Styrene Ethylene Butylene Research Articles

Flexible mechano-optical dual-responsive perovskite molecular ferroelectric composites for advanced anticounterfeiting and encryption.

Hybrid organic-inorganic molecular ferroelectrics have emerged as promising materials for multifunctional piezoelectric devices. However, they present challenges in practical applications because of their inherent brittleness and poor ductility. Herein, we present a flexible mechano-optical dual-responsive molecular ferroelectric composite by incorporating trimethylchloromethyl ammonium (TMCM)-MnCl3 into styrene ethylene butylene styrene (SEBS) matrix. The SEBS/TMCM-MnCl3 exhibits excellent stretchable mechanical properties (tensile strain >1300%, thickness of 30 μm), piezoelectricity, and photoluminescence, enabling advanced visual-tactile-fused anticounterfeiting and encryption applications. Anticounterfeiting and antitampering tags are developed to judge whether the valued items are true or tampered with based on pattern recognition and piezoelectric response, respectively. Additionally, high-security password keyboards featuring triple-layer encryption are designed, offering more password combinations (524,288 times greater than those of traditional password devices relying solely on digital encryption) and enhanced security reliability against cracking attempts. This work can inspire designs of multifunctional optoelectronic materials and enable visual-tactile-fused intelligent applications in human-machine interfaces, information security, and advanced robotics.

Research on temperature control of smartwatch based on composite phase change material

The smartwatch is one of the most widely used wearable electronics, which combines networking, health monitoring, communication, and other multifunctional features. As it gets smaller, more integrated, and denser, its power consumption increases. Owing to its strong sealing and waterproof capabilities, the equipment has trouble dissipating the heat produced during operation, which raises the equipment's temperature. Since smartwatches come into direct contact with human skin, they can burn skin when temperatures rise beyond 45 °C. Phase change material (PCM) is suitable for thermal management of intermittent electronic devices because they absorb a large amount of heat and can maintain a constant temperature during the phase transition, which means that they absorb heat when the device is in use and release heat when it is out of use. In this study, paraffin wax (PA) is used as the phase change material, styrene ethylene butylene styrene (SEBS) is used as the flexible support material, and expanded graphite (EG) is used as the thermal conductivity enhancer to prepare PCM sheets for thermal management of smartwatches. The effects of SEBS and EG on the shape stability, enthalpy, and thermal conductivity of the composite phase change material (CPCM) with different ratios were investigated, in which PA:SEBS of 7:3 has better shape stability, so CPCM with a PA:SEBS ratio of 7:3 and different EG contents was used to make PCM sheet, which were placed in the smartwatch, and it was verified experimentally that this PCM sheet could delay the temperature rise of the case and chip of the smartwatch and prolong its usage time. This CPCM is promising for smartwatch thermal management applications.

Effects of ultraviolet and thermal oxygen ageing on the rheological properties of SEBS/MWCNTs composite-modified asphalt

To enhance the anti-ageing properties of asphalt binder, multiwalled carbon nanotubes (MWCNTs) and styrene-ethylene-butylene-styrene (SEBS) were used to create a composite-modified asphalt (CMA). The ageing resistance was assessed through rheological property changes, using a dynamic shear rheometer (DSR) for various tests. FTIR spectroscopy analyzed the ageing mechanism. The results showed that CMA exhibited significantly better rutting resistance than matrix and SBS asphalt. Although the fatigue life of CMA was lower than SBS asphalt, ist was still dramatically higher than matrix asphalt. MWCNTs reduced the low-temperature relaxation performance of unaged asphalt. Notably, CMA showed superior ageing resistance against both thermal oxygen and UV ageing, with decreases of about 30% and 28% in the UV ageing index and long-term ageing index, respectively, compared to matrix asphalt. The carbonyl and sulfoxide indices increased after ageing, with the composite containing 3% SEBS demonstrating optimal ageing resistance and road performance.

Development of High-Aspect-Ratio Soft Magnetic Microarrays for Magneto-Mechanical Actuation via Field-Induced Injection Molding.

Magnetorheological elastomers (MREs) are in demand in the field of high-tech microindustries and nanoindustries such as biomedical applications and soft robotics due to their exquisite magneto-sensitive response. Among various MRE applications, programmable actuators are emerging as promising soft robots because of their combined advantages of excellent flexibility and precise controllability in a magnetic system. Here, we present the development of magnetically programmable soft magnetic microarray actuators through field-induced injection molding using MREs, which consist of styrene-ethylene/butylene styrene (SEBS) elastomer and carbonyl iron powder (CIP). The ratio of the CIP/SEBS matrix was designed to maximize the CIP fraction based on a critical solids loading. Further, as part of the design of the magnetization distribution in micropillar arrays, the magnetorheological response of the molten composites was analyzed using the static and dynamic viscosity results for both the on and off magnetic states, which reflected the particle dipole interaction and subsequent particle alignment during the field-induced injection molding process. To develop a high-aspect-ratio soft magnetic microarray, X-ray lithography was applied to prepare the sacrificial molds with a height-to-width ratio of 10. The alignment of the CIP was designed to achieve a parallel magnetic direction along the micropillar columns, and consequently, the micropillar arrays successfully achieved the uniform and large bending actuation of up to approximately 81° with an applied magnetic field. This study suggests that the injection molding process offers a promising manufacturing approach to build a programmable soft magnetic microarray actuator.

Photochromic and photo-regulated fluorescent coordination polymers derived from thiazolothiazole extended viologen in solid state and polymer film

In this study, we addressed the efforts of controlling the structures of coordination polymers (CPs) for enhanced photochromism by modulating interactions between electron donors (EDs) and acceptors (EAs) or boosting EAs' electron affinity. Two new CPs, [Cd (TTVP)0.5 (2,6-NDC) (H2O)]·0.5DMF (1) and [Cd (TTVP)0.5 (4,4′-BPC) (H2O)2]·0.5H2O (2) have been successfully synthesized using the thiazolothiazole extended viologen ligand TTVP (TTVP = 2,5-bis(pyridinium-4-yl)thiazolo [5,4-d]thiazole propionate) as an EA and different aromatic carboxylic acids as EDs. Complex 1 features a 3D supramolecular structure with interpenetrating layers with n-π and π-π interactions, while complex 2 adopts a 2D structure with layer stacking through n-π interactions. Both CPs exhibit notable photochromism via photo-introduced electron transfer (PIET) process, with different ED/EA arrangements (ED-EA-ED-EA for 1 and ED-EA-ED for 2) affecting their photoresponse. UV irradiation reveals varying photochromic response rates and color contrasts in the two CPs, highlighting EDs' influential role. Furthermore, both CPs showed a synergistic response of photochromism and photo-controlled fluorescence. Notably, a composite polymer film with reversible photochromic and photo-controlled fluorescence behaviors was fabricated by integrating compound 1 into a styrene ethylene butylene styrene (SEBS) matrix. This study presents a new approach for improving the performance of photochromic materials with potential applications in daily life.

Statistical modeling and optimization of process parameters for additive manufacturing of styrene–ethylene–butylene–styrene block copolymer parts using solvent cast 3D printing technique

AbstractAdditive manufacturing of thermoplastic elastomers is challenging using fused deposition modeling due to their high melt viscosity, low column strength, and poor fusion among layers. Solvent‐cast 3D printing (SC‐3DP) is an efficient alternative to successfully 3D print such materials. However, selection of suitable 3D printing parameters is crucial to realize parts with optimum physicomechanical properties. In this work, statistical modeling and SC‐3DP parameter optimization for styrene–ethylene–butylene–styrene (SEBS) block copolymer were performed. The effect of 3D printing process parameters on shrinkage, relative density, and tensile strength was analyzed using response surface methodology. Experiments were planned as per central composite design and analysis of variance was performed to evaluate the significant parameters. SEBS content in the polymer solution significantly affected the shrinkage of SC‐3DP samples. Moreover, relative density and tensile strength were significantly affected by print speed and layer height. A significant interaction between print speed and layer height was also noticed for tensile strength and relative density of printed samples. Multi‐objective optimization using genetic algorithm was also performed to minimize shrinkage and maximize relative density and tensile strength. Finally, a case study was conducted comparing the physicomechanical properties of SC‐3DP samples printed at optimized process parameters and compression molded samples.Highlights Statistical models were developed using response surface methodology. Genetic algorithm based multi‐objective optimization was performed. Optimum solvent‐cast 3D printing (SC‐3DP) process parameters were determined.

Magnetorheological and magnetic actuation behaviour of solvent cast 4D printed styrene-ethylene-butylene-styrene block copolymer based magnetorheological elastomeric materials

In this work styrene-ethylene-butylene-styrene (SEBS) block copolymer based smart magnetorheological elastomeric (MREs) materials have been additively manufactured using solvent-cast 4D Printing (SC-4DP) technique. The effect of carbonyl iron powder (CIP) content on the particle distribution, particle–matrix adhesion, surface and layer morphology of the 4D Printed MRE sample was investigated. CIP particles were observed to be well embedded and dispersed up to 60 wt% content. However, at higher CIP content the tendency of the particles to agglomerate increased significantly. Furthermore, samples with CIP content ≥70 wt% showed poor particle–matrix adhesion and possessed inter-layer coalescence defects. Investigations were also performed to evaluate the magnetic properties of MREs at room temperature. Magnetorheological behaviour was studied to evaluate the effect of varying magnetic field on dynamic viscoelastic properties. Magnetorheological effect increased from ∼79 % to ∼211 % with an increase in CIP content. However, the particle–matrix adhesion also significantly affected the magnetorheological effect for higher CIP content samples. Magnetic actuation capability of flexible MRE samples was evaluated for gripper-based application. SC-4D Printed flexible grippers were able to successfully grip, lift, and drop both the soft deformable and rigid freeform profile objects in different media (air and sodium hydroxide solution) suggesting suitability for remotely actuated gripper-based applications.

Organic long-persistent luminescence materials with stretchability enabled by SEBS

Polymer-based organic long-persistent luminescence materials (OLPLMs) with good stretchability have attracted considerable attention due to their effective response to environmental stimuli and wide selection of application scenarios. However, the lack of a suitable stretchable polymer matrix has been a major limitation in the development of strongly stretchable OLPLMs. Here, we present a straightforward and universal method to fabricate a stretchable afterglow effect under ultraviolet or visible light by blending the flexible polymer styrene-ethylene-butylene-styrene (SEBS) with various phosphors that display superior stretchability compared to the reported OLPLMs. To further highlight the outstanding benefits of such stretchable OLPLMs in the field of security applications, we show their practical cases in safety warning, identity recognition and oxygen detection scenarios. This universal material preparation strategy will simplify the production of stretchable OLPLMs and broaden the application range of phosphors or luminescent dyes.

A Breathable and Strain‐Insensitive Multi‐Layered E‐Skin Patch for Digital Healthcare Wearables

AbstractIn this study, a breathable and strain‐insensitive multi‐layered electronic skin (e‐skin) capable of real‐time detection and distinction of electrocardiogram (ECG) signals, temperature, and skin hydration is developed. Leveraging a scalable benchtop method, sensing elements are transferred onto porous and hydrophobic substrates, followed by multi‐layer stacking to enable multimodal sensing. The sensing elements, a combination of carbon nanotube and nanoporous carbon (CNT@NPC) ink, are applied using strain‐insensitive patterned masks, then spray‐coated with styrene–ethylene–butylene–styrene (SEBS) to create a hierarchical porous network through phase separation. The CNT@NPC networks exhibit an improvement in strain insensitivity with active sensing capabilities due to their adaptable molecular tuning capacity and exceptional electrical conductivity. The porous SEBS substrate offers strong bonding with CNT@NPC attributed to the π–π interactions and high kinetic energy dispersion from spray coating allowing effective transfer. This unique design facilitates breathability, and miniaturization that minimizes the interference between different sensing modalities, ensuring accurate and reliable data acquisition. The breathability (3.49 mg cm−2 h−1) and the non‐smearing nature of the multi‐layered e‐skin enables simultaneous monitoring of temperature (0.198% °C−1), skin hydration (relative humidity = 0.77% %−1), and ECG (26 ± 1 dB) with continuous data transmission to a remote smartphone interface.

BEAD SIZE AND RHEOLOGICAL PROPERTIES OF SEBS-BASED ELASTIC BEADS

ABSTRACT Styrene–ethylene–butylene–styrene (SEBS) is a thermoplastic elastomer that has applications in robotics and shock absorption. Although SEBS as a bulk material as well as an additive to solid composites has been extensively studied, this work focuses on developing SEBS-based beads to enhance material elasticity. SEBS bead mixtures were developed by mixing SEBS elastomer, water, and surfactant (Triton X-100) at high temperature. Stability, rheology, and microscopy of SEBS bead mixtures were studied as a function of neat SEBS concentration in SEBS elastomer, SEBS elastomer concentration, and surfactant concentration. Resulting bead mixtures were classified as creamed, homogenous and stable, or aggregated based on the mixture’s tendency to separate into layers and its ability to disperse in excess water. Microscopic studies suggest that although bead mixtures exhibit size polydispersity, the average bead size is a strong function of neat SEBS, SEBS elastomer, and surfactant concentrations. Rheological studies suggest that all the bead mixtures exhibit shear thinning behavior, and the overall viscosity of a given bead mixture is a function of both SEBS elastomer and surfactant concentration. The developed SEBS elastic beads can be used as additives to enhance the viscoelastic properties of fluid-based systems such as magnetorheological and damping fluids.

Room-temperature flexible phase change material with high emissivity and high enthalpy for building energy saving

Summer heatwave events become more and more frequent, building cooling load continues to rise, and the traditional cooling method using air conditioning consumes a lot of energy. New technologies and materials with high efficiency, energy saving and low cost are urgently needed to solve the problem of high energy consumption in buildings. In this paper, by combining phase change storage technology with passive cooling technology of sky radiation, a new type of high-emission flexible composite phase change material (CPCM) was prepared using polypropylene hollow fiber (PP hollow fiber), Styrene-Ethylene-Butylene-Styrene (SEBS) and paraffin wax (PA). The prepared CPCM with excellent thermophysical properties, including a latent heat of 175.19 J/g, room temperature flexibility, the contact angle of the hydrophobic test of 129.15°, and the infrared emissivity of the atmospheric window of 0.942. The cooling experiment results show that the maximum temperature difference between CPCM and the environment is 2.6 °C lower than the ambient temperature. In addition, the simulation results show that the external surface temperature of the CPCM roof can be reduced by 23.15 K at the highest compared with a common roof, and the maximum energy saving can reach 13.24 W/m2. Compared with the high emissivity roof without CPCM, the external surface temperature is further reduced by 0.47K, the delay time is 50min, and the maximum energy saving can reach 0.76 W/m2. It's worth getting excited that CPCM can delay the opening time of air conditioning for 10 days. In addition, the application efficiency of cities in typical climate regions is simulated, and outstanding energy-saving efficiency is obtained, among which the maximum saving energy in Guangzhou is as high as 20.16 W/m2. The successful preparation of the novel CPCM material provides a new direction for the development of radiation-cooling technology.

Investigation of Toughening Mechanisms in Elastomeric Polycarbonate Blends through Morphological and Mechanical Characterization at Small and Medium Strain Rates.

Despite polycarbonate (PC) being a widely used engineering plastic, its notch and crack sensitivity pose challenges in critical applications. To address this, PC was blended with elastomeric polymers to explore the improvement in toughness. This study systematically investigates the toughening mechanisms of PC blended with acrylonitrile-butadiene-styrene (ABS), copolyether ester elastomer (COPE), and ABS and styrene-ethylene-butylene-styrene (SEBS) copolymer grafted with maleic anhydride (MA). The morphology and mechanical behavior were evaluated under quasi-static and medium-strain-rate tensile tests and Charpy impact tests using optical, electronic, and atomic force microscopy and Raman mapping spectroscopy. The morphological analysis reveals cavitation and crazing phenomena for COPE and SEBS-g-MA systems, and mostly debonding for ABS, indicating an improvement in toughening. While the addition of ABS improves the PC plastic deformation, modifying ABS with maleic anhydride enhances the elastic modulus. Blending PC with SEBS-g-MA increases the strain at break, and the addition of COPE significantly improves the deformation behavior of PC (by around 115%). This comparative study provides valuable insights into the performance of different PC-elastomer blends under similar conditions, supporting the selection of appropriate materials for given applications.

Fused deposition modeling of polyethylene (PE): Printability assessment for low-density polyethylene and polystyrene blends

There is a global emphasis on recycling and reuse of plastic waste. Despite constituting over one-third of the world's annual plastic production, only 10 % of polyethylene is recycled. This study explores the use of fused deposition modeling (FDM) to enable the recycling of industrial waste of low-density polyethylene (LDPE) blended with expanded polystyrene (EPS). Two LDPE/EPS ratios (50/50 and 70/30) were investigated, and two types of styrene-ethylene-butylene-styrene (SEBS) rubber were incorporated as compatibilizers. The mechanical, rheological, thermal, and morphological properties of these blends were analyzed to assess their printability. Results indicate that the use of SEBS enhances the mechanical properties, thermal stability, and morphological uniformity of the blends. Particularly, malleated SEBS exhibited superior compatibilizing ability, fostering strong interactions at the LDPE/EPS interface. The best blend, based on printability assessments, was the 50/50 LDPE/EPS ratio with a 5 wt% malleated SEBS. Consequently, this blend was extruded into feedstock filaments, and it was successfully printed via FDM. The proposed blends are anticipated to perform effectively in various applications and serve as a foundation for future development of wear-resistant materials. The outcomes of this study present a novel approach for upcycling LDPE waste while promoting sustainable FDM practices.

An electric conductive wide-temperature flexible phase change material for all-climate battery thermal management

Battery thermal management with phase change materials (PCM) has been limited by leakage, low thermal conductivity and rigidity, and the inability to preheat at low temperatures. To solve these problems, a wide-temperature flexible composite PCM (FCPCM) was prepared with a high-temperature open refining method. Styrene ethylene butylene styrene (SEBS) and expanded graphite (EG) absorb paraffin (PA) onto a three-dimensional network. The FCPCM possesses good flexibility before and after phase transition. It can be bent and stretched arbitrarily at room temperature, and the shape memory function enable it can be restored to its original state after heating. The latent heat of the FCPCM-15 is 159.9 J/g and its thermal conductivity was 7.45 times higher than that of pure paraffin. The FCPCM also possesses a good volume conductivity of 92–2952 S/m and allows for uniform electrical heating. The excellent thermal and electrical performance of the FCPCM allows it to cool batteries at high temperatures and preheat batteries at low temperatures. After ten charge/discharge cycles at 30 °C, the battery pack’s temperature based on FCPCM cooling is still reduced by 3.9 °C. At a low temperature of −20 °C, the preheating rate of the battery pack can reach 12.9 °C/min, and the discharge voltage and capacity of the battery pack were increased by 15 % and 20.8 % after preheating. The FCPCM suggests a promising and practical approach way for the all-climate thermal management of batteries.

Tailoring physicochemical properties of quaternized polystyrene-ethylene/butylene-styrene membrane for enhanced pervaporation desalination

Pervaporation offers unique advantages for desalination of hypersaline water using highly hydrophilic and selective membrane. Positively charged membrane is superior in repelling cations and preventing scaling through electrostatic repulsion. This study investigates the quaternization and crosslinking of block copolymer styrene-ethylene-butylene-styrene (SEBS) membrane and explores the potential of quaternized membrane for pervaporation desalination. A one-step immersion process was proposed to easily adjust the physicochemical properties of membrane using trimethylamine (TMA) and N,N,N′,N′-tetramethyl-1,6-hexanediamine (TMHDA) for ammonium grafting and crosslinking. Compared to the quaternization with TMA or TMHDA alone, the combination of TMA and TMHDA produces a synergistic effect, improving crosslinking efficiency and facilitating the grafting reaction. This results in high ion exchange capacity (IEC) values and a transformation of microphase separation structure with more interconnected hydrophilic domains. An ultrahigh water permeability coefficient of 0.6 × 106–1.2 × 106 Barrer and highly intrinsic salt rejection were obtained in treating 3.5–20 wt% NaCl solution. The thin film composite QEBS/nylon membranes showed a superior water flux of 116.5 kg·m−2·h−1 and salt rejection of >99.99 % in desalinating 5 wt% NaCl solution at 85 °C. Additionally, the membrane exhibited excellent long-term performance stability and resistance to acid and alkali environment, showing great potential for desalination of hypersaline water.

SISAL FIBER REINFORCED AND CENOSPHERE HYBRIDIZED POLYPROPYLENE-SEBS COMPOSITE: AN INSIGHT INTO CRYSTALLOGRAPHIC, DYNAMIC MECHANICAL AND RHEOLOGICAL BEHAVIOR.

The current study attempts to explore the crystallographic, rheological and dynamic mechanical properties of the submicron-treated cenosphere (t- CSF) particles and sisal fiber (SF) reinforced Styrene-(Ethylene-Butylene)-Styrene (SEBS) toughened PP hybrid composites. Moreover, the composites reinforced with 25 wt.% of SF and 5 wt.% of CSF (Treated 6 wt.% cetrimonium bromide (CTAB)) demonstrated the most significant storage modulus (E'), loss modulus (E"), and lowest damping (tan δ) factor throughout the temperature range. Likewise, X-ray diffraction techniques were used to assess the samples' crystallographic properties. The composites reported an enhanced β phase (responsible for high impact strength and reduced α phase of the base matrix compared to pristine PP. Likewise, all the composites' rheological properties showed an improved complex viscosity (η*) compared to the BM but lower than that of the pristine PP. Overall processing parameters of the BM and composites were improved due to the decrement in the η* of all the composites. The rheological properties confirmed the easy processing of the fabricated composites due to the improved flowability. The storage (G') and loss (G") modulus of all the composites were desirably higher than that of the BM.

Optical tuning of copolymer-in-oil tissue-mimicking materials for multispectral photoacoustic imaging

Objective. The availability of tissue-mimicking materials (TMMs) for manufacturing high-quality phantoms is crucial for standardization, evaluating novel quantitative approaches, and clinically translating new imaging modalities, such as photoacoustic imaging (PAI). Recently, a gel comprising the copolymer styrene-ethylene/butylene-styrene (SEBS) in mineral oil has shown significant potential as TMM due to its optical and acoustic properties akin to soft tissue. We propose using artists’ oil-based inks dissolved and diluted in balsam turpentine to tune the optical properties. Approach. A TMM was fabricated by mixing a SEBS copolymer and mineral oil, supplemented with additives to tune its optical absorption and scattering properties independently. A systematic investigation of the tuning accuracies and relationships between concentrations of oil-based pigments and optical absorption properties of the TMM across visible and near-infrared wavelengths using collimated transmission spectroscopy was conducted. The photoacoustic spectrum of various oil-based inks was studied to analyze the effect of increasing concentration and depth. Main results. Artists’ oil-based inks dissolved in turpentine proved effective as additives to tune the optical absorption properties of mineral oil SEBS-gel with high accuracy. The TMMs demonstrated long-term stability and suitability for producing phantoms with desired optical absorption properties for PAI studies. Significance. The findings, including tuning of optical absorption and spectral shape, suggest that this TMM facilitates the development of more sophisticated phantoms of arbitrary shapes. This approach holds promise for advancing the development of PAI, including investigation of the spectral coloring effect. In addition, it can potentially aid in the development and clinical translation of ultrasound optical tomography.

Insulator Polymer Matrix Construction on All-Small-Molecule Photoactive Blend Towards Extrapolated 15000 Hour T80 Stable Devices.

To boost the stability of all-small-molecule (ASM) organic photovoltaic (OPV) blends, an insulator polymer called styrene-ethylene-butylene-styrene (SEBS) as morphology stabilizer is applied into the host system of small molecules BM-ClEH:BO-4Cl. Minor addition of SEBS (1mg/ml in host solution) provides a significantly enhanced T80 value of 15000 hours (extrapolated), surpassing doping-free (0mg/ml) and heavy doping (10mg/ml) counterparts (900 hours, 30 hours). The material reproducibility and cost-effectiveness of the active layer will not be affected by this industrially available polymer, where the power conversion efficiency (PCE) can be well maintained at 15.02%, which is still a decent value for non-halogen solvent-treated ASM OPV. Morphological and photophysical characterizations clearly demonstrate SEBS's pivotal effect on suppressing the degradation of donor molecules and blend film's crystallization/aggregation reorganization, which protects the exciton dynamics effectively. This work pays meaningful attention to the ASM system stability, performs a smart strategy to suppress the film morphology degradation, and releases a comprehensive understanding of the mechanism of device performance reduction.

A high-performance TFN membrane prepared by a novel PE support layer, a polydopamine interlayer, and a doped MoS2 quantum dots@ZnO nanocomposites-incorporated polyamide active layer

Herein, thin film nanocomposite (TFN) membranes were prepared with excellent chemical stability and separation performance for organic solvent nanofiltration (OSN) applications. The support membrane was synthesized via a new approach, in which a blend of two immiscible polymers, i.e. high density polyethylene (HDPE)-polystyrene (PS), which were compatibilized with styrene-ethylene-butylene-styrene (SEBS), was prepared through mixing by a Brabender, followed by fabricating blend sheets through a hot press machine. The PE support was then prepared by extracting the PS/compatibilizer phase from the blend sheet. The hydrophilicity of the PE support membrane was considerably enhanced with a polydopamine (PDA) layer. Different nanoparticles including nanoflower (NF) ZnO, nanosphere (NS) ZnO, MoS2 Quantum dots-nanoflower ZnO nanocomposite (QDs@NF ZnO), and MoS2 Quantum dots-nanosphere ZnO nanocomposite (QDs@NS ZnO) were incorporated into the polyamide (PA) active layer of the membranes to enhance the performance of the TFN membranes. The separation performance of the TFN membranes was investigated for rejecting different dyes dissolved in methanol. Our results demonstrate outstanding separation performance, with a dye rejection of 99.6 %, 99.6 %, 99.8 %, and 99.9 % for methylene blue, crystal violet, rhodamine B, and methyl green, respectively. Additionally, the TFN membranes incorporated with QDs@NF ZnO nanoparticles showed great solvent resistance, with a methanol permeance up to 6.7 L/m2.h.bar after activation with dimethylformamide.

Fabrication of Triblock Elastomer Foams and Gelation Studies for Oil Spill Remediation.

Polymeric foamed materials are among the most widely utilized technologies for oil spill accidents and releases of oil-contaminated wastewater oil due to their porosity to absorb and separate oil/water effectively. However, a major limitation of traditional polymeric foams is their reliance on an ad/absorption mechanism as the sole method of oil capture, leading to potential oil leakage once their saturation point is exceeded. Tri-block polymer styrene-ethylene-butylene-styrene (SEBS) is a fascinating absorbent material that can bypass this limitation by both capturing oil and providing a sealing mechanism via gelation to prevent oil leakage due to its unique chemical structure. SEBS foams are produced via simultaneous crosslinking and foaming that results in an impressive expansion ratio of up to 15.2 with over 93% porosity. Most importantly, the SEBS foams show great potential as oil absorbents in spill remediation, demonstrating rapid and efficient oil absorption coupled with superhydrophobic properties. Moreover, the unique interaction between the oil and SEBS enables the formation of a physical gel, acting as an effective barrier against oil leakage. These findings indicate the potential for commercializing SEBS foam as a viable option for geotextiles to mitigate oil spill concerns from infrastructures.