Structural Parameters Research Articles

An integrative analysis of functional consequences of PKD2 missense variants on RNA and protein structures: a computational approach

BackgroundThe PKD2, encoding polycystin-2 (PC2) protein, is second major genetic determinant of autosomal dominant polycystic kidney disease (ADPKD) after PKD1. However, the structural and functional consequences of genetic variants in PKD2 remain poorly understood. Given the complexity and heterogeneous nature of ADPKD, understanding its pathogenesis at cellular and molecular levels is vital for deciphering genotype–phenotype correlations and disease severity, thus informing patient-centered treatments. We analyzed missense variants of PKD2 to assess their impact on RNA structure using computational tools and explored associated protein structure dynamics through MD simulation.ResultsOur findings reveal distinct structural alterations and dynamic behaviors associated with specific missense variants. The variants such as c.1789C > A (p.L597M), c.1109G > A (p.S370N), c.1849C > A (p.L617I), and c.646 T > C (p.Y216H) induced major changes not only in RNA structure and accessibility profile but also in protein structure dynamics. In contrast, variants such as c.915C > A (p.N305K), c.1354A > G (p.I452V), and c.568G > A (p.A190T) resulted in minor alterations in RNA structure but exhibited noticeable effects on certain parameters of protein structure dynamics.ConclusionThis study suggests the multifaceted impact of these missense variants on both RNA and protein levels. It lays the groundwork in identifying high-impact variants in terms of pathogenicity and prioritizing these for further implications in understanding disease heterogeneity and eventually contributing to the development of targeted therapeutic interventions for ADPKD.Graphical Study HighlightsPKD2 missense variants analyzed for impact on RNA and protein StructuresAlterations in RNA Structures and protein dynamics observedComputational integration of analyses aids in prioritizing variants for further studyProvide insights into disease heterogeneity and potential therapeutic targets

Exploiting Friedel pairs to interpret scanning 3DXRD data from complex geological materials

The present study introduces a processing strategy for synchrotron scanning 3D X-ray diffraction (s3DXRD) data, aimed at addressing the challenges posed by large, highly deformed, polyphase materials such as crystalline rocks. Leveraging symmetric Bragg reflections known as Friedel pairs, our method enables diffraction events to be precisely located within the sample volume. This method allows for fitting the phase, crystal structure and unit-cell parameters at the intra-grain scale on a voxel grid. The processing workflow incorporates several new modules, designed to (i) efficiently match Friedel pairs in large s3DXRD datasets containing up to 108 diffraction peaks; (ii) assign phases to each pixel or voxel, resolving potential ambiguities arising from overlap in scattering angles between different crystallographic phases; and (iii) fit the crystal orientation and unit cell locally on a point-by-point basis. We demonstrate the effectiveness of our technique on fractured granite samples, highlighting the ability of the method to characterize complex geological materials and show their internal structure and mineral composition. Additionally, we include the characterization of a metal gasket made of a commercial aluminium alloy, which surrounded the granite sample during experiments. The results show the effectiveness of the technique in recovering information about the internal texture and residual strain of materials that have undergone high levels of plastic deformation.

THE EFFECT OF EMPAGLIFLOZIN AND RANOLAZINE ON THE DYNAMICS OF STRUCTURAL AND FUNCTIONAL PARAMETERS OF THE HEART AND LEVELS OF BIOMARKERS NT-proBNP AND SOLUBLE (s)ST-2 IN PATIENTS WITH ATRIAL FIBRILLATION AND HEART FAILURE

Atrial fibrillation (AF) is the most common long-term arrhythmia worldwide and has a strong association with heart failure (HF).Aim. To investigate the effect of empagliflozin and ranolazine in addition to standard therapy on the dynamics of structural and functional parameters of the heart and levels of biomarkers NT-proBNP and soluble (s)ST-2 in patients with atrial fibrillation and heart failure.Materials and Methods. We examined 300 patients aged 45-65 years. All patients were divided into groups: Group I - patients with HF without AF (n=150). Group II - patients with HF and AF (permanent form) (n=150). Group of 136 practically healthy individuals. All patients underwent clinical examination, echocardiography (Echo), determination of NT-proBNP and (s)ST-2 levels by enzyme-linked immunosorbent assay.Results. The dynamics of parameters of the LV in the main group was more significant compared to the control group (p<0.05). After treatment, the concentration of circulating NT-ProBNP in the control group decreased by an average of 26.2% (p<0.05), and in the main group of patients - by 15.9% (p<0.05). As for the blood levels of the (s)ST-2 biomarker, after treatment in the control group there was an average decrease of 13.1% (p<0.05) compared with the dynamics in the main group of patients - by 38.8% (p<0.05).Conclusions. The use of INSKTG-2 empagliflozin against the background of standard therapy of heart failure reduction of myocardial remodelling and increase ejection fraction. Complex treatment with empagliflozin and ranolazine as INZCTG-2 helps to reduce the level of NT-ProBNP and (s)ST-2 in the blood serum.

Impact of U-shaped waveguide structures on optical comb generation in microresonator systems

In the research of soliton microcombs, the pump energy conversion efficiency (ECE) of the microcomb is an important parameter. However, in traditional microresonator systems, the ECE is only a few percent. Researchers have enhanced it by introducing additional feedback coupling structures or composite cavity structures into the microresonator system to suppress the output of pump light in the soliton generation region. The additional structures may affect the output comb characteristics of the system, but most articles do not delve into this issue, which hinders the practical application of high-efficiency soliton microcombs. In this paper, we establish rate equations describing the nonlinear dynamics of a microresonator with a U-shaped waveguide feedback coupling structure (coupled-cavity system, CCS), and numerically simulate and conduct steady-state analysis of the simulation results to obtain the influence of the U-shaped waveguide on the CCS’s output comb characteristics. Then we optimize the structural parameters of the CCS reducing the parametric oscillation threshold of the pump by more than 50%, while increasing the ECE to over 25% when the optical field in the microresonator propagates in the form of a single soliton.

Model analysis and experiment study for effects of thermal viscous and fluid flow on ventilated acoustic metamaterials labyrinth

In many noise scenarios, ventilation is necessary. The practical realization of noise attenuation under the premise of ensuring ventilation is an urgent problem to be solved. In this paper, a ventilated acoustic metamaterial labyrinth (VAML) is proposed, and the corresponding analytical and numerical computational models are developed considering the thermal viscous effect (TVE). The loss in sound transmission of the VAML is quantitatively obtained and experimentally verified. The theoretical results are compared with the experimental results with an error of 0.6%. By comparing the transmission coefficient and the impedance at the entrance of the side branches, the mechanism of the TVE on the performance of VAML is analyzed, and it is clarified that the TVE is responsible for the sound absorption coefficient. The effects of structure parameters on the transmission coefficient of the VAML are analyzed individually. The results show that the resonant frequency of the system decreases as the length of channel 1 l1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$l_1$$\\end{document}, the length of channel 2 l2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$l_2$$\\end{document}, and the width of channel d increase. By adjusting the magnitude of these three parameters, the control of the resonant frequency can be realized. Meanwhile, as l1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$l_1$$\\end{document}, l2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$l_2$$\\end{document} and ventilation radius R decrease the valley of transmission coefficient decreases which means better noise reduction. Finally, the effect of flow velocity on the transmission coefficient is analyzed, revealing the mechanism of fluid action on macroscopic acoustic properties.

High-Pressure Monosulfide Solid Solution FexNi1−xS Phases: X-Ray Diffraction Analysis and Raman Spectroscopy

High-pressure high-temperature (HPHT) crystalline monosulfide solid solution (Mss) phases (FexNi1−xS, x = 0.90, 0.75, 0.50, 0.25), troilite (FeS I), and α-NiS of the Fe-Ni-S system were synthesized at 7 GPa and 900–1550 °C. The structural parameters of the obtained phases were refined by XRD using the Rietveld method. Factor group analysis revealed the number of active Raman modes for FeS I and α-NiS. Raman spectra of troilite, α-NiS, and Mss phases were obtained. It was shown that the Raman spectra of Mss phases and α-NiS have a similar topology. The Raman spectra of the experimental phases in the Fe-Ni-S system were analyzed with non-negative matrix factorization, which provided a meaningful concentration dependence of the spectral patterns. The spectral components were assigned to the FeS I and α-NiS structures. The structural and spectroscopic studies show linear dependencies of unit cell parameters and spectral components on composition and confirm the existence of a series of monosulfide solid solution FexNi1−xS.

Saturation model for pore-type gas hydrate based on additional muddy conductive digital core

Abstract Original natural gas hydrate rock samples readily decompose under environmental changes during extraction, presenting challenges to conventional rock electrical analysis. This results in difficulty obtaining the cementation factor m and saturation exponent n of hydrate samples, thereby complicating the evaluation of hydrate saturation. Therefore, a method for revising the rock electrical parameters by digital core technology is proposed. Utilizing X-ray CT images of artificial gas hydrate samples, digital core models of natural gas hydrates were established. An erosion algorithm was employed to simulate the variation in mud content within the digital core, followed by the calculation of resistivity using the finite element method after meshing. Through analyzing the primary micro-pore structure parameters that influence the rock electrical parameters, the saturation model was subsequently refined. The results showed that the resistivity of hydrate digital core magnifies with increasing saturation of hydrate, tortuosity, and pore-throat ratio, but decreases with increasing coordination number and mud content. The rock electrical parameters were changed with the alteration of micro-pore structure. Based on the relationship between m, n, and micro-pore structure parameters, established a correction equation for them, further improved the Indonesian equation. The saturation of hydrate reservoir in Shenhu Sea area was evaluated using the modified Indonesian equation. The modified equation reduced the relative error from 34.8% to 15.6%, significantly enhanced the calculation accuracy.

Structural Design and Optimization on Three‐Row J‐Type Air Cooling Channel of Pouch LiB Module

To enhance the cooling efficiency of pouch lithium‐ion battery modules, a three‐row J‐type air cooling channel structure is proposed, utilizing the previously developed multiple inlet/outlet air cooling frames. The influence of the location and number of inlets and outlets on heat dissipation performance is investigated through six air cooling channel schemes, providing a baseline for the multiobjective structural optimization of the proposed structure. Three important structural parameters, , , and l, of its air convergence and divergence plenums are selected as the design variables to improve the airflow uniformity in branch channels and minimize the pressure drop between inlets and outlets. The final design exhibits superior heat dissipation performance compared to baseline. It is noted that the airflow root mean square error in branch channels is reduced by 75.64%, while the pressure drop is increased by 19.74%. These are the critical factors for ensuring the heat dissipation performance of battery module. The maximum temperature and the maximum temperature difference of battery module are reduced by 5.29% and 23.91%, respectively, which help maintain its working temperature within a reasonable range.

Correlation Analysis of Subjective and Objective Texture Properties: Color and Heterocyclic Amine Content of Grilled Chicken Breast Fillet

The present study discusses the technofunctional properties (color, texture) of grilled chicken with both objective (colorimeter, texture profile) analysis and subjective (sensory) analysis. Besides them, the total content of potentially carcinogenic heterocyclic amines (HCAs) was also monitored by the applied grilling time–temperature combinations. The same samples were analyzed during the heat treatment of chicken breast samples for 5–15 min at 150–230 °C on an electric contact grill. The grilling variables included the effect of skin cover. Among the structural parameters, hardness exhibited a significant difference between the groups of skin-covered and not-covered ones, and in this case, a linear connection was also found with the time and temperature values, respectively. The structural parameters obtained by sensory and instrumental analysis were compared to each other. In addition, the structural parameters were compared to the color ones (sensory, color according to the CIELAB system: brightness, redness, and yellowness) and to the total HCA content. In the case of closed grilling, sensory-evaluated parameters such as juiciness and tenderness showed a strong negative correlation to instrumentally measured hardness (R = −0.879; −0.749) and chewiness (R = −0.872; −0.718) due to the water loss from the increase in grilling temperature and time. The total HCA content positively correlated to chewiness (R = 0.789). The sensory color parameter and the brightness had a strong connection with juiciness (R = 0.738; 0.723), hardness (R = −0.795; −0.706), and chewiness (R = −0.843; −0.818); redness showed positive correlation to cohesiveness (R = 0.764) and chewiness (R = 0.829). Accordingly, juiciness and chewiness showed a connection to the total HCA levels, which makes it possible to carry out further research on instrumental and sensory parameters that may predict the formation of hazardous amounts of carcinogenic heterocyclic amines.

Up and down quark structure of the proton

We report an improved measurement of the valence u and d quark distributions from the forward-backward asymmetry in the Drell-Yan process using 8.6 fb−1 of data collected with the D0 detector in pp¯ collisions at s=1.96. This analysis provides the values of new structure parameters that are directly related to the valence up and down quark distributions in the proton. In other experimental results measuring the quark content of the proton, d quark contributions are mixed with those from other quark flavors. In this measurement, the u and d quark contributions are separately extracted by applying a factorization of the QCD and electroweak portions of the forward-backward asymmetry. Published by the American Physical Society 2024

The Influences of Parameters on the Dynamic Characteristics of a Multi-Foil Aerodynamic Journal Bearing with Bump-Backing Foils: Model Predictions

In this work, the development and implementation of a dynamic characteristics model for a specific multi-foil aerodynamic journal bearing with bump-backing foils (MFJB) is considered. Based on the previously established static characteristics model, the elastohydrodynamic influence is carefully considered, and the perturbation method is adopted, as this model is more effective and computationally efficient. The effects of the operational, structural, and geometric parameters on stiffness and damping coefficients are emphasized. The results show that the eccentricity ratio effects are more intensive when the bearing speed is at a moderately high level, which is no more than approximately 30,000 rpm. The foil thickness has obvious effects on dynamic characteristics, whereas the influence of the elastic modulus is limited. Within the research scope, the eight-foils bearing exhibits a better performance than the four-foils. This paper is designed to provide effective methods and supply theoretical guidance for improving the engineering design and operational stability of bearings.

Research of Options for Constructing Information Management Systems Based on Network Models of Queuing Systems

The use of information management systems (IMSs) for the management of technical facilities is currently one of the directions for further improvement and increase in the effectiveness of the use of technical facilities in solving their target tasks. The existing modern IMSs are a set of hardware and software tools designed for collecting, processing and storing information and management. In the presence of a large amount of information and contradictory factors affecting the quality of management, making informed and timely decisions in the management process is impossible without the use of IMSs. The IMSs currently being developed are, for the most part, specialized systems and are designed to solve specific tasks. In this regard, the development and design of IMSs should be carried out taking into account the relationship with the target indicators and features of the management facilities, the results of a comprehensive analysis of information about the IMS elements in the process of functioning, and structural and algorithmic parameters that affect performance indicators. The use of mathematical models for the study of options for the construction of an IMS is the basis for the design and development of devices and subsystems of an IMS. The IMS models currently being developed make it possible to conduct research for single-stage management processes with the presence of similar service facilities in the system. At the same time, modern technical facilities and control systems are complex complexes with cyclically repeating control processes of various types of means. As a rule, such complexes have a set of parallel operating devices (control channels) that provide control of different types of objects at various stages of information processing. In this case, the structure of the IMS must be represented as a multiphase multichannel technical system in which the process of simultaneous management of several objects of various types takes place. In this regard, the purpose of the article is to develop a mathematical model of an IMS with two phases of management and the presence of an arbitrary number of serviced different types of management facilities. The basis of the model is a multiphase CFR network model with a limited waiting time for an application in the service queue. The study on the model allows choosing an option for building an IMS, in particular, choosing the optimal number of control channels for various types of objects according to the criterion of optimality and restrictions on the cost and time of management. An algorithm for selecting an option for building an IMS has been developed, and an example of calculating the number of control channels for managing three types of objects is given.

Scalable robust photothermal superhydrophobic coatings for efficient anti-icing and de-icing in simulated/real environments

Photothermal superhydrophobic coatings are supposed promising to prevent ice accumulation on infrastructures but often experience significant performance degradation in real icing conditions and lack mechanical robustness. Here, we report design of robust photothermal superhydrophobic coatings with three-tier hierarchical micro-/nano-/nanostructures by deposition of nanosized MOFs on natural attapulgite nanorods, fluorination, controlled phase separation of a hydrophobic adhesive and spraying assembly. Phase separation degree and adhesive content significantly influence the coatings’ properties by regulating the structural parameters and morphology. In simulated/real icing environments, the coatings simultaneously show (i) high superhydrophobicity and stable Cassie-Baxter states due to their low-surface-energy, three-tier micro-/nano-/nanostructure, (ii) excellent photothermal effect primarily due to nanosized MOFs, and (iii) good mechanical robustness by the phase-separated adhesive, reinforcement with attapulgite and the coatings’ self-similar structure. Accordingly, combined with low thermal conductivity, the coatings exhibit remarkable anti-icing/frosting (e.g., no freezing in at least 150 min and almost free of frost in 25 min) and de-icing/frosting performances (e.g., fast de-icing in 12.7 min and fast de-frosting in 16.7 min) in such environments. Furthermore, we realize large-scale preparation of the coatings at reasonable costs. The coatings have great application potential for anti-icing and de-icing in the real world by efficiently using natural sunlight.

Continuous fiber printing path generation based on Euler diagram division

Continuous fiber printed structures are widely used in aerospace applications because of their excellent performance and high design freedom. Existing path planning methods optimize the continuous fiber printing direction by stress lines or discrete angles, but these methods are far from perfect printing paths and lack planning for connectivity relations. In this study, a planning method for continuous fiber printing paths based on constructing Eulerian circuits from a weighted undirected graph is proposed. The principal stress lines are transformed into a weighted undirected graph, which divides the Eulerian subgraph by splitting the common nodes to plan the continuous fiber printing path circuit. Subsequently, the printing structure parameters are optimized based on simulation analysis. The experimental results, taking MBB (Messerschmitt-Bolkow-Blohm) beams as an example, show that the printing path designed in this paper improves the structural strength by 52.9% and the structural stiffness by 81.7% compared with the conventional printing path.

A FRACTAL PORE-SCALE MODEL OF STRESS-DEPENDENT THERMAL CONDUCTIVITY IN A RECTANGULAR CROSS-SECTION TREE-LIKE MICROFRACTURE NETWORK

Stress is an important external element influencing effective thermal conductivity (ETC). However, previous theoretical investigations of stress-dependent effective thermal conductivity have used a simplified parallel plate model, overlooking the complex structure of rock fracture networks. Therefore, this paper establishes a new fractal model for the stress-dependent ETC of a rectangular cross-section tree-like microfracture network. The model derives a constitutive equation between the stress-dependent ETC and the microscopic geometry structural parameters of the microfracture network. The model’s validity is confirmed by the error of less than 0.291% between the theoretical predictions and the experimental data. The influence of geometry structural parameters of the microfracture network (length ratio, width ratio, height ratio, angle, total number of branches and ratios of soft part, hard part, etc.) on the ETC under the low-stress state has been analyzed. It was discovered that the soft part of the rock microfracture network has the most impact on ETC. The fractal pore-scale model clarifies heat transfer mechanism in rock microfracture network under effective stress, with each parameter physically defined and independent of empirical constants.

Association of biomarkers of cardiac remodeling, myocardial fibrosis and inflammation with parameters of heart function and structure in patients with arterial hypertension.

Early evaluation of cardiac remodeling may be useful in predicting heart failure in patients with arterial hypertension. The identification of biomarkers as useful clinical tools in this regard is ongoing. The aim of this study was to evaluate the association of selected cardiac biomarkers levels with parameters of cardiac structure and function in patients with arterial hypertension. Included in the study were patients with arterial hypertension with normal left ventricular ejection fraction (LV EF) and absence of signs of heart failure. The levels of selected biomarkers: NT-proBNP, sST2, Galectin-3, GDF-15, Cystatin C, TIMP-1 and ceruloplasmin were measured and assessed together with other biochemical and echocardiographic parameters. A total of 92 patients (61% men) mean age 61.5 years were included. Mean LV EF was 64.7% and mean LV mass index was 91.7 g/m2. NT-proBNP level correlated significantly with the parameters of LV diastolic function: velocity of E wave (r=0.377, P<0.002), and with E/A ratio, (r=0.455, P<0.0001), with E lat (r=-0.354, P=0.006), E/E' ratio, r=0.393, P<0.002, with ePAP (r=0.390, P=0.014), and with age (r=0.384, P<0.0001). Statistically significant correlations for GDF-15 were as follows: with age (r=0.426, P<0.0001) and left atrial diameter (LA) (r=0.401, P<0.0001), for Cystatin C there are statistically significant correlation with age (r=0.288, P=0.006) and LA (r=0.329, P=0.004). Only sST2 level correlated significantly with parameters of cardiac structure: with LV mass (r=0.290, P<0.01) and LV mass index (r=0.307, P=0.012) and with posterior wall thickness PW (r=0.380, P<0.001). No other observed variables including Galectin-3 and TIMP-1, correlated significantly with age or echocardiographic variables. In a comparison of patients with and without left ventricular hypertrophy, statistically significant differences were found only in LA (P<0.0001) and sST2 (P=0.004). In a multivariate logistic regression, sST2 and TIMP were independent predictors of left ventricular hypertrophy. NT-proBNP level as a biomarker of cardiac remodeling correlated with parameters of LV diastolic function in patients with arterial hypertension. Soluble ST2 correlated with parameters of cardiac structure. Biomarkers sST2 and TIMP-1 were associated with left ventricular hypertrophy.

Research on the Configuration Optimization of All-Metal Micro Resonant Hemisphere

As the core component of the all-metal micro resonant gyroscope, the structural parameters and form and position errors of the resonator significantly influence its vibration characteristics, and consequently, the accuracy of the gyroscope. By establishing the finite element model of an ideal hemispherical resonator and optimizing the meshing method, we refined the frequency difference to 0.1 Hz, enhancing the accuracy of the simulation model. Through finite element simulation, we examined the impact of various structural parameters and processing errors on the natural frequencies of each mode. We analyzed how form and position errors, including shell thickness error, central axis error, equatorial plane error, and edge rectangular tooth position error, affect the frequency splitting of the resonator. We provided optimization suggestions for the structural parameters, ensuring frequency splitting variations of less than 1 Hz. Theoretical modeling and simulation analysis indicated that the primary factors influencing the vibration modes and frequency splitting are the rectangular tooth structure and shell thickness. Following the optimized parameters, the frequency splitting of the All-Metal Micro Resonant Hemisphere was reduced by an order of magnitude to 14 Hz, demonstrating that these optimized conditions can significantly enhance the resonator’s performance.

Multiple surface lattice resonances in symmetric nanocuboid dimer arrays

Abstract Surface lattice resonances based on nanoparticle arrays have significant characteristics such as localized field enhancement and high quality factor, and can be applied in fields such as optical sensors and lasers. In this work, we propose a symmetric Si/SiO2 nanocuboid dimer array that can generate and regulate two surface lattice resonances. One of the surface lattice resonances (named SLR1) is mainly due to the coupling between the electric dipole resonance of single Si/SiO2 nanocuboid dimers and the diffraction waves perpendicular to the applied electric field. Another surface lattice resonance (named SLR2) mainly originates from the coupling between the magnetic dipole resonance of single Si/SiO2 nanocuboid dimers and the diffraction waves parallel to the direction of the applied electric field. The research results indicate that the polarization direction of the incident field, the period of the array, the gap between the nanocuboids in the dimer, particle size, and the medium environment are all important for regulating the two surface lattice resonances. The sensing application of multiple surface lattice resonances is also investigated. The results show that under appropriate structural parameters, SLR1 can provide good stability for sensing applications, its sensitivity and figures of merit are 472 nm/RIU and 104, respectively. However, SLR2 is very weak or suppressed when the refractive index of the medium environment is greater than or equal to 1.2. This characteristic limits the application range of SLR2 in sensing. This work is of great significance for the design of micro-nano photonic devices based on multiple surface lattice resonances.

Low thickness effect on the properties of Mn-doped ZnO thin films synthesized by sol-gel spin coating technique

In this study, 7% manganese-doped zinc oxide (MZO) thin films with varying low thicknesses were synthesized using the spin coating method. The structural, optical, and morphological properties of MZO films with different film thickness, were systematically investigated. The crystallite structure, superficial morphology, and optical characteristics were analyzed using X-ray diffraction (XRD), atomic force microscopy (AFM), scanning electron microscopy (SEM), and ultraviolet–visible spectroscopy (UV-Vis). Structural analysis confirmed that all films exhibit a hexagonal wurtzite phase with a pronounced peak along the c-axis, and slight variation in low thickness significantly affected the structural parameters. The surface morphology demonstrated good uniformity, characterized by rounded grain shapes in the plane, while surface roughness was found to be increased with increasing film thickness. Optical analysis revealed that as the number of coatings increased, both transmittance and band gap energy decreased, accompanied by a redshift in the absorption edge across all samples. This behavior is attributed to light scattering, as well as an increase in the refractive index and dielectric function with visible light energy, influenced by the number of layers and corresponding crystallite size.

Intermetallic Compounds for Hydrogen Storage: Current Status and Future Perspectives.

Intermetallic compounds are an emerging class of materials with intriguing hydrogen activation and storage capabilities garnering attention for their application in low-temperature hydrogen storage and metal hydride batteries. However, none of the existing intermetallic compounds have met the gravimetric hydrogen storage capacity target of 5.5wt.%. Some A2B-type intermetallic compounds, like Mg2Ni, Mg2Co, and Mg2Fe, approach this target but require high temperatures for hydrogen desorption limiting their use in low-temperature hydrogen storage and automotive applications. Conversely, some intermetallic compounds like ZrV2 and LaNi5, exhibit hydrogen desorption at ambient conditions but with comparatively lower hydrogen storage capacities. This review article provides a comprehensive account of the different types of intermetallic compounds, their synthesis using different solidification-based and solid-state diffusion-based approaches, and their metallurgical and structural properties. It examines the complex interdependencies between the structural parameters of intermetallic compounds and hydrogen storage performance. A definitive but non-linear correlation is identified between void volume and gravimetric hydrogen storage capacities while lattice structure, evolution of lattice structure with hydrogen absorption, enthalpy of hydride formation, and hydrogen activation reactivities of intermetallic compounds are identified as critical parameters governing hydrogen storage performance.