India is developing lead lithium cooled ceramic breeder (LLCB) blanket for its DEMO fusion reactor. The mock-up blanket (TBM), using this concept, will be tested in ITER for its tritium breeding and high-grade heat extraction efficiency. In this TBM, pressurized helium is used to remove the heat from first wall, top and bottom plates of TBM. The Pb–Li is used to extract heat from the breeder zones. The flow of Pb–Li with average velocity 0.1m/s inside the channel can be significantly modified due to MHD effects, which arise because of the presence of strong toroidal magnetic field. A numerical approach is established to capture this flow modification at higher Hartmann numbers (≥20,000). As a validation part of the developed code, MHD phenomenon is studied in 2-D square geometry and numerically obtained velocity profile is compared with available Hunt's analytical results. Thermo-fluid MHD analysis using this code, has been carried out for single rectangular duct of LLCB TBM. The heat transfer has been studied by keeping hot breeders at both sides of the flow channel. The results suggest modification in steady state MHD velocity profile as the liquid flows along the flow length. However, the temperature in various zone remains well within the maximum allowable limit.