ABSTRACTTemplate attack, as a classic side‐channel attack method, has attracted extensive attention due to its ease of deployment and small number of hyperparameters. However, traditional template attacks (TA) suffer from high preprocessing complexity and poor performance in certain masked applications. To address these issues, this paper proposes a novel template attack method leveraging a weighted quadruple residual network. Specifically, we improve the quadruple network model by assigning different weights to the negative samples selected by the model, which balances the influence of the samples on the model's feedback. Aiming at the fact that the quadruple network ignores the label characteristics of samples in the side‐channel, the distance metric in the quadruple network model is improved, which can help the model select more suitable samples. The residual network designed in this paper enables the quadruplet network model to reduce feature dimensionality, thereby facilitating more effective analysis attacks in TA. Experimental results demonstrate a notable reduction in leaked traces required by the optimized template attack on the synchronous ASCAD dataset, achieving a 62.5% decrease compared to an advanced template attack scheme. On the AES_HD dataset, the energy trace needed for a successful attack diminishes by 46.5% in comparison to the advanced template attack scheme.