Sucrose Esters Research Articles

Phenylpropanoids from Sparganium stoloniferum and their antiplatelet aggregation activities

Four new ferulic acid sucrose esters, β-D-(1-O-acetyl-6-O-trans-feruloyl)fructofuranosyl-a-D-2',6'-O-diacetylglucopyranoside (1), β-D-(1-O-acetyl-6-O-trans-feruloyl)fructofuranosyl-a-D-2',4'-O-diacetylglucopyranoside (2), β-D-(6-O-trans-feruloyl)fructofuranosyl-a-D-2',4',6'-O-triacetylglucopyranoside (3), β-D-(1-O-acetyl-6-O-trans-feruloyl)fructofuranosyl-a-D-4',6'-O-diacetylglucopyranoside (4), together with four known phenylpropanoids (5–8) were isolated from the rhizome of Sparganium stoloniferum (Graebn.) Buch.-Ham. ex Juz. Their structures were elucidated by chemical evidence and spectral analysis. Compounds 1–8 exhibited obvious inhibitory effects on ADP-induced platelet aggregation.

Investigation of the Emulsifying and In Vitro Digestive Properties of High-Purity Sucrose Monostearate Esters

Long-chain fatty acid mono- and higher-order esters of sucrose are important chemicals, often produced at kilotonne scales, due to their wide range of commercial applications, including as food emulsifiers. While the monoester content of commercial sucrose stearate ester products range up to 75% (in S-1670), this can be further increased to >99% when enzymatic techniques are deployed for product preparation. Although the emulsifying properties of sucrose stearate ester-containing products (such as S-1670) are well-defined, formulations with monoester contents greater than 75% have never been prepared and evaluated. In this study, three sucrose stearate samples with an 80, 85, or 90% monoester content (samples 1–3, respectively) were prepared and the influence of these on their digestive, emulsifying, and rheological properties was studied. The results show that emulsions stabilized by S-1670 (75%) and sample 1 (80%) exhibited the best digestive behavior in a gastrointestinal behavior model, recording 69 and 78% free fatty acid release, respectively. Counterintuitively, an inverted V-shaped profile was observed when the monoester content, which ranged from 75–99%, was plotted as a function of emulsifying properties. These results should serve as an important guide for the development of new sucrose ester products in the food industry.

Microwave‐assisted low‐cost synthesis of sucrose‐soya ester from vegetable oil refinery by‐product and its application in toothpaste formulation for oral hygiene

AbstractThe major drawbacks of the sucrose ester (SE), in spite of being a green nonionic surfactant, are the difficulty of synthesis and higher cost. Distilled soya acid oil (DSAO) obtained as by‐product from a vegetable oil refinery was used for the synthesis of fatty acid methyl ester (SAFAME). Microwave‐assisted method (680 watts system), which is greener and more efficient was used for the synthesis of SAFAME at 99.3% conversion using 2 wt% sulfuric acid catalyst within 30 min as well as for the synthesis of SE at 82.5% conversion using 5 wt% K2CO3 catalyst within 45 min. Both synthesis steps were monitored and characterized by using thin‐layer chromatography, gas chromatography, 1H NMR, and FT‐IR. The surface tension of 1% aq. solution of SE was 29.58 mN m−1, while the interfacial tension of n‐heptane‐1% aq. solution was observed to be 3.29 mN m−1. The critical micelle concentration was 74.24 mg L−1. Foaming properties, emulsion stability, and wetting power were determined by using standard techniques. The SE was used for the development of desensitizing anticavity toothpaste formulation and the various properties were evaluated in comparison with the commercial toothpaste formulation available in the market. The results show that the partially renewable surfactants like sodium dodecyl sulfate (SDS) and sodium lauryl ether sulfate (SLES) can be replaced partially or fully with the biobased renewable SE surfactants in the various personal care formulations including toothpaste.

Metabolomics combined to chemometrics reveals the putative α-glucosidase and α-amylase inhibitory metabolites of ground cherry (Physalis pruinosa L.)

In this work, metabolic profiling of the different parts of ground cherry (P. pruinosa) including fruits, calyces, leaves, stems and roots using UPLC-MS/MS analysis combined to chemometric analysis was attempted. A total of 82 chromatographic peaks belonging to different metabolite classes were identified including terpenes, flavonoids genin and glycosides, withanolides, physalins, sucrose esters, fatty acids and other miscellaneous compounds with withanolides being the most predominant class. Roots extracts possessed the highest relative content of the identified 5β,6β-epoxy withanolides and intermediate withanolides, while sucrose esters and flavonoidal glycosides were found in a great abundance in calyces extracts. Moreover, physalins were found in all extracts except for roots extracts. Studying the coefficients plots revealed that terpenes and physalins (physanicantriol, loliolide, physalisitin C) were responsible for discrimination of fruits extracts. Calyces, leaves and stems extracts were found to possess antioxidant activity and higher inhibition of α-glucosidase activity. In an attempt to identify the compounds responsible for the hypoglycemic activity using both α-amylase and α-glucosidase inhibition assays, OPLS models coefficient plots were constructed which indicated that physangulide B, physaperuvin G, neophysalin A, and acylsucroses were positively correlated to α-glucosidase inhibition, while guaiacyl-primeveroside, phyperunolide C, physalactone, physalolactone C and perulactone, were positively correlated to α-amylase inhibitory activity.

The Role of Cytokinins and Gibberellins on Post-Harvest Longevity of Florists’ Greens

Florists’ greens are a very important element of floral compositions, and their vase life must match that of the flowers, hence this review presents the results of research that has been conducted over the years in order to improve the post-harvest longevity of species that are grown for florists’ greens using growth regulators from groups of gibberellins (GAs) and cytokinins (CKs). Florists’ greens include foliage, the leafy and non-leafy stems of herbaceous plants, trees, bushes, and phylloclades. The post-harvest longevity of florists’ greens is influenced by genetics. Also strongly affected by the growing conditions and the conditions of the transport of the florists’ greens and the conditions when supplying them to markets are also significant. Moreover, florists’ greens are not supplied with growth regulators, which play a critical role in their ageing process. The CKs and GAs are considered to be inhibitors of ageing; however, unfortunately, their content in plant tissues decreases during the progressive ageing process, while the amount of regulators that accelerate ageing increases. International research is focusing on the use of growth regulators in the post-harvest treatment of florists’ greens. Their effectiveness has been shown to depend on the species, the cultivar, the concentration, and the method of application, therefore, there is no ready-made recipe that can be used for all species. The growth regulators from the CK and GA groups are used to condition the florists’ greens. Few studies to date point to the possibility of using topolines (Ts) and ionic liquids in order to extend the post-harvest longevity of florists’ greens. The standard cut flower medium containing 2% sucrose and hydroxyquinoline esters—sulphate or citrate (8HQS and 8HQC)—at a concentration of 200 mg·dm−3, which is used to conditioning, does not have a positive effect on florists’ greens of most species.

In Vitro and in Silico Analysis of Phytochemicals From Fallopia dentatoalata as Dual Functional Cholinesterase Inhibitors for the Treatment of Alzheimer’s Disease

Current studies have found that butyrylcholinesterase (BuChE) replaces the biological function of acetylcholinesterase (AChE) in the late stage of Alzheimer’s disease. Species in the genus of Fallopia, rich in polyphenols with diverse chemical structures and significant biological activities, are considered as an important resource for screening natural products to against AD. In this study, thirty-four compounds (1–34) were isolated from Fallopia dentatoalata (Fr. Schm.) Holub, and their inhibitory effects against AChE and BuChE were assessed. Compounds of the phenylpropanoid sucrose ester class emerged as the most promising members of the group, with 31–33 displaying moderate AChE inhibition (IC50 values ranging from 30.6 ± 4.7 to 56.0 ± 2.4 µM) and 30–34 showing potential inhibitory effects against BuChE (IC50 values ranging from 2.7 ± 1.7 to 17.1 ± 3.4 µM). Tacrine was used as a positive control (IC50: 126.7 ± 1.1 in AChE and 5.5 ± 1.7 nM in BuChE). Kinetic analysis highlighted compounds 31 and 32 as non-competitive inhibitors of AChE with Ki values of ∼30.0 and ∼34.4 µM, whilst 30–34 were revealed to competitively inhibit BuChE with Ki values ranging from ∼1.8 to ∼17.5 µM. Molecular binding studies demonstrated that 30–34 bound to the catalytic sites of BuChE with negative binding energies. The strong agreement between both in vitro and in silico studies highlights the phenylpropanoid sucrose esters 30–34 as promising candidates for use in future anti-cholinesterase therapeutics against Alzheimer’s disease.

Ibuprofen Nanoemulsion as a Promising Drug Delivery Strategy

Phenyl propionic acid derivative drug Ibuprofen was selected for the study’s model medication. It is hypothesized that nanoemulsion might be a useful medication delivery method for enhancing oral absorption. According to the findings, the nanoemulsion formulation greatly enhanced the drug’s anti-inflammatory capabilities when compared to the Ibuprofen solution. Ibuprofen’s solubility and oral bioavailability are enhanced using nanoemulsion technology. To evaluate and pinpoint nanoemulsion area’s are made of glycerol, olive oil, and various sucrose esters, a pseudo ternary phase diagram was created (co-surfactant). Following the discovery of such a nanoemulsion zone, a colloidal system was created to serve as an ibuprofen carrier system. Droplet size, polydispersity index, zeta potential, and morphological measurements were made to determine the characteristics of the chosen nanoemulsion (NE) area.

QTOF-ESI MS Characterization and Antioxidant Activity of Physalis peruviana L. (Cape Gooseberry) Husks and Fruits from Costa Rica.

There is increasing interest in research of secondary metabolites from Physalis peruviana (Cape gooseberry) because of their potential bioactivities. In this study, the profile of compounds found in fruits and husks from Costa Rica was determined through ultra-performance liquid chromatography coupled with high-resolution mass spectrometry using a quadrupole time-of-flight analyzer (UPLC-ESI-QTOF MS) on extracts (n = 10) obtained through pressurized liquid extraction (PLE) conditions. In total, 66 different compounds were identified, comprising 34 withanolides, 23 sucrose ester derivatives and 9 flavonoids. UPLC-DAD analysis was performed to determine the β-carotene in fruits and to quantify the flavonoids in all 10 samples, with the results showing higher contents in samples from the Dota region (58.6–60.1 μg/g of dry material versus 1.6–2.8 mg/g of dry material). The Folin–Ciocalteau total polyphenolic content (FC) and antioxidant activity using the DPPH method showed better results for the husk extracts, with the ones from the Dota region holding the best values (4.3–5.1 mg GAE/g of dry material versus IC50 = 1.6–2.3 mg of dry material/mL). In addition, a significant negative correlation was found between the RU, FC and DPPH values (r = −0.902, p < 0.05), aligning with previous reports on the role of polyphenols in antioxidant activity. Principal correlation analysis (PCoA) and hierarchical clustering (HC) analysis were performed on HRMS results, and they indicated that the D1 and D2 fruit samples from the Dota region were clustered with husks related to a higher presence of the analyzed metabolites. In turn, principal component analysis (PCA) performed on the flavonoid content and antioxidant activity yielded results indicating that the D1 and D2 husks and fruit samples from the Dota region stood out significantly, showing the highest antioxidant activity. In summation, our findings suggest that P. peruviana husks and fruits from Costa Rica constitute a substrate of interest for further studies on their potential health benefits.

Improvement of whole wheat dough and bread properties by emulsifiers

Whole wheat bread is widely available worldwide, but it is always associated with less desirable dough processibility, small loaf volume, firm and gritty texture, and other distinctive attributes compared to white bread. Emulsifiers are commonly used to improve dough handling and baking quality during bread production. In present study, five emulsifiers (diacetyl tartaric acid esters of mono- and di-glycerides (DATEM), polysorbate 80, sodium stearoyl lactylate (SSL), soy lecithin, and sucrose esters) were added during dough preparation of the whole wheat flour at 0.2%, 0.5%, and 1.0% (flour weight basis). Dough rheological behavior and bread quality attributes, such as specific loaf volume and hardness, were measured. The results showed that DATEM, sucrose esters, and SSL increased the resistance to extension of the dough, whereas soy lecithin and polysorbate 80 increased the extensibility. Soy lecithin and polysorbate 80 were the only emulsifiers that significantly increased loaf volume compared to the control. Adding higher levels (1.0%) of sucrose esters, polysorbate 80, and SSL increased the formation of amylose-lipid complex and mitigate the crumb staling during storage. The results suggested that the emulsifiers could be applied to contribute to optimum functional quality of whole wheat bread.

Formulation of lyotropic liquid crystal emulsion based on natural sucrose ester and its tribological behavior as novel lubricant

The tribological behavior of oil-in-water emulsions formulated with natural lyotropic liquid crystal (LLC) emulsifiers based on natural sucrose ester was studied for the first time. Polarized optical microscopy, synchrotron radiation small-angle X-ray scattering, wide-angle X-ray scattering, and synchrotron radiation infrared microspectroscopy demonstrated that LLC emulsifiers were tightly ordered at the oil—water interface with a distinct nematic texture. The viscosity of emulsion was observed to change over time. Moreover, the zeta potential and laser particle size distribution verified the emulsion’s satisfactory stability. The frictional shearing test proved that the coefficient of friction of the emulsion versus pure oil decreased by 34.2%. The coefficient of friction of the emulsion with liquid crystal decreased 10.1% versus that without liquid crystal. Although liquid crystal emulsion did not exhibit outstanding anti-wear performance compared with pure oil, its wear volume was 29.4% less than the emulsion without liquid crystal. X-ray photoelectron spectroscopy and scanning electron microscope—energy dispersive X-ray spectroscopy (SEM—EDS) proved that the tribo-film of the emulsion with liquid crystal was formed synergistically by the liquid crystal phase with the base oil. The formulation affecting the lubricant quality was further studied by orthogonal experiments. The resulting Stribeck curve behavior suggested that proper composition with a slightly higher viscosity can better reduce friction in both boundary lubrication and mixed lubrication regimes. The lubrication mechanism indicated that the periodically ordered liquid crystal was transported to the sliding asperity in the form of emulsion droplets, which bored the pressure and released the oil to form a tribo-film. This LLC emulsion is environmentally friendly and potentially non-irritant to the skin. Thus, it has promising application prospects as novel water-based and biological lubricants.

A combination of sugar esters and chitosan to promote in vivo wound care

In recent years, researchers are exploring innovative green materials fabricated from renewable natural substances to meet formulation needs. Among them, biopolymers like chitosans and biosurfactants such as sugar fatty acid esters are of potential interest due to their biocompatibility, biodegradability, functionality, and cost-effectiveness. Both classes of biocompounds possess the ability to be efficiently employed in wound dressing to help physiological wound healing, which is a bioprocess involving uncontrolled oxidative damage and inflammation, with an associated high risk of infection.In this work, we synthesized two different sugar esters (i.e., lactose linoleate and lactose linolenate) that, in combination with chitosan and sucrose laurate, were evaluated in vitro for their cytocompatibility, anti-inflammatory, antioxidant, and antibacterial activities and in vivo as wound care agents. Emphasis on Wnt/β-catenin associated machineries was also set. The newly designed lactose esters, sucrose ester, and chitosan possessed sole biological attributes, entailing considerable blending for convenient formulation of wound care products. In particular, the mixture composed of sucrose laurate (200 µM), lactose linoleate (100 µM), and chitosan (1%) assured its superiority in terms of efficient wound healing prospects in vivo together with the restoring of the Wnt/β-catenin signaling pathway, compared with the marketed wound healing product (Healosol®), and single components as well. This innovative combination of biomaterials applied as wound dressing could effectively break new ground in skin wound care.

Sucrose esters from the calyxes of Physalis chenopodifolia

Three new sucrose esters, physachenoses A-C (1–3) and the known withanolide, physachenolide D (4), were isolated from the calyxes of Physalis chenopodifolia Lam. Analysis of the MS, 1D and 2D NMR spectra of the new compounds allowed to determine their structures as 3′-O-dodecanoyl-2,3,4-tri-O-isobutyrylsucrose (1), 3′-O-dodecanoyl-2,4-di-O-isobutyryl-3-O-2-methylbutanoylsucrose (2), and 3′-O-dodecanoyl-2-O-isobutyryl-3-O-2-methylbutanoylsucrose (3).

Effect of hydrophilic–lipophilic balance values of sucrose esters on cornstarch retrogradation

AbstractBackground and objectivesThe relationship between the different hydrophilic–lipophilic balance (HLB) values of sucrose esters and the retardant effect on the cornstarch retrogradation have not been investigated. The present research was aimed to evaluate the effects of the sucrose esters with different HLB values on the retrogradation properties by analyzing the changes in the crystalline structure and water mobility of cornstarch gels after storage.FindingsAll sucrose ester with HLB value (2–15), especially the HLB 15, could retard the long‐term retrogradation of cornstarch gels. After being stored for the same time, the retrograded cornstarch gels containing sucrose ester of HLB 15 had the lowest hardness, relative crystallinity, and R1047/1022. Compared with the additive‐free cornstarch, the hardness, relative crystallinity, and R1047/1022 of cornstarch with sucrose ester of HLB 15 were significantly decreased by 142 g, 8.66%, and 0.41, respectively, after being stored at 4°C for 7 days.ConclusionsSucrose ester with a high HLB value showed a strong retardant effect on the starch retrogradation.Significance and noveltyThese results suggested that sucrose ester with higher HLB value might be a more effective additive in retarding the retrogradation of cornstarch gels.

Natural Products from Physalis alkekengi L. var. franchetii (Mast.) Makino: A Review on Their Structural Analysis, Quality Control, Pharmacology, and Pharmacokinetics.

The calyxes and fruits of Physalis alkekengi L. var. franchetii (Mast.) Makino (P. alkekengi), a medicinal and edible plant, are frequently used as heat-clearing and detoxifying agents in thousands of Chinese medicine prescriptions. For thousands of years in China, they have been widely used in clinical practice to treat throat disease, hepatitis, and bacillary dysentery. This systematic review summarizes their structural analysis, quality control, pharmacology, and pharmacokinetics. Furthermore, the possible development trends and perspectives for future research studies on this medicinal plant are discussed. Relevant information on the calyxes and fruits of P. alkekengi was collected from electronic databases, Chinese herbal classics, and Chinese Pharmacopoeia. Moreover, information was collected from ancient documents in China. The components isolated and identified in P. alkekengi include steroids, flavonoids, phenylpropanoids, alkaloids, nucleosides, terpenoids, megastigmane, aliphatic derivatives, organic acids, coumarins, and sucrose esters. Steroids, particularly physalins and flavonoids, are the major characteristic and bioactive ingredients in P. alkekengi. According to the literature, physalins are synthesized by the mevalonate and 2-C-methyl-d-erythritol-4-phosphate pathways, and flavonoids are synthesized by the phenylpropanoid pathway. Since the chemical components and pharmacological effects of P. alkekengi are complex and varied, there are different standards for the evaluation of its quality and efficacy. In most cases, the analysis was performed using high-performance liquid chromatography coupled with ultraviolet detection. A pharmacological study showed that the crude extracts and isolated compounds from P. alkekengi had extensive in vitro and in vivo biological activities (e.g., anti-inflammatory, anti-tumor, immunosuppressive, antibacterial, anti-leishmanial, anti-asthmatic, anti-diabetic, anti-oxidative, anti-malarial, anti-Alzheimer’s disease, and vasodilatory). Moreover, the relevant anti-inflammatory and anti-tumor mechanisms were elucidated. The reported activities indicate the great pharmacological potential of P. alkekengi. Similarly, studies on the pharmacokinetics of specific compounds will also contribute to the progress of clinical research in this setting.

Targeted Synthesis of 3,3'-, 3,4'- and 3,6'-Phenylpropanoid Sucrose Esters.

In this study, we report on an orthogonal strategy for the precise synthesis of 3,3′-, 3,4′-, and 3,6′-phenylpropanoid sucrose esters (PSEs). The strategy relies on carefully selected protecting groups and deprotecting agents, taking into consideration the reactivity of the four free hydroxyl groups of the key starting material: di-isopropylidene sucrose 2. The synthetic strategy is general, and potentially applies to the preparation of many natural and unnatural PSEs, especially those substituted at 3-, 3′-, 4′- and 6′-positions of PSEs.

An orthogonal approach for the precise synthesis of phenylpropanoid sucrose esters

Phenylpropanoid sucrose esters (PSEs) are plant-derived metabolites that exist widely in medicinal plants and possess important bioactivities.

New, Biocompatible, Chitosan-Gelled Microemulsions Based on Essential Oils and Sucrose Esters as Nanocarriers for Topical Delivery of Fluconazole.

Biocompatible gel microemulsions containing natural origin excipients are promising nanocarrier systems for the safe and effective topical application of hydrophobic drugs, including antifungals. Recently, to improve fluconazole skin permeation, tolerability and therapeutic efficacy, we developed topical biocompatible microemulsions based on cinnamon, oregano or clove essential oil (CIN, ORG or CLV) as the oil phase and sucrose laurate (D1216) or sucrose palmitate (D1616) as surfactants, excipients also possessing intrinsic antifungal activity. To follow up this research, this study aimed to improve the adhesiveness of respective fluconazole microemulsions using chitosan (a biopolymer with intrinsic antifungal activity) as gellator and to evaluate the formulation variables’ effect (composition and concentration of essential oil, sucrose ester structure) on the gel microemulsions’ (MEGELs) properties. All MEGELs were evaluated for drug content, pH, rheological behavior, viscosity, spreadability, in vitro drug release and skin permeation and antifungal activity. The results showed that formulation variables determined distinctive changes in the MEGELs’ properties, which were nevertheless in accordance with official requirements for semisolid preparations. The highest flux and release rate values and large diameters of the fungal growth inhibition zone were produced by formulations MEGEL-FZ-D1616-CIN 10%, MEGEL-FZ-D1216-CIN 10% and MEGEL-FZ-D1616-ORG 10%. In conclusion, these MEGELs were demonstrated to be effective platforms for fluconazole topical delivery.

Identification of Chemical Components of Qi-Fu-Yin and Its Prototype Components and Metabolites in Rat Plasma and Cerebrospinal Fluid via UPLC-Q-TOF-MS

Qi-Fu-Yin, a traditional Chinese medicine formula, has been used to treat Alzheimer's disease (AD, a neurodegenerative disorder) in clinical setting. In this study, the chemical components of Qi-Fu-Yin and its prototype components and metabolites in rat plasma and cerebrospinal fluid, after oral administration, were preliminarily characterized via ultrahigh-performance liquid chromatography coupled with quadrupole time-of-flight tandem mass spectrometry (UPLC-Q-TOF-MS). A total of 180 compounds, including saponins, flavonoids, organic acids, sucrose esters, oligosaccharide esters, phthalides, phenylethanoid glycosides, alkaloids, xanthones, terpene lactones, ionones, and iridoid glycoside, were tentatively characterized. For the first time, 51 prototypical components and 26 metabolites, including saponins, phthalides, flavonoids, sucrose esters, organic acids, alkaloids, ionones, terpene lactones, iridoid glycoside, and their derivatives, have been tentatively identified in the plasma. Furthermore, 10 prototypical components (including butylidenephthalide, butylphthalide, 20(S)-ginsenoside Rh1, 20(R)-ginsenoside Rh1, and zingibroside R1) and 6 metabolites were preliminarily characterized in cerebrospinal fluid. These results were beneficial to the discovery of the active components of Qi-Fu-Yin anti-AD.

Effect of Spontaneous and Water-Based Passivation on Components and Parameters of Ti6Al4V (ELI Grade) Surface Tension and Its Wettability by an Aqueous Solution of Sucrose Ester Surfactants

Solid wettability is especially important for biomaterials and implants in the context of microbial adhesion to their surfaces. This adhesion can be inhibited by changes in biomaterial surface roughness and/or its hydrophilic–hydrophobic balance. The surface hydrophilic–hydrophobic balance can be changed by the specifics of the surface treatment (proper conditions of surface preparation) or adsorption of different substances. From the practical point of view, in systems that include biomaterials and implants, the adsorption of compounds characterized by bacteriostatic or bactericidal properties is especially desirable. Substances that are able to change the surface properties of a given solid as a result of their adsorption and possess at least bacteriostatic properties include sucrose ester surfactants. Thus, in our studies the analysis of a specific surface treatment effect (proper passivation conditions) on a biomaterial alloy’s (Ti6Al4V ELI, Grade 23) properties was performed based on measurements of the contact angles of water, formamide and diiodomethane. In addition, the changes in the studied solid surface’s properties resulting from the sucrose monodecanoate (SMD) and sucrose monolaurate (SML) molecules’ adsorption at the solid–water interface were also analyzed. For the analysis, the values of the contact angles of aqueous solutions of SMD and SML were measured at 293 K, and the surface tensions of the aqueous solutions of studied surfactants measured earlier were tested. From the above-mentioned tests, it was found that water environment significantly influences the components and parameters of Ti6Al4V ELI’s surface tension. It also occurred that the addition of both SMD and SML to water (separately) caused a drop in the water contact angle on Ti6Al4V ELI’s surface. However, the sucrose monolaurate surfactant is characterized by a slightly better tendency towards adsorption at the solid–water interface in the studied system compared to sucrose monodecanoate. Additionally, based on the components and parameters of Ti6Al4V ELI’s surface tension calculated from the proper values of components and parameters of model liquids, it was possible to predict the wettability of Ti6Al4V ELI using the aqueous solutions of SMD and SML at various concentrations in the solution.

The effect of sucrose esters S1570 on partial coalescence and whipping properties

This study investigated the effect of different hydrophilic sucrose ester S1570 concentrations on interfacial properties, emulsion characteristics and whipping properties of whipped cream. S1570 at low concentration range (≤0.10 wt%) can coexist with proteins at the oil/water interface. At high concentration range (>0.10 wt%), S1570 would induce crystals piercing interfacial layers and displace the proteins from the oil/water interface. And higher concentration serum protein can prevent fat droplets from entering the air/water interface. An increase of S1570 level at low concentration range can retard partial coalescence during the whole whipping process, thus causing longer optimum whipping time, higher overrun, lower firmness and stabilities of whipped cream. The increase of S1570 at high concentration range increased shear-induced partial coalescence but retard surface-mediated partial coalescence, which caused higher overrun and shorter optimum whipped time. Furthermore, samples with 0.50 wt% S1570 exhibited higher firmness and stabilities. Correlation analysis evidenced that synergistic and competitive adsorption of proteins and sucrose ester S1570 at oil/water interface account for different influence mechanics of shear-induced partial coalescence and surface-mediated partial coalescence during whipping process.