Subatmospheric Pressure Research Articles

Experimental and numerical study of turbulent fluid flow of jet impingement on a solid block in a confined duct with baffles

This study investigates the heat transfer and fluid flow characteristics of turbulent flow resulting from jet impingement on a heated solid block positioned on the lower wall of a duct with baffles. Both experimental and numerical methods were employed in this research. The flow was presumed to be three-dimensional, steady, incompressible, and turbulent. The study involved the installation of one baffle on the lower wall and another one on the upper wall. Three variants of the k-ε turbulence model (the standard, the RNG, and the realizable) were numerically compared. The realizable k-ε model has shown the most reliable results compared to the other models, and thus is utilized in all calculations.The flow characteristics were experimentally and numerically studied by varying jet Reynolds number (38,957 ≤ Re ≤ 77,315), baffle height (hb /d = 0.6,0.8 and 1.0), baffles' locations arrangement [(L1/d with L2/d) as (3 with 4), (4 with 6), (6 with 8) and (6 with 4)], solid block temperature (333 o K ≤ Tb ≤ 363 o K) at an aspect ratio (w/a) of 5.25.The results showed that several vortices were formed: a main vortex close to the upper wall, a smaller one above the hot solid block, a vortex adjacent to the solid block, and additional vortex zones both in front of and behind the lower and upper baffles. The vortices intensity increases as the Reynolds number grows up. When the baffle locations change downstream, the sizes of these generated vortices increase, the height of the recirculation zone behind the lower baffle is slightly higher than that behind the upper baffle, and the primary vortex diminishes. Besides, all recirculation zones grow up in sizes when swapping the baffle locations.The study also revealed that the pressure is higher when the baffle is presented in the domain than the case of no baffle. The pressure value at the stagnation point, peak sub-atmospheric pressure value and maximum pressure value increase as the Reynolds number increases. They also increase with the increase of baffle height. However, it was found that the pressure values decay when the positions of the baffles get changed in the downstream direction.In addition, the results showed that the maximum deviation in temperature between the experimental and theoretical results was about 3 %. Besides, the increase in the maximum temperature value in the presence of baffles was about 10.8 % as compared to the case without baffles. Furthermore, the temperature increases as the Reynolds number decreases while it increases with the increase of solid block temperature and/or baffles height and location.

Investigation of NO emission characteristics from co-combustion of methane and ammonia at high-altitude areas

The high-altitude areas of China are abundant in renewable energy and have a natural advantage in ammonia production. Based on this advantage, this paper proposes a co-combustion strategy for methane and ammonia to reduce carbon emissions in these areas. However, the NO emission characteristics associated with this strategy remain uncertain. A custom-designed combustion system capable of simulating high-altitude environments was used to investigate the effect of ammonia mixing ratio, equivalence ratio, and pressure on NO emission in methane/ammonia/air flames. Additionally, chemical kinetic calculations were conducted to explore the mechanisms of how sub-atmospheric pressure influences NO emission. The results indicate that for stoichiometric flames, NO increases with the ammonia mixing ratio. In fuel-rich flames, NO remains nearly constant once the ammonia mixing ratio exceeds 10%. Sub-atmospheric pressure leads to higher NO, particularly in fuel-rich flames, where the increase can reach up to 24.4%. Analysis of nitrogen reaction pathways and key radical concentrations reveals that sub-atmospheric pressure has a minimal effect on nitrogen conversion pathways. The variation in NO is achieved by altering the pathway contributions and the concentrations of H, NH, and N. This work provides direction and guidance for improving the application of methane and ammonia co-combustion in high-altitude areas.

Mathematical Approach for Directly Solving Air–Water Interfaces in Water Emptying Processes

Emptying processes are operations frequently required in hydraulic installations by water utilities. These processes can result in drops to sub-atmospheric pressure pulses, which may lead to pipeline collapse depending on soil characteristics and the stiffness of a pipe class. One-dimensional mathematical models and 3D computational fluid dynamics (CFD) simulations have been employed to analyse the behaviour of the air–water interface during these events. The numerical resolution of these models is challenging, as 1D models necessitate solving a system of algebraic differential equations. At the same time, 3D CFD simulations can take months to complete depending on the characteristics of the pipeline. This presents a mathematical approach for directly solving air–water interactions in emptying processes involving entrapped air, providing a predictive tool for water utilities. The proposed mathematical approach enables water utilities to predict emptying operations in water pipelines without needing 2D/3D CFD simulations or the resolution of a differential algebraic equations system (1D model). A practical application is demonstrated in a case study of a 350 m long pipe with an internal diameter of 350 mm, investigating the influence of air pocket size, friction factor, polytropic coefficient, pipe diameter, resistance coefficient, and pipe slope. The mathematical approach is validated using an experimental facility that is 7.36 m long, comparing it with 1D mathematical models and 3D CFD simulations. The results confirm that the derived mathematical expression effectively predicts emptying operations in single water installations.

Effects of sub-atmospheric pressure on appearance and pollutant formation of inverse diffusion flame within a confined space

Gas-fired boilers operating at high-altitude regions often suffer from inadequate output, decreased thermal efficiency, and excessive NOx emissions. The effect of sub-atmospheric pressure on flame appearance and pollutant formation is the main reason for those problems, and thus needs to be clarified particularly under furnace combustion conditions with a fixed excess air coefficient. Inverse diffusion is a widely employed fuel–air configuration in burners of gas-fired boilers, and therefore the flame appearance, CO generation, and NO generation were experimentally investigated in this paper by adopting a low-pressure quartz tube reactor. Results show that the flame is elongated from reducing pressure under fuel-lean conditions, mainly due to the reduced oxygen mass concentration and the elevated jet velocity. Under fuel-rich combustion conditions, however, the flame is shorted at sub-atmospheric pressure from the suppressed soot formation. The reduced pressure leads to an increase in the global strain rate, making the flame more prone to uplift. With decreasing pressure, the increased air–fuel mixing and flame length facilitate the gas burnout, thus decreasing CO generation. The sub-atmospheric pressure could evidently reduce the NO generation under fuel-rich conditions, but slightly increase it under fuel-lean conditions. Under fuel-lean conditions, the NO major pathways (prompt, thermal, NNH, and N2O) are promoted which leads to an increase in NO generation with decreasing pressure. Under fuel-rich conditions, however, NO formation is suppressed from the decreased rate of reaction N2+CH↔HCN+N.

Experimental study of fuel distribution and combustion characteristics under subatmospheric pressure in an afterburner

The fuel distribution and ignition characteristics of an afterburner with typical components under subatmospheric inlet conditions are important references for improving the performance of the afterburner at high flight altitudes. In this work, lean ignition limits, outlet temperature distributions, fuel droplet size distributions and flame propagation processes in the afterburner were obtained experimentally. The results show that with increasing fuel injection angle, the fuel atomization characteristics improve, but the flame intensity fluctuation increases, and the ignition performance deteriorates; thus, a proper ratio of liquid-phase fuel to vapor-phase fuel is one of the key elements for successful ignition. On the one hand, the increased stabilizer blockage ratio results in a localized flow velocity increase near the trailing edge of the stabilizer, which effectively promotes fuel atomization in the shear layer, resulting in a fuel droplet size reduction of 25–30 μm. On the other hand, the extent of the recirculation zone increases, and a large low-pressure and low-turbulence recirculation zone is not conducive to fuel atomization in the flow direction. During the ignition process in an afterburner with all the typical components, the flame kernel first propagates along the flow direction for a certain distance and then propagates and anchors toward the shear layer. At subatmospheric pressures, the decrease in the intensity of the combustion reaction causes a reduction in the heat released by combustion, and the fuel droplet size increases by 10–25 μm, which requires more heat for evaporation. Therefore, the flame propagates an increased distance along the flow as the pressure decreases. Furthermore, the difficulty of ignition increases, and the ignition equivalence ratio increases by 0.1–0.15.

Effects of Pressure, Surfactant Concentration, and Heat Flux on Pool Boiling Using Expanding Microchanneled Surface for Two-Phase Immersion Cooling.

Deionized water is replacing fluorinated liquids as the preferred choice for two-phase immersion cooling in data centers. Yet, insufficient bubble removal capability at low saturated pressure is a key challenge hindering the widespread application. To solve this issue, this study employs non-ionic surfactant (Tween 20) and asymmetric structures (expanding microchannel) to enhance the boiling performances of deionized water under sub-atmospheric pressure. The research examines the effects of pressure (8.8~38.5 kPa), surfactant concentration (0.1~0.5 mL/L), and heat flux density (10~180 W/cm2) on the boiling heat transfer characteristics and analyzes the mechanism of unusual temperature oscillations induced by surfactants. It was found that the trade-off between the sub-atmospheric pressure, surface tension coefficient, and reduced static contact angle results in pronounced intermittent boiling on the heated surface. Even with the addition of surfactants, the improvement in heat transfer requires demanding conditions. Boiling enhancement throughout all heat flux conditions was achieved when the surfactant concentration was higher than 0.2 mL/L for the expanding microchanneled surface. The heat transfer coefficient reached 6.89 W·cm-2·K-1 under 8.8 kPa, which was 45% higher than without the surfactant. Under the same heat flux and sub-atmospheric pressure, as the concentration increased from 0.1 to 0.5 mL/L, the amplitudes of temperature fluctuation of the plane surface and expanding microchanneled surface decreased from 10 K to 2 K and 18 K to 1 K, respectively. The onset of nucleate boiling and wall superheat of the expanding microchanneled surface gradually decreased with the increase in surfactant concentration, where the onset of nucleate boiling decreased by 10.54 K. When the heat flux is 160 W/cm2, the wall superheat is reduced by 12.8 K.

Low-pressure oxidation for improving interface properties and voltage instability of SiO2/4H-SiC MOS capacitor

The impact of high-temperature sub-atmospheric oxidation pressure on the interface properties of n-type 4H-SiC metal–oxide–semiconductor capacitors has been systematically investigated in this report. The bias temperature instability measurement was used to calculate the mobile ions and near-interface trap density that led to device instability at high temperatures. The density of near interface traps decreased from 88.3 × 1011 cm−2 to 10.2 × 1011 cm−2 when the growth pressure of SiO2 was reduced from 1 atm to 0.1 atm, while the mobile ions density decreased from 83.5 × 1011 to 4.18 × 1011 cm−2. The results show that SiO2 growing under lower oxidation pressure has better interfacial quality. The underlying mechanism was explored by secondary ion mass spectrometry (SIMS) and x-ray photoelectron spectroscopy (XPS). It is speculated that the SiO2/SiC interface was reconstructed under low-pressure oxidation: the excess Si-related defects near the interface, such as SiOxCy, were released while O atoms were accumulated to promote a complete oxidation reaction, thereby effectively reducing the number of defects in the SiO2 film and improving device performance.

Study on discharge characteristics of low-temperature sub-atmospheric pressure under steep change rate voltage

Study on discharge characteristics of low-temperature sub-atmospheric pressure under steep change rate voltage

Performances of the ITER Pressure Suppression System during unstable steam condensation regimes

Abstract The paper deals with the qualification of the main safety system of the nuclear fusion reactor ITER: the Vacuum Vessel Pressure Suppression System (VVPSS). This safety system manages the Loss of Coolant Accident (LOCA), that could occur in the Vacuum Vessel (VV), avoiding a significant increase of the internal pressure that could breach the primary confinement barrier. Steam condensation occurs at sub-atmospheric pressure. This condition is original respect the usual applications of steam direct condensation in nuclear fission reactors. An extensive experimental research program, funded by ITER Organization, on reduced scale experimental rigs (scale 1/22 and 1/10) have been carried out at the University of Pisa. Unstable condensation regimes occurred during some tests at about 500 g/s of steam mass flow rate (10 % of the maximum steam mass flow rate foreseen for the relevant accidental scenarios). In these conditions, high intensity vibrations of the whole experimental rig occurred. These events can be classified as ‘Chugging’ or Condensation Induced Water Hammer (CIWH). 
The performed tests have been analysed elaborating the images of the video-cameras located in the pool and comparing the steam jet shape with the acceleration values recorded by an accelerometer mounted on the sparger structure.
These elaborations permitted to evaluate the dynamic of bubble collapse, the volume of the developed external bubbles, the collapse frequency as function of thermal-hydraulic parameters. 
Moreover, the paper emphasizes the beneficial effects of non-condensable gases on the unstable condensation regimes. In fact, the non-condensable gas inhibits the occurrences of Water Hammer inside the sparger and eliminates the thermal stratification inside the water pool increasing the turbulence.

Critical Closing Pressure (Pcrit) and Negative (Subatmospheric) Expiratory Pressure (NEP) for Diagnosis of Pharyngeal Collapsibility in Patients With Obstructive Sleep Apnea (OSA)

The determination of critical closing pressure (Pcrit) is the diagnostic gold standard for assessing the severity of pharyngeal instability. Pcrit measurements are typically performed during natural nocturnal sleep (NREM Stage 2) in combination with polysomnography. However, determining Pcrit during sleep is time-consuming and impractical for routine use. Alternatively, Pcrit measurements can also be done during drug-induced sleep. A disadvantage of this method is the varying doses of propofol needed to induce sleep, which can affect muscle tone differently. As an alternative to these methods, the application of negative pressure during wakefulness (NEP test) has proven effective. In this test, the patient is administered a subatmospheric pressure of -5 or -10 cmH2O via mask at the beginning of expiration, and the change in expiratory airflow in the pharynx is measured. NEP test can be performed in both sitting and lying position. According to current knowledge, the NEP test appears to be a diagnostic procedure comparable to critical closing pressure (Pcrit) for assessing upper airway collapsibility.

Experimental study on the transitional behavior of the room fire under sub-atmospheric pressures

Fuel diffusion combustion and flame behavior within a confined space is a fundamental scientific problem in the energy and combustion field, it involves complicated chemical reaction, fire behavior, thermal dynamics, heat transfer, room-opening flowing and sub-processes of over-ventilated and under-ventilated room fire. However, previous classical knowledges and models about it are usually at standard atmospheric pressure (100 kPa), no work considers the fire evolution and flame behavior within the room for various sub-atmospheric pressures. In this paper, the experiment is carried by utilizing a 0.3 m × 0.3 m × 0.3 m reduced-scale cubic room with an opening of various dimensions, and using propane as fuel to simulate fuel combustion inside, which was placed at the Low Pressure Chamber creating various atmospheric pressures. The flame behavior and temperature evolution within the room was recorded and measured with 693 experimental conditions. The experimental results show that, (1) the air inflowing rate through opening into room and heat release rate within the room increase with atmospheric pressure; (2) the flame extinction or reaching well-mixed condition are more easily occurred for lower atmospheric pressure and opening dimension. These characteristic parameters and fire behaviors could be well described by new corrected opening ventilation factor involving effect of atmospheric pressure and the opening dimension. The research work fills the gap in basic scientific research of building fire at sub-atmospheric pressures, which also has important practical applicability of urban building fire protection design code (such as the materials in wall) in different altitudes, room fire suppression, and protecting urban safety.

A composite model for nucleate boiling heat transfer in a slush nitrogen pool

The pool boiling of slush nitrogen (SlN2) with various solid volume fractions at subatmospheric pressures is studied to establish a semi-empirical model considering the effects of phase-change solid nitrogen (SN2) particles on convective heat flux and boiling heat flux. The convective heat flux is studied with the modified correlation based on Sindt's fitting, while an improved correlation based on Rohsenow correlation with the dimensionless form of wall superheat in the range of 0<Ja∗ρ∗0.14<0.04 is obtained for the boiling heat flux. With the increasing wall superheat, the enhancement weakens till vanishes at the transition point. This point marks the separation between low- and high-heat-flux regions, where the probability of SN2 invading to thermal boundary layer diminishes to 0 %. The low-heat-flux boiling correlation considers the heat transfer enhancement due to SN2 concentration while the high-heat-flux one ignores the impact of SN2. As the components of SlN2 nucleate boiling model, the convective and boiling heat flux both show the accuracy of ±20 % with experiments. Upon analyzing the boiling curves of SlN2 with various solid volume fractions, SlN2 outperforms LN2 in coolant efficiency at moderate heat load.

Efficacy and Safety of "Vacuum Swallowing" Based on a Strong Negative Esophageal Pressure in Healthy Individuals.

Vacuum swallowing is a unique method for improving the pharyngeal passage of a bolus by creating subatmospheric negative pressure in the esophagus. However, whether healthy individuals and other patients with dysphagia can reproduce vacuum swallowing remains unclear. Therefore, this study aimed to assess whether healthy individuals verified using high-resolution manometry (HRM) could reproduce vacuum swallowing and evaluate its safety using a swallowing and breathing monitoring system (SBMS). Two healthy individuals who mastered vacuum swallowing taught this method to 12 healthy individuals, who performed normal and vacuum swallowing with 5 mL of water five times each. The minimum esophageal pressure and the maximum pressure of the lower esophageal sphincter (LES) were evaluated during each swallow using the HRM. Additionally, respiratory-swallowing coordination was evaluated using the SBMS. Ten individuals reproduced vacuum swallowing, and a total of 50 vacuum swallows were analyzed. The minimum esophageal pressure (-15.0 ± 4.9 vs. -46.6 ± 16.7 mmHg; P < 0.001) was significantly lower, and the maximum pressure of the LES (25.4 ± 37.7 vs. 159.5 ± 83.6 mmHg; P < 0.001) was significantly higher during vacuum swallowing. The frequencies of the I-SW and SW-I patterns in vacuum swallowing were 38.9% and 0%, respectively, using the SBMS. Vacuum swallowing could be reproduced safely in healthy participants with instruction. Therefore, instructing exhalation before and after vacuum swallowing is recommended to prevent aspiration.

Analysis of a plasma reactor performance for direct nitrogen fixation by use of three-dimensional simulations and experiments

This study utilizes state-of-the-art in-situ measurements and advanced three-dimensional simulations to investigate the operation of a microwave plasma reactor for nitrogen fixation at a high subatmospheric pressure under various power inputs. It is shown that the system should be treated as a warm plasma due to negligible differences in vibrational and rotational temperatures and that it is required to account for chemical non-equilibrium. Complex flow field and significant temperature and concentration gradients are observed, emphasizing the need for three-dimensional simulations to accurately describe the interactions between mass, heat, and momentum transport and chemical reactions in non-equilibrium conditions. The innermost plasma regions reach temperatures close to 6000 K, while wall temperatures remain low due to presence of a low-temperature swirling flow field around the hot core. Analysis reveals that the swirling flow field around the hot core provides intrinsic partial quenching in regions with large temperature gradients which counteract the return to chemical equilibrium and enrich the flow surrounding the hot core. The inner flow exhibits a recirculation zone, stagnation point, and a transition into an increasingly parabolic flow profile closer to the reactor outlet. The agreement between the numerical modeling and the measurements is strong. In-situ Raman spectroscopy measurements confirm the calculated temperature field inside the reactor. Thermocouple measurements on the reactor wall are also in good agreement with the simulation. Additionally, Fourier-transform infrared spectroscopy measurements agree very well with the simulated amount of nitrogen oxide exiting the reactor at different microwave power inputs. The understanding and modeling capabilities are expected to support the development of future reactor designs that can facilitate higher yields.

The influence of air distribution ratio on the fluctuation characteristics and stability of horizontal jet diesel non-premixed flame under extreme sub-atmospheric pressures

The burning problem in the plateau environment attracts more and more people’s attention, and the plateau adaptability and flame stability of burner are the focus of recent research. The main purpose of this paper is to reveal the horizontal jet spray flame fluctuation characteristics and stability change rule under extremely low pressure (0.05 MPa) at a high altitude (about 5500 m) inhabited by human beings. Flame morphology and temperature properties were investigated in a low-pressure chamber with different secondary air ratios (23–53 %). It is found that the normalization of the flame trajectory equation is not affected by the ratio of secondary air. The temperature in the flame recirculation zone can be increased by 110 K as the proportion of secondary air increases to 45 %, but the maximum temperature is still lower than 1500 K. A continuous flame image processing method was implemented to define and analyze the flame fluctuation region. The results show that the dimensionless fluctuation parameter γ can predict the flame stability in advance than β. When the secondary air ratio is 40 %, the flame has the largest upward fluctuation; and when it exceeds 45 %, the flame stability becomes worse. This work is the first to obtain the results of the study on flame morphology and stability of horizontal jet spray flame distribution ratio under extremely low atmospheric pressure, which provides a theoretical scientific basis for the design of plateau burner, flame control, and flame stability improvement.

Assessment of the INRIM trace water generator and analysis of the uncertainty components down to −100 °C frost-point temperature

A low frost-point generator (INRIM 03) able to operate at sub-atmospheric pressure has been recently designed, constructed, and assessed at the Istituto Nazionale di Ricerca Metrologica (INRiM) with the aim of providing the metrological traceability both to instruments developed for the measurement of humidity in atmosphere and to sensors and analysers used in industry for controlling and measuring the amount of water vapour in manufacturing processes. The humidity generator operates in a single temperature single pressure mode, letting the carrier gas (nitrogen) achieve saturation in a single passage through an isothermal saturator. Its working range encompasses a frost-point temperature range from −100 °C to −20 °C, in a pressure range between 200 and 1100 hPa, corresponding to an amount of water fraction range from 13 · 10−9 mol·mol−1 to 6.2 · 10−3 mol·mol−1. In a previous work its performance was assessed in the frost-point temperature range from −75 °C to −20 °C (Cuccaro et al 2018 Meas. Sci. Technol. 29 054002). In this work, a comprehensive set of tests for its characterisation and performance evaluation between −75 °C and −100 °C is presented. A detailed uncertainty analysis in the above temperature range is reported, taking into account all the sources of uncertainty that affect the humid gas generation. An expanded uncertainty (k= 2) of 0.07 °C was found for frost-point temperature measurements between −75 °C and −95 °C, while an expanded uncertainty of 0.26 °C resulted at a frost-point temperature of −100 °C. The relative expanded uncertainty (k = 2) associated with water vapour amount fraction measurements was estimated equal to or better than 1.2% between 35 · 10−9 mol·mol−1 and 6.1 · 10−3 mol·mol−1, increasing up to 6.5% at 13∙10−9 mol·mol−1.

The Acid Roles of PtSn@Al2O3 in the Synthesis and Performance of Propane Dehydrogenation.

In this study, a PtSn/Al2O3 catalyst with bimetallic uniform distribution in the sphere was synthesized. The PDH performance and characterization analyses, such as with FTIR, XPS, and NH3-TPD, were investigated. The effects of acid on the PDH performance were analyzed. Citric acid (CA) acted as a competing adsorbent in the preparation process of the PtSn/Al2O3 catalyst to synthesize the uniform catalyst. Water washing and alkali-treated samples were also studied. SEM line scanning revealed that increased the apparent concentration of Pt metal from 0.23 to 0.30 with citric acid. In contrast to the fresh PtSn/Al2O3 catalyst, the addition of citric acid increased the PDH selectivity from 74% to 93%. After alkali or water washing treatments, the catalyst's selectivity further increased to 96%. Strong acid sites promoted the breaking of C-C bonds during the PDH reaction, resulting in more methane and ethylene byproducts, and decreased catalyst selectivity for fresh PtSn/Al2O3. From the PDH reaction thermodynamic analysis, a relatively sub-atmospheric pressure environment with a lower propane pressure could be the reasonable choice.

Microdroplet-accelerated cycloaddition of gaseous phenylacetylene and indoline derivatives to form tricyclic quinolines

Microdroplets have exhibited distinct acceleration effects on many reactions, but most of which involve dissolved reactants within the droplets. Here, we modified a sub-atmospheric pressure electrospray ionization source (SAP-ESI) as a reactor to perform the cycloadditions of gaseous phenylacetylene and indoline derivatives to yield tricyclic quinolines. The reactions were found to proceed rapidly with the assist of charged microdroplets in a nitrogen atmosphere. Real-time and on-site capture of the intermediates and products by mass spectrometry reveals the reaction mechanism at the microdroplet interface, which is somewhat different from the conventional catalytic cycloaddition processes. In particular, the radical cations of dimer phenylacetylenes are first generated in microdroplets and then promote the catalyst-free cycloaddition. This research showcases the new potential of microdroplet chemistry to advance gas-phase reactions.

Prediction of the influence of pressure on flash points of liquid fuels at sub-atmospheric pressure

Aircraft fuel tanks experience sub-atmospheric pressure during flight, and so do fuels during storage and transportation at high altitudes. Additionally, chemical processes commonly operate at non-atmospheric pressure. Flash points measured at sub-atmospheric pressure are lower than those measured at the standard atmospheric pressure of 101.3 kPa, signifying that ignitable liquids at sub-atmospheric pressure are more hazardous than those at 101.3 kPa. This study developed a model for predicting the influence of pressure on flash points on the basis of basic thermodynamic characteristics; this model was validated against experimental data obtained from the literature for six single-component and multiple-component liquid fuels at sub-atmospheric pressure. The proposed model effectively predicts closed-cup flash points, with small deviations in the range 0.18 °C–1.25 °C. However, because the model's assumption of vapor–liquid equilibrium was violated in the experiments, the predicted open-cup flash points did not agree well with their experimental counterparts, with the deviations in the range 1.11 °C–12.55 °C. Nevertheless, the trends predicted by the model agreed with those in the experimental data. Furthermore, standard flash point test method (such as ASTM D56-22, ASTMD93-20, and ASTMD7094-17) are based on a linear formula for correcting flash points measured at pressures other than 101.3 kPa. When the ambient pressure is approximately 101.3 kPa during flash point testing, the slope value of the correction formula should be changed from 0.25 to 0.20.

Explore the feasibility of electrospray ionization high-resolution mass spectrometry in elemental analysis

As a representative soft ionization technique, electrospray ionization (ESI) is commonly applied for the analysis of organic and biological compounds and is less used in inorganic applications. This study introduces the performance of ESI high-resolution mass spectrometry (HRMS) in the detection of elements. The HRMS instrument was equipped with a sub-atmospheric pressure (SAP) ESI source to reduce sample consumption and simplify the sampling operations. In addition, in-source collision-induced dissociation (IS-CID) was introduced into the analysis to generate simple metallic ion species such as atomic ions and charged oxides and reduce organic peak interferences. Various solutions containing metal salts and organometallic compounds were analyzed, demonstrating a picogram-level absolute detection limit and accurate multi-element identification capability of the instrument. Furthermore, SAP-ESI-HRMS exhibits diverse analytical performances, enabling both elemental and organic analyses by simply regulating the IS-CID energy in the measurement.