Strong Polarization Research Articles

Hydrogel Sensors in an IoT System for Self-Monitoring and Remote Monitoring of Massage Pressure.

The effectiveness of massage can be enhanced if the pressure applied can be monitored continuously. In this study, we described an Internet-of-Things (IoT) system based on hydrogel sensors, which allows for self-monitoring and remote monitoring of massage pressure. The piezoresistive hydrogel with the compressive energy loss coefficient of 15.7% was developed, which was attributed to the strong polarization of ammonium phosphate on water molecules, which was evidenced by nuclear magnetic resonance (NMR) transverse relaxation analyses and atomic force microscopy. Using this hydrogel as a pressure-sensing component, we assembled a wearable sensor capable of quantifying and transmitting massage pressure with insignificant energy dissipation. By integrating RGB LED arrays, the message pressure was indicated by the color states of the LEDs. Furthermore, the wearable sensors and LEDs were connected to a microcontroller (MCU) chip, an IoT chip, and a cloud server to form a sensing-controlled IoT system, enabling visible and remote monitoring of massage pressure.

Polarization-selective dual-band infrared metamaterial perfect absorber

Abstract Metamaterial absorbers have significant effects and great potential for applications in a variety of important sciences and technologies, including infrared imaging, thermal emitters, electromagnetic shielding, and photodetectors. However, conventional absorbers with a single function are difficult to meet the growing demand of devices, especially for the situations where the absorption and polarization are simultaneously required in infrared detection. If the polarization absorption function is realized by integrating absorption and polarization elements, it will lead to a large overall system size and slow response time. To solve this problem, we propose a dual-band polarization-selective metamaterial perfect absorber, whose maximum absorptions at resonant wavelengths of λ1=2.824μm and λ2=7.622μm are 99.99% and 99.88%, respectively. The absorber exhibits strong polarization sensitivity, absorbing TM-polarized incident light and reflecting TE-polarized incident light at the two resonant wavelengths. The extinction ratios of the absorber at the two referred resonant wavelengths are 90.9 and 142.7, respectively. The proposed absorber would be beneficial for infrared polarization detection and imaging.

Tuning local charge polarization of covalent organic frameworks for enhanced photocatalytic uranium (VI) reduction

The introduction of local charge polarization is an effective strategy to improve the electrostatic potential difference of covalent organic frameworks (COFs) photocatalysts. Herein, BPDA-COF with donor–acceptor (D-A) structure was firstly synthesized by using triphenyl-triazine and biphenyl monomers. Subsequently, the hydroxyl and bis(2-methoxyethyl)ether (PEO)-chains with increasing local charge polarization were introduced to synthesize DHBD-COF and PEO-COF, respectively. PEO-COF with electronegative and flexible PEO-chains created a strong local charge polarization to enhance the electrostatic potential differences, thus promoting the spontaneous transfer of electrons and inhibiting the recombination of electrons and holes. Furthermore, the super-hydrophilic PEO-chains provided super-strong uranium mass transfer capacity. Benefiting from these, PEO-COF exhibited excellent photocatalytic uranium reduction capabilities (1427.9 mg g−1). This work provides a novel insight to adjust the local charge polarization at the molecular level and broadens the strategy of photocatalytic reduction of U(VI) with COFs.

Oriented Crystal Polarization Tuning Bulk Charge and Single-Site Chemical State for Exceptional Hydrogen Photo-Production.

Rapid bulk charge recombination and mediocre surface catalytic sites harshly restrict the photocatalytic activities. Herein, the aforementioned concerns are well addressed by coupling macroscopic spontaneous polarization and atomic-site engineering of CdS single-crystal nanorods for superb H2 photo-production. The oriented growth of CdS nanorods along the polar axis, vectorially superimposing substantial polar units with orderly arrangement, renders a strong polarization electric field (20.1 times enhancement), which boosts bulk charge separation with an efficiency up to 72.4% (80.4-fold). Remarkably, polarization electric field alters the chemical state of Pt single sites by orderly reducing the binding energy of Pt atom with stepwise polarization enhancement of CdS substrate, which increases the onsite electron density of Pt from 10.232 to 10.261e- and *H key intermediates, providing preponderant Volmer-Tafel/Volmer-Heyrovsky reaction pathways with significantly decreased energy barriers for H2 production. Thus, highly polarized CdS nanorods with atomically dispersed Pt sites perform an outstanding H2 space-time yield of 118.5mmol g-1 h-1 and apparent quantum efficiency of 57.7% at λ = 420nm, and a record-high H2 turnover frequency of 57798.4 h-1, being one of the best catalysts for photocatalytic H2 evolution. This work highlights the function of polarization in manipulating charge separation and catalytic reaction.

Optimisation and Characterisation of Improved Nanoemulsion Formulations Containing Ceramide 3

AbstractCeramide3 (Cer3) is one of the important components of stratum corneum (SC) lipids with good moisturizing and repairing properties. However, it suffers from (a) poor solubility, (b) easy crystallization and precipitation, and (c) strong polarity and difficulty in transdermal application. This study aimed to load Cer3 into nanoemulsions (NEs) to overcome these mentioned defects. The optimized NEs formulation was prepared by high pressure homogenization method and characterized by several methods. The optimized ceramide3 nanoemulsions (Cer3‐NEs) exhibited a good physico‐chemical stability over 3 months under different conditions, with droplet size of 103.1 nm, PDI of 0.178, zeta potential of −39.09 mV, pH of 6.20 and encapsulation efficiency of 96.39 %. Turbiscan results showed that formulations containing Cer3‐NEs have better stability than those containing free Cer3. The dermal delivery ability of Cer3‐NEs was assessed by Franz diffusion and confocal Raman spectroscopy (CRM). In vitro and in vivo penetration studies showed that Cer3‐NEs serum have almost 2–3 times higher retention in the skin and permeation in the receptor solution compared to serum with free Cer3. The findings show NE is a promising carrier of Cer3 for topical administration in the treatment of dryness and barrier damage due to higher stability and better skin permeability.

Exploring the mechanisms of benzanilide crystal growth and morphology: Crystal surface structure, solvent diffusion and solvent-interface interactions

Flaky crystals are fragile, rendering them unsuitable for various applications including use, processing, storage and transportation. This work investigates the growth and morphology regulation mechanisms of flaky crystals using benzanilide as a model material. Initially, block-like crystals are prepared by solvent screening and cooling crystallization with its morphology greatly improved. Subsequently, growth kinetics of (111), (1–10) and (020) faces are established with crystal growth experiments. The crystal growth of (001) face is also determined to follow a two-dimensional nucleation model with the microscopic surface analysis using atomic force microscopy. The changes of the surface integration resistance and the growth step height are regarded as kinetic mechanisms of the growth behavior and crystal morphology modulation by solvent and supersaturation. Finally, the molecular mechanism of the modulation of the solvent in crystal morphology is revealed base on crystal surface structure analysis and molecular dynamics simulations. The weak solvent-interface polar interactions facilitate the incorporation of benzanilide molecules into the weak polarity (001) face, leading to the surface roughening and increased crystal thickness when employing strongly polar solvents such as acetonitrile. Unlike the former, the relatively weak hydrogen bonding interactions between solvents and strong polarity (020) face, and the higher diffusion ability of molecules promote the rapid growth and disappearance of (020) face in ethanol and acetonitrile with strong hydrogen bond formation ability. This study can contribute to a deeper understanding of the solvent effect on crystal morphology and provide guidance for optimizing crystallization conditions to obtain shape-tailored crystal products.

Electron Spin Polarization in the Triplet State of Methoxy-substituted Phosphorus(V) Tetraphenyl Porphyrins

Photoexcited triplet states of porphyrins are of great relevance in various applications due to their high yield, long lifetime, and strong electron spin polarization. This study delves into properties and spin dynamics of the triplet state of a series of hypervalent phosphorus(V) porphyrins. Transient Electron Paramagnetic Resonance (TrEPR) measurements, supported by quantum chemical calculations as well as by optical absorption/luminescence experiments, reveal that, unlike singlet states, the lowest triplet state does not exhibit charge-transfer (CT) character upon photoexcitation. However, the presence of excited CT singlet states alters the intersystem crossing in phosphorus(V) porphyrins, leading to a sign change in the initial multiplet polarization of the photoexcited triplet state. TrEPR results further demonstrate that significant net polarization develops in the triplet states of the phosphorus(V) porphyrins due to the dynamic Jahn-Teller effect. Yet, this effect remains largely unaffected by differences in their molecular structures.

Use of the 5P3/2→6P3/2 electric dipole forbidden transition in Rb as a non-perturbing probe of atom dynamics in an operating magneto-optical trap

Abstract Results of spectroscopy experiments using the $5P_{3/2} \to 6P_{3/2}$ electric dipole forbidden transition in cold rubidium atoms are presented. Production of this forbidden transition is detected by observing the emission of the $420 $ nm fluorescence photons that result from the decay of the $6P_{3/2} $ state into the ground state. The experiments are performed under the steady state operation conditions of a magneto-optical trap (MOT), and thus provide non-perturbing information on the atom-light system. The hyperfine structure of the $6P_{3/2}$ level is completely resolved, and the fluorescence peaks show the expected Autler-Townes (AT) splitting of the emission lines. This hyperfine structure is used to calibrate the frequency scale of all spectra recorded. A combination of this absolute frequency scale and an expression for the AT profile allows an absolute determination of the effective Rabi frequency and detuning of the MOT. The behavior of these AT doublets is studied as a function of frequency detuning and also as a function of the trapping light intensity.
The experiments also take full advantage of the strong polarization dependence of the relative intensities of the hyperfine fluorescence components.
This study results in a sensitive probe of the relative populations of the magnetic sublevel projections relative to the trapping magnetic field gradient.
An almost isotropic population distribution was found, but small deviations from isotropy could be determined with this electric dipole forbidden probe.

Preparation, Modification and Property Characterization of Nano-TiO2

Abstract In view of the strong polarity and easy agglomeration of nano TiO2 in practical applications, its excellent performance cannot be fully exerted. In this paper, nano titanium dioxide was prepared by liquid phase hydrolysis method using TiCl4 and oxalic acid as raw materials, and then the surface modification of nano TiO2 was carried out with sodium dodecylbenzenesulfonate(SDS). The optimal modification process conditions were obtained through single-factor experiment and orthogonal experiment. The products before and after modification were characterized by scanning electron microscopy, infrared spectroscopy, particle size analysis. The results indicated that the modified nano titanium dioxide adsorbed a certain amount of modifier on the surface, with small and uniform particles that are not easily agglomerated. This greatly improved its dispersibility and stability in media, providing better guarantee for its application in various fields.

Measurement of the polarizations of prompt and non-prompt and [formula omitted] mesons produced in pp collisions at [formula omitted]

The polarizations of prompt and non-prompt ▪ and ψ(2S) mesons are measured in proton-proton collisions at s=13 TeV, using data samples collected by the CMS experiment in 2017 and 2018, corresponding to a total integrated luminosity of 103.3fb−1. Based on the analysis of the dimuon decay angular distributions in the helicity frame, the polar anisotropy, λϑ, is measured as a function of the transverse momentum, pT, of the charmonium states, in the 25–120 and 20–100 GeV ranges for the ▪ and ψ(2S), respectively. The non-prompt polarizations agree with predictions based on the hypothesis that, for pT≳25GeV, the non-prompt ▪ and ψ(2S) are predominantly produced in two-body B meson decays. The prompt results clearly exclude strong transverse polarizations, even for pT exceeding 30 times the ▪ mass, where λϑ tends to an asymptotic value around 0.3. Taken together with previous measurements, by CMS and LHCb at s=7 TeV, the prompt polarizations show a significant variation with pT, at low pT.

Weak nonlinearity engineering induced excellent low-field energy storage performance in BNTST-based lead-free relaxors

With continuously developing of electronic power systems, ceramic dielectrics with superior energy-storage performance have received widespread attention. Relaxor ferroelectric ceramics have become a research hotspot due to the small hysteresis, while how to modify the strong nonlinear and limited polarization difference is still a huge challenge for achieving a desirable discharge energy density (Wdis). In this work, a linear-like relaxors system with high polarization is constructed by introducing antiferroelectric phase (NaNbO3, NN) into relaxor ferroelectric phase (0.6Bi0.5Na0.5TiO3-0.4SrTiO3, BNTST). Benefitting from the improvement on DC-bias stability and the high zero-field dielectric constant, the 0.90BNTST-0.10NN ceramic successfully keeps a high effective dielectric constant even at high electric fields (εr@120kV/cm=1670), which ensures the high polarization and optimized linearity of P-E loops. As a result, 0.90BNTST-0.10NN ceramics achieve superior energy storage performance with a high Wdis (5.79 J/cm3) and high efficiency (91.5 %). These findings provide an effective nonlinearity-weakening approach to explore promising candidate in practical energy-storage applications.

A Hybrid Perovskite-Based Electromagnetic Wave Absorber with Enhanced Conduction Loss and Interfacial Polarization through Carbon Sphere Embedding.

Electronic equipment brings great convenience to daily life but also causes a lot of electromagnetic radiation pollution. Therefore, there is an urgent demand for electromagnetic wave-absorbing materials with a low thickness, wide bandwidth, and strong absorption. This work obtained a high-performance electromagnetic wave absorption system by adding conductive carbon spheres (CSs) to the CH3NH3PbI3 (MAPbI3) absorber. In this system, MAPbI3, with strong dipole and relaxation polarization, acts dominant to the wave absorber. The carbon spheres provide a free electron transport channel between MAPbI3 lattices and constructs interfacial polarization loss in MAPbI3/CS. By regulating the content of CSs, we speculate that this increased effective absorption bandwidth and reflection loss intensity are attributed to the conductive channel of the carbon sphere and the interfacial polarization. As a result, when the mass ratio of the carbon sphere is 7.7%, the reflection loss intensity of MAPbI3/CS reaches -54 dB at 12 GHz, the corresponding effective absorption bandwidth is 4 GHz (10.24-14.24 GHz), and the absorber thickness is 2.96 mm. This work proves that enhancing conduction loss and interfacial polarization loss is an effective strategy for regulating the properties of dielectric loss-type absorbing materials. It also indicates that organic-inorganic hybrid perovskites have great potential in the field of electromagnetic wave absorption.

The Polarity Oscillations of the Equatorial Electrojet in Response to the Geomagnetic Storm on 1 December 2023

AbstractThe moderate geomagnetic storm on 1 December 2023 is interesting that the aurora is unexpectedly observed in Beijing. During this storm, the behaviors of the equatorial electrojet (EEJ) might deserve to be explored. When the polarization of the daytime electric field changes westward, the direction of EEJ turns westward as well, termed the counter electrojet (CEJ). Using the total electron content from Global Navigation Satellite System, observed EEJ from Tatuoca station and low‐orbit Swarm satellites, and the corresponding simulations from the Thermosphere‐Ionosphere Electrodynamic General Circulation Model, the polarization oscillations of EEJ responses (ΔEEJ) during the geomagnetic storm on 1 December 2023 are explored. A significant polarity oscillation is established in the Swarm‐observed ΔEEJ at 9.6 and 12.8 local time (LT). A similar oscillation is also found at 15 LT. The strong polarity oscillations of ΔEEJ are dominated by the electric field, with ignorable effects from the ionospheric Cowling conductivity. The correlation coefficient between ΔEEJ and electric field changes (ΔE) is larger than 0.87, confirming the roles of the electric field. In the pre‐noon sector, the quasi‐oscillations of ΔEEJ are controlled by both the neutral winds and the prompt penetration electric field (PPEF). At noon, ΔEEJ is primarily driven by the PPEF, with minor effects from neutral winds. At afternoon, ΔEEJ is attributed to the PPEF, and the effects of neutral winds are ignorable.

Synergistically magnetic and dielectric properties of two dimensional Fe3Al@PPy lamellae exhibiting broadband and strong electromagnetic wave absorption

Addressing the issue of low impedance characteristics is essential to improve the electromagnetic wave absorption performance of magnetic materials. Herein, two dimensional Fe3Al@polypyrrole (PPy) lamellae with synergistic magnetic and dielectric properties are fabricated by a mechanical alloying, ordering transformation and polymerization process, which exhibits excellent electromagnetic wave absorption performance. By carefully controlling the thickness of the PPy shell, the optimized Fe3Al@PPy lamellae show a minimum reflection loss of −45.6 dB and an effective absorption bandwidth of 9.1 GHz at a thickness of only 1.5 mm. The conformal growth of Fe3Al@PPy lamellae can induce strong interfacial polarization, dipole polarization, multiple scattering effect and magnetic loss behaviors for the attenuation of electromagnetic waves. This study demonstrates a facile strategy for the development of efficient Fe3Al@PPy composite absorbents showing great potential for practical applications.

Hybrid Anapole Induced Chirality in Metasurfaces.

The interaction between light and matter, particularly chirality, plays a pivotal role in modern science and technology. Typically, metasurfaces achieve chiro-optical effects by coupling electric and magnetic dipoles in specific orientations. In this work, the design and optimization of an asymmetric H-shaped metasurface is explored to induce hybrid anapole (HA) for optical activity. When the symmetry of the metasurface structure is disrupted, the design can simultaneously excite first-order and pseudo high-order HA under illumination with a specific circular polarization, both occurring within the same spectral regime. This results in high reflection for one circular polarization and a significant reduction in reflection for the orthogonal polarization, thereby exhibiting exceptional chiro-optical activity. Moreover, the HA-based chiral metasurface demonstrates strong polarization control capabilities, as verified by Stokes parameter analysis, revealing high birefringence and a pronounced dependence on the incident polarization angle. These results provide valuable insights for the design and optimization of HA metasurfaces for advanced optical applications and polarization control, paving the way for new developments in chiral nanophotonics.

Thermal-triggered healing strategy for efficient and stable perovskite solar cells with efficiency over 25 %

The power conversion efficiency (PCE) of organic-inorganic hybrid perovskite solar cells (PSCs) is hindered by the abundant defects within the grain boundaries (GBs) of perovskite films. Herein, a directed thermal-triggered healing strategy based on phthalide-3-acetic acid (P3AC) is proposed, aiming to mitigate GBs defects and optimize energy level arrangement by utilizing the strong polarity effect of P3AC and its thermal-triggered interaction with perovskite. The introduced dual-sites molecular (P3AC) anchors at the GBs of perovskite, which can passivate the uncoordinated Pb2+ and form hydrogen bonds with FA+, yielding dense, uniform and low-defects and large-grain perovskite film. Compared to the pristine devices, the P3AC-modified devices achieved a champion PCE of 25.28 % (certified PCE of 24.46 %) and impressive operational stability. This work provides an effective and direct solution for enhancing the performance of PSCs.

Unveiling the Unusual Electron–Phonon Interaction and Quasi‐Particle Dynamics in type‐II Weyl Semimetal NbIrTe4

AbstractLayered ternary type‐II Weyl semimetals demonstrate promising applications in high‐performance and broadband optoelectronics, therefore it is crucial to gain insights into their photocarriers’ dynamics. In this work, the probing polarization dependence of non‐equilibrium dynamics in NbIrTe4 is investigated by using transient reflectivity spectroscopy. Following photoexcitation at 3.18 eV, the dynamical response of 1.59 eV probe pulse exhibits a strong dependence on probe polarization. The relaxation comprises two components: a rapid recovery of ≈0.6 ps attributed to the electron–phonon scattering, and an anomalous slow recovery spanning hundreds of picoseconds attributed to the photoinduced quasi‐particle. The polarization dependence of rapid relaxation time τ is indicative of the in‐plane anisotropy of electron–phonon coupling in NbIrTe4. The slow relaxation modulated by a latest reported 16 cm−1 coherent phonon also shows strong probing polarization dependence, further revealing the anisotropic nature of electron–phonon coupling and the possibility of anisotropic lattice distortion, as well as photoinduced polaron, under ultrafast photoexcitation in NbIrTe4. The dynamical anisotropy in NbIrTe4 has provided valuable guidance for the application of NbIrTe4 in polarization‐sensitive nonlinear optics or optoelectronic devices and offers insights into the unique carrier transport as well as phonon transport properties of this newly established topological material.

Engineering the structure-directed functional properties of brominated organic additives for high-performance Li-CO2 batteries

In recent years, functional brominated organic additives in electrolytes have been widely studied during the CO2ER (CO2 evolution reaction) and CO2RR (CO2 reduction reaction) processes for Li-CO2 batteries. Due to their different structures, the functions of these additives are always unpredictable, multiple and limited. There seems to be a lot of materials to choose from for an additive, but there is no well-established and effective methodology to guide the selection. Herein, we introduced B3BPE, E4BCT and BPB into electrolytes for Li-CO2 batteries and focused on the structure-directed engineering of additives, including the position of halide substituent groups, the chain length of organic materials, their chain-break product as well as their corresponding difference in electrochemical properties, as additives for comparison. As a result, B3BPE has the longest chain length and strongest polarity. Experiments coupled with density functional theory simulations indicate that this structure exhibits the stronger interaction with Li2CO3, which benefits the CO2ER process, the charging voltage can be maintained at 3.90 V for 120 cycles even with a Super P cathode. In this work, we provided an electrolyte-selection engineering for brominated organic compounds, further inspiring in-depth understanding for bromide additives in future high-performance Li-CO2 batteries.

Reduced dielectric loss of MXene/PVDF composites with adding MnO2 nanorods

To reduce the dielectric loss of MXene/PVDF composites near the percolation threshold, a MnO2/MXene hybrid structure was successfully synthesized via an ultrasonic-assisted solution process, and MnO2/MXene/PVDF composite films were prepared by a solution casting method. The effects of different amounts of MnO2 nanorods on the microstructure, thermal stability, dielectric properties and mechanical properties of the composite films were investigated. At 1 kHz, the dielectric constant of 7 wt% MnO2/MXene/PVDF is 37.3, and the dielectric loss is as low as 0.05. The electric modulus curve, Nyquist curve and equivalent analog circuit of the composites revealed strong interface polarization and microcapacitance effects in the composites. In addition, the composite films exhibit excellent mechanical properties, and the storage modulus of the composite film loaded with 10 wt% MnO2 is 1990.5 MPa, which is 3.44 times that of pure PVDF. This study confirms that incorporating MnO2 nanorods into MXene/PVDF composites is an effective approach for fabricating high-performance dielectric composites.

Lanthanide Complexes Containing a Terminal LnIII−O Bond: Hydrolysis as a Tool to Assess f‐Element Bond Covalency

AbstractWe report the preparation, isolation, and reactivity of gas‐phase lanthanide nitrate and acetate complexes featuring the elusive trivalent LnIII=O bond. Complexes [LnIII(O)(X)2]− (X=NO3− or CH3CO2−; Ln=La, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Tm, Lu) are prepared from [LnIII(CH3CO2)(X)3]− precursors through decarboxylation followed by nitromethane or acetone elimination. The oxo complexes hydrolyze at rates indicating LnIII=O bond stability. The rates for [LnIII(O)(NO3)2]− are essentially invariant, whereas those for [LnIII(O)(CH3CO2)2]− exhibit a moderate decrease across the lanthanide series. The kinetics of lanthanide‐oxo bond hydrolysis are assessed in the context of participation of 5d2 electrons in bonding, changes in covalency via variations in 5d orbital energies and radial extensions, and steric crowding around the lanthanide center. The observed fast hydrolysis rates and lack of correlation to electronic and qualitative covalent considerations confirm the expected strong polarization in LnIII=O bonding, with variations in covalency minimally impacting reactivity. The LnIII=O bond reactivity is compared with previous results for LnIII−O⋅ and LnIV=O, and actinide AnIII=O and AnIV=O; implications for lanthanide/actinide and lanthanide/lanthanide partitioning are discussed. Additionally, nitromethane and acetone elimination are demonstrated as useful for inducing a 2e− O‐atom transfer resulting in non‐oxidative formation of lanthanide‐oxos.