Every model planetary atmosphere implicitly establishes unique altitude distributions for the saturation vapor pressures of its minor constituents solely by relating ambient atmospheric pressures and temperatures to altitude. It is therefore possible to determine for any model atmosphere the altitude regions where cloud formation due to condensation or sublimation of minor constituents is permitted or forbidden by basic thermodynamic laws, regardless of the amounts of the minor constituents present. As an example, this exclusion principle is applied to the formation of H2O clouds in the earth's upper atmosphere for conditions given by supplemental model atmospheres for latitudes 15° to 75°. The specific results presented permit inferences about the expected seasonal distribution of noctilucent clouds and serve generally to illustrate the application of a basic principle of thermodynamics to the study of planetary atmospheres.
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