Strong Deviations Research Articles

Discovery and Geological Significance of Neoproterozoic Bimodal Intrusive Rocks in the Dabie Orogen, China

The Mingshan reservoir of the Dabie Orogen has a number of Neoproterozoic bimodal intrusive rocks. We focused on the zircon U-Pb chronology, Hf isotopes, and bulk-rock geochemistry of these rocks. The results showed the following: (1) The bimodal intrusive rocks mainly consist of monzogranitic gneiss and plagioamphibolite, with zircon U-Pb ages of 785.0 ± 7.1 Ma and 787.3 ± 6.1 Ma, respectively. These ages indicate that they were formed in the late Qingbaikou epoch of the Neoproterozoic era. (2) The monzogranitic gneiss was dominated by peraluminous features and displayed a strong right deviation of REE (rare-earth element) patterns and a negative δEu anomaly. It is enriched in the LILEs (large-ion lithophile elements) Rb, Ba, and K, but slightly depleted in Nb, Sr, P, and Ti, with low 10,000* Ga/Al values, indicating that it is similar to Al-type granite. The plagioamphibolite belongs to the metaluminous, peraluminous series. It has a Mg# (molar ratio of Mg to Mg + Fe) of 36.1~55.9 and is enriched in the LILEs Rb, Ba, and K, with a slight positive anomaly of Ba, and is depleted in Nb and Sr. (3) The monzogranite shows negative zircon εHf(t) values ranging from −13.4 to −7.2 and a Paleoproterozoic TDM2(Hf) (two-stage depleted mantle model age) of 1969–2298 Ma. The zircon εHf(t) values and TDM2(Hf) of the plagioamphibolite were concentrated around 2.9–5.7 and 1257–1410 Ma, respectively. The geochemistry and Hf isotopes show that the monzogranitic gneiss and plagioamphibolite have distinct magmatic sources. The plagioamphibolite formed from mantle and partial continental crustal materials. The monzogranitic gneiss, on the other hand, was formed as a result of the partial melting of the shallow ancient felsic crust caused by mafic rock heating or upwelling. Taking into account regional correlation, the middle Neoproterozoic bimodal intrusive rocks originated in the structural framework of an extensional setting.

Comparison of dU/dQ, Voltage Decay, and Float Currents via Temperature Ramps and Steps in Li‐ion Batteries

Comparison of dU/dQ, Voltage Decay, and Float Currents via Temperature Ramps and Steps in Li‐ion Batteries

Testing the Accuracy of Spectral Energy Distribution Modeling Techniques Using the NIHAO-SKIRT-Catalog

We use simulated galaxy observations from the NIHAO-SKIRT-Catalog to test the accuracy of spectral energy distribution (SED) modeling techniques. SED modeling is an essential tool for inferring star formation histories from nearby galaxy observations but is fraught with difficulty due to our incomplete understanding of stellar populations, chemical enrichment processes, and the nonlinear, geometry-dependent effects of dust. The NIHAO-SKIRT-Catalog uses hydrodynamic simulations and radiative transfer to produce SEDs from the ultraviolet (UV) through the infrared (IR), accounting for dust. We use the commonly used Prospector software to perform inference on these SEDs and compare the inferred stellar masses and star formation rates (SFRs) to the known values in the simulation. We match the stellar population models to isolate the effects of differences in the star formation history, the chemical evolution history, and the dust. For the high-mass NIHAO galaxies (>109.5 M ⊙), we find that model mismatches lead to inferred SFRs that are on average underestimated by a factor of 2 when fit to UV through IR photometry, and a factor of 3 when fit to UV through optical photometry. These biases lead to significant inaccuracies in the resulting specific SFR–mass relations, with UV through optical fits showing particularly strong deviations from the true relation of the simulated galaxies. In the context of massive existing and upcoming photometric surveys, these results highlight that star formation history inference from photometry may remain imprecise and inaccurate and that there is a pressing need for more realistic testing of existing techniques.

Correcting for Replicated Genotypes May Introduce More Problems Than it Solves.

Across the tree of life, many organisms are able to reproduce clonally, via vegetative spread, budding or parthenogenesis. In population genetic analyses of clonally reproducing organisms, it is common practice to retain only a single representative per multilocus genotype. Though this practice of clone correction is widespread, the theoretical justification behind it has been very little studied. Here, I use individual-based simulations to study the effect of clone correction on the estimation of the genetic summary statistics HO, HS, FIS, FST, F''ST and Dest. The simulations follow the standard finite island model, consisting of a set of populations connected by gene flow, but with a variable rate of sexual versus asexual reproduction. The results of the simulations show that by itself, the inclusion of replicated genotypes does not lead to a deviation in the values of the summary statistics, except when the rate of sexual reproduction is less than about one in thousand. However, clone correction can introduce a strong deviation in the values of most of the statistics, when compared to a scenario of full sexual reproduction. For HS and FIS, this deviation can be informative about the process of asexual reproduction, but for FST, F''ST and Dest, clone correction can lead to incorrect conclusions. I therefore argue that clone correction is not strictly necessary, but can in some cases be insightful. However, when clone correction is applied, it is imperative that results for both the corrected and uncorrected data are presented.

Extending the Asteroseismic Calibration of the Stellar Rossby Number

The stellar Rossby number (Ro) is a dimensionless quantity that is used in the description of fluid flows. It characterizes the relative importance of Coriolis forces on convective motions, which is central to understanding magnetic stellar evolution. Here we present an expanded sample of Kepler asteroseismic targets to help calibrate the relation between Ro and Gaia color, and we extend the relation to redder colors using observations of the mean activity levels and rotation periods for a sample of brighter stars from the Mount Wilson survey. Our quadratic fit to the combined sample is nearly linear between 0.55 < G BP − G RP < 1.2, and can be used to estimate Ro for stars with spectral types between F5 and K3. The strong deviation from linearity in the original calibration may reflect an observational bias against the detection of solar-like oscillations at higher activity levels for the coolest stars.

Machine learning-augmented modeling on the formation of Si-dominated Non-β″ early-stage precipitates in Al-Si-Mg alloys with Si supersaturation induced by non-equilibrium solidification

Recent experiments have shown that Al-Si-Mg alloys solidified under high cooling rates may lead to the nucleation of Si-enriched clusters that are remarkably different from the conventional Mg-Si co-clusters (e.g. β″ particles), and yet the responsible mechanism remains to be elucidated. Here we tackle the problem using a multiscale modeling framework that integrates atomistic modeling, energy landscape sampling, and lattice-based kinetic Monte Carlo (kMC) simulation. The migration energy barriers for vacancy-mediated diffusion amid complex local chemical environments are predicted on-the-fly using a surrogate machine learning model. We discover that the actual vacancy-Si migration barriers are much lower than those assumed in the classic linear interpolation approximation. Such a strong deviation from conventional wisdom, in conjunction with differing Si solute composition, can lead to a great variety in the nucleated early-stage precipitates. More specifically, a high-level supersaturation of Si solute (i.e.xSi/(xSi+xMg)>0.75) would lead to an unexpectedly high enrichment of Si in the nucleated clusters with the Si:Mg ratio up to 5∼6; while at a lower-level supply of Si solute the Mg-Si co-clusters (i.e. Si:Mg ratio around 1∼2) are nucleated instead. These findings provide a viable explanation for the diverse types of early-stage precipitates observed in various experiments, from Si-enriched precipitates in high-pressure die cast Al alloys to β″ particles in conventional casting and/or heat-treated alloys. The implications of our findings are also discussed.

Large enhancement of properties in strained lead-free multiferroic solid solutions with strong deviation from Vegard’s law

Large enhancement of properties in strained lead-free multiferroic solid solutions with strong deviation from Vegard’s law

Unveiling the Burden of Hepatitis A in Salerno, Italy: A Comprehensive 9-Year Retrospective Study (2015-2023) on the Seroprevalence of HAV Antibodies and Age/Sex Distribution.

Background: Hepatitis A virus (HAV) infection is a significant global cause of viral hepatitis. At present, the anti-HAV vaccine in Italy is proposed exclusively for specific high-risk groups, and a universal vaccination program is not implemented. Objectives: This study aimed to assess the level of immunity against HAV in patients of both sexes across age groups ranging from 0 to 95 years admitted to the San Giovanni di Dio e Ruggi d'Aragona Hospital in Salerno, Italy, over a 9-year period (2015-2023). Methods: The total HAV seroprevalence by chemiluminescence Vitros system immunodiagnostics (ortho-diagnostics) was obtained by database analysis, stratifying patients for gender and age group in both the pre-pandemic (2015-2019) and pandemic (2020-2023) periods. Results: Out of 28,104 samples collected in 2015-2023, 20,613 resulted positive by total HAV immune screening, with a significant reduction in the annualized proportion of events during the pandemic period compared to the pre-pandemic period. HAV was more abundant in males than females in both periods (exceeding the 70%), with a statistically significant decrease in HAV in females in 2015-2019. The 61-70-year-old age group is more susceptible for both genders, with a strong deviation from the 41-50-year-old age group compared to the 51-60-year-old group. The pandemic period affected the number of analyzed samples in 2020. Conclusions: The study revealed high HAV seroprevalence, especially in males and individuals aged 61-70 years. There was a notable decrease in seroprevalence during the pandemic compared to pre-pandemic years. These results emphasize the need for ongoing monitoring and suggest that a universal vaccination program could address regional immunity gaps and lower disease incidence.

Non-Idealities in adsorption thermodynamics for CO2 capture from humid natural gas using CALF-20

The focus of this article is on CO2 capture from natural gas under humid conditions using CALF-20. Configurational-Bias Monte Carlo (CBMC) simulations are used to investigate adsorption of CO2/CH4/H2O mixtures in CALF-20 with varying relative humidities in the bulk gas phase. The CBMC simulations reveal that the mixture adsorption equilibrium shows strong deviations from the estimations of the Ideal Adsorbed Solution Theory (IAST). CBMC simulations for mixture adsorption of the constituent binary pairs, CH4/H2O, and CO2/H2O, reveal that the origin of thermodynamic non-idealities stem from segregated nature of the adsorbed phase and inhomogeneous distribution of guest adsorbates within the pore landscape of CALF-20. The extent and nature of the segregation depends strongly on the % relative humidity of the bulk gas mixture.The important message that emerges from this investigation is the need to incorporate the Real Adsorbed Solution Theory (RAST) for quantitative modelling of fixed-bed adsorbers in natural gas purification with CALF-20.

2023 temperatures reflect steady global warming and internal sea surface temperature variability

2023 was the warmest year on record, influenced by multiple warm ocean basins. This has prompted speculation of an acceleration in surface warming, or a stronger than expected influence from loss of aerosol induced cooling. Here we use a recent Green’s function-based method to quantify the influence of sea surface temperature patterns on the 2023 global temperature anomaly, and compare them to previous record warm years. We show that the strong deviation from recent warming trends is consistent with previously observed sea surface temperature influences, and regional forcing. This indicates that internal variability was a strong contributor to the exceptional 2023 temperature evolution, in combination with steady anthropogenic global warming.

Magnetic irreversibility and magnetization processes in Ni5Al3/NiO core/shell nanoparticle system

This work brings out many interesting facets of magnetism in the Ni5Al3/NiO core/shell nanoparticle system. Theweakandstrongmagnetic irreversibility lines (TWI(H)andTSI(H)) reproduce the previously reportedH - Tphase diagram at fieldsH⩽30 Oe, but strong departures occur forH > 30 Oe. Comparison with the theoretically predictedH - Tphase diagram allows us to identifyTWIwithTCG+SG, where the paramagnetic (PM)-chiral glass (CG) and PM-spin glass (SG) phase transitions occursimultaneously, andTSIwithTSG, the temperature at which transition to the replica symmetry breakingSGstate takes place. TheTSI(H)transition line abruptly ends at the point (H≃30 Oe,T≃90K). AsHexceeds 30 Oe, a new transition appears which gets completely suppressed at fieldsH>1 kOewhere the magnetic irreversibility ceases to exist. Nointrinsiclong-range ferromagnetic ordering exists but fields as low as 3 kOe suffice to induce long-range ferromagnetic order. At fixed temperatures, the magnetocrystalline anisotropy fluctuations essentially govern the 'approach-to-saturation' in magnetization for fields in the range 3 - 70 kOe. The present nanocrystalline system behaves as an isotropic system with random easy axis in which the magnetization reversal occurs through the coherent rotation of the magnetizations of weakly-interacting single-domain Ni5Al3particles. Saturation magnetization, likeM(T) atH⩾2 kOe, exhibits an anomalous upturn at temperatures below ≈ 30 K. This upturn is associated with the anomalous softening of spin-wave modes which results in the thermal excitation of a large number of non-equilibrium (finite lifetime) magnons. At sub-Kelvin temperatures, these magnons undergo Bose-Einstein condensation.

Non-Gaussianity consistency relations and their consequences for the peaks

Strong deviations from scale invariance and the appearance of high peaks in the primordial power spectrum have been extensively studied for generating primordial black holes (PBHs) or gravitational waves (GWs). It is also well-known that the effect of non-linearities can be significant in both phenomena. In this paper, we advocate the existence of a general single-field consistency relation that relates the amplitude of non-Gaussianity in the squeezed limit f NL to the power spectrum and remains valid when almost all other consistency relations are violated. In particular, it is suitable for studying scenarios where scale invariance is strongly violated.We discuss the general and model-independent consequences of the consistency relation on the behavior of f NL at different scales.Specifically, we study the size, sign and slope of f NL at the scales where the power spectrum peaks and argue that generally the peaks of f NL and the power spectrum occur at different scales.As an implication of our results, we argue that non-linearities can shift or extend the range of scales responsible for the production of PBHs or GWs, relative to the window as determined by the largest peak of the power spectrum, and may also open up new windows for both phenomena.

Collective Charge Excitations between Moiré Minibands in Twisted WSe_{2} Bilayers Probed with Resonant Inelastic Light Scattering.

We establish low-temperature resonant inelastic light scattering (RILS) spectroscopy as a tool to probe the formation of a series of moiré bands in twisted WSe_{2} bilayers by accessing collective inter-moiré-band excitations (IMBEs). We observe resonances in RILS spectra at energies in agreement with inter-moiré-band transitions obtained from an abinitio based continuum model. Transitions between the first and second moiré band for a twist angle of about 8° are reported and between the first and the third, and higher bands for a twist of about 3°. The signatures from IMBE for the latter highlight a strong departure from parabolic bands with flat minibands exhibiting very high density of states in accord with theory. These observations allow one to quantify the transition energies at the K point where the states relevant for correlation physics are hosted.

Effect of Aerosol Size on Glass Transition Temperature.

The amorphous phase state of suspended nanoparticles affects their atmospheric lifetimes and environmental impact. Influence of relative humidity and chemical composition on the glass-to-liquid transition is well-known. However, the influence of the particle size on the phase transition remains uncertain. Here we show experimental data that probe the amorphous phase transition of suspended sucrose particles as a function of particle size. The depression in glass-transition temperature follows the Gibbs-Thomson or Keesom-Laplace predicted proportionality of ΔTg ∝ D-1 for particles 100-700 nm in diameter, but the proportionality changes to ΔTg ∝ D-1/2 for smaller sizes. Literature data for glass-transition temperature depression in thin films and nanoconfined compounds show similar and strong deviations from the expected D-1 behavior. While the observed proportionalities remain incompletely understood, the results here provide evidence that the deviation from ΔTg ∝ D-1 is not attributable to substrate effects.

Turbulence Modulation By Large Heavy Particles In Wall-Bounded Turbulence

"Most studies on particle laden flows have focused either on small heavy particles or large neutrally buoyant particles. We present, for the first time (to the best of our knowledge), results in the regime of large and heavy particles, investigating the particle-turbulence dynamics over a parameter space covering a wide range of particle-volume fractions, Stokes and Froude numbers. We consider a flow in a pipe aligned with the gravitational vector, thus allowing for the investigation of the two-way coupling between particles and carrier phase turbulence, while excluding the effect of gravity on the wall-normal migration of particles. Time-resolved images of both tracers (10 micrometers particles) and the dispersed particles (700 micrometers in diameter) were taken in the streamwise-wall-normal pipe plane using a planar particle image velocimetry (PIV) system consisting of a high speed camera (Phantom VEO 440), and an Nd:YLF Laser as light source. Using Voronoi tessellations to analyze the inertial particle dynamics, we show a strong deviation from Poisson behaviour for cases with and without turbophoresis. From the time-resolved PIV measurements, we also show that the carrier phase turbulence is modulated even at particle concentrations as low as 0.3% indicating that particle-induced stresses due to distortion of fluid streamlines cannot be neglected. An increase or decrease in the peak streamwise velocity fluctuation in the particle laden flow was observed, depending on the Stokes number, while the radial velocity fluctuation was found either to be the same as in the single phase flow case or higher. Furthermore, pressure drop measurements indicate a linear increase in the skin friction coefficient with volume fraction of particles. This was true for all Stokes and Froude numbers considered. The growth rate (β) of the skin friction coefficient was however observed to be only a function of the Froude number. A power-law fit to the data shows that β scales inversely with the Froude number indicating that for Froude numbers less than 1, the influence of gravity cannot be neglected. "

Density and surface tension of liquid Al, V and their binary alloys measured by electromagnetic levitation

Both density and surface tension were systematically investigated over a wide temperature and compositional range for the liquid Al–V alloy system. The thermophysical properties were measured in an electromagnetic levitation device. A linear decrease in surface tension and density with increasing temperature was observed for every alloy composition investigated. Additionally, a decrease in density and surface tension was observed for increasing aluminum content among the different probed samples. This decrease is, a strong deviation from an ideal mixing behavior which was experienced for both properties. Different models, including variants of the well-established Butler model, were employed to better describe the compositional dependence of density and surface tension in the liquid Al–V system. The advantages and disadvantages were discussed for each model describing the measured thermophysical property data. Strong similarities were observed when comparing the mixing behavior and segregation effects of the investigated Al–V system with already established works for the liquid Al–Ti system. The results suggest that both vanadium and titanium show similar mixing behavior when alloyed with aluminum.

X-Ray Emission from Atomic Systems Can Distinguish between Prevailing Dynamical Wave-Function Collapse Models.

In this work the spontaneous electromagnetic radiation from atomic systems, induced by dynamical wave-function collapse, is investigated in the x-ray domain. Strong departures are evidenced with respect to the simple cases considered until now in the literature, in which the emission is either perfectly coherent (protons in the same nuclei) or incoherent (electrons). In this low-energy regime the spontaneous radiation rate strongly depends on the atomic species under investigation and, for the first time, is found to depend on the specific collapse model.

Beyond the standard model of topological Josephson junctions: From crystalline anisotropy to finite-size and diode effects

A planar Josephson junction is a versatile platform to realize topological superconductivity over a large parameter space and host Majorana bound states. With a change in the Zeeman field, this system undergoes a transition from trivial to topological superconductivity accompanied by a jump in the superconducting phase difference between the two superconductors. A standard model of these Josephson junctions, which can be fabricated to have a nearly perfect interfacial transparency, predicts a simple universal behavior. In that model, at the same value of Zeeman field for the topological transition, there is a π phase jump and a minimum in the critical superconducting current, while applying a controllable phase difference yields a diamond-shaped topological region as a function of that phase difference and a Zeeman field. In contrast, even for a perfect interfacial transparency, we find a much richer and nonuniversal behavior as the width of the superconductor is varied or the Dresselhaus spin–orbit coupling is considered. The Zeeman field for the phase jump, not necessarily π, is different from the value for the minimum critical current, while there is a strong deviation from the diamond-like topological region. These Josephson junctions show a striking example of a nonreciprocal transport and superconducting diode effect, revealing the importance of our findings not only for topological superconductivity and fault-tolerant quantum computing but also for superconducting spintronics.

Measurement of the e+e−→π+π− cross section from threshold to 1.2 GeV with the CMD-3 detector

The cross section of the process e+e−→π+π− has been measured in the center of mass energy range from 0.32 to 1.2 GeV with the CMD-3 detector at the electron-positron collider VEPP-2000. The measurement is based on a full dataset collected below 1 GeV during three data taking seasons, corresponding to an integrated luminosity of about 62 pb−1. In the dominant ρ-resonance region, a systematic uncertainty of 0.7% has been reached. At energies around ϕ-resonance the π+π− production cross section was measured for the first time with high beam energy resolution. The forward-backward charge asymmetry in the π+π− production has also been measured. It shows a strong deviation from the theoretical prediction based on the conventional scalar quantum electrodynamics framework, and it is in good agreement with the generalized vector-meson-dominance and dispersive-based predictions. The impact of the presented results on the evaluation of the hadronic contribution to the anomalous magnetic moment of muon is discussed. Published by the American Physical Society 2024

Towards a greater understanding of the deep eutectic phenomenon through examination of the lidocaine-NSAID therapeutic deep eutectic systems

Therapeutic deep eutectic solvents (THEDES) have been attracting increasing attention in the pharmaceutical literature as a promising enabling technology capable of improving physicochemical and biopharmaceutical properties for difficult-to-deliver drug compounds. The current literature has explored amide local anaesthetics and carboxylic acid nonsteroidal anti-inflammatories (NSAIDs) as commonly used THEDES formers for their active hydrogen-bonding functionality. However, little is known about what happens within the “deep eutectic” region where a range of binary compositions present simply as a liquid with no melting events detectable across experimentally achievable conditions. There is also very limited understanding of how parent compounds’ physicochemical properties could impact upon the formation, interaction mechanism, and stability of the formed liquid systems, despite the significance of these information in dose adjustment, industrial handling, and scaling-up of these liquids.In the current work, we probed the “deep eutectic” phenomenon by investigating the formation and physicochemical behaviours of some chosen lidocaine-NSAID systems across a wide range of composition ratios. Our data revealed that successfully formed THEDES exhibited composition dependent Tg variations with strong positive deviations from predicted Tg values using the Gordon-Taylor theory, suggesting substantial interactions within the formed supramolecular structure. Interestingly, it was found that the parent compound’s glass forming ability had a noticeable impact upon such profound interaction and hence could dictate the success of THEDES formation. It has also been confirmed that all successful systems were formed based on charge-assisted hydrogen bonding within their THEDES network, affirming the significant role of partial protonisation on achieving a profound melting point depression. More importantly, the work found that within the “deep eutectic” region there was still an ideal, or thermodynamically preferrable “THEDES point”, which would exhibit excellent stability upon exposure to stress storage conditions.The discoveries of this study bring the literature one step closer to fully understanding the “therapeutic deep eutectic” phenomenon. Through correlation between parent reagents’ physicochemical properties and the synthesised products’ characteristics, we establish a more educated process for the prediction and engineering of THEDES.