Subpolar Mode Water Research Articles

Interannual Variability of Subpolar Mode Water in the Subpolar North Atlantic

AbstractSubpolar Mode Water (SPMW) is an important water mass originating in the eastern North Atlantic. Its formation, subject to modification through oceanic interior mixing, can directly influence the volume of water contributing to the Atlantic meridional overturning circulation. Utilizing observation‐based data sets spanning from 1993 to 2018, we estimated the formation rates and volume of SPMW within isopycnal layers and examined its temporal variability. Two complementary approaches were used to estimate the formation rate: a thermodynamic approach focusing on the air‐sea interactions and a kinematic approach involving volume transport from the mixed layer to the ocean's interior, including the entrainment/detrainment of the mixed layer itself. This is the first time that thermodynamic and kinematic approaches are applied to observation‐based data in the North Atlantic. Our results suggest a substantial role of diapycnal mixing in diluting the dense waters formed by air‐sea fluxes toward the range of SPMW densities. The study reveals a complex interplay of processes, with entrainment being the primary driver of subduction/obduction rates, while advection contributes to the overall small‐scale dynamics. Variations in the volume and location of SPMW formation are observed from year to year. Notably, when SPMW forms extensively in lighter isopycnal layers, the volume occupied by denser isopycnals decreases and vice versa. We attributed this compensation effect to a propagation signal, where formation in the lightest isopycnal bins influences the formation in denser isopycnal bins with a delay of a few years, emphasizing the circulation's role in shaping the SPMW distribution.

Anthropogenic carbon pathways towards the North Atlantic interior revealed by Argo-O2, neural networks and back-calculations

The subpolar North Atlantic (SPNA) is a region of high anthropogenic CO2 (Cant) storage per unit area. Although the average Cant distribution is well documented in this region, the Cant pathways towards the ocean interior remain largely unresolved. We used observations from three Argo-O2 floats spanning 2013-2018 within the SPNA, combined with existing neural networks and back-calculations, to determine the Cant evolution along the float pathways from a quasi-lagrangian perspective. Our results show that Cant follows a stepwise deepening along its way through the SPNA. The upper subtropical waters have a stratified Cant distribution that homogenizes within the winter mixed layer by Subpolar Mode Water formation in the Iceland Basin. In the Irminger and Labrador Basins, the high-Cant footprint (> 55 μmol kg−1) is mixed down to 1400 and 1800 dbar, respectively, by deep winter convection. As a result, the maximum Cant concentration is diluted (<45 μmol kg−1). Our study highlights the role of water mass transformation as a first-order mechanism for Cant penetration into the ocean. It also demonstrates the potential of Argo-O2 observations, combined with existing methods, to obtain reliable Cant estimates, opening ways to study the oceanic Cant content at high spatio-temporal resolution.

Recent acceleration in global ocean heat accumulation by mode and intermediate waters

The ocean absorbs >90% of anthropogenic heat in the Earth system, moderating global atmospheric warming. However, it remains unclear how this heat uptake is distributed by basin and across water masses. Here we analyze historical and recent observations to show that ocean heat uptake has accelerated dramatically since the 1990s, nearly doubling during 2010–2020 relative to 1990–2000. Of the total ocean heat uptake over the Argo era 2005–2020, about 89% can be found in global mode and intermediate water layers, spanning both hemispheres and both subtropical and subpolar mode waters. Due to anthropogenic warming, there are significant changes in the volume of these water-mass layers as they warm and freshen. After factoring out volumetric changes, the combined warming of these layers accounts for ~76% of global ocean warming. We further decompose these water-mass layers into regional water masses over the subtropical Pacific and Atlantic Oceans and in the Southern Ocean. This shows that regional mode and intermediate waters are responsible for a disproportionate fraction of total heat uptake compared to their volume, with important implications for understanding ongoing ocean warming, sea-level rise, and climate impacts.

Mixing and air–sea buoyancy fluxes set the time-mean overturning circulation in the subpolar North Atlantic and Nordic Seas

Abstract. The overturning streamfunction as measured at the OSNAP (Overturning in the Subpolar North Atlantic Program) mooring array represents the transformation of warm, salty Atlantic Water into cold, fresh North Atlantic Deep Water (NADW). The magnitude of the overturning at the OSNAP array can therefore be linked to the transformation by air–sea buoyancy fluxes and mixing in the region north of the OSNAP array. Here, we estimate these water mass transformations using observational-based, reanalysis-based and model-based datasets. Our results highlight that air–sea fluxes alone cannot account for the time-mean magnitude of the overturning at OSNAP, and therefore a residual mixing-driven transformation is required to explain the difference. A cooling by air–sea heat fluxes and a mixing-driven freshening in the Nordic Seas, Iceland Basin and Irminger Sea precondition the warm, salty Atlantic Water, forming subpolar mode water classes in the subpolar North Atlantic. Mixing in the interior of the Nordic Seas, over the Greenland–Scotland Ridge and along the boundaries of the Irminger Sea and Iceland Basin drive a water mass transformation that leads to the convergence of volume in the water mass classes associated with NADW. Air–sea buoyancy fluxes and mixing therefore play key and complementary roles in setting the magnitude of the overturning within the subpolar North Atlantic and Nordic Seas. This study highlights that, for ocean and climate models to realistically simulate the overturning circulation in the North Atlantic, the small-scale processes that lead to the mixing-driven formation of NADW must be adequately represented within the model's parameterisation scheme.

Observation-based estimates of volume, heat, and freshwater exchanges between the subpolar North Atlantic interior, its boundary currents, and the atmosphere

Abstract. The Atlantic Meridional Overturning Circulation (AMOC) transports heat and salt between the tropical Atlantic and Arctic oceans. The interior of the North Atlantic subpolar gyre (SPG) is responsible for the much of the water mass transformation in the AMOC, and the export of this water to intensified boundary currents is crucial for projecting air–sea interaction onto the strength of the AMOC. However, the magnitude and location of exchange between the SPG and the boundary remains unclear. We present a novel climatology of the SPG boundary using quality-controlled CTD (conductivity–temperature–depth) and Argo hydrography, defining the SPG interior as the oceanic region bounded by 47∘ N and the 1000 m isobath. From this hydrography we find geostrophic flow out of the SPG around much of the boundary with minimal seasonality. The horizontal density gradient is reversed around western Greenland, where the geostrophic flow is into the SPG. Surface Ekman forcing drives net flow out of the SPG in all seasons with pronounced seasonality, varying between 2.45 ± 0.73 Sv in the summer and 7.70 ± 2.90 Sv in the winter. We estimate heat advected into the SPG to be between 0.14 ± 0.05 PW in the winter and 0.23 ± 0.05 PW in the spring, and freshwater advected out of the SPG to be between 0.07 ± 0.02 Sv in the summer and 0.15 ± 0.02 Sv in the autumn. These estimates approximately balance the surface heat and freshwater fluxes over the SPG domain. Overturning in the SPG varies seasonally, with a minimum of 6.20 ± 1.40 Sv in the autumn and a maximum of 10.17 ± 1.91 Sv in the spring, with surface Ekman the most likely mediator of this variability. The density of maximum overturning is at 27.30 kg m−3, with a second, smaller maximum at 27.54 kg m−3. Upper waters (σ0&lt;27.30 kg m−3) are transformed in the interior then exported as either intermediate water (27.30–27.54 kg m−3) in the North Atlantic Current (NAC) or as dense water (σ0&gt;27.54 kg m−3) exiting to the south. Our results support the present consensus that the formation and pre-conditioning of Subpolar Mode Water in the north-eastern Atlantic is a key determinant of AMOC strength.

Deep ocean prokaryotes and fluorescent dissolved organic matter reflect the history of the water masses across the Atlantic Ocean

Organic matter is known to influence community composition and metabolism of marine prokaryotes. However, few studies have addressed this linkage in the deep ocean. We studied the relationship between fluorescent dissolved organic matter and prokaryotic community composition in meso- and bathypelagic water masses along a surface productivity gradient crossing the subtropical and tropical Atlantic Ocean. Four fluorescence components were identified, three humic-like and one protein-like. The distributions of the humic-like components were significantly explained by water mass mixing, apparent oxygen utilisation (AOU) and epipelagic productivity proxies in varying degrees, while the protein-like component was explained only by water mass mixing and epipelagic productivity. The diversity and taxonomic composition of the prokaryotic community differed between water masses: the Nitrosopumilales order dominated in water masses with high AOU and humic-like fluorescence (notably, the SubPolar Mode Water), and tended to co-occur with Marine Group II archaea, the SAR324 clade and Thiomicrospirales, while bathypelagic water masses displayed greater abundances of members of Marinimicrobia, SAR202 and SAR324. Water mass mixing regression models suggested that the distribution of some taxa (e.g., Marinimicrobia, SAR202) was dominated by mixing and selection within the water masses during ageing, while others (chiefly, Alteromonadales) were mostly influenced by local processes. Our results suggest a link between the composition of the prokaryotic community, oxygen utilisation and the signal of fluorescent dissolved organic matter, and has implications for our understanding of the processes that shape carbon cycling and prokaryotic communities in the deep ocean.

Dissolved and suspended organic matter dynamics in the Cape Verde Frontal Zone (NW Africa)

The Cape Verde Frontal Zone (CVFZ) is a highly dynamic region located in the southern boundary of the Canary Current Eastern Boundary Upwelling Ecosystem. Due to the interaction of the Cape Verde Front with the Mauritanian coastal upwelling, the area features large vertical and horizontal export fluxes of organic matter. While the flux, composition and biogeochemical role of sinking organic matter have been thoroughly studied, much less attention has been paid to the dissolved (DOM) and suspended particulate (POM) organic matter fractions. Full-depth profiles of DOM and POM were recorded during an oceanographic cruise in the CVFZ, with four consecutive transects defining a box embracing the giant filament of Cape Blanc and the Cape Verde front. The distributions of DOM and POM and their C:N stoichiometric ratios in the epipelagic layer were strongly influenced by the position of the transects relative to the giant filament and the front. Geographical heterogeneity in POM and DOM distributions and elemental composition was also observed within each of the different water masses of contrasting origin present in the area (North and South Atlantic Central Water, Subpolar Mode Water, Mediterranean Water, Antarctic Intermediate Water, Labrador Sea Water and North East Atlantic Deep Water). These facts suggest that water masses properties are re-shaped by biogeochemical processes occurring within the CVFZ. Nevertheless, our analysis indicates that DOM and POM mineralisation represents only 8.1% of the inorganic carbon and 17.8% of the inorganic nitrogen produced by the local mineralisation of organic matter. Intense lateral export of POM and DOM out of the boundaries of the CVFZ is the likely reason behind these low contributions, which confirm the prominent role of sinking fluxes of organic matter for mineralisation processes in this region. The DOM distribution in the CVFZ interior is apparently affected by the dissolution of fast sinking particles.

Role of air–sea fluxes and ocean surface density in the production of deep waters in the eastern subpolar gyre of the North Atlantic

Abstract. Wintertime convection in the North Atlantic Ocean is a key component of the global climate as it produces dense waters at high latitudes that flow equatorward as part of the Atlantic Meridional Overturning Circulation (AMOC). Recent work has highlighted the dominant role of the Irminger and Iceland basins in the production of North Atlantic Deep Water. Dense water formation in these basins is mainly explained by buoyancy forcing that transforms surface waters to the deep waters of the AMOC lower limb. Air–sea fluxes and the ocean surface density field are both key determinants of the buoyancy-driven transformation. We analyze these contributions to the transformation in order to better understand the connection between atmospheric forcing and the densification of surface water. More precisely, we study the impact of air–sea fluxes and the ocean surface density field on the transformation of subpolar mode water (SPMW) in the Iceland Basin, a water mass that “pre-conditions” dense water formation downstream. Analyses using 40 years of observations (1980–2019) reveal that the variance in SPMW transformation is mainly influenced by the variance in density at the ocean surface. This surface density is set by a combination of advection, wind-driven upwelling and surface fluxes. Our study shows that the latter explains ∼ 30 % of the variance in outcrop area as expressed by the surface area between the outcropped SPMW isopycnals. The key role of the surface density in SPMW transformation partly explains the unusually large SPMW transformation in winter 2014–2015 over the Iceland Basin.

Cold-water corals in the Subpolar North Atlantic Ocean exposed to aragonite undersaturation if the 2 °C global warming target is not met

The net uptake of carbon dioxide (CO 2 ) from the atmosphere is changing the ocean's chemical state. Such changes, commonly known as ocean acidification, include a reduction in pH and the carbonate ion concentration ([CO 3 2− ]), which in turn lowers oceanic saturation states (Ω) for calcium carbonate (CaCO 3 ) minerals. The Ω values for aragonite (Ω aragonite ; one of the main CaCO 3 minerals formed by marine calcifying organisms) influence the calcification rate and geographic distribution of cold-water corals (CWCs), important for biodiversity. Here, high-quality measurements, collected on thirteen cruises along the same track during 1991–2018, are used to determine the long-term changes in Ω aragonite in the Irminger and Iceland Basins of the North Atlantic Ocean, providing the first trends of Ω aragonite in the deep waters of these basins. The entire water column of both basins showed significant negative Ω aragonite trends between −0.0014 ± 0.0002 and −0.0052 ± 0.0007 per year. The decrease in Ω aragonite in the intermediate waters, where nearly half of the CWC reefs of the study region are located, caused the Ω aragonite isolines to rapidly migrate upwards at a rate between 6 and 34 m per year. The main driver of the decline in Ω aragonite in the Irminger and Iceland Basins was the increase in anthropogenic CO 2 . But this was partially offset by increases in salinity (in Subpolar Mode Water), enhanced ventilation (in upper Labrador Sea Water), and increases in alkalinity (in classical Labrador Sea Water, cLSW; and overflow waters). We also found that water mass aging reinforced the Ω aragonite decrease in cLSW. Based on these Ω aragonite trends over the last three decades, we project that the entire water column of the Irminger and Iceland Basins will likely be undersaturated for aragonite when in equilibrium with an atmospheric mole fraction of CO 2 (xCO 2 ) of ~880 ppmv, corresponding to climate model projections for the end of the century based on the highest CO 2 emission scenarios. However, intermediate waters will likely be aragonite undersaturated when in equilibrium with an atmospheric xCO 2 exceeding ~630 ppmv, an xCO 2 level slightly above that corresponding to 2 °C global warming, thus exposing CWCs inhabiting the intermediate waters to undersaturation for aragonite. • Aragonite saturation state significantly decreased for 1991–2018. • Anthropogenic CO 2 uptake is the main driver for the observed decrease. • At cold-water corals (CWC) depths, the aragonite isolines shoaled at 6–34 m yr −1 . • Projection of future change in aragonite saturation state based on observed change. • CWC reefs exposed to undersaturation at atmospheric CO 2 levels causing 2 °C warming.

A multi-decadal record of oceanographic changes of the past ~165 years (1850-2015 AD) from Northwest of Iceland.

Extending oceanographic data beyond the instrumental period is highly needed to better characterize and understand multi-decadal to centennial natural ocean variability. Here, a stable isotope record at unprecedented temporal resolution (1 to 2 years) from a new marine core retrieved off western North Iceland is presented. We aim to better constrain the variability of subsurface, Atlantic-derived Subpolar Mode Water (SPMW), using near surface-dwelling planktic foraminifera and Arctic Intermediate Water (AIW) mass changes using benthic foraminifera over the last ~165 years. The reconstruction overlaps in time with instrumental observations and a direct comparison reveals that the δ18O record of Neogloboquadrina pachyderma is reliably representing temperature fluctuations in the SPMWs. Trends in the N. pachyderma δ13C record match the measured phosphate concentration in the upper 200 m on the North Icelandic Shelf well. Near surface-dwelling foraminifera trace anthropogenic CO2 in the Iceland Sea by ~ 1950 ± 8, however, a reduced amplitude shift in the Marine Suess effect is identified. We argue that this is caused by a contemporary ongoing increase in marine primary productivity in the upper ocean due to enhanced Greenland’s freshwater discharge that has contributed to a nutrient-driven fertilization since the 1940s/50s (Perner et al., 2019). Multi-decadal variability is detected. We find that the 16-year periodicity evident in SPMW and AIWs based on the δ18O of N. pachyderma and M. barleeanum is a signal of SST anomalies propagated into the Nordic Seas via the Atlantic inflow branches around Iceland. Spectral analyses of the planktic foraminiferal δ13C signal indicate intermittent 30-year cycles that are likely reflecting the ocean response to atmospheric variability, presumably the East Atlantic Pattern. A long-term trend in benthic δ18O suggests that Atlantic-derived waters are expanding their core within the water column from the subsurface into deeper intermediate depths towards the present day. This is a result of increased transport by the North Icelandic Irminger Current to the North Iceland Shelf over the historical era.

An Updated View on Water Masses on the pan‐West Greenland Continental Shelf and Their Link to Proglacial Fjords

AbstractThe accelerated melt of the Greenland Ice Sheet has been linked to a sudden increase in the presence of warm subsurface coastal water in west Greenland. Yet pathways of warm coastal water along the entire west Greenland coast have remained largely unstudied. Here we present the first, near‐synoptic hydrographic observations at both the continental slope and fjord entrances of the west Greenland coastal system from Cape Farewell (59°N) to Melville Bay (75°N) in summer 2016. We observed a distinct north‐south division in the water mass distribution in west Greenland, approximately partitioned by the northern part of Davis Strait, and a division between the continental slope and fjord entrances. Waters from the regional southern freshwater source with origin in the East Greenland Current that rounds Cape Farewell are not observed to enter Baffin Bay. The regional heat source transported by the West Greenland Current is blocked by Southwest Greenland Coastal Water in the south but the deep connections in the north allow warm deep Subpolar Mode Water to enter fjords. Furthermore, we observed cold and relative saline Baffin Bay Polar Water over the inner part of the banks, periodically reaching as far south as 64°N, suggesting the presence of an undescribed southward current at the Southwest Greenland continental shelf.

The Vertical Structure of Open-Ocean Submesoscale Variability during a Full Seasonal Cycle

AbstractSubmesoscale dynamics are typically intensified at boundaries and assumed to weaken below the mixed layer in the open ocean. Here, we assess both the seasonality and the vertical distribution of submesoscale motions in an open-ocean region of the northeast Atlantic. Second-order structure functions, or variance in properties separated by distance, are calculated from submesoscale-resolving ocean glider and mooring observations, as well as a 1/48° numerical ocean model. This dataset combines a temporal coverage that extends through a full seasonal cycle, a horizontal resolution that captures spatial scales as small as 1 km, and vertical sampling that provides near-continuous coverage over the upper 1000 m. While kinetic and potential energies undergo a seasonal cycle, being largest during the winter, structure function slopes, influenced by dynamical characteristics, do not exhibit a strong seasonality. Furthermore, structure function slopes show weak vertical variations; there is not a strong change in properties across the base of the mixed layer. Additionally, we compare the observations to output from a high-resolution numerical model. The model does not represent variability associated with superinertial motions and does not capture an observed reduction in submesoscale kinetic energy that occurs throughout the water column in spring. Overall, these results suggest that the transfer of mixed layer submesoscale variability down to depths below the traditionally defined mixed layer is important throughout the weakly stratified subpolar mode waters.

Subtropical Mode Water and Permanent Pycnocline Properties in the World Ocean

AbstractA global reference state of the subtropical mode water and permanent pycnocline properties for the 2000–2015 period is presented. The climatology is obtained from a pattern recognition algorithm applied to stratification profiles from the Argo global array. The stratification features are identified as permanent upper ocean pycnostad and pycnocline even when the seasonal pycnocline is developed. The climatology shows that both Northern Hemisphere subtropical gyres have a qualitatively very similar stratification structure. The permanent pycnoclines in the North Atlantic and North Pacific show two deep centers colocated with thick subtropical and subpolar mode waters. These centers coincide with modes in the density and stratification space. These deep pycnocline centers are separated by a region with a shallower and thinner permanent pycnocline that is located downstream of Western Boundary Current Extensions and upstream of Eastern Subtropical Fronts. This feature creates a remarkable double‐bowl pattern at the basin scale. In the subtropical gyres of the South Atlantic and South Pacific Oceans, the mode water and permanent pycnocline structures are characterized by two modes in the density and stratification space that, unlike in the Northern Hemisphere, do not necessarily correspond to deep and thick permanent pycnocline regions. In the subtropical gyre of the South Indian Ocean, a single mode is found to correspond to a single center in the western part of the gyre. This study also shows that away from these deep centers where the pycnocline depth almost follows isopycnals, the permanent pycnocline experiences significant thermohaline gradients that are not density compensated.

Limited influence of basalt weathering inputs on the seawater neodymium isotope composition of the northern Iceland Basin

Radiogenic neodymium (Nd) isotopes have been widely used as a proxy for tracing present and past water masses and ocean circulation, yet relatively few data exist for seawater from the important deep water formation area around Iceland. We have analyzed the dissolved seawater Nd isotope compositions (expressed as ƐNd) of 71 seawater samples, as well as Nd concentrations [Nd] of 38 seawater samples, collected at full water column profiles from 18 stations in the shelf area off the southern coast of Iceland. The goal of this work was to determine to what extent weathering inputs from Icelandic basalts, which are characterized by a distinctly radiogenic ƐNd signature within the North Atlantic, contribute to the Nd isotope and concentration signatures of water masses in the northern Iceland Basin.Radiogenic ƐNd values of up to −3.5 and elevated concentrations of up to 21 pmol/kg compared to nearby open ocean sites were found in surface waters at shallow sites closest to shore and to river mouths of Iceland. This documents partial dissolution of highly radiogenic basaltic particles, which are transported northwards by the coastal currents. A comparable signal is not observed, however, in offshore surface waters likely as a result of the advection of surface currents mainly directed onshore, thus isolating these sites from Icelandic weathering contributions. The dominance of Subpolar Mode Waters and Intermediate Water unaffected by Icelandic contributions in the offshore study area is supported by unradiogenic ƐNd signatures between −15 and −12.In agreement with hydrographic data, highly radiogenic bottom waters at one site on the Iceland-Faroe Ridge (ƐNd = −7.5) reveal the presence of almost pure Iceland Scotland Overflow Water (ISOW) near its formation site further to the east. In bottom waters of all deeper offshore sites, the combination of depleted Nd concentrations and similar ƐNd values (averaging at ≃−11.75 for the R/V Poseidon data and ≃−11 for the R/V Thalassa data) confirms the rapid entrainment of Atlantic mid-depth and deep waters into the overflow waters, which is accompanied by near bottom Nd removal via particle scavenging. Overall, our findings demonstrate that at present, apart from the radiogenic isotope signature of ISOW itself, the direct contribution of radiogenic Nd originating from weathering of Iceland basalts to the water column of the Iceland Basin is limited. This supports the reliable application of ƐNd values to trace changes in the mixing of open North Atlantic water masses (including ISOW).This article is part of a special issue entitled: “Cycles of trace elements and isotopes in the ocean – GEOTRACES and beyond” - edited by Tim M. Conway, Tristan Horner, Yves Plancherel, and Aridane G. González.

First Direct Estimates of Volume and Water Mass Transports Across the Reykjanes Ridge

AbstractThe Reykjanes Ridge is a major topographic feature located south of Iceland in the North Atlantic Ocean that strongly influences the subpolar gyre circulation. Based on velocity and hydrographic measurements carried out along the crest of the Reykjanes Ridge from the Icelandic continental shelf to 50°N during the RREX cruise in June–July 2015, we derived the first direct estimates of volume and water mass transports over the Reykjanes Ridge. North of 53.15°N, circulation was mainly westward; south of this latitude it was mainly eastward. The westward transport was estimated at 21.9 ± 2.5 Sv (Sv = 106 m3 s−1) and represents the subpolar gyre intensity. The westward flows followed two main pathways at 57°N near the Bight Fracture Zone and at 59–62°N. We argue that those pathways were connected to the northern branch of the North Atlantic Current and to the Sub‐Arctic Front, respectively, which were both intersected by the southern part of the section. In addition to this horizontal circulation, mixing and bathymetry shaped the water mass distribution. Water mass transformations in the Iceland Basin lead to the formation of weakly stratified Subpolar Mode Water. We explain why Subpolar Mode Water, the main water mass contributing to the westward flow, was denser at 57°N than at 59–62°N. At higher densities, both Intermediate Water and Icelandic Slope Water contributed more to the westward transport across the Reykjanes Ridge than the sum of Labrador Sea Water and Iceland‐Scotland Overflow Water.

Structure and Formation of Anticyclonic Eddies in the Iceland Basin

AbstractThe Iceland Basin has the most energetic eddy activities in the subpolar North Atlantic. This study documents the structure for an anticyclonic eddy in the Iceland Basin using high‐resolution hydrographic and velocity observations. The eddy core waters have lens‐like structure with warm and salty features in the upper 1,000 m. The eddy distorts the density surface by doming the upper isopycnals and deepening the ones near the permanent pycnocline. The eddy has a diameter of about 120 km with substantial barotropic component in the velocity profiles. One branch of the North Atlantic Current in the central Iceland Basin is superimposed onto the eddy, leading to asymmetric velocity structure. Satellite maps show that eddy first shows up over the western slope of the Hatton Bank and moves westward to the central Iceland Basin. The waters enclosed in the eddy core share the same properties with Subpolar Mode Waters. Similar anticyclonic eddies are also found in high‐resolution numerical model simulations, which is used to explore eddy formation. The model results reveal that the potential vorticity gradient prior to the eddy event change signs in both horizontal and vertical directions. This potential vorticity gradient structure meets the necessary condition for the barotropic and baroclinic instabilities. Further calculation of the energy conversions suggests that eddies extract mean potential energy from the large‐scale isopycnal slope and gain the mean kinetic energy in the upper ocean. Therefore, both barotropic and baroclinic instabilities are involved to support the eddy growth.

Fe(II) oxidation kinetics in the North Atlantic along the 59.5° N during 2016

The Fe(II) oxidation rate was studied in different water masses present in the subarctic North Atlantic ocean along the 59.5° N transatlantic section. Temperature, pH, salinity and total organic carbon (TOC) in natural conditions, fixed temperature conditions and both fixed temperature and pH conditions, were considered in order to understand the combined effects of the variables that control the Fe(II) oxidation kinetics in the ocean. The study shows that in natural conditions, temperature was the master variable which controlled 75% of the pseudo-first order kinetics rate (k′). This value rose to 90% when pHF (free scale) and salinity were also considered. At a fixed temperature, 72% of k′ was controlled by pH and at both fixed temperature and pH, salinity controled 62% of the Fe(II) oxidation rate. Sources and characteristics of TOC are important factors influencing the oxidation of Fe(II). The organic matter had both positive and negative effects on Fe(II) oxidation. In surface and coastal waters, TOC accelerated k′, decreasing the Fe(II) half-life time (t1/2). In Subpolar Mode Water, Labrador Sea Water (for the Irminger Basin) and Denmark Straight Overflow Water, TOC slowed down k′, increasing Fe(II) t1/2. This shifting behaviour where TOC affects Fe(II) oxidation depending on its marine or terrestrial origin, depth and remineralization stage proves that TOC cannot be used as a variable in an equation describing k′. The temperature dependence study indicated that the energy requirement for Fe(II) oxidation in surface waters was 32% lower than the required for bottom waters at both pH 7.7 and 8.0. This variability confirmed the importance of the organic matter composition of the selected samples. The Fe(II) oxidation rate constants in the region can be obtained from an empirical equation considering the natural conditions of temperature, pHF and salinity for the area, producing an error of estimation of 0.0072 min−1. This equation should be incorporated in global Fe models.

Water mass distributions and transports for the 2014 GEOVIDE cruise in the North Atlantic

Abstract. We present the distribution of water masses along the GEOTRACES-GA01 section during the GEOVIDE cruise, which crossed the subpolar North Atlantic Ocean and the Labrador Sea in the summer of 2014. The water mass structure resulting from an extended optimum multiparameter (eOMP) analysis provides the framework for interpreting the observed distributions of trace elements and their isotopes. Central Waters and Subpolar Mode Waters (SPMW) dominated the upper part of the GEOTRACES-GA01 section. At intermediate depths, the dominant water mass was Labrador Sea Water, while the deep parts of the section were filled by Iceland–Scotland Overflow Water (ISOW) and North-East Atlantic Deep Water. We also evaluate the water mass volume transports across the 2014 OVIDE line (Portugal to Greenland section) by combining the water mass fractions resulting from the eOMP analysis with the absolute geostrophic velocity field estimated through a box inverse model. This allowed us to assess the relative contribution of each water mass to the transport across the section. Finally, we discuss the changes in the distribution and transport of water masses between the 2014 OVIDE line and the 2002–2010 mean state. At the upper and intermediate water levels, colder end-members of the water masses replaced the warmer ones in 2014 with respect to 2002–2010, in agreement with the long-term cooling of the North Atlantic Subpolar Gyre that started in the mid-2000s. Below 2000 dbar, ISOW increased its contribution in 2014 with respect to 2002–2010, with the increase being consistent with other estimates of ISOW transports along 58–59° N. We also observed an increase in SPMW in the East Greenland Irminger Current in 2014 with respect to 2002–2010, which supports the recent deep convection events in the Irminger Sea. From the assessment of the relative water mass contribution to the Atlantic Meridional Overturning Circulation (AMOC) across the OVIDE line, we conclude that the larger AMOC intensity in 2014 compared to the 2002–2010 mean was related to both the increase in the northward transport of Central Waters in the AMOC upper limb and to the increase in the southward flow of Irminger Basin SPMW and ISOW in the AMOC lower limb.

Biological and Climate Controls on North Atlantic Marine Carbon Dynamics Over the Last Millennium: Insights From an Absolutely Dated Shell‐Based Record From the North Icelandic Shelf

AbstractGiven the rapid increase in atmospheric carbon dioxide concentrations (pCO2) over the industrial era, there is a pressing need to construct long‐term records of natural carbon cycling prior to this perturbation and to develop a more robust understanding of the role the oceans play in the sequestration of atmospheric carbon. Here we reconstruct the past biological and climate controls on the carbon isotopic (δ13Cshell) composition of the North Icelandic shelf waters over the last millennium, derived from the shells of the long‐lived marine bivalve mollusk Arctica islandica. Variability in the annually resolved δ13Cshell record is dominated by multidecadal variability with a negative trend (−0.003 ± 0.002‰ yr−1) over the industrial era (1800–2000 Common Era). This trend is consistent with the marine Suess effect brought about by the sequestration of isotopically light carbon (δ13C of CO2) derived from the burning of fossil fuels. Comparison of the δ13Cshell record with Contemporaneous proxy archives, over the last millennium, and instrumental data over the twentieth century, highlights that both biological (primary production) and physical environmental factors, such as relative shifts in the proportion of Subpolar Mode Waters and Arctic Intermediate Waters entrained onto the North Icelandic shelf, atmospheric circulation patterns associated with the winter North Atlantic Oscillation, and sea surface temperature and salinity of the subpolar gyre, are the likely mechanisms that contribute to natural variations in seawater δ13C variability on the North Icelandic shelf. Contrasting δ13C fractionation processes associated with these biological and physical mechanisms likely cause the attenuated marine Suess effect signal at this locality.

Subpolar mode water classes in the northeast Atlantic: Interannual and long-term variability

We distinguish the classes of Subpolar Mode Waters (SPMWs), calculate their long-term characteristics, and analyze their interannual and long-term variability based on data from the transatlantic section along 59.5° N measured in 2002–2016. The branches of the North Atlantic Current are horizontal boundaries of the SPMW classes. Modern cooling and freshening of SPMW cores are revealed due to the increased winter atmospheric circulation over the North Atlantic and decline of the Arctic ice cover. In 2010–2016, the potential temperature of the SPMW core in the Iceland Basin dropped by 2.12°C, while its salinity decreased by 0.23 psu.