Electrical properties can be tailored to a specific requirement by the addition of suitable dopant materials. A few studies on the effect of an impurity such as iodine on the conductivity of polymers are available, e.g. polyethylene [1, 2], poly(vinyl acetate) [3] , poly(vinyl chloride) [4] , poly(vinyl fluoride) [5] and poly(vinyl formal) [6]. The electrical conduction mechanism in cellulose acetate-butyrate films was investigated and the results were reported in [7]. In continuation of these studies, the conduction mechanism in iodine-doped cellulose acetate-butyrate films was investigated as a function of the dopant concentration, field and temperature, and is discussed in this letter. Pure and iodine-doped cellulose acetate-butyrate films of thickness 5/xm were grown by isothermal immersion [8] of glass substrates coated with metal electrodes. The films were dried in an hot-air oven for 24 h at a temperature of around 350 K. The top electrode was vacuum evaporated on the dried films. The thickness of the films was measured using the mechanical stylus method and was verified by the capacitance method. The electrical conduction of pure and doped cellulose acetate-butyrate films was studied in the sandwich configuration. The conductivity of the film was measured as a function of temperature, using a stabilised d.c. power supply, an electrometer (Keithley 617C) and a digital voltmeter. Before actual measurements were made, the films were annealed as described in [9]. The optical absorption measurements were made using a Hitachi U3400 u.v.visible spectrophotometer. Fig. 1 shows the conductivity of pure and iodinedoped cellulose acetate-butyrate films at a field strength of 5 x 106 Vm -1. Curve a corresponds to pure cellulose acetate-butyrate films and curves b-g correspond to iodine-doped cellulose acetate-butyrate films having iodine concentrations of 0.1, 0.25, 0.5, 0.75, 1.0 and 2.0 wt%, respectively. From the plots it is seen that the conductivity increases with temperature consist of two distinct regions of conduction. From the plots it is clear that the conductivity in the sample increases with increasing concentration of iodine up to 0.5 wt %. Above this concentration, however, the conductivity is found to decrease continuously with increasing iodine concentration. It is also observed that the conductivity in the doped sample is always more than that in the pure sample, even at higher concentration. The conductivity of the samples at 300 and 400 K are shown in Table I.