AbstractDetermining the mechanisms responsible for intraplate volcanism ‐ such as slab devolatilization melting versus active mantle plumes ‐ remains a challenge. The greater South China Sea (SCS) region has experienced extensive intraplate Cenozoic volcanism across areas including Hainan, Southeast Indochina, northern Borneo, the northern SCS, and the post‐spreading SCS basin. The prevalence of volcanism distributed widely across this region prompts fundamental questions about the key geodynamic processes driving such diverse magmatic activities. In this study, we elucidate the mantle transition zone (MTZ) discontinuities in this region using SS precursors, which helps to overcome the sparse seismic coverage due to its predominantly oceanic setting. We collected over 16,000 high‐quality seismograms that sample the upper mantle and MTZ beneath this region from global earthquakes and stations. After correcting for the effects of shallow crustal variations and upper mantle heterogeneity on traveltimes of SS phases and their precursors, we unveil lateral variations in the MTZ boundaries (d410 and d660) and intricate features of the mid‐MTZ reflectors (S520S). Significant MTZ thinning and normal S520S waveforms beneath Hainan provide compelling evidence for mantle upwelling through the MTZ. Conversely, the evident splitting of S520S beneath the northern SCS, Southeast Indochina, and northern Borneo, all characterized by stagnant subducted slabs, indicates that the volcanism in these regions likely originated from a mechanism distinct from the active upwelling beneath Hainan. Dehydration melting attributed to devolatilizing stagnant slabs in the MTZ is a potential cause for Cenozoic volcanism in these regions.
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