In recent years, there has been concern about the resurgence of sick house syndrome caused by volatile organic compounds (VOCs) emitted from building materials, and there is an urgent need to develop sensors that can continuously detect VOCs with high sensitivity. Our research group is conducting research on VOC detection characteristics using SmFeO3. SmFeO3 is a p-type semiconductor with a perovskite crystal structure and has high oxidation activity against VOCs. However, SmFeO3 has high electrical resistance in air, and sensors using SmFeO3 require heating to a measurable resistance range (approximately 300°C or higher), and also require a measurement system with high input impedance. For this reason, a high cost for apparatus and high power consumption are issues for practical application. Therefore, in this study, we focused on SmFe1-xCoxO3 as the sensing electrode material to operate sensors at reduced temperature. Since SmFeO3 is a p-type semiconductor, Co substitution or hole doping is expected to increase electrical conductivity, and a good redox property of cobalt ion may enhance catalytic activity of VOC decomposition. Regarding the oxidation activity of SmFe1-xCoxO3 powder, the oxidation activity against toluene increased with increasing Co content. T50 = 210oC (x=0), 205 oC (x=0.1), 155 oC (x=0.3), 165 oC (x=0.5). The oxidation activity for ethanol also increased with the amount of substitution, T50 =130oC (x=0), 110 oC (x=0.1), 85 oC (x=0.3), 75 oC (x=0.5). The temperature at which the maximum response value of each sensor was shown is 300℃ (x=0), 250℃ (x=0.1), 250℃(x=0.3), and 200oC (x=0.5). It was found that the Co substitution effectively reduce operating temperature. The response value (RVOC/Rair) in ethanol was results in S=4.6 (x=0 at 300oC), S=6.4 (x=0.1 at 250oC) and the sensor with x=0.1 increased sensor response at reduced temperature. The increase in the response value is thought to be because the sensor with x=0.1 has a higher oxidation activity at 250 oC than that with x=0 at 300 oC, The response of the sensors followed the power law, S=aPVOC n. Here, a and n are constants, and PVOC is the partial pressure of the gas. The constants a and n were determined from the equation log(S)=log(a)+nlog(PVOC), and the response value to 0.1 ppm ethanol was predicted as S=1.11 (x=0), 1.88 (x=0.1), 1.88 (x=0.3), and 1.94 (x=0.5), and it was expected that the response values at 0.1 ppm would increase due to cobalt substitution. Sensor properties mainly depend on material properties and sensor structure (sensing membrane structure). Therefore, it is suggested that higher sensitivity can be achieved by optimizing the sensor structure in the future, and it is considered that the use of cobalt substitutes as a sensor material is useful from the viewpoint of sensitivity.
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