Submerged Anaerobic Membrane Bioreactor Research Articles

Investigating effective strategies for sustainable operation of a submerged anaerobic membrane bioreactor (SAnMBR) coupled with ceramic ultrafiltration membrane

This study presents a mechanistic approach to explore the key operational parameters governing the flux performance of an SAnMBR system coupled with a ceramic flat-sheet ultrafiltration membrane. Experiments were conducted at mixed liquor suspended solid (MLSS) concentrations of 12, 18, and 24 g/L using biogas sparging, backwashing, and a combination of both to investigate the most effective fouling mitigation strategy by exploring the fouling mechanism at a critical flux regime. To validate the experimental findings, a mathematical model was used to simulate the time-based variation of membrane effective pore radius (m), decrease in membrane porosity (%), thickness of cake layer (m), and membrane resistance (1/m). The study found that at a low biomass concentration, there was a sharp decline in the membrane pore radius leading to an increase in membrane resistance in the absence of any fouling mitigation strategies. However, by implementing these strategies individually and in combination, they maintained a higher pore radius and controlled the increase in membrane resistance even at high biomass concentrations. It was observed that biogas sparging outperformed the conventional backwashing strategy and the SAnMBR system exhibited superior performance attaining higher flux rates for prolonged duration. The advanced spectroscopic analysis confirmed the presence of a higher concentration of polysaccharides responsible for cake layer biofouling, and significant pore blocking due to inorganic foulants at high biomass concentrations. This suggests that the SAnMBR system must be operated at optimised biomass levels below the critical flux for sustained operation. Additionally, the key operational parameters identified using the mathematical model provide a precise assessment of SAnMBR performance, to improve its design efficiency for field applications.

Treatment and recovery of phosphate from submerged anaerobic membrane bioreactor effluent using thermally treated biowaste and powder activated carbon

This study presents a novel treatment system using a submerged anaerobic membrane bioreactor (SAnMBR) followed by adsorption onto thermally treated biowaste, and ending with a final treatment using powdered activated carbon (PAC). Despite limited phosphate and ammonium ion removal during SAnMBR operation, thermally treated eggshell (EGSL) and seagrass (SG) received SAnMBR effluent and enhanced phosphate recovery, achieving removal rates of 71.8–99.9% and 60.5–78.0%, respectively. The SAnMBR achieved an 85% COD removal, which was slightly reduced further by biowaste treatment. However, significant further reductions in COD to 20.2 ± 5.2 mg/L for EGSL effluent and 57.0 ± 13.3 mg/L for SG effluent were achieved with PAC. Phytotoxicity tests showed the SAnMBR effluent after PAC treatment notably improved seed growth compared to untreated wastewater. In addition, volatile organic compounds (VOCs) were significantly reduced in the system, including common wastewater contaminants such as dimethyl disulfide, dimethyl trisulfide, phenol, p-cresol, nonanal, and decanal. Fractionation analysis of the solid fraction, post-adsorption from both synthetic and domestic wastewater, indicated that for SG, 77.3%–94% of the total phosphorus (TP) was inorganically bound, while for EGSL, it ranged from 94% to 95.3%. This study represents the first attempt at a proof-of-concept for simultaneous treatment of domestic wastewater and phosphorus recovery using this integrated system.

Recovery of phosphates from anaerobic MBR effluent using columns of eggshell and seagrass residues and their final use as a fertilizer

The combination of a submerged anaerobic membrane bioreactor (SAnMBR) and two biowaste adsorption columns (eggshell (EGSL) and seagrass (SG)) was studied for the first time to evaluate the recovery of phosphates from wastewater. Reject wastewater from anaerobic sludge dewatering process was fed into the SAnMBR and the results showed a COD removal of 50%. The phosphate removal efficiency was low and as such, the effluent from SAnMBR was then passed through two columns containing thermally treated eggshell and seagrass residues for further phosphate removal. The final effluent analysis confirmed that phosphates could be additionally removed resulting in over 95% recovery (flow rate 0.3 L d−1), for both biowaste materials. The ammonium and COD removal after the adsorption columns was low, indicating the high selectivity towards phosphates. Moreover, the solid residues after adsorption were evaluated as soil conditioners on Lepidium sativum and Sinapis alba seeds. The SG end product exhibited high GI values for both seeds tested indicating a positive effect on plant growth, while the EGSL end product negatively affected the seed germination. The fractionation analysis of phosphorus showed that inorganically bound phosphorus (IP) was the major phosphorus fraction in EGSL and SG end product, accounting for 92.6 and 95.7% of TP, respectively. The results of this study suggest that the SG and EGSL could be effectively reclaimed as selective adsorbents towards phosphates in combination with a SAnMBR and the SG solid residues after adsorption can be directly applied for agricultural purposes, contributing to the development of a zero-waste technology.

Development of a dynamic model for effective mitigation of membrane fouling through biogas sparging in submerged anaerobic membrane bioreactors (SAnMBRs)

The deterministic mechanistic model derived from the fundamental of the dynamical fouling system was investigated to estimate fouling parameters, with theoretical biogas sparging performance evaluated of a Submerged Anaerobic Membrane Bioreactor treating trade wastewater. The result showed that the sparging effectiveness of EPSc removal was average, 35% higher than the sparging effectiveness of EPSp, with the coefficient of fouling removal characterizing the dynamic time behaviour increasing with the organic loading rate. The dynamic system analysis predicted that the process gain for SAnMBR-1 was more than 30% compared with SAnMBR-2, which supported a widely known theory of fouling dependence of organic loading rate.

Recovery of biomethane from a submerged anaerobic membrane bioreactor treating domestic wastewater blended with semi-solid organic wastes discharged from residential establishments

Recent research studies on the innovative concept of submerged anaerobic membrane bioreactor (SAnMBR) technology have demonstrated superior treatment and operational performance for treating a broad range of waste streams discharged from various industries. This study aimed to investigate the treatment and recovery of biomethane (bio-CH4) performance of ceramic ultrafiltration (UF) coupled with ”co-digestion based SAnMBR”, which was not previously studied by others, for treating an organic fraction of food waste (OFFW) blended with domestic wastewater (DWW) at surge organic loading rates (OLRs) disposed at modern high-rise establishments and similar residential clusters. The SAnMBR was operated in five phases (Phase 1–5), with different organic loading rates (OLRs) varying from 0.49 to 22.57 kg-COD/m3/d. All bio-CH4, mixed liquor sludge, and treated permeate samples were analyzed using standard methods. The key parameters representing the cumulative bio-CH4 yield during each phase were estimated using sigmoidal models, and the simulated results were validated using ANOVA. It was found that the SAnMBR produced high-quality, low-turbid reclaimed water showing an increasing trend in yield of bio-CH4 with an increase of OLR. It was also observed that the SAnMBR demonstrated stable and superior treatment performance at shock-loads of organics. The maximum bio-CH4 yield recorded during the study was 73.06 ± 6.48%. The findings of this study confirmed the suitability of applying this novel concept of ”co-digestion-based SAnMBR” towards sustainable and efficient waste management in modern-high rise establishments.

Evaluation of membrane cake fouling mechanism to estimate design parameters of a submerged AnMBR treating high strength industrial wastewater

A mathematical model, which was previously developed for submerged aerobic membrane bioreactors, was successfully applied to elucidate the membrane cake-layer fouling mechanisms due to bound extracellular polymeric substances (eEPS) in a submerged anaerobic membrane bioreactor (SAnMBR). This biofouling dynamic model explains the mechanisms such as attachment, consolidation and detachment of eEPS produced in the bioreactor on the membrane surface. The 4th order Runge-Kutta method was used to solve the model equations, and the parameters were estimated from simulated and experimental results. The key design parameters representing the behaviour of cake fouling dynamics were systematically investigated. Organic loading rate (OLR) was considered a controlling factor governing the mixed liquor suspended solids (MLSS), eEPS production, filtration resistance (Rt), and transmembrane pressure (TMP) variations in a SAnMBR. eEPS showed a proportional relation with OLR at subsequent MLSS variations. The consolidation of EPS increased the specific eEPS resistance (αs), influencing the cake resistance (Rc). The propensities of eEPS showed a positive correlation with Rt and TMP. The outcomes of the study also estimated a set of valuable design parameters which would be vital for applying in AnMBRs treating industrial wastewater.

Chemical oxygen demand and nitrogen transformation in a large pilot-scale plant with a combined submerged anaerobic membrane bioreactor and one-stage partial nitritation-anammox for treating mainstream wastewater at 25 °C

A novel municipal wastewater treatment process towards energy neutrality and reduced carbon emissions was established by combining a submerged anaerobic membrane bioreactor (SAnMBR) with a one-stage partial nitritation-anammox (PN/A), and was demonstrated at pilot-scale at 25 °C. The overall COD and BOD5 removal efficiencies were 95.1% and 96.4%, respectively, with 20.3 mg L−1 COD and 5.2 mg L−1 BOD5 remaining in the final effluent. The total nitrogen (TN) removal efficiency was 81.7%, resulting 7.3 mg L−1 TN was discharged from the system. The biogas yield was 0.222 NL g−1 COD removed with a methane content range of 78–81%. Approximately 90% of influent COD was removed in the SAnMBR, and 70% of influent nitrogen was removed in the PN/A. The denitrification which occurred in the PN/A enhanced overall COD and nitrogen removal. The successful operation of this pilot-scale plant indicates the SAnMBR-PN/A process is suitable for treating real municipal wastewater.

Fouling Behavior in a High-Rate Anaerobic Submerged Membrane Bioreactor (AnMBR) for Palm Oil Mill Effluent (POME) Treatment.

The characteristics of foulant in the cake layer and bulk suspended solids of a 10 L submerged anaerobic membrane bioreactor (AnMBR) used for treatment of palm oil mill effluent (POME) were investigated in this study. Three different organic loading rates (OLRs) were applied with prolonged sludge retention time throughout a long operation time (270 days). The organic foulant was characterized by biomass concentration and concentration of extracellular polymeric substances (EPS). The thicknesses of the cake layer and foulant were analyzed by confocal laser scanning microscopy and Fourier transform infrared spectroscopy. The membrane morphology and inorganic elements were analyzed by field emission scanning electron microscope coupled with energy dispersive X-ray spectrometer. Roughness of membrane was analyzed by atomic force microscopy. The results showed that the formation and accumulation of protein EPS in the cake layer was the key contributor to most of the fouling. The transmembrane pressure evolution showed that attachment, adsorption, and entrapment of protein EPS occurred in the membrane pores. In addition, the hydrophilic charge of proteins and polysaccharides influenced the adsorption mechanism. The composition of the feed (including hydroxyl group and fatty acid compounds) and microbial metabolic products (protein) significantly affected membrane fouling in the high-rate operation.

Important effects of temperature on treating real municipal wastewater by a submerged anaerobic membrane bioreactor: Removal efficiency, biogas, and microbial community

A submerged anaerobic membrane bioreactor (SAnMBR) was used in the treatment of real municipal wastewater at operation temperatures ranging from 15 °C to 25 °C and hydraulic retention time (HRT) of 6 h. The treatment process was evaluated in terms of organic removal efficiency, biogas production, sludge growth and membrane filtration. During long-term operation, the SAnMBR achieved chemical oxygen demand removal efficiencies of about 90% with a low sludge yield (0.12–0.19 g-VSS/g-CODrem) at 20–25 °C. Approximately 1.82–2.27 kWh/d of electric energy was generated during the wastewater treatment process at 20–25 °C, 0.67 kWh/d was generated at 15 °C. The microbial community analysis results showed that microbial community was dominated by aceticlastic methanogens, coupled by hydrogenotrophic methanogens and a very small quantity of methylotrophic methanogens. It was also shown that the stabilization of the microbial community could be attributed to the carbohydrate-protein degrading bacteria and the carbohydrate degrading bacteria.

One-year operation of a 20-L submerged anaerobic membrane bioreactor for real domestic wastewater treatment at room temperature: Pursuing the optimal HRT and sustainable flux

A 20 L hollow-fiber submerged anaerobic membrane bioreactor (SAnMBR) was used to treat real domestic wastewater at 25 °C with hydraulic retention times (HRTs) ranging from 4 to 12 h. The process performance was evaluated by organic removal efficiency, biogas production, sludge yield, and filtration behaviors during one-year's operation. For HRTs ranging between 6 and 12 h, the AnMBR showed good organic removal efficiency with chemical oxygen demand (COD) and biochemical oxygen demand (BOD) removal efficiencies of about 89% and 93%, respectively. The biogas yield was 0.26 L-gas/g-CODfed, with approximately 80% methane content, and the sludge yield was 0.07–0.11 g-VSS/g-CODrem. While at an HRT of 4 h, with the higher wastewater treatment capacity and organic loading rate (OLR), the biogas production was lower (0.17 L-gas/g-CODfed), and the sludge production was higher (0.22 g-VSS/g-CODrem). The organic removal performance (COD 84% and BOD 89%) at HRT of 4 h was acceptable due to the effective separation effect of the membrane filtration process. According to COD balance analysis, the low biogas yield and high sludge yield at HRT of 4 h were due to insufficient biodegradation under an OLR of 2.05 g-COD/L-reactor/d. Theoretical calculations based on Henry's law indicate that the ideal methane content in the biogas should be 82–85% when the operational temperature was 25 °C. To achieve a high flux and sustainable AnMBR operation, the impact of mixed liquor suspended solid (MLSS) and gas sparging velocity (GSV) on the filtration performance was analyzed. The critical flux increased with increase in the GSV from 24.2 to 174.3 m/h, but decreased with increase in the MLSS concentration from 8.2 to 20.2 g/L. Therefore, decreasing fouling rate to 0.8–1.2 kPa/d by efficiently controlling GSV and MLSS, sustainable operation could be achieved at a flux of 0.34 m/d.

Comparison of soluble microbial product (SMP) production in full-scale anaerobic/aerobic industrial wastewater treatment and a laboratory based synthetic feed anaerobic membrane system

This study focused on the characterisation of soluble microbial products (SMPs) produced from a full-scale multi-stage (anaerobic/aerobic) industrial wastewater treatment plant, and contrasted them to the SMPs detected in the effluent of a lab-scale AnMBR treating synthetic wastewater to determine if there were any common solutes detected irrespective of the feed organics. Recently developed analytical methods using gas chromatography coupled mass spectrometry (GC–MS) and liquid chromatography coupled quadrupole-time-of-flight (LC-Q-ToF) for SMP characterisation in a wide molecular weight (MW) range of 30–2000 Da (Da) were applied. Samples collected from the Industrial Wastewater plant were the upflow anaerobic sludge blanket (UASB) influent and effluent, and aerobic membrane bioreactor (MBR) effluent before discharge. The GC–MS detected a spike in cyclooctasulphur in the UASB effluent, an indicator of shock-loading, which disappeared after the MBR process. Alkanes, acids and nitrogenous compounds were found to be the end-products from the GC–MS results, while LC-Q-ToF analysis revealed that eicosanoids, a group of cell-signalling molecules, were produced in the aerobic MBR, and made up 71% of its effluent. A comparison of the submerged anaerobic membrane bioreactor (SAMBR) and aerobic MBR effluents using GC–MS showed that there was only a small degree of similarity between the SMPs, comprising mainly long chain alkanes and phthalate. On the other hand, LC-Q-ToF showed a large contrast in compound composition, mostly having cell-signalling functions, which deepened our understanding of the different metabolic processes occurring in aerobic and anaerobic systems. These data could be useful for future work in various areas such as controlling quorum-sensing and biofilm formation, process optimisation and control, and microbial ecology.

Effect of Biogas Sparging Flow on Fouling Control in Anaerobic Membrane Bioreactors

Membrane fouling behaviors were investigated to different biogas sparging flows such as 0.5, 1.0, and 1.5 L biogas/min for anaerobic submerged membrane bioreactor (AnSMBR) treating synthetic wastewater in a laboratory-scale. For each different biogas flow rate, the membrane module of the same feature was used in the system and the effect of biogas sparging flow on fouling control was examined in the process. Surface area of the used membrane module was selected as 162.6 cm2. The sprarging biogas was supplied from the gas formed in reactor system. Treatment parameters were analyzed in the process of reactor operation. Also, a series of analysis, including soluble microbial products (SMP), extracellular polymeric substances (EPSs), scanning electron microscopy, energy dispersive X-ray spectroscopy, particle size distribution, and filtration resistances were performed by considering the membrane module. The AnSMBR accomplished COD removal efficiencies between 95 and 98%. Total organic carbon and sulfate concentration in permeate were found in the range of 25–56 and 90–200 mg/L, and 96–98 and 38–65% in removal percentage; respectively. TSS and VSS concentrations in permeate were less than 10 mg/L that means removal efficiencies of 98%. Methane production rate in the system was determined of 0.35 ± 0.08 LCH4/g COD removed. The results showed that differences between COD and TOC removals were negligible at different biogas sparging flows. The priority of biogas sparging flows in terms of providing high permeate fluxes were found to be 1.5 L biogas/min > 1.0 L biogas/min > 0.5 L biogas/min. The same order was found with the fluxes in terms of both SMP and EPS within cake formed on the fibers in membrane module. Studying results showed that biogas sparging flow increasing was found to effective on membrane fouling controls. It has been determined that sparging gas at an optimum flow rate (1.0 L biogas/min) can be effective in controlling membrane fouling.

Performance and membrane fouling behaviors analysis with SVR-LibSVM model in a submerged anaerobic membrane bioreactor treating low-strength domestic sewage

Abstract A submerged anaerobic membrane bioreactor (SAnMBR) was operated for low-strength domestic sewage treatment over a period of 190 days. Average chemical oxygen demand (COD) removal efficiency ranged from 64.41 to 83.49%, and the removal of ammonia nitrogen (NH 4 + -N) and total phosphorus (TP) were relatively poor. No acidification occurred in the reactor during operation. The performance and membrane fouling behaviors of SAnMBR were investigated and support vector regression model with LibSVM package (SVR-LibSVM) was established to predict performance and analyze the effect of extracellular polymeric substances (EPSs) on membrane fouling. The effect of organic loading rate (OLR) on COD removal efficiency at each stage was also studied according to the model. Both transmembrane pressure (TMP) and total membrane resistance ( R t ) have a significant decline when membrane flushing was carried out. However, physical flushing could alleviate rather than eliminate membrane fouling.

Submerged anaerobic membrane bioreactor for low-concentration domestic sewage treatment: performance and membrane fouling

A submerged anaerobic membrane bioreactor (SAnMBR) was used to treat low-concentration domestic sewage. The effects of hydraulic retention time (HRT) and organic load (OLR) on chemical oxygen demand (COD) removal, methanogenesis, and membrane fouling of the system were investigated. The SAnMBR achieved good COD removal efficiency as well as stable methane production, which were significantly affected by both OLR and HRT. The influent dissolved organic matter (DOM) was decomposed and transformed over time, and DOM concentration was gradually reduced. It can be inferred that the SAnMBR can effectively intercept the production of extracellular polymeric substances and improve effluent quality. The phenomenon of membrane fouling was investigated using various analytical tools. Results demonstrated that the SAnMBR was achieved good transmembrane pressures (TMP) (10-15kPa), and the hydraulic force generated by the stirring device has a dynamic physical shearing action on the surface of the membrane, which can partly alleviate membrane fouling.

Size-dependent microbial diversity of sub-visible particles in a submerged anaerobic membrane bioreactor (SAnMBR): Implications for membrane fouling

Sub-visible particles, an often-overlooked fine particle (0.45–10 μm) with a size between sludge solids and soluble microbial products (SMP), have recently been identified as a critical foulant in anaerobic membrane bioreactors (AnMBRs), and our recent new insights into the size-fractionation and composition of sub-visible particles in AnMBRs have enabled fouling to be understood in more depth. Here, we investigated the microbial diversity of the sub-visible particles in three size fractions (i.e., 5–10, 1–5, and 0.45–1 μm) from bulk and cake solutions in a lab-scale AnMBR, and their fouling potential was further explored based on their filtration behavior and biofilm formation. Results show that with decreasing particle size, a significant shift in microbial communities was observed for the sub-visible particles in both bulk and cake solutions; (a) with notable decreases in filamentous microbes in the order SJA-15, GCA004, and Anaerolineales of phylum Chloroflexi, and, (b) with substantial increases in sulfate-reducing bacteria (i.e., the family Syntrophobacteraceae, genus DCE29 of family Thermodesulfovibrionaceae, Desulfovibrio, and Geobacter). More importantly, the filamentous microbes associated with micro-particles (5–10 μm) led to higher cake fouling resistances while free living cells in the form of colloidal particles (0.45–1 μm) induced severer pore blocking. Moreover, the micro-particles had an enhanced capacity to favor biofilm formation (OD595 = 1.0–2.5, categorized as highly positive), thus potentially aggravating biofouling. This work advances our knowledge on the effect of particle size on communities and underlying fouling behavior of microbes associated with fine particles in AnMBRs.

Anaerobic submerged membrane bioreactor (AnSMBR) treating municipal wastewater at ambient temperature: Operation and potential use for agricultural irrigation

A 496 L pilot scale anaerobic submerged membrane bioreactor (AnSMBR) for the treatment of municipal wastewater was evaluated during a year of stable operation at ambient (28–10 °C) temperature, and inoculated with mesophilic inoculum. The temperature was the main parameter affecting the process performance. The chemical oxygen demand (COD) of the effluent was around 150 mg O2/L in the summer period, operating with a volumetric loading rate (VLR) of 5 kg COD/m3 d and hydraulic retention time (HRT) of 8–10 h, with a specific methane production between 0.09 and 0.14 Nm3/kg CODremoved. However, during the winter season, an important increase of effluent COD was observed, and therefore the VLR was decreased to values around 1 kg COD/m3 d in order to recover the quality of the effluent. Biogas production was negligible in this period. The effluent complies with the parameters stipulated by Spanish law regarding the use of treated wastewater for agricultural irrigation.

Dissection and characterization of the prokaryotic community during the long-term operation of a submerged anaerobic membrane bioreactor for the anaerobic treatment of N, N-dimethylformamide-containing wastewater with a co-cultured inoculum

A submerged anaerobic membrane bioreactor (SAnMBR) was operated for the anaerobic treatment of wastewater containing approximately 2000 mg L−1N, N-dimethylformamide (DMF). Inoculated with a co-cultured inoculum, the SAnMBR obtained an excellent DMF removal under a low organic loading rate (OLR) of 3.14–4.16 g COD L−1 d−1. However, the elevation of OLR limited hydrolysis. While the co-cultured inoculum initially contains abundant DMF-hydrolyzing bacteria with potential to hydrolyze DMF into intermediates, such as Paracoccus, Hyphomicrobium, Burkholderia, Catellibacterium, Bacillus and Bradyrhizobium, since these bacteria are facultative anaerobes which survive anaerobically, they kept decaying rather than proliferating, resulting in the weakening of the DMF-hydrolyzing ability. Each re-inoculation of new sludge only temporarily revitalized hydrolysis activity for a short period. Due to the lack of nitrate, these bacteria were unable to proliferate. This suggests that a small dose of nitrate would help to enrich these bacteria and establish a stable DMF-degrading consortium.

Anaerobic treatment of N,N-dimethylformamide-containing high-strength wastewater by submerged anaerobic membrane bioreactor with a co-cultured inoculum

The anaerobic treatment of wastewater containing approximately 2000 mg L−1N,N-dimethylformamide (DMF) was conducted by a lab-scale submerged anaerobic membrane bioreactor (SAnMBR). The inoculum consisted of aerobic DMF-hydrolyzing activated sludge (DAS) and anaerobic digested sludge (ADS). A rapid start-up was achieved with thorough DMF methanogenic degradation on the first day. The results of a 250-day long-term experiment demonstrated that under a low organic loading rate (OLR) of 3.14–4.16 g COD L−1 d−1, SAnMBR maintained excellent DMF removal efficiency along with high methane conversion. However, the elevation of OLR significantly limited DMF hydrolysis. When OLR exceeded 6.54 g COD L−1 d−1, both removal efficiency and methane production dramatically dropped. The DMF-hydrolyzing bacteria originating from the DAS gradually decayed under the anaerobic condition, resulting in the weak hydrolysis of DMF. The shortening of hydraulic retention time (HRT) is not recommended for the SAnMBR because severe membrane fouling occurred when HRT was shortened to 8 h. To handle high OLRs, an appropriate solution is to maintain a low F/M ratio by increasing both the influent DMF concentration and sludge concentration. The high CH4 content in the biogas, exceeding 85%, was shown to be the reason for the suitability of anaerobic treatment to DMF. Some improvements which would help to maintain the effective hydrolysis are proposed: a side-stream system to replenish DAS to the SAnMBR is helpful; slight dosage of nitrate could also help to enrich the DMF-hydrolyzing bacteria; and the co-digestion of DMF and other organics might be convenient to establish a stable DMF-degrading consortium.

Specific approach for membrane fouling control and better treatment performance of an anaerobic submerged membrane bioreactor

This paper investigated a strategy to minimize membrane fouling and increase treatment efficiency through an investigation of a specific approach by adding sponges into a conventional submerged anaerobic membrane bioreactor (CAnSMBR). During the operation, the protein-based soluble microbial products as the main factor affecting the membrane fouling could be reduced by sponge addition in the CAnSMBR (SAnSMBR). Furthermore, reducing HRT from 18 h to 12 h could shorten the membrane fouling cycle to 62% and 87% in CAnSMBR and SAnSMBR, respectively. At the initial of COD/NO3 ratio ranges from 5 to 4, only 88% of nitrogen in CAnSMBR was removed, while the SAnSMBR could remove more than 90%. TOC removal efficiency could reach more than 95% under a good stirring scenario. It is evident that the SAnSMBR is a promising solution for improving overall CAnSMBR performance and substantially mitigating membrane fouling.

Wastewaters treatment containing phenol and ammonium using aerobic submerged membrane bioreactor

Phenolic wastewater was treated using anaerobic submerged membrane bioreactor (ASMBR). Effect of different solids retention times on MBR performance was studied. Various ratios of carbon to nitrogen were used in the synthetic wastewaters. During the operation, phenol concentration of feed was changed from 100 to 1000 mg L−1. Phenol concentration was increased stepwise over the first 30 days and kept constant at 1000 mg L−1, thereafter. For the first 100 days, a chemical oxygen demand (COD) to N ratio of 100:5.0 was used and this resulted in phenol and COD removal more than 99 and 95%, respectively. However, the ammonium removal decreased from 95 to 40% by increasing the phenol concentration of feed, from 100 to 1000 mg L−1. For the last 25 days, a COD to N ratio of 100:2.1 was used due to the ammonium accumulation in the ASMBR. This led to the complete ammonium removal and no ammonium was detected in the ASMBR permeate. These results suggest that in the ASMBR at high phenol loading of 1000 mg L−1, COD to N ratio of the phenolic wastewater must be 100:2.1 for ammonium removal, while at low phenol loading, COD to N ratio of 100:5.0 can be used.