Electrical Conductivity Studies Research Articles

The Study of Electrical Conductivity and Dielectric Relaxation in the Organic Ferroelectric Diisopropylammonium Iodide (dipaI)

The Study of Electrical Conductivity and Dielectric Relaxation in the Organic Ferroelectric Diisopropylammonium Iodide (dipaI)

Effect of Gd doping on the microstructure and electrical characteristics of Maghemite (γ-Fe₂O₃) ceramics

AbstractThis paper presents a novel study on the microstructure and electrical properties of gadolinium (Gd) doped maghemite (γ-Fe₂O₃) nanoparticles, emphasizing their significance for advanced applications in efficient materials. X-ray diffraction analysis confirmed that both pure and doped samples crystallized in a cubic structure (P4332 space group) with high purity. Gd doping significantly increased crystallite size and altered particle morphology, as shown by transmission electron microscopy (TEM), which revealed larger nanoparticles with cubic shapes. Thermal analysis (TGA and DTG) indicated that higher Gd concentrations enhanced thermal instability, affecting structural integrity. FTIR spectra showed shifts in Fe-O bond vibrations, suggesting lattice distortions and increased disorder. BET measurements indicated that higher Gd doping led to greater mesoporosity and surface area, countering expectations of densification. Electrical conductivity and impedance studies revealed two distinct regions: a constant conductivity at low frequencies and an exponential increase at high frequencies, attributed to small polaron hopping. Activation energy values below 200 meV support this mechanism. Gd doping decreased overall conductivity due to disrupted atomic arrangements, increased electron scattering, and modifications in the electronic band structure. Complex impedance spectroscopy illustrated higher real impedance values for doped samples, with increased Gd concentration leading to enhanced impedance. These findings elucidate the impact of Gd on the electrical properties of maghemite nanoparticles and highlight their importance in meeting the growing demands for highly efficient technologies in energy storage and electronic devices. Graphical Abstract

Photoinduced modulation and the effect of CNT loading on field effect transistor characteristics of CNT/ZnO/PVDF composite.

Carbon nanotube (CNT)/ZnO/ polyvinylidene fluoride (PVDF) polymer composite phototransistor is studied for the effect of CNT loading and the photoinduced modulation on its transfer characteristics. XRD study shows that the induced strain in the composite is due to the addition of CNT to the ZnO/PVDF composite. The percentage ofβ-phase present in PVDF is estimated through Raman spectroscopy and the composite's spectral response is determined by UV-Vis absorbance spectroscopy. From the DC electrical conductivity study it is found that the percolation threshold for the composites is obtained for 0.3 wt% of CNT, and 0.44 wt % of CNT loading makes the composite conductive. On adding 1 wt% of CNT, the electrical conductivity of the ZnO/PVDF composite increases 40 times (∼0.2μS m-1). The temperature-dependent DC conductivity shows that the conductivity of the composites changes from variable range hopping to band conductance upon an increase in CNT loading above the percolation threshold and exhibits a negative temperature coefficient. Two terminal photoconductivity studies are done to understand the photo enhancement and sensitivity of all the devices. PE hysteresis studies show that the polarization of the composites increases drastically from 0.05μC cm-2below the percolation threshold to 10-30μC cm-2above the percolation threshold of CNT in the composite. To study the effect of interfacial polarization on photoconductivity, the composite is studied in a three-terminal device format using SiO2as a gate dielectric. A band diagram analysis of the oxide-composite and CNT/ZnO interface is done to understand the mechanism behind the photoinduced field effect on transfer characteristics and the effect of CNT loading. The switching behavior and decay time under UV illumination are studied to understand the effect of CNT loading and photoinduced polarization. The persistent photoconductivity decreases and the charge collection efficiency of the FET increases as the CNT loading increases.

Electrical conductance study of Schiff base in different solvents and temperatures: DFT calculation

The electrical conductivities of the N-(2-chlorobenzylidene)benzylamine (NCB) as Schiff bases (SB) compound in water and methanol were studied in different temperatures, the mixtures of methanol and water studied in various percentages of methanol at 298 K. Initially, the relationship between equivalent conductivity and the square root of molar concentration was plotted to find electrolyte types using Kohlrausch equations. The plot indicates that NCB was weakly associated with water, methanol, and mixtures. Lee-Wheaton equation treated the experimental results of symmetrical electrolytes (1:1) to calculate the conductivity confines: equivalent conductance at infinite dilution Λₒ, association constant KA, and the main distance between ions in solution (R) at best-fit values of (ϬΛ). Thermodynamic quantities for the ion association reaction (∆Go, ∆Ho and ∆So) have been measured. Also, the theoretical calculation was used to optimize the energy of the molecule in the gas phase then measured many descriptors by using (AM1, PM3) then DFT. In addition, recalculated the optimization energy in water, and methanol. After theoretical calculation and analysis, it was found that the Λₒ value is related to the molecular volume of the system (molecules assembled in the solvent). As the molecular volume increases, the Λₒ value decreases due to association. KEY WORDS: Schiff bases, Electrical conductivities, Lee-Wheaton equation, Thermodynamic parameter, DFT Bull. Chem. Soc. Ethiop. 2025, 39(1), 177-187. DOI: https://dx.doi.org/10.4314/bcse.v39i1.15

Optical, electrical, structural properties by of PFO-PMMA films loaded with TiO2 nanoparticles

The authors studied Poly (methyl methacrylate) also called PMMA films with different concentrations of Poly (9, 9′-di-n-octylfuorenyl-2, 7-diyl) also called PFO and concluded that 1% PFO blended with PMMA is the best choice for opto-electronic applications. In the present study, the authors prepared nanocomposite films of PMMA + 1% PFO + different concentrations of TiO2 nanoparticles. The resulting films were subjected to FTIR, XRD, UV–visible, fluorescence and electrical conductivity studies. The polymer matrix undergoes modifications in its molecular and microstructural characteristics as evidenced by FTIR and XRD results. The addition of TiO2 nanoparticles leads to a uniform dispersion and good interaction with the blend matrix resulting in homogeneous films. The additional peaks were found at a wavenumber of 3620 cm−1 in FTIR can be attributed to stretching vibration of TiO2. The presence of TiO2 nanoparticles is confirmed by the distinctive diffraction peaks observed at 25.4°, 37.8°, 48.3°, 54.3°, 55.2°, and 62.8°. With a shift in the absorption peak towards higher wavelengths, the nanocomposites show greater absorption in the UV and visible regions. As the concentration of TiO2 increases, the optical parameters such as absorption coefficient, extinction coefficient, Urbach energy, refractive index and optical conductivity also increase. The direct optical band gap of the PNC films decreases from 5.03 to 3.06 eV and indirect band gap decreases from 4.52 to 1.92 eV at 10 wt% of TiO2 concentration. The addition of TiO2 nanoparticles to the PFO/PMMA matrix resulted in an increase in fluorescence emission intensity. The AC electrical conductivity exhibits increasing trend with frequency in Audio-Frequency range. Thus TiO2 nanoparticles improve the overall optical, electrical, and structural properties of PFO-PMMA nanocomposites. This means that they can be used in a variety of optoelectronic and advanced optical devices.

Preparation, structural, electrical, and ferroelectric properties of solid and lead zirconium titanate ink

The novelty of the work lies in the design and development of a significantly low-cost lead zirconate titanate (PZT) ink similar in its electrical properties to its original solid materials, which can be used for 3-D printing to print electronic circuits, shape memory, and devices quickly. The Zr/Ti=52/48 ratio was achieved during the solid-state reaction to create the PZT powder. XRD, FT-IR, and SEM characterized the synthesized material. The PZT powder was found to form in a tetragonal phase. The PZT powder was used to prepare PZT ink with a 13 % Wt/Wt solid content composition. The ink's rheological characteristics and physical properties, such as particle size distribution, surface tension, viscosity, and electrical properties, were studied. Dielectric properties like dielectric constant (ε/) and dielectric loss (ε") indicate the poly-dispersive nature of the material. The temperature-dependent dielectric constant (ε/) curve indicates relaxor behavior with a maximum at high temperatures. The poly-dispersive nature of the material was analyzed using Cole-Cole plots. The frequency dependence of AC conductivity follows the universal power law. The temperature dependence of dc-conductivity follows the Arrhenius law, with an activation energy of 0.14 eV at lower temperatures and 0.85 eV at higher temperatures. The electrical conductance study showed that PZT ceramic can be used in electronic circuits because of its high resistivity value and small temperature coefficient of resistance. The piezoelectric measurement displays d33 as 129 pC/N at room temperature.

A Comprehensive Study of Density, Viscosity, and Electrical Conductivity of Choline Halide-Based Eutectic Solvents in H2O

A Comprehensive Study of Density, Viscosity, and Electrical Conductivity of Choline Halide-Based Eutectic Solvents in H₂O

Microstructural, microhardness and electrical conductivity analysis of AD31T alloy processed by friction stir processing

PurposeThis research aims to examine the impact of friction stir processing (FSP) treatment on an aluminum alloy, especially the AD31T alloy derived from the Al-Fe-Mg-Si system. The aim is to assess the influence of different processing techniques on the microstructure and physical and mechanical characteristics of the material, with a specific focus on structural and bulk imperfections inside the stir zone (SZ).Design/methodology/approachThe study demonstrates that augmenting the linear velocity of the tool within the 25–100 mm/min range results in significant enhancements. The enhancements include a decrease in the heat-affected zone (HAZ), a reduction in the extent of volume defects inside the SZ and a more uniform deformation. The microstructural analysis results are corroborated by data acquired from microhardness and electrical conductivity studies, confirming the beneficial influence of modifying the tool’s linear velocity on the material parameters.FindingsThis study provides significant observations on the changes in microstructure and the generation of flaws throughout the process of FSP of AD31T alloy. These results have practical implications for improving the characteristics of the alloy and optimizing the production conditions.Originality/valueAll samples exhibit a distinct reduction in electrical conductivity within the initial third of the sample, aligning with the transitional region between the base metal (BM) and the HAZ. This underscores the importance of understanding the transitional zones during FSP.

Study of Mechanical Properties and Electrical Conductivity in Al-Mg-Zn Systems Subjected to a T8 Treatment

Study of Mechanical Properties and Electrical Conductivity in Al-Mg-Zn Systems Subjected to a T8 Treatment

Low-temperature decomposable industrial surfactant for stabilization of few-layered graphene in water

Surface-active agents, such as surfactant molecules, are essential for stabilizing liquid-exfoliated graphene and other 2D nanosheets in water through electrostatic or steric repulsion. It is important to note that surfactants are no longer necessary for solutions converted into thin films for electronic devices, sensors, and composite applications. High-temperature (∼400–500 °C) thermal annealing is one of the performed methods to remove surfactant molecules. However, the surfactant residues present on the graphene nanosheets by post-annealing may adversely impact the electronic properties of the graphene film, potentially resulting in additional doping and defects. To address this challenge, we report a low-temperature decomposable (∼320 °C), eco-friendly and industrially viable surfactant, i.e., coco-glucoside, for the efficient liquid-phase exfoliation and stabilization of graphene nanosheets in water. Compared with the well-studied surfactants in liquid exfoliation such as sodium dodecyl benzene sulphonate (SDBS) and sodium cholate (SC), ∼90 % of this surfactant molecules completely decomposed at ∼320 °C in an air atmosphere for coco-glucoside. Electrical conductivity studies suggested that annealing at 320 °C enhanced the conductivity by 15 times for the coco glucoside-stabilized graphene film; however, marginal change in the conductivity was observed for the SDBS and SC-stabilized graphene film. To demonstrate the viability of the concept, a wallpaper-based rapid fire alarm application utilizing coco glucoside-stabilized graphene/cellulose paper was demonstrated.

Cytotoxicity and bioavailability assessment from micellar system based Thiamine-Phospholipid complexes

Poor absorption (3–5 %) of thiamine hydrochloride (TH), is primarily concerned with impaired permeability across intestinal mucosa. To modulate the permeability of TH, a phospholipid (PL) interaction-based hydrophobic complex of thiamine was investigated. Using the solvent evaporation approach, thiamine-phospholipid complexes (TPCs) were prepared between free bases of thiamine and PLs in the weight ratio (1:1, 1:2, and 2:1) and characterized using FTIR, spectrophotometry, XRD, and conductometric methods. Electrical conductivity and partition coefficient studies demonstrated that TPCs were hydrophobic transformations formed via PL interaction with a free thiamine base. TPCs were embedded into the micellar system (Tween20/Ethanol), characterized by electrical conductivities and zeta-sizing studies, and exploited in its micellar delivery system design. TPC 1:1 & 1:2 had much lower conductivity than TH and its physical mixture (TH/PL) in the Tween20/Ethanol environment diluted with an aqueous phase. The average size of micellar systems loaded with TPC (10 % w/w) was within the range of 12–25 nm, and conductivity was in the range of 122-130µS/cm. In vitro release characterization from complexes and their micellar systems in HCl 1.2, phosphate buffer (PB) 6.8, and bidistilled water showed a delayed release pattern. TPC modulated the intestinal permeability of thiamine as revealed from ex vivo studies. TPC (1:1) and its micellar system produced significant differences in drug permeability (p < 0.001) compared to TH and physical mixture. Pharmacokinetic assessment of the micellar system of complexes in Wistar rats showed that the TPC (1:1) loaded micellar system produced a 2.4-fold enhancement of AUC(0−24) over (TH) followed by oral administration. Assessment of cell viability in mouse fibroblast cell line (L929) culture showed that TPC or micellar system did not inhibit cell growth and was safe at various concentration levels. TPc complexes developed using phospholipid complexation yield hydrophobic transformation in TH and their micellar system-based delivery modulates the intestinal permeability and bioavailability enhancement.

Structural and electrical conductivity studies of Polyaniline - WO3 hybrid nanocomposites for gas sensing applications

Abstract Conducting polymer – metal oxide based hybrid nanocomposites are a fascinating class of materials for miniaturized and flexible gas sensor devices. They exhibit enhanced physiochemical properties such as sensitivity, selectivity towards various volatile and hazardous chemical and bioanalytes. Our study focuses on conducting polyaniline (PANI) and WO3 nanocomposites, where different weight percentages (wt.%) of WO3 nanoparticles are embedded within the conducting PANI matrix using an in-situ oxidation polymerization synthesis technique. The surface morphology analysis indicated that the WO3 nanoparticles with an average grain size of ~200 nm are homogeneously distributed within the PANI nanofibers. The Fourier Transform Infra-Red (FTIR) spectrum analysis showed that the absorption peaks at 1111,1291, 1385, 1474, and 1560 cm−1 are typical of the conducting PANI emeraldine phase. We attribute the additional broad peak ranging between 840 to 720 cm−1 in the spectrum to WO3 phase, wherein, the intensity of the peak increases with WO3 content in case of hybrid composites. Current-voltage (I-V) characteristics for all our samples showed linear behaviour up to 1.2 volts. Temperature-dependent DC electrical conductivity (σ) studies measured from room temperature to 120°C for pure PANI, and PANI-WO3 composites showed an enhanced electrical conductivity of values up to 0.12 S/cm for PANI as compared to WO3 with σ ~ 1.4 x 10−3 S/cm. Pure PANI exhibits semiconducting behavior with an increase in electrical conductivity with temperature due to the charge carrier delocalization within the dispersed PANI backbone. The addition of higher concentrations of WO3 in composites leads to a metallic-like behavior, characterized by a decrease in electrical conductivity with temperature. These observations are attributed to the field-assisted band bending effects at the interfaces of PANI and WO3. Our composites show desired electrical characteristics suitable for gas sensing applications.

Electrical conduction and impedance spectroscopic studies for KNbO3–NaNbO3 high Tc electroceramics with enhanced d33 via BaTiO3 co-doping approach

Electrical conduction and impedance spectroscopic studies for KNbO3–NaNbO3 high Tc electroceramics with enhanced d33 via BaTiO3 co-doping approach

Zinc and [Zinc, Nickel]: Co‑doped SnO2 nanoparticles as prospective electron transport layer materials for efficient lead free-MASnI3 perovskite solar cells

In this study, we explore the potential of both pristine and doped tin oxide (SnO2) as promising materials as the electron transport layer (ETL) for efficient lead free-methylammonium tin iodide (MASnI3) perovskite solar cells (PSCs). The pristine, Zinc (Zn) doped, and Nickel (Ni)-Zn co-doped SnO2 nanoparticles with a constant concentration of Zn while changing the concentration of Ni were synthesized by using the hydrothermal method. The effect of doping and co-doping on optical, structural, and electrical properties of SnO2 nanoparticles was investigated using different microscopic and spectroscopic tools. The X-ray diffractograms showed that pristine, doped, and co-doped SnO2 nanoparticles have better crystallinity and tetragonal rutile crystal structure. The fingerprint functional groups and elemental composition were confirmed by FTIR absorption peaks, EDX, and XPS, respectively. The UV–Vis DRS spectroscopy results revealed that the optical band gap reduced from 2.90 eV for pristine SnO2 to 2.26 eV for co-doped 1 wt (wt) % Ni-Zn-SnO2 nanoparticles and can be tuned with a variation of wt % of Ni. Further, the photoluminescence emissions of all SnO2 nanoparticles in the range of 307 to 494 nm are related to oxygen vacancies or defects. Moreover, BET results confirms larger surface area for 1 wt % Ni-Zn-SnO2, which can help in better electron-hole pair separation. The electrical conductivity studies confirm that the synthesized nanoparticles exhibit excellent ohmic contact behavior and show a notable increase in electrical conductivity for 1 wt% Ni-Zn-SnO2 nanoparticles. Further, the suitability of both pristine and doped SnO2 as ETL material for the MASnI3-based PSCs was simulated using SCAPS-1D software. The best power conversion efficiency of 29.60 % was achieved for FTO/1 wt % Ni-Zn-SnO2/MASnI3/Spiro-OMeTAD/Au. This investigation highlights the potential of co-doped materials as promising candidates for the development of efficient PSCs.

Photocatalytic degradation of Rhodamine B dye via Bi2O3 embedded BaO-P2O5-TeO2 glass nanocomposites: An ab initio study of structural, optical, and electrical transport properties

Bismuth incorporated glassy systems with composition xBi2O3-(1-x) [0.3BaO-0.3P2O5-0.4TeO2] (where x = 0.10, 0.15, 0.20, and 0.25) are synthesized by melt quenching technique. The glassy systems are examined for their structural, and surface morphological properties using XRD, SEM, and EDX analysis. A study of photocatalytic activity for the degradation of common organic dyes like Rhodamine B (RhB) dye under visible light is also carried out. From UV-vis absorbance data, the calculated optical band gap energy values declined from (2.99-2.56) eV, whereas the Urbach energy and refractive index values increased from (0.35 -0.52) eV, and (2.39 - 2.52), respectively with the rise of Bi2O3 content(x). Additionally, the fundamental processes of electrical conductivity have been studied within the framework of Jonscher's universal power law and the Almond-West formalism. The Mott and Greaves model asserts that the small polaron hopping model underlies DC conductivity; as Bi2O3 content increases, DC conductivity rises, but hopping distance (Rhop) and hopping energy (Whop) drop dramatically. The electrical conductivity study reveals the semi-conducting nature of the as-prepared samples. In our present study, we are focusing on the structural, optical, and electrical transportation properties, additionally, we investigated this class of glassy materials as a promising candidate for photocatalytic dye degradation. Our study reveals that RhB dye can degrade up to 75% within 340 min of visible light illumination. Moreover, the test demonstrates the production of superoxide radicals by the CB-electrons and hydroxyl radicals by the VB holes enables efficient photocatalytic dye degradation.

Exploring the impact of solvent additives on dielectric properties in polymer photovoltaics: A deconvolution and in-depth study of electrical modulus, complex conductivity, and impedance responses

Impedance and dielectric spectroscopy is a well-known technique for characterizing interfaces, especially donor/receiver interfaces in bulk heterojunction (BHJ) solar cells. This technique was employed to investigate the interface of poly (4,8-bis-alkyloxybenzo(1,2-b:4,5-b0) dithio-phene-2,6-diyl-alt- (alkyl thieno (3,4-b) thiophene-2-carboxylate)-2,6-diyl) (PBDTTT-C): PC70BM in bulk heterojunction with DIO as additive. For this reason, a simulation was carried out to generate the complex impedance, modulus, and complex conductivity data based on the electrical parameters extracted from the equivalent circuit. Therefore, a new approach based on the coupling of complex functions such as impedance, modulus, and conductivity has been proposed. In addition, an extrapolation and deconvolution approaches are used to highlight the relaxation processes, the BHJ layer process, the two electrical contacts of the interfaces between PEDOT: PSS/PBDTTT-C: PC70BM and PBDTTT-C: PC70BM/Ca process, and the electrode polarization process. In the next step, the remove the low-frequency process enhances the visibility of other processes, particularly observable in the evolution of the electrical modulus and the conduction parameters associated with each process. In the complex functions, there was a good correlation between all parameters derived from both processes. The characteristics of the conduction processes, such as conductivity values at low and high frequencies and ionic strength were then extracted. All these parameters were evaluated and discussed as a function of the thickness of the active layer. Finally, we demonstrate that the electrical modulus and complex conductivity can be perfect tools to characterize the donor/acceptor interfaces.

Investigation of AC and DC Electrical Conductivity in Ethyl Cellulose (EC) and Poly Methyl Methacrylate (PMMA) Polyblends

The study of AC and DC electrical conductivity is crucial for understanding the behavior of charge carriers within materials and their mobility. Ethyl cellulose (EC) stands out among cellulose ethers due to its favorable electrical, mechanical, and weathering properties. Poly Methyl Methacrylate (PMMA) is a thermoplastic known for its rigidity, transparency, and outdoor durability, making it a valuable material. Despite being insulating materials, both EC and PMMA exhibit limited free charge carriers and low mobility. In this research, AC and DC electrical properties of Ethyl Cellulose (EC), Poly Methyl Methacrylate (PMMA), and their blends doped with tetrahydrofuran (THF) film were investigated using isothermal evaporation techniques. The investigation focused on the effects of temperature, electric field, and frequency on electrical conduction mechanisms. Measurements were conducted across frequencies ranging from 1 KHz to 1 MHz at temperatures between 323 K and 373 K. Results indicate that AC electrical conductivity of Ethyl Cellulose (EC), Poly Methyl Methacrylate (PMMA), and their blend (EC/PMMA) increases with higher frequencies of the applied electric field. Meanwhile, DC electrical conductivity of Ethyl Cellulose (EC), Poly Methyl Methacrylate (PMMA), and their blend (EC/PMMA) rises with increasing temperature. X-ray diffraction (XRD) analysis further supports these conductivity changes in the blend.

Synthesis and characterization of new Ce doped‐semiconductor nanocomposite with high specific capacitance

In this study, we introduce an effective strategy to prepare electrodes containing new nanocomposites with high specific capacity. This research led to the preparation of CoFe2‐xCexO4/rGO‐Pani nanocomposite with an extraordinary specific capacitance of 3257.83 F·g−1 (at 10 mV·s−1), a power density of 349.951 W/kg, and an energy density of 3.52 Wh/kg. Also, electrical conductivity studies for new nanocomposite showed good electrical conductivity and better semiconducting properties compared with its similar compounds. Also, the synthesized compounds were characterized and identified by other analyses. FT‐IR analysis for reduced graphene oxide showed that graphene oxide was well reduced. It also confirmed the presence of Ce‐O for both CoFe2‐xCexO4/rGO‐Pani and CoFe2O4‐CeO2/rGO‐Pani magnetic nanocomposites. XRD analysis confirmed the crystal structure for rGO, CoFe2‐xCexO4/rGO‐Pani, and CoFe2O4‐CeO2/rGO‐Pani. VSM analysis was done to check the magnetic properties of the nanocomposite, and the magnetic values were measured as expected. In the following, morphological studies and the uniformity of distribution of elements in magnetic nanocomposite were carried out with FE‐SEM and Map, respectively.

Study of electrical conductivity, biocompatibility and degradation effect of copper electrodes with hydrogel coatings for use in flexible electronics

Study of electrical conductivity, biocompatibility and degradation effect of copper electrodes with hydrogel coatings for use in flexible electronics

Synthesis, Characterization, Dielectric, and Electrical Conductivity Studies of Zinc Oxide Nanoparticles

A co-precipitation technique is used to synthesize of ZnO nanoparticles. The synthesized ZnO nanoparticles were characterized by UV-visible spectroscopy, scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), photoluminescence, Fourier-Transform Infrared Spectroscopy (FTIR), and X-ray diffraction (XRD). The size of the nanoparticles was wide-ranging from 1 nm to 100 nm, corresponding to the HR-TEM analysis. The photoluminescence study of ZnO nanoparticle shows emission in the UV region. The particle dimension of ZnO nanoparticle has also been studied through XRD. Dielectric spectroscopy of synthesized ZnO NPs pellet has been studied at a wide frequency range 10−1 to 105 Hz. The capacitance and dielectric permittivity of ZnO nanoparticles drop continuously with frequency as dipoles have less time to align in the field. Dielectric permittivity of ZnO pellets increase up to 5 mm thickness and subsequently drop, perhaps due to raise in resistivity. The dielectric loss of ZnO pellet has been examined as a function of frequency. The electrical conductivity of ZnO nanoparticles rise exponentially with frequency. Based on the dielectric studies, the dielectric permittivity and electrical conductivity of ZnO are highly depending on thickness and frequency range. The percolation threshold of ZnO pellets has been found between 4-5 mm thicknesses.