry - in aqueous systems at ambient conditions. As experimental basis, a co-titration procedure with potentiometric, turbidimetric and conductometric detection was developed, allowing solution speciation and the formation of crystallization precursors to be monitored quantitatively as the level of nominal (super)saturation gradually increases. The nature and spatiotemporal evolution of these precursors was further elucidated by time-resolved small-angle X-ray scattering (SAXS) and analytical ultracentrifugation (AUC) experiments, complemented by cryogenic transmission electron microscopy (cryo-TEM) as a direct imaging technique. The results reveal how ions associate into nanometric primary species, which subsequently aggregate and develop anisotropic order by intrinsic structural reorganization. Our observations challenge the common understanding of fundamental notions such as the nucleation barrier or the meaning of supersaturation, with broad implications for mineralization phenomena in general and the formation of calcium sulfate in geochemical settings and industrial applications in particular.

From Ions to Crystals: A Comprehensive View of the Non‐Classical Nucleation of Calcium Sulfate

After years of intensive research and numerous important observations, our understanding of the early stages of crystallization is still limited due to the complexity of the underlying processes and their elusive character. In the present work, we provide a detailed view on the nucleation of calcium sulfate mineralization – an abundant mineral with broad use in construction industry – in aqueous systems at ambient conditions. As experimental basis, a co‐titration procedure with potentiometric, turbidimetric and conductometric detection was developed, allowing solution speciation and the formation of crystallization precursors to be monitored quantitatively as the level of nominal (super)saturation gradually increases. The nature and spatiotemporal evolution of these precursors was further elucidated by time‐resolved small‐angle X‐ray scattering (SAXS) and analytical ultracentrifugation (AUC) experiments, complemented by cryogenic transmission electron microscopy (cryo‐TEM) as a direct imaging technique. The results reveal how ions associate into nanometric primary species, which subsequently aggregate and develop anisotropic order by intrinsic structural reorganization. Our observations challenge the common understanding of fundamental notions such as the nucleation barrier or the meaning of supersaturation, with broad implications for mineralization phenomena in general and the formation of calcium sulfate in geochemical settings and industrial applications in particular.

The Role of Hydrocarbons in the Genesis of Mississippi-Valley-Type (MVT) Zn–Pb Deposits: Insights from In Situ Sulfur Isotopes of Sphalerite from the Southwestern Margin of the Yangtze Block, SW China

The coexistence of numerous Mississippi-Valley-type (MVT) Zn–Pb deposits and (paleo) oil/gas reservoirs in the world suggests a close genetic relationship between mineralization and hydrocarbon accumulation. Xuequ–Shandouya middle MVT Zn–Pb deposits are mainly hosted in the Lower Cambrian Maidiping Member siliceous dolostone on the southwestern margin of the Yangtze Block, accompanied by large amount of bitumen in the orebodies. Therefore, this type of Zn–Pb deposit is a natural laboratory for studying the relationship between the mineralization and the accumulation of paleo-oil/gas reservoirs. The deposit is characterized by spheroidal and concentric banded sphalerite. In situ sulfur isotope studies are carried out to determine the sulfur sources, sulfate reduction mechanisms, and role of hydrocarbons in the zinc–lead mineralization process. According to the mineral paragenesis and relative temporal relationship, two mineralization stages (1 and 2) are identified. An in situ sulfur isotope analysis of spheroidal and concentric banded sphalerite particles from Stage 2 shows that there are the two following types of sulfur isotopes in the sphalerite: one with relatively invariable δ34S values in the core (+8.31 to +9.30‰), and the other with a gradual increase from the core margin (core) to the rim (+0.39 to +16.18‰). These two types reflect that they may have formed in different times, with first type forming in the early period of Stage 2, while the second type was formed in the late period of Stage 2. The sulfur isotopic data suggest the sulfur source of evaporated sulfate minerals and multiple formation mechanisms for reduced sulfur (H2S). In the early period of Stage 2 mineralization, the sulfate reduction mechanism is mainly a mixture of bacterial sulfate reduction (BSR) and/or thermochemical sulfate reduction (TSR), while a very small amount may come from the thermal decomposition of organic compounds (DOCs). In the late period of Stage 2, TSR is dominant, and the gradual increase in the δ34S value may be related to Rayleigh fractionation. The oil/gasreservoir not only acts as a reducing agent to provide the required hydrogen sulfide for zinc–lead mineralization through TSR or BSR, but also provides reduced sulfur for mineralization through the thermal decomposition of organic compounds directly.

Effective selenate removal using pH modulated synthesis of biogenic jarosite: Comparative insight with non-biogenic jarosite and biogenic schwertmannite

Selenium, a crucial trace element for many organisms, including prokaryotes and humans, is toxic at high concentrations, necessitating its removal from wastewater. This study investigates the use of jarosite, a naturally occurring iron sulfate mineral with excellent heavy metal attenuation properties, for selenate (Se(VI)) removal for the first time. Biogenic jarosite was synthesized through Fe(II) oxidation by Acidithiobacillus ferrooxidans at an initial pH ranging from 1.5 to 4.0 (J-1.5 to J-4.0). This resulted in the formation of morphologically diverse particles of biogenic jarosite owing to varying Fe(II) oxidation and precipitation rates. For comparative analysis, non-biogenic jarosite (J-90C) and biogenic schwertmannite (S-2.5) were also synthesized. At 0.2 mM initial Se(VI) concentration, J-2.5 demonstrated superior Se(VI) removal compared to J-3.5 and J-90C. At 2.0 mM Se(VI), J-2.5 still outperformed J-3.5 and J-90C although its overall removal efficiency decreased. Notably, at 0.2 mM concentration, Se(VI) removal by J-2.5 was 63 %, which is comparable to 77 % removal by S-2.5. Furthermore, sulfate release from J-2.5 was significantly lower than that from S-2.5 in both Se-free and Se-containing solutions. This study provides critical insights into the synthesis and application of biogenic jarosite as a replacement for metastable schwertmannite, emphasizing its potential as an excellent Se sink for wastewater treatment.

Industrial by-products (ferrous sulfate minerals and stone powder) can serve as amendments to remediate Cd-As paddy soil, alleviating Cd-As accumulation in rice

Our previous research has shown that industrial by-products such as ferrous sulfate mineral and stone powder as amendments can remediate Cadmium (Cd) and arsenic (As) soil. However, their role in the soil-rice system is unknown. Therefore, this article explored the effects of the combined use of industrial by-products and commercial conditioners on the accumulation of Cd-As in weakly alkaline and acidic soil-rice systems. Potted experiments shown that SL (stone powder+ferrous sulfate mineral) and SLW (stone powder+ferrous sulfate mineral+Weidikang conditioner) could reduce the availability of Cd-As in soil by adjusting soil pH and CEC, increase iron film content on the root surface, strengthening the “barrier” for fixing Cd-As. Brown rice Cd was lower than the national food safety standard of 0.20 mg kg−1 (GB2762–2022). 1 % SLW could reduce brown rice As from 1.24 mg kg−1 to 0.83 mg kg−1. The results of field experiments confirmed the conclusion of pot experiments. SL and SLW not only reduced the accumulation of Cd-As in rice but also significantly increased rice yield by 16.58 % and 11.68 %, respectively. Compared to the two types of conditioning agents sold in the market, the material costs have been reduced by 79.1 % -86.5 % and 12.4 % -43.3 %, respectively. In summary, this study demonstrates that ferrous sulfate minerals and stone powder could efficiently remediate Cd-As pollution in paddy soil under different acid-base conditions, providing an application example for the resource utilization of industrial by-products for the remediation of Cd-As pollution in paddy soil.

A 2‐Billion‐Year History of Water‐Alteration in Terra Sirenum, Mars: Volcanism's Influence on Aluminum Clay Formation and Chemically Distinct Waters Forming Sulfates and Chlorides Into the Amazonian

AbstractTerra Sirenum, a region of Noachian highlands southwest of the Tharsis volcanic complex, is unique in the number, proximity, and diversity of orbital detections of secondary minerals, as the sole region found to date hosting large‐scale deposits of all of Mars' major salts (chlorides, sulfates, carbonates) as well as diverse hydrated silicates. We combine mineralogical information, high‐resolution imagery, and elevation models to investigate the geologic context of these secondary minerals to understand the sources of water and ions for each type of deposit and their spatial/temporal relationships. Carbonates, where present, are part of Noachian basement rocks exposed through cratering and do not appear associated with evaporative sequences. Numerous small detections of the acid sulfate minerals alunite and jarosite mirror the dominant clay cation in the localities they are found—Al phyllosilicates and Fe phyllosilicates, respectively—suggesting in situ formation. We interpret a previously discovered kaolinite‐rich unit overlying Fe/Mg clays across northeast Terra Sirenum as remnants of a widespread ash unit rather than a pedogenic weathering sequence. Sulfate and chloride detections are decoupled, with sulfates in topographic lows likely precipitated from volcanism‐associated groundwaters, while chloride detections are consistent with surface water runoff, in some instances clearly post‐dating volcanic units capping sulfate detections. Volcanic resurfacing of craters in the region is progressively younger from west to east, and crater statistics‐based ages indicate localized sulfate‐ and chloride‐forming processes continue to occur from ∼3.5 to ∼1.4 Ga. We hypothesize that their decoupling points to disconnected, episodic surface and groundwater reservoirs, perhaps separated by a permafrost layer.

Possibility of using industrial by-product combinations to remediate cadmium and arsenic contaminated soil

It is inevitable to produce by-products in industrial and mining production, and how to deal with these by-products has become a major environmental issue. Meanwhile, many studies have shown that applying soil amendments is a feasible measure for effectively controlling soil pollution. Finding low-cost and efficient soil passivators is an effective way to safely utilize polluted soil. This article provides a method of “treating contamination with waste”. Through spinach pot experiments, different proportions and doses of granite powder (A, quarry waste), market purchased conditioner (B), “granite powder+iron sulfate mineral (titanium powder industrial waste)” (C), and “granite powder+iron sulfate mineral+market purchased conditioner” (CB) were used to treat soil co-contaminated with cadmium (Cd) and arsenic (As). The results indicate that amendments affect the available Cd and As in soil by changing soil pH and cation exchange capacity. The amendment of A, B, C, and CB all has remarkable reduction rates of soil available Cd at 65.48 %, 57.02 %, 61.37 %, and 43.15 %, respectively, compared to the control. Both A and B increase the available As content in the soil and the As content in spinach. However, both C and CB reduced the available As content in the soil by 60.32 % and 12.48 %. CB treatment could simultaneously reduce the accumulation of Cd and As in spinach, increase chlorophyll content, and promote spinach growth. It was worth noting that the 3 % CB treatment has the best effect, with Cd and As content in spinach stems and leaves decreasing by 51.13 % - 69.62 % and 35.46 % - 59.53 %, respectively, and the repair cost being as low as 76.5 $ ton−1. Therefore, the combined application of granite powder, market purchased conditioner, and iron sulfate minerals for the remediation of Cd and As co-polluted soil was a cost-effective and environmentally friendly technology. However, applying these soil composite amendments also requires attention to adjusting with the soil type and with pollution type, which we are currently studying.

Production of low-sulphur tailings by hydrocycloning

Acid mine drainage (AMD) is an environmental problem in gold mines containing sulphur minerals. The potential for acid drainage in tailings facilities must be considered when studying their dry closure. Therefore, controlling the sulphur content in the final layer of tailings deposition has the potential to prevent AMD after closure. In this context, the rougher flotation tailings were hydrocycloning in a pilot plant in a gold mining company to assess the potential for generating modified tailings with low-sulphur content. A total of 10 samples were composited over one hour of pilot plant operation. The hydrocyclone overflow showed an average reduction of 36.2% in sulphur content and an average metallurgical recovery of 20.0%. The underflow had an average increase in sulphur content of 16.8% and 80.0% metallurgical recovery. These results demonstrated the possibility of generating modified tailings with reduced sulphur content through hydrocycloning.

Influence of zwitterionic amphiphilic copolymers on heterogeneous gypsum formation: A promising approach for scaling resistance

This study aims to investigate the influence of zwitterionic amphiphilic copolymers (ZACs) in the nucleation and growth of heterogeneous CaSO4 at the zwitterion-water interface, which is crucial for the prevention of mineral scaling and consequent downtime or suboptimal performance in industries like membrane desalination, heat exchangers, and pipeline transportation. In situ grazing incidence small angle X-ray Scattering (GISAXS), and quartz crystal microbalance with dissipation (QCM-D) techniques were used to analyze the evolution of CaSO4 particles on two new ZAC coatings: poly-(trifluoroethyl methacrylate-random-sulfobetaine methacrylate) (PTFEMA-r-SBMA, or PT:SBMA) and poly(trifluoroethyl methacrylate-random-2-methacryloyloxyethyl phosphorylcholine) (PTFEMA-r-MPC, or PT:MPC). The results showed that PT:MPC coatings promoted nucleation but inhibited crystal growth, resulting in slower overall reaction kinetics on PT:MPC coatings compared to PT:SBMA coatings. Interfacial interactions involving the substrates, sulfate minerals, and ions were examined, revealing that calcium ion adsorption, primarily governed by electrostatic attraction, played a crucial role in the nucleation and growth processes on both ZAC coatings. The crystal characterization revealed a phase transition from bassanite to gypsum on both ZAC coatings, suggesting that these zwitterionic materials can influence the mineral phase of heterogeneously formed CaSO4 crystals. These findings enhance our understanding of the fundamental mechanisms underlying heterogeneous CaSO4 scaling in the presence of zwitterionic materials.

Mineral composition of lake Sabakty sediments as an indicator of paleoclimate, Southern Urals, Russia

Relevance. Reconstruction of climatic changes based on the lacustrine sediments of lakes makes it possible to identify climatic trends and events in the late Quaternary. The Urals is considered as one of the climatic divisions, therefore, studies of the conditions of lake sedimentation, including climatic ones, are relevant in this area. Aim. To study mineral composition as an indicator of paleoclimate of Lake Sabakty sediments. Object. Core of Lake Sabakty sediments (length is 298 cm). The age of the core is ~25 thousand years old. Materials and methods. Sampling was carried out taking into account seismoacoustic data, lithological description, as well as measurements of magnetic susceptibility and radiometric dating data. The granulometric analysis was carried out by laser granulometry using a Bluewave particle size analyzer (Microtrac, USA) combined with a sample loading and circulation system with an integrated ultrasonic dispersant. Mineral composition of the sediments was determined using the D2 PHASER X-ray diffractometer and the Merlin auto-emission scanning electron microscope. Results. The predominance of the siltstone fraction was established. The mineral composition is characterized by the predominance of allotigenic minerals in sediments (quartz, microcline, albite, mica, chlorite, mixed-layer clay minerals, hornblende, kaolinite) according to X-ray diffraction and electron microscopy. Autigenic minerals include biogenic silica (cristobalite, tridymite), pyrite, carbonates (calcite, dolomite), sulfates (gypsum, barite). Conclusions. The ratio of allogenic and autogenic components reflects the changes in the accommodation of the reservoir and the supply of clastic material associated with changes in climate humidity. Changes in climate humidity are reflected in changes in the contents of carbonate and sulfate minerals. At the beginning of sedimentation, Lake Sabakty was shallow and mineralized due to climate aridization, which probably included the global Bond 8 event (~26000–11700 BP). The study of the mineral composition of the sediments of Lake Sabakty allowed us to establish the events of climate aridization: ~10000 BP, ~7600 BP, ~6900 BP ~1900 BP and ~1400 BP. In Sabakty Lake, there is a bright episode of a decrease in climate humidity in the range of ~7300-5200 BP, which is marked by an increase in carbonate content up to 70% and the detection of gypsum at ~6900 BP.

Mineralization of phosphorus and sulfur in concentrated organic fertilizer under anaerobic laboratory conditions

Mineralization of phosphorus and sulfur in concentrated organic fertilizer under anaerobic laboratory conditions

Hydrogeochemical characteristics and agricultural suitability of shallow groundwater quality in a concentrated coalfield area of Huaibei Plain, China.

Groundwater is one of the chief water sources for agricultural activities in an aggregation of coal mines surrounded by agricultural areas in the Huaibei Plain. However, there have been few reports on whether mining-affected groundwater can be adopted for agricultural irrigation. We attempted to address this question through collecting 71 shallow groundwater samples from 12 coal mining locations. The Piper trilinear chart, the Gibbs diagram, the proportional coefficient of major ions, and principal component analysis were examined to characterize the source, origin, and formation process of groundwater chemical composition. The suitability for agricultural irrigation was evaluated by a final zonation map that establishes a comprehensive weighting model based on analytic hierarchy process and criteria importance though the intercriteria correlation (AHP-CRITIC). The results revealed that the groundwater was classified as marginally alkaline water with a predominant cation of HCO3- and anion of Na+. Total hardness, total dissolved solids, sulfate (SO42-), sodium (Na+), and fluoride (F-) were the primary ions that exceeded the standard. The results also indicated that the dominant hydrochemical facies were Ca-HCO3 and Na-Cl. The dissolution of carbonate, silicate, sulfate minerals, along with cation exchange, were the main natural drivers controlling the hydrogeochemical process of groundwater. The zonation map suggested that 43.17%, 18.85%, and 37.98% of the study area were high, mediate, and low suitability zones, respectively. These results from this study can support policymakers for better managing groundwater associated with a concentration of underground coal mines.

Comprehending Spatial Distribution and Controlling Mechanisms of Groundwater in Topical Coastal Aquifers of Southern China Based on Hydrochemical Evaluations

Groundwater quality and availability in coastal aquifers have become a serious concern in recent times due to increased abstraction for domestic, agricultural and industrial purposes. (1) Background: Zhuhai city is selected as a representative coastal aquifer in Southern China to comprehensively evaluate the hydrochemical characteristics, spatial distribution and controlling mechanisms of groundwater. (2) Methods: A detailed study utilizing statistical analyses, a Piper diagram, Gibbs plots, and ion ratios was conducted on 114 surface water samples and 211 groundwater samples. (3) Results: The findings indicate that the pH of most groundwater is from 6.06 to 6.52, indicating a weakly acidic environment. The pH of surface water ranges from 5.35 to 9.86, with most values being weakly alkaline. The acidity in the groundwater may be related to the acidic atmospheric precipitation, an acidic unsaturated zone, oxidation of sulphide minerals and tidal action. The groundwater chemical types are predominantly mixed, followed by Ca-Mg-HCO3 type. Surface water samples are predominantly Na-Cl-SO4 type. The NO3− concentration in groundwater is relatively high, with a mean value of 17.46 mg/L. The NO2− and NH4+ concentrations in groundwater are relatively low, with mean values of 0.46 mg/L and 7.58 mg/L. (4) Conclusions: The spatial distribution of the principal chemical constituents in the groundwater is related to the landform. The chemical characteristics of groundwater in the study area are mainly controlled by the weathering and dissolution of silicate and sulfate minerals, evaporation, seawater mixing and cation exchange. Nitrate in clastic fissure groundwater, granite fissure groundwater and unconfined pore groundwater primarily originates from atmospheric precipitation, agricultural activities of slope farmland and forest land. Nitrate in confined pore groundwater and karst groundwater primarily originates from domestic sewage and mariculture wastewater. Our findings elucidate the processes characterizing the hydrogeology and surface water interactions in Zhuhai City’s coastal system, which are relevant to other catchments with similar geological characteristics.

Lotsberg Formation: lithological and geochemical constraints for a prime H2 cavern target in Alberta, Canada

Abstract Homogenous and thick (approximately 40–170 m) halite intervals in the upper part of the Lotsberg Formation are most favored targets for hydrogen (H2) storage caverns in Alberta. However, repurposing cavern-making technologies for H2 storage must consider higher diffusivity and higher reactivity of H2, including its known dissolving effect on sulfate minerals and intense production of H2S through bacterial sulfate reduction. New core observations, geochemical and XRD data made on a continuous core through the upper informal member of the Lotsberg Formation and overlying red beds elucidate high content of anhydrite nodules and partings in these red beds, whereas the thick (42.9 m in our test well), exceptionally clean and homogeneous upper halite in this succession contains anhydrite only in trace amounts. A dolomarl-rich interval at 1894.0–1899.45 m, traced regionally as the L2 marker, represents a solution-collapse breccia, thus indicating an intraformational unconformity and an episode of meteoric salt removal prior to deposition of the upper-most halite of the Lotsberg Formation. If the cavern roof is made close to the overlying anhydritic dolostone of the Ernestina Lake Formation, reactivity of H2 may cause rapid dissolution of anhydrites leading to roof collapse, as well as accumulation of H2S through bacterial sulfate reduction. We infer that preserving a thick salt roof during cavern making may be a solution to prevent these damaging effects. Reactivity of H2 with carbonates in the caprock should also be considered. Anhydrite nodules also occur in the basal one-third of the upper Lotsberg, the interval containing more non-halite impurities than the upper salt unit of this member. In this part of the section, anhydrites do not seem to represent the same concern as they will be exposed to cavern-floor sump and cushion gas, whereas H2 reservoir can be operated within the limits of the clean and homogeneous upper halite of the upper Lotsberg Formation. Emplacement of horizontally elongated two-well caverns may represent an adequate way to overcome cavern size limitations, especially in overlying, thinner-bedded halites of the Prairie Evaporite Formation. Résumé Des intervalles homogènes et épais (d’environ 40 m à 170 m) d’halite dans la partie supérieure de la Formation de Lotsberg sont parmi les plus ciblés pour stocker l’hydrogène (H2) dans des cavités en Alberta. Cependant, adapter les technologies pour créer des cavernes de stockage de H2 doit considérer la diffusivité et la réactivité plus élevées de l’H2, y compris son effet dissolvant connu sur les minéraux sulfatés et son intense production de H2S par la sulfatoréduction bactérienne. De nouvelles observations sur les carottes avec données géochimiques et diffractions de rayon X faites sur une carotte continue à travers le membre supérieur officieux de la Formation de Lotsberg et des lits rouges sus-jacents élucident le contenu élevé de nodules et d’inclusions stériles dans ces lits rouges, tandis que le plan d’halite (de 42,9 m d’épaisseur de notre puits d’essai) de la partie supérieure de cette succession se révèle exceptionnellement propre et homogène et ne contient que des traces d’anhydrite. Un intervalle riche en marne dolomitique dans la partie comprise de 1894,0 m à 1899,45 m est l’horizon marqueur L2 au niveau régional. Celui-ci représente une brèche d’effondrement par dissolution, ce qui indique par conséquent une discordance intraformationnelle et un épisode d’élimination saline par météorisation avant le dépôt d’halite le plus élevé de la Formation de Lotsberg. Si le toit de la cavité est créé près de la dolomie anhydritique sus-jacente de la Formation d’Ernestina Lake, la réactivité de l’H2 pourrait causer une dissolution rapide des anhydrites et entraîner l’effondrement du toit, ainsi qu’à l’accumulation de H2S par la sulfatoréduction bactérienne. Nous supposons que la préservation d’un épais toit salin durant la création de cavités serait la solution pour prévenir ces effets dommageables. Nous devrions également considérer la réactivité de l’H2 avec les carbonates de la roche couverture. De plus, les nodules d’anhydrite se présentent également dans la tierce partie basale de la Formation de Lotsberg, l’intervalle contenant plus d’impuretés non liées à l’halite que l’halite de la partie supérieure de Lotsberg. Dans la partie de cette section, l’anhydrite ne semble pas représenter les mêmes préoccupations puisqu’elle sera exposée au puisard du fond de la cavité et au gaz-coussin, tandis que le réservoir H2 peut être exploité dans les limites de l’halite supérieure propre et homogène de la Formation de Lotsberg supérieure. L’emplacement de cavités à deux puits horizontaux allongés peut représenter un moyen adéquat pour résoudre les limites quant à la grandeur des cavités, en particulier lorsqu’il s’agit de minces lits d’halites sus-jacents de la Formation d’halite des Prairies. Michel Ory ACRONYMY AB Alberta AIHA Alberta’s Industrial Heartland Association CRM Critical Raw Minerals EPG Elk Point Group LNG Liquefied Natural Gas LPG Liquefied Petroleum Gas R&D Research and Development SK Saskatchewan UHS Underground Hydrogen Storage XRD X-ray diffraction WCSB Western Canada Sedimentary Basin

Proximate and Organoleptic Analysis on Campor Lorjuk (Solen sp) seasoning, a typical Madura Ingredient

Abstract Rich mineral sea salt is salt with a low NaCl content. The low NaCl content in salt indicates that the salt has a high mineral content. The minerals contained such as magnesium chloride, magnesium sulfate, calcium chloride, and other minerals. This research combined rich minerals sea salt with typical Madurese food named campor lorjuk seasoning and dried lorjuk as additional nutrition. Lorjuk in Madurese or better known as knife clams is a type of shellfish that has high nutritional value. The treatment applied to the Campor Lorjuk seasoning formulations was the difference in NaCl content for each formula. This research was conducted to determine the proximate content and to find out the seasoning results those consumers like most. The results showed that the highest protein content was in F1 with results of 7.62%, not significantly different from F3 but significantly different from control and F2. The highest water and ash contents were control which was not significantly different from F1, F2, and F3. The highest fat content was F2 and the lowest is control. The highest carbohydrate content is in control formula 68.35%, the lowest is F1 63.66%. The organoleptic test show that the formula that consumers like most is F3.

Calorimetry and structural analysis of uranyl sulfates with rare topologies

Abstract Uranyl sulfate minerals are the most rapidly expanding group of uranium minerals, with dozens of species described in the past decade from the localities of White Canyon, U.S.A. and Jáchymov, Czech Republic. Synthetic analogs of a suite of uranyl sulfate minerals were crystallized, characterized, and the standard-state enthalpies of formation (ΔHfo) were determined. Synthetic lussierite is monoclinic, space group Cc, a = 9.2896, b = 28.685, c = 9.6155 Å, β = 93.504°. Synthetic geschieberite is ortho-rhombic, space group Pna21, a = 13.7408, b = 7.2713, c = 11.5844 Å. The standard-state enthalpies of formation from the binary oxides for lussierite, péligotite, shumwayite, geschieberite, and bluelizardite are –3214 ± 78, –2026 ± 33, –587 ± 22, –966.1 ± 10.9, and –2084 ± 21 kJ/mol, respectively, while the standard-state enthalpies of formation of each phase from its elements are –9743 ± 78, –7220 ± 33, –5255 ± 22, –3916 ± 20, and –7117 ± 21 kJ/mol, respectively. The ΔHfo of péligotite was accurately estimated using the ΔHfo of lussierite, bluelizardite, and literature values of the oxide components of each phase. This implies that estimates can be made accurately of the ΔHfo of uranyl sulfates of minerals without synthetic analogs.

Fabrication of omniphobic PVDF membrane with SiO2–FeOOH hierarchical structures for robust membrane distillation

Omniphobic membrane has been demonstrated as an effective strategy to mitigate membrane wetting and fouling risks in membrane distillation (MD) processes. In this work, novel omniphobic membranes with hierarchical re-entrant surface structure were fabricated. Firstly, the FeOOH nanorods were deposited on the polydopamine (PDA) pre-treated poly (vinylidene fluoride) PVDF membrane. After that, the SiO2 nanoparticles (NPs) were coated on the FeOOH nanorods via electrostatic attraction to form hierarchical structures. Finally, the fluorosilane was utilized to reduce the membrane surface free energy, contributing to PVDF based omniphobic membranes. The effects of reaction time, FeCl3·6H2O and SiO2 NPs concentrations on membrane properties, including membrane surface morphology, average pore size, contact angles (CAs), surface roughness and permeate flux, were investigated in detail. The resulting omniphobic membranes showed high CAs towards various tested liquids, such as 0.4 mM sodium dodecyl sulfate (SDS) solution (143.9 ± 0.8°), hexadecane (113.5 ± 3.2°) and mineral oil (132.5 ± 2.8°). This membrane exhibited outstanding performance in a continuous 50-h vacuum membrane distillation (VMD) process with a 10 wt% NaCl feed solution. Besides, the anti-oil-fouling properties were further assessed with a feed solution containing 200-ppm hexadecane and 3.5-wt% NaCl, the omniphobic membrane exhibited steady permeate flux of above 24.18 kg m−2 h−1 and a 99.99 % rejection rate during 50-h testing. Finally, the omniphobic membrane showed high anti-wetting properties by SDS/salt solution. This work introduces a new strategy for fabricating omniphobic membranes that shows significant potential for treating complex industrial wastewaters.