Butadiene Styrene Research Articles

Preparation of Poly(Butadiene–Styrene–Vinyl Pyridine)/Poly(Acrylonitrile–Butadiene) Core–Shell Nanoparticles by Intermittent Seeded Emulsion Polymerization and Their Catalytic Latex Hydrogenation

Preparation of Poly(Butadiene–Styrene–Vinyl Pyridine)/Poly(Acrylonitrile–Butadiene) Core–Shell Nanoparticles by Intermittent Seeded Emulsion Polymerization and Their Catalytic Latex Hydrogenation

Fatigue response of multiscale extrusion-based additively manufactured acrylonitrile butadiene styrene-graphene nanoplatelets composites

This study investigates the effect of varying concentrations of graphene nanoplatelets (GNPs) on the mechanical and fatigue characteristics of acrylonitrile butadiene styrene (ABS)/GNPs nanocomposites, both in filament form and as 3D-printed parts with different raster orientations. Quasi-static and cyclic loading tests were performed on specimens containing 0.1 wt%, 0.5 wt%, 1.0 wt%, and 2.0 wt% GNPs. The results indicated that the addition of 0.1 wt% GNPs to the ABS polymer matrix increased the ultimate tensile strength (UTS) of the filament by 18 %. Addition of 1.0 wt% and 2.0 wt% GNPs to the matrix improved the Young's modulus of the filament by up to about 35 % but did not enhance the UTS. The filament containing 0.5 wt% GNPs demonstrated the highest fatigue life, even higher than that of the standard samples fabricated through injection molding technique. This was due to its high static strength, Young's modulus, and ductility. However, when the ABS/GNPs nanocomposites were 3D-printed, the addition of GNPs had no major impact on their fatigue life, especially in the higher load levels. Inadequate adhesion and reduced interlayer bonding strength resulted in a detrimental impact on fatigue life of 3D-printed objects. The extrudate-swell phenomenon seems to significantly affect this reduction in fatigue life. To address this, larger nozzle diameter (0.6 mm) was used in fabricating 3D-printed samples. Results indicated that samples with less distortion and smaller extrudate-swell had higher fatigue life. It highlights the importance of considering GNP concentration and printing parameters for optimal fatigue properties in ABS/GNPs composites.

An Antimicrobial Copper-Plastic Composite Coating: Characterization and In Situ Study in a Hospital Environment.

A method has been proposed for creating an operationally durable copper coating with antimicrobial properties for the buttons of electrical switches based on the gas dynamic spray deposition of copper on acrylonitrile butadiene styrene (ABS) plastic. It is shown that during the coating process, a polymer film is formed on top of the copper layer. Comparative in situ studies of microbial contamination have shown that the copper-coated buttons have a significant antimicrobial effect compared to standard buttons. Analysis of swabs over a 22-week study in a hospital environment showed that the frequency of contamination for a copper-coated button with various microorganisms was 2.7 times lower than that of a control button. The presented results allow us to consider the developed copper coating for plastic switches an effective alternative method in the fight against healthcare-associated infections.

High-temperature energy storage with a new tri-layers polymer composites via hybrid assembly engineering

Dielectric film capacitors are fundamental components in advanced electrical fields such as smart grids and hybrid electric vehicle. The commercial film capacitors made by biaxially oriented polypropylene (BOPP) have high energy efficiency, but low energy density of only 2.0-3.0 J/cm3, while the inferior thermal stability restricts their high temperature applications. In this work, hybrid assembly engineering is proposed to design composite films with a new polymer of poly(acrylonitrile butadiene styrene) (ABS) as the matrix, boron nitride nanosheets (BNNS) and Na0.5Bi0.5TiO3-Sr0.7Bi0.2TiO3 (NBT-SBT) as two different fillers to improve high-temperature performance. The optimized composites SBS (NBT-SBT/ABS composites layer in the outside and BNNS/ABS composites layer in the middle) exhibit excellent high temperature energy storage characteristics, and its underlying mechanism is also understood by phase-field simulations. In particular, the maximum energy density at 120 °C can reach 15.0 J/cm3 at 575 MV/m, which is 8 times that of BOPP, while the efficiency is maintained at 89 %, far exceeding the performance of BOPP (<70 % at 120 °C). Together with their excellent cycling reliability (106 cycles) and thermal stability, this strategy shows a great potential for high-temperature and high-power energy storage capacitors.

Consumer products are important reservoirs and sources of organophosphate tri-esters and di-esters: Characteristics, mass inventory, and implication for waste management

Numerous studies documented the occurrence of organophosphate tri-esters (tri-OPEs) and di-esters (di-OPEs) in the environment. Little information is available on their occurrence in waste consumer products, reservoirs and sources of these chemicals. This study collected and analyzed 92 waste consumer products manufactured from diverse polymers, including polyurethane foam (PUF), polystyrene (PS), acrylonitrile butadiene styrene (ABS), polypropylene (PP), and polyethylene (PE) to obtain information on the occurrence and profiles of 16 tri-OPEs and 10 di-OPEs. Total concentrations of di-OPEs (18−370,000 ng/ g, median 1,700 ng/g) were one order of magnitude lower than those of tri-OPEs (94−4,500,000 ng/g, median 5,400 ng/g). The concentrations of both tri- and di-OPEs in products made of PUF, PS, and ABS were orders of magnitude higher than those made of PP and PE. The compositional patterns of OPEs varied among different polymer types but were generally dominated by bisphenol A bis(diphenyl phosphate), triphenyl phosphate, tris(1-chloro-2-propyl) phosphate, di-phenyl phosphate (DPHP), and bis (2-ethylhexyl) phosphate. Two industrially applied di-OPEs (di-n-butyl phosphate and DPHP) exhibited higher levels than their respective tri-OPEs, contrary to their production volumes. Some non-industrially applied chlorinated di-OPEs were also detected, with concentrations up to 97,000 ng/g. These findings suggest that degradation of tri-OPEs during the manufacturing and use of products is an important source of di-OPEs. The mass inventories of tri-OPEs and di-OPEs in consumer products were estimated at 3,100 and 750 tons/year, respectively. This study highlights the importance of consumer products as emission sources of a broad suite of OPEs.

Bio-synthesized TiO2 nanoparticles and the aqueous binder-based anode derived thereof for lithium-ion cells.

Titanium dioxide nanoparticles (TiO2-NPs) are a promising anode material for Lithium-ion batteries (LIBs) due to their good rate capability, low cost, non-toxicity, excellent structural stability, extended cycle life, and low volumetric change (∼4%) during the Li+insertion/de-insertion process. In the present paper, anatase TiO2-NPs with an average particle size of ~ 12nm were synthesized via a green synthesis route using Beta vulgaris (Beetroot) extract, and the synthesized TiO2-NPs were evaluated as anode material in LIBs. Furthermore, we employed an aqueous binder (1:1 mixture of carboxy methyl cellulose and styrene butadiene) for electrode processing, making the process cost-effective and environmentally friendly. The results revealed that the Li/TiO2 half-cells delivered an initial discharge capacity of 209.7 mAh g-1 and exhibited superior rate capability (149 mAh g-1 at 20 C) and cycling performances. Even at the 5C rate, the material retained a capacity of 82.2% at the end of 100 cycles. The synthesis route of TiO2-NPs and the aqueous binder-based electrode processing described in the present work are facile, green, and low-cost and are thus practically beneficial for producing low-cost and high-performance anodes for advanced LIBs.

The Effects of Printing Temperature on the Mechanical Properties of 3D-Printed Acrylonitrile Butadiene Styrene

The Effects of Printing Temperature on the Mechanical Properties of 3D-Printed Acrylonitrile Butadiene Styrene

Thermo-mechanical aging of carbon-black reinforced styrene-butadiene rubber under cyclic-loading

PurposeThe research aims to investigate the impact of thermo-mechanical aging on SBR under cyclic-loading. By conducting experimental analyses and developing a 3D finite element analysis (FEA) model, it seeks to understand chemical and physical changes during aging processes. This research provides insights into nonlinear mechanical behavior, stress softening and microstructural alterations in SBR compounds, improving material performance and guiding future strategies.Design/methodology/approachThis study combines experimental analyses, including cyclic tensile loading, attenuated total reflection (ATR), spectroscopy and energy-dispersive X-ray spectroscopy (EDS) line scans, to investigate the effects of thermo-mechanical aging (TMA) on carbon-black (CB) reinforced styrene-butadiene rubber (SBR). It employs a 3D FEA model using the Abaqus/Implicit code to comprehend the nonlinear behavior and stress softening response, offering a holistic understanding of aging processes and mechanical behavior under cyclic-loading.FindingsThis study reveals significant insights into SBR behavior during thermo-mechanical aging. Findings include surface roughness variations, chemical alterations and microstructural changes. Notably, a partial recovery of stiffness was observed as a function of CB volume fraction. The developed 3D FEA model accurately depicts nonlinear behavior, stress softening and strain fields around CB particles in unstressed states, predicting hysteresis and energy dissipation in aged SBRs.Originality/valueThis research offers novel insights by comprehensively investigating the impact of thermo-mechanical aging on CB-reinforced-SBR. The fusion of experimental techniques with FEA simulations reveals time-dependent mechanical behavior and microstructural changes in SBR materials. The model serves as a valuable tool for predicting material responses under various conditions, advancing the design and engineering of SBR-based products across industries.

Meta-structure based on coupled resonators for low-frequency broadband sound absorption

This work investigates and explains the behavior of an acoustic meta-structure based on different coupled Helmholtz resonators (HR). The analytical formulation of the Maa model is used to represent both the acoustic impedance and the sound absorption mechanism of the absorber. The structures are numerically modeled using finite element method and validated experimentally in an impedance tube considering sound waves of normal incidence. The absorber samples were manufactured in ABS (acrylonitrile butadiene styrene) polymer material with the additive manufacturing technique by extrusion of material. The results of the impedance tube, numerical and theoretical tests showed agreement and the sound absorber showed a sub-wavelength scale with perfect sound absorption ( 0.97) and broadband of 292 Hz in the low frequency region (200 - 600 Hz). We deduced that the excellent experimental result obtained is due to the high resolution used in the sample manufacturing (± 0.1 mm) which minimized manufacture errors. Finally, the influences of the main parameters of the HR panel (width and depth of the micro-slit) on the sound absorption coefficient of the absorber were also analyzed.

Unlocking the nanoparticle emission potential: a study of varied filaments in 3D printing.

This study investigates nanoparticle emission during 3D printing processes, assessing various filament materials' impact on air quality. Commonly used 3D printers, including both filament and resin-based types, were examined. The study's scope encompasses diverse filament materials like ABS (acrylonitrile butadiene styrene), PLA (polylactic acid), PETG (polyethylene terephthalate glycol), ASA (acrylonitrile styrene acrylate), TPU (thermoplastic polyurethane), PP (polypropylene), nylon, and wood-based variants, alongside three types of resins. The research delves into the relationship between the type of material and nanoparticle emissions, emphasizing temperature's pivotal role. Measurement instruments were employed for nanoparticle quantification, including an engine exhaust particle sizer spectrometer, condensation particle counter, and nanozen dust counters. Notably, results reveal substantial variations in nanoparticle emissions among different filament materials, with ASA, TPU, PP, and ABS showing considerably elevated emission levels and characteristic particle size distribution patterns. The findings prompt practical recommendations for reducing nanoparticle exposure, emphasizing printer confinement, material selection, and adequate ventilation. This study offers insights into potential health risks associated with 3D printing emissions and provides a basis for adopting preventive measures.

Evaluation of the Viability of 3D Printing in Recycling Polymers.

The increased use of plastics in industrial and agricultural applications has led to high levels of pollution worldwide and is a significant challenge. To address this plastic pollution, conventional methods such as landfills and incineration are used, leading to further challenges such as the generation of greenhouse gas emissions. Therefore, increasing interest has been directed to identifying alternative methods to dispose of plastic waste from agriculture. The novelty of the current research arose from the lack of critical reviews on how 3-Dimensional (3D) printing was adopted for recycling plastics, its application in the production of agricultural plastics, and its specific benefits, disadvantages, and limitations in recycling plastics. The review paper offers novel insights regarding the application of 3D printing methods including Fused Particle Fabrication (FPF), Hot Melt Extrusion (HME), and Fused Deposition Modelling (FDM) to make filaments from plastics. However, the methods were adopted in local recycling setups where only small quantities of the raw materials were considered. Data was collected using a systematic review involving 39 studies. Findings showed that the application of the 3D printing methods led to the generation of agricultural plastics such as Polylactic Acid (PLA), Acrylonitrile Butadiene Styrene (ABS), Polyethylene Terephthalate (PET), and High-Density Polyethylene (HDPE), which were found to have properties comparable to those of virgin plastic, suggesting the viability of 3D printing in managing plastic pollution. However, limitations were also associated with the 3D printing methods; 3D-printed plastics deteriorated rapidly under Ultraviolet (UV) light and are non-biodegradable, posing further risks of plastic pollution. However, UV stabilization helps reduce plastic deterioration, thus increasing longevity and reducing disposal. Future directions emphasize identifying methods to reduce the deterioration of 3D-printed agricultural plastics and increasing their longevity in addition to UV stability.

Mechanical Properties and Performance of 3D-Printed Acrylonitrile Butadiene Styrene Reinforced with Carbon, Glass and Basalt Short Fibers.

This paper presents the results of experimental investigation of the mechanical characteristics of 3D-printed acrylonitrile butadiene styrene (ABS) and its modifications reinforced with different types of short-fiber fillers: carbon, glass, and basalt. Elastic modulus, tensile and bending strength, as well as fracture toughness were determined in series of mechanical tests for samples produced with different manufacturing parameters, such as nozzle diameter and infill angle. It was found that the use of ABS filament reinforced with the short fibers can significantly improve the mechanical properties of 3D-printed devices when the infill angle is oriented along the vector of the applied load. In such a case, the elastic modulus and tensile strength can be increased by more than 1.7 and 1.5 times, respectively. The use of a larger nozzle diameter led to the growth of tensile strength by an average of 12.5%. When the macroscopic load is applied along the normal to the printed layers, the addition of short fibers does not give much gain in mechanical properties compared to pure ABS, which was confirmed by both standard tensile and fracture toughness tests. The surface of the fractured samples was examined using scanning electronic microscopy, which allowed us to make conclusions on the type of defects as well as on the level of adhesion between the polymeric matrix and different types of short fibers.

Interrelations between Printing Patterns and Residual Stress in Fused Deposition Modelling for the 4D Printing of Acrylonitrile Butadiene Styrene and Wood–Plastic Composites

Four dimensional printing enables the advanced manufacturing of smart objects that can morph and adapt shape over time in response to stimuli such as heat. This study presents a single-material 4D printing workflow which explores the residual stress and anisotropy arising from the fused deposition modelling (FDM) printing process to create heat-triggered self-morphing objects. In particular, the study first investigates the effect of printing patterns on the residual stress of FDM-printed acrylonitrile butadiene styrene (ABS) products. Through finite element analysis, the raster angle of printing patterns was identified as the key parameter influencing the distribution of residual stresses. Experimental investigations further reveal that the non-uniform distribution of residual stress results in the anisotropic thermal deformation of printed materials. Thus, through the design of printing patterns, FDM-printed materials can be programmed with desired built-in residual stresses and anisotropic behaviours for initiating and controlling the transformation of 4D-printed objects. Using the proposed approach, any desktop FDM printers can be turned into 4D printers to create smart objects that can self-morph into target geometries. A series of 4D printing prototypes manufactured from conventional ABS 3D printing feedstock are tested to illustrate the use and reliability of this new workflow. Additionally, the custom-made wood–plastic composite (WPC) feedstocks are explored in this study to demonstrate the transposability of the 4D printing approach.

A novel strategy to prepare rubber/clay nanocomposites via compounding clay gel into cocoamidopropyl betaine modified styrene butadiene rubber

In this study, high performance styrene-butadiene rubber (SBR)/clay nanocomposites (NCs) modified by cocoamidopropyl betaine (CAPB) are prepared via an efficient and facile strategy. CAPB-modified SBR was compounded with clay gel via gel compounding method to obtain SBR/clay composites. The effect of processing condition and CAPB on the mechanical properties of the SBR/clay composites was investigated. XRD and TEM results show that clay dispersion in SBR matrix is significantly improved due to the success of CAPB in the hydrophilic modification of SBR. The clay-SBR interaction is enhanced and more SBR molecular chains are adsorbed to the clay, significantly improving the mechanical properties of SBR/CAPB/clay NCs, as demonstrated by SEM and DMA. The maximum tensile strength of SBR/CAPB/clay NCs achieved 16.3 MPa at a clay loading of 40 phr, which is 10 times that of pure SBR. The tensile strength of the SBR/CAPB/clay NC incorporated with 20 phr clay has exceeded that of the SBR composite incorporated with 40 phr commercial organic clay. This work demonstrates that this strategy, which combines the CAPB-modification of SBR with the gel compounding method, is an effective and feasible method to improve the mechanical strength of SBR.

Designing Centrifugal Membrane Filters with uniform-pressure for UF/NF/RO separations

A novel Ortho-Centrifugal Membrane Filter (O-CMF) was designed and assessed to tackle common issues in conventional laboratory centrifugal membrane filters, e.g. non-uniform transmembrane pressure and concentration polarization, and to ease membrane replacement. The O-CMF, manufactured by additive 3D printing in acrylonitrile butadiene styrene, with membrane area of 0.95 cm2, was designed to process a maximum liquid sample of 9 mL. It was tested with nanofiltration of aqueous solutions of NaCl, MgSO4, and lactose (concentrations of 1–20 g/L) at transmembrane pressures of 6–24 bar. Complementary Computational Fluid Dynamics (CFD) simulations, employing a custom solver from the open-source OpenFOAM-2306 c++ toolbox, were also run to seek insight of the O-CMF main features.The permeation experiments displayed minimal impact of concentration polarization. CFD simulations showed that concentration polarization is nearly uniform and that concentrate chamber is homogenized by centrifugal convection. The CFD permeate flux predictions, based on the osmotic pressure model, closely matched experimental data, and a correlation for predicting concentration polarization was also developed.The O-CMF device represents a substantial breakthrough in the technology of centrifugal membrane filters, consistently maintaining uniform transmembrane pressure and effectively minimizing concentration polarization. The device was evaluated using nanofiltration, but its pressure range is versatile enough to cover conditions suitable for both ultrafiltration and reverse osmosis operations. This adaptability extends its application across a variety of laboratory experiments, including sample concentration, hydraulic permeability tests, and membrane screening.

Material recycling of acrylonitrile butadiene styrene (ABS) from wiring devices using mechanical recycling

Plastics play a significant role in various sectors by offering advantages such as durability, cost-effectiveness, and lightweight properties. However, the extensive production and consumption of plastics create significant environmental threats, leading to high carbon footprints, global warming, and the accumulation of hard-to-recycle waste. This study explores innovative recycling technologies, focusing on the circular economy and zero waste strategies. In line with this scope, the study aims to conduct research on the reuse of coated plastic materials in production, specifically selecting ABS materials that are difficult to recycle. In the study, wiring devices were prepared using 70% raw ABS (Acrylonitrile Butadiene Styrene) material and 30% recycled ABS (rABS) material, with this cycle being repeated three times. Experiments have been conducted to evaluate the suitability and performance of recycled ABS material for mass production. The results have revealed a slight decrease in tensile strength and impact strength compared to raw ABS material, yet significant mechanical performance has been maintained, thus demonstrating the viability of rABS in preserving product quality throughout successive recycling processes.

COMPATIBILITY STUDY OF HYDROCARBON RESINS WITH RUBBER COMPOUNDS FOR TIRE APPLICATIONS

ABSTRACT The addition of hydrocarbon resins to rubber compounds has a significant impact on their properties such as wet grip and rolling resistance. These performance characteristics have a strong correlation with the compatibility of the resin with the rubber matrix. Incompatible resins can cause excessive broadening of the damping curve, which results in poor rolling resistance. Compatibility, however, allows maximization of wet grip while minimizing the effect on rolling resistance. Compatibility is promoted by lower resin molecular weight and structural similarity to the polymers being blended. In this study, a method based on the Fox equation has been developed to quantitatively characterize the compatibility between resin and natural rubber (NR), a binary system. The dynamic shear rheometer (DSR), a tool new to the tire industry, is used to investigate the interaction between resin and two rubbers (i.e., a ternary system of NR–butadiene rubber [BR]–resin and solution polymerized styrene–butadiene rubber [SSBR]–butadiene rubber [BR]–resin), with a specific emphasis on resin partitioning among rubber blends. In addition, the DSR is applied to assess the Tg shift and tangent delta peak height, providing insight into the compatibility between rubbers and resin. A curve-fitting model was developed for the SSBR–BR–resin system to depict the relationship between these two parameters and the physical and chemical properties of resins, with the selection of resins featuring different degrees of aromaticity, Tg, and molecular weight. The findings indicated that higher Tg increased aromaticity and that lower molecular weight of the resin resulted in an elevated Tg shift in the blend, while lower molecular weight led to an increase in the tangent delta peak height. Our findings supply insight into the performance of rubber–resin blends and introduce a new screening tool for characterizing these blends in their green state.

Engineering Ce/P-functionalized g-C3N4 for advanced ABS nanocomposites exhibiting unparalleled fire retardancy, enhanced thermal and mechanical properties

The nanomaterials have been deeply explored as flame retardants for various polymeric materials due to their multifunctionality, but they often fail to significantly increase the limiting oxygen index (LOI) and vertical burning UL-94 rating, thus unable to meet industrial needs (LOI>27.0 % and UL-94 V-0 rating). Herein, we fabricated a cerium/phosphorus-doped g-C3N4 (Ce/P-CN) nanohybrid as a multifunctional high-efficiency fire retardant for acrylonitrile–butadiene–styrene (ABS). The Ce/P-CN nanoflakes featured a strengthening effect towards ABS, 10 wt% of which increased the tensile strength of ABS/(Ce/P-CN) by 33.8 %. Meanwhile, the ABS/(Ce/P-CN) nanocomposites showed remarkably enhanced high-temperature stability and carbonization performances relative to virgin ABS. Ce/P-CN simultaneously improved the anti-ignition, fire retardancy and smoke suppression of ABS due to the barrier effect of g-C3N4 nanoflakes and the catalytic carbonization effect of cerium and phosphorus. Notably, adding 10 wt% Ce/P-CN increased the LOI and UL-94 rating of ABS to 28.6 % and V-0, respectively, demonstrating its high flame-retardant efficiency. Thus, the high flame-retardant efficiency and multifunctionality enable Ce/P-CN to outperform previous flame retardants for ABS. This work offers a novel strategy for the development of high-efficiency g-C3N4 nanoflakes, which endow ABS with improved mechanical robustness and fire retardancy and show broad industrial prospects.

Quantitative Insight into the Compressive Strain Rate Sensitivity of Polylactic Acid, Acrylonitrile Butadiene Styrene, Polyamide 12, and Polypropylene in Material Extrusion Additive Manufacturing

Herein, a research and engineering gap, i.e., the quantitative determination of the effects of the compressive loading rate on the engineering response of the most popular polymers in Material Extrusion (MEX) Additive Manufacturing (AM) is successfully filled out. PLA (Polylactic Acid), ABS (Acrylonitrile Butadiene Styrene), PP (Polypropylene), and PA12 (Polyamide 12) raw powders were evaluated and melt-extruded to produce fully documented filaments for 3D printing. Compressive specimens after the ASTM-D695 standard were then fabricated with MEX AM. The compressive tests were carried out in pure quasi-static conditions of the test standard (1.3 mm/min) and in accelerated loading rates of 50, 100, 150, and 200 mm/min respectively per polymer. The experimental and evaluation course proved differences in engineering responses among different polymers, in terms of compressive strength, elasticity modulus, toughness, and strain rate sensitivity index. A common finding was that the increase in the strain rate increased the mechanical response of the polymeric parts. The increase in the compressive strength reached 25% between the lowest and the highest strain rates the parts were tested for most polymers. Remarkable variations of deformation and fracture modes were also observed and documented. The current research yielded results with valuable predictive capacity for modeling and engineering modeling, which hold engineering and industrial merit.

The influence of palm oil-derived plasticizers and lubricants on the rheological and mechanical properties of styrene butadiene rubber

Researchers have recently focused on green processing aids made from plants and vegetables to avoid the high concentration of polycyclic aromatic hydrocarbons (PAHs) from petroleum-based processing oils, which is hazardous to human health. This paper focuses on the effect of lubricants and plasticisers produced from palm oil on the rheological, mechanical and thermal aging properties of styrene-butadiene rubber (SBR). These lubricants and plasticisers are known as glycerol trioleate (GTO), n-butyl stearate (NBS), ethylene bis-steramide (EBS), ethylene bis-oleamide (EBO), pentaerythritol tetrastearate (PETS) and stearyl stearate. The abrasion performance, visual inspection appearance, and cure characteristics of the lubricants and plasticisers on SBR were examined and compared to processing oil-treated distillate aromatic extract (TDAE), paraffin wax, microcrystalline wax, polyethylene (PE) wax, epoxidised soybean oil (ESBO), and stearic acid. It discovered that rubber compounds based on GTO, stearic acid, and EBS exhibited better abrasion resistance and cure properties than rubber compounds based on processing oil. These samples were selected and subjected to mechanical properties, thermal aging effects analysis and comparison with processing oil. Tensile strength shows that SBR with EBS (22.49 MPa) and EBS with GTO (EBS/GTO; 21.25 MPa) are closely similar to SBR compounds with processing oil (21.02 MPa). The findings imply that EBS and EBS/GTO, green plasticisers and lubricants, are viable alternatives to petroleum-based processing oils while being cost-effective for tire production.