In this article, we establish a characterization of the set M(Bp,∞0,b(Rn))\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$M(B^{0,b}_{p,\\infty }({\\mathbb {R}}^n))$$\\end{document} of all pointwise multipliers of Besov spaces Bp,∞0,b(Rn)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B^{0,b}_{p,\\infty }({\\mathbb {R}}^n)$$\\end{document} with only logarithmic smoothness b∈R\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$b\\in {\\mathbb {R}}$$\\end{document} in the special cases p=1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$p=1$$\\end{document} and p=∞\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$p=\\infty $$\\end{document}. As applications of these two characterizations, we clarify whether or not the three concrete examples, namely characteristic functions of open sets, continuous functions defined by differences, and the functions eik·x\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$e^{ik\\cdot x}$$\\end{document} with k∈Zn\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$k\\in {\\mathbb {Z}}^n$$\\end{document} and x∈Rn\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$x\\in {\\mathbb {R}}^n$$\\end{document}, are pointwise multipliers of B1,∞0,b(Rn)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B^{0,b}_{1,\\infty }({\\mathbb {R}}^n)$$\\end{document} and B∞,∞0,b(Rn)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B^{0,b}_{\\infty ,\\infty }({\\mathbb {R}}^n)$$\\end{document}, respectively; furthermore, we obtain the explicit estimates of ‖eik·x‖M(B1,∞0,b(Rn))\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Vert e^{ik \\cdot x}\\Vert _{M(B^{0,b}_{1,\\infty }({\\mathbb {R}}^n))}$$\\end{document} and ‖eik·x‖M(B∞,∞0,b(Rn))\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Vert e^{ik \\cdot x}\\Vert _{M(B^{0,b}_{\\infty ,\\infty }({\\mathbb {R}}^n))}$$\\end{document}. In the case where p∈(1,∞)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$p\\in (1,\\infty )$$\\end{document}, we give some sufficient conditions and some necessary conditions of the pointwise multipliers of Bp,∞0,b(Rn)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$B^{0,b}_{p,\\infty }({\\mathbb {R}}^n)$$\\end{document} and a complete characterization of M(Bp,∞0,b(Rn))\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$M(B^{0,b}_{p,\\infty }({\\mathbb {R}}^n))$$\\end{document} is still open. However, via a different method, we are still able to accurately calculate ‖eik·x‖M(Bp,∞0,b(Rn))\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Vert e^{ik \\cdot x}\\Vert _{M(B^{0,b}_{p,\\infty }({\\mathbb {R}}^n))}$$\\end{document}, k∈Zn\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$k\\in {\\mathbb {Z}}^n$$\\end{document}, in this situation. The novelty of this article is that most of the proofs are constructive and these constructions strongly depend on the logarithmic structure of Besov spaces under consideration.