In this paper, the influence of the silicon (Si) content on microstructure and impact property of submerged arc weld metals (WMs) for weathering bridge steel was clarified. Actual submerged arc welding (SAW) was carried out to produce WMs with 0.18 wt.%, 0.36 wt.%, 0.51 wt.%, and 0.60 wt.% of Si. The low temperature impact property of weld metal was detected, and the weld microstructures were characterized by optical microscopy (OM), scanning and transmission electron microscope (SEM and TEM), and electron backscatter diffraction (EBSD). The results indicate that WMs consist of polygon ferrite (PF), acicular ferrite (AF), granular bainitic ferrite (GBF), and martensite/austenite (M/A) constituents in each Si content. With increasing Si, the proportion of PF increased, while AF and GBF coarsened, the area fraction, fM/A, and the mean size, dM/A, of M/A constituents increased, the number of inclusions decreased, but the size increased. Further, the fraction of high-angle grain boundaries (HAGBs) with the misorientation tolerance angles (MTAs) greater than 15° reduced, while the mean equivalent diameter, MEDMTA≥15°, of ferrite grains with HAGBs increased. Accordingly, the impact toughness of WM was degraded from 108.1 J to 39.4 J with the increase in Si. The increase in M/A constituents and inclusions size reduced the critical fracture stress, thereby formation of larger microcracks and cleavage planes occurred. The reduced HAGBs exhibited a low hindering effect on crack propagation, and, consequently, the impact toughness decreased with increasing Si content.
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