Stringent Conditions Research Articles

Near-Unity Photoluminescence Quantum Yield of Core-Only InP Quantum Dots via a Simple Postsynthetic InF3 Treatment.

Indium phosphide (InP) quantum dots (QDs) are considered the most promising alternative for Cd and Pb-based QDs for lighting and display applications. However, while core-only QDs of CdSe and CdTe have been prepared with near-unity photoluminescence quantum yield (PLQY), this is not yet achieved for InP QDs. Treatments with HF have been used to boost the PLQY of InP core-only QDs up to 85%. However, HF etches the QDs, causing loss of material and broadening of the optical features. Here, we present a simple postsynthesis HF-free treatment that is based on passivating the surface of the InP QDs with InF3. For optimized conditions, this results in a PLQY as high as 93% and nearly monoexponential photoluminescence decay. Etching of the particle surface is entirely avoided if the treatment is performed under stringent acid-free conditions. We show that this treatment is applicable to InP QDs with various sizes and InP QDs obtained via different synthesis routes. The optical properties of the resulting core-only InP QDs are on par with InP/ZnSe/ZnS core-shell QDs, with significantly higher absorption coefficients in the blue, and with potential for faster charge transport. These are important advantages when considering InP QDs for use in micro-LEDs or photodetectors.

Centimeter-scale nanomechanical resonators with low dissipation

High-aspect-ratio mechanical resonators are pivotal in precision sensing, from macroscopic gravitational wave detectors to nanoscale acoustics. However, fabrication challenges and high computational costs have limited the length-to-thickness ratio of these devices, leaving a largely unexplored regime in nano-engineering. We present nanomechanical resonators that extend centimeters in length yet retain nanometer thickness. We explore this expanded design space using an optimization approach which judiciously employs fast millimeter-scale simulations to steer the more computationally intensive centimeter-scale design optimization. By employing delicate nanofabrication techniques, our approach ensures high-yield realization, experimentally confirming room-temperature quality factors close to theoretical predictions. The synergy between nanofabrication, design optimization guided by machine learning, and precision engineering opens a solid-state path to room-temperature quality factors approaching 10 billion at kilohertz mechanical frequencies – comparable to the performance of leading cryogenic resonators and levitated nanospheres, even under significantly less stringent temperature and vacuum conditions.

Detection of fucosylated extracellular vesicles miR-4732-5p related to diagnosis of early lung adenocarcinoma by the electrochemical biosensor

Our preliminary investigation has identified the potential of serum fucosylated extracellular vesicles (EVs) miR-4732-5p in the early diagnosis of lung adenocarcinoma (LUAD) by a fucose-captured strategy utilizing lentil lectin (LCA)-magnetic beads and subsequent screening of high throughput sequencing and validation of real-time quantitative polymerase chain reaction (RT-qPCR). Considering the relatively complicated procedure, expensive equipment, and stringent laboratory condition, we have constructed an electrochemical biosensor assay for the detection of miR-4732-5p. miR-4732-5p is extremely low in serum, down to the fM level, so it needs to be detected by highly sensitive electrochemical methods based on the Mg2+-dependent DNAzyme splitting nucleic acid lock (NAL) cycle and hybridization chain reaction (HCR) signal amplification. In this study, signal amplification is achieved through the dual amplification reactions using NAL cycle in combination with HCR. In addition, hybridized DNA strands bind to a large number of methylene blue (MB) molecules to enhance signaling. Based on the above strategy, we further enhance our signal amplification strategies to improve detection sensitivity and accuracy. The implementation of this assay proceeded as follows: initially, miR-4732-5p was combined with NAL, and then Mg2+-dependent DNAzyme splitted NAL to release auxiliary DNA (S1) strands, which were subsequently captured by the immobilized capture probe DNA (C1) strands on the electrode surface. Following this, abundant quantities of DNA1 (H1) and DNA2 (H2) tandems were generated by HCR, and S1 strands then hybridized with the H1 and H2 tandems through base complementary pairing. Finally, MB was bonded to the H1 and H2 tandems through π–π stacking interaction, leading to the generation of a signal current upon the detection of a potential capable of inducing a redox change of MB by the electrode. Furthermore, we evaluated the performance of our developed electrochemical biosensor assay. The results demonstrated that our assay is a reliable approach, characterized by its high sensitivity (with a detection limit of 2.6 × 10−17 M), excellent specificity, good accuracy, reproducibility, and stability. Additionally, it is cost-effective, requires simple operation, and is portable, making it suitable for the detection of serum fucosylated extracellular vesicles miR-4732-5p. Ultimately, this development has the potential to enhance the diagnostic efficiency for patients with early-stage LUAD.

Egypt: Recent Developments in Arbitration Law

Egypt: Recent Developments in Arbitration Law

Dyakonov surface waves in dielectric crystals with negative anisotropy

Abstract Since the initial discovery of Dyakonov surface waves at a flat infinite interface of two dielectrics, at least one of which is positively anisotropic, extensive research has been conducted towards their theoretical and experimental studies in materials with positive anisotropy. The potential applications of these waves were initially limited due to the stringent conditions for their existence and the requirement for position anisotropy. In our study, we present the theoretical prediction and experimental observation of a novel type of Dyakonov surface waves that propagate along the flat strip of the interface between two dielectrics with negative anisotropy. We demonstrate that the conditions for surface waves are satisfied for negatively anisotropic dielectrics owing to the specific boundaries of the strip waveguide confined between two metallic plates. We study such modes theoretically by using the perturbation theory in the approximation of weak anisotropy and demonstrate that the electromagnetic field distribution in these modes is chiral. Experimental verification of theoretical predictions is made in the microwave range using 3D-printed negatively anisotropic water-dielectric metamaterial slabs. The existence of Dyakonov surface waves in negative crystals prompts a reassessment of the list of materials suitable for practical realization of these waves in the visible and infrared ranges. Due to the ability of the considered modes to transmit chiral light, they have potential in the sensing of chiral organic molecules.

Lignin-Derived Lightweight Carbon Aerogels for Tunable Epsilon-Negative Response.

Electromagnetic (EM) metamaterials have garnered considerable attention due to their capacity to achieve negative parameters, significantly influencing the integration of natural materials with artificially structural media. The emergence of carbon aerogels (CAs) offers an opportunity to create lightweight EM metamaterials, notable for their promising EM shielding or absorption effects. This paper introduces an efficient, low-cost method for fabricating CAs without requiring stringent drying conditions. By finely tuning the ZnCl2/lignin ratio, the porosity is controlled in CAs. This control leads to an epsilon-negative response in the radio-frequency region, driven by the intrinsic plasmonic state of the 3D carbon network, as opposed to traditional periodic building blocks. This approach yields a tunable and weakly epsilon-negative response, reaching an order of magnitude of -103 under MHz frequencies. Equivalent circuit analysis highlights the inductive characteristics of CAs, correlating their significant dielectric loss at low frequencies. Additionally, EM simulations are performed to evaluate the distribution of the electric field vector in epsilon-negative CAs, showcasing their potential for effective EM shielding. The lignin-derived, lightweight CAs with their tunable epsilon-negative response hold promise for pioneering new directions in EM metamaterials and broadening their application in diverse extreme conditions.

A novel approach for sludge deep-dewatering via flowing-out enhancement but not relying on cell lysis and bound water release

Effective deep-dewatering is crucial for wastewater sludge management. Currently, the dominant methods focus on promoting cell lysis to release intracellular water, but these techniques often lead to secondary pollution and require stringent conditions, limiting their practical use. This study explores an innovative method using a commercially available complex quaternary ammonium salt surfactant, known as G-agent. This agent remarkably reduces the sludge water content from 98.6 % to 56.8 % with a low dosage (50 mg/g DS) and under neutral pH conditions. This approach surpasses Fenton oxidation in terms of dewatering efficiency and avoids the necessity for cell lysis and bound water release, thereby reducing the risk of secondary pollution in the filtrate, including heavy metals, nitrogen, phosphorus, and other contaminants. The G-agent plays a significant role in destabilizing flocs and enhancing flocculation during the conditioning and initial dewatering stages, effectively reducing the solid-liquid interfacial affinity of the sludge. In the compression filtration stage, the agent's solidification effect is crucial in forming a robust skeleton that improves pore connectivity within the filter cake, leading to increased water permeability, drainage performance and water flow-out efficiency. This facilitates deep dewatering of sludge without cell lysis. The study reveals that the G-agent primarily improves water flow-out efficiency rather than water flowability, indicating that cell lysis and bound water release are not indispensable prerequisites for sludge deep-dewatering. Furthermore, it presents an encouraging prospect for overcoming the limitations associated with conventional sludge deep-dewatering processes.

Improved weighted centroid localization algorithm based on multiple magnetic beacons

To address challenges associated with the traditional drill positioning method, which demands manual walking tracking and imposes stringent environmental conditions, this paper introduces an improved weighted centroid localization (WCL) algorithm based on multiple magnetic beacons. This algorithm alleviates the environmental requirements. Initially, a magnetic beacon measurement model immune to sensor attitude is formulated, followed by the development of a positioning model based on multiple magnetic beacons. The WCL algorithm is then introduced and refined for positioning with multiple magnetic beacons. Finally, the effectiveness of the proposed approach is validated through simulation experiments, revealing an average error of 0.632 m in large-scale positioning. This demonstrates clear advantages over traditional methods, making it highly applicable.

Lower Band Chorus Wave Scattering Causing the Extensive Morningside Diffuse Auroral Precipitation During Active Geomagnetic Conditions: A Detailed Case Study

AbstractThe diffuse aurora is a natural phenomenon observed over the Earth's polar region. Compared with the nightside diffuse aurora, the brightness of the dayside diffuse aurora (0600–1800 magnetic local time (MLT)) is relatively weak, thus requiring more stringent observation conditions. Therefore, the current understanding of what causes the dayside diffuse aurora is still quite limited. Here, we present an intense morningside diffuse aurora (0600–1000 MLT) event observed on 1 January 2016 during the recovery phase of the substorm, using conjugate observations of wave and particle spectrum from the Radiation Belt Storm Probes and auroral emission from the Special Sensor Ultraviolet Spectrographic Imagers on the Air Force Defense Meteorological Satellite Program (DMSP/SSUSI). We perform calculations of diffusion coefficients and simulations of the electron fluxes for this event. Our results show that the chorus waves are the primary contributors to the formation of the morningside diffuse aurora, with precipitated electron energies ranging from a few keV to tens of keV. The lower band chorus shows significant pitch angle scattering efficiency for electrons with energies from 5 to 20 keV. The upper band chorus waves induce acceleration effects on 1–20 keV electrons. We suggest that the upper band chorus waves accelerate low‐energy electrons to higher energies, enabling them to engage in the scattering process of the lower band chorus waves. Our study makes a contribution to recent research on the formation mechanisms of diffuse aurora and deepens our understanding of wave‐particle interactions leading to dayside electron precipitation.

Interlayer Entropy Engineering Inducing the Symmetry-Broken Layered Oxide Cathodes to Activate Reversible High-Voltage Redox Reaction.

The as-reported doping entropy engineering of electrode materials that are usually realized by the sharing of multiple metal elements with the metal element from the lattice body, potentially has three shortages of stringent synthesis conditions, large active element loss, and serious lattice distortion. Herein, an interlayer entropy engineering of layered oxide cathodes is proposed, where the multiple metal ions are simultaneously intercalated into the same interlayer sites, thus avoiding the three shortages. Concretely, a novel interlayer medium-entropy V2O5 ((MnCoNiMgZn)0.26V2O5∙0.84H2O) is successfully constructed by a one-step hydrothermal method. The interlayer medium-entropy effect is revealed to be that five metal ions pre-intercalation induces the local symmetry-broken [VO6] octahedra in bilayer V2O5, thus activating the reversible high-voltage redox reaction, inhibiting the layer slip and following phase transformation by its pinning effect, and enhancing the charge transfer kinetics. As a result, the medium-entropy cathode realizes the trade-off between specific capacity and structural stability with a discharge capacity of 152mAhg-1 at 0.1Ag-1 after 100 cycles, and a capacity retention rate of 98.7% at 0.5Ag-1 after 150 cycles for Li+ storage. This engineering provides a new guideline for the rational design of high-performance layered oxide cathodes.

Self-assembled peptide nanotubes (SPNTs)/SnO2 nanocomposites for high-performance NO2 sensing at room temperature

Nitrogen dioxide (NO2) is a major pollutant that poses significant risks to sustainable human life. As a result, a growing focus has been placed on the development of highly selective and sensitive gas sensors for NO2. Traditional cutting-edge non-organic NO2 gas detectors often necessitate stringent production conditions and potentially harmful materials, which are not environmentally friendly, and these shortcomings have limited their widespread practical use. To overcome these challenges, we synthesized self-assembled peptide nanotubes (SPNTs) through a molecular self-assembly process. The SPNTs were then combined with SnO2 in varying proportions to construct NO2 gas sensors. The design of this sensor ensured efficient electron transfer and leverage the extensive surface area of the SPNTs for enhanced gas adsorption and the effective dispersion of SnO2 nanoparticles. Notably, the performance of the sensor, including its sensitivity, response time, and recovery rate, along with a lower detection threshold, could be finely tuned by varying the SPNTs content. This approach illustrated the potential of bioinspired methodologies, using peptide self-assemblies, to develop integrated sensors for pollutant detection, providing a significant development in environmentally conscious sensor technology.

VIBRATORY DRYERS AS AN EFFECTIVE TOOL FOR REDUCING ENERGY CONSUMPTION IN PRODUCTION

Drying of materials is a complex technological process used in various industries and often is one of the main stages of production. This process, in particular for bulk materials, depends on humidity, particle size, hydrodynamic conditions of the particles flowing through the drying agent and environmental parameters. Grain dryers expose grain to more stringent conditions than natural drying, which can potentially lead to a deterioration in grain quality. The combination of these factors determines the nature of the entire process. In agricultural production, the drying stage is one of the most important for grain preservation. Currently, the convective drying method is widely used for this process. However, along with its advantages, this method also has a number of significant disadvantages, one of the most significant of which is its high energy consumption. In this regard, scientific research is being intensively conducted to develop ways and methods to reduce the energy intensity of the convective drying method. The effects of vibration on raw materials are being rapidly introduced in various industries. The use of vibration technologies during drying intensifies the process of processing grain raw materials due to the rapid renewal of its surface in contact with the drying agent. Fast and efficient drying with vibration technology reduces moisture content and the risk of the appearance of bacteria and mold in the grain. The construction of the dryer using vibration technology helps to avoid overheating of the grain, providing optimal temperature conditions, which contributes to the preservation of nutrients and other useful properties of bulk agricultural materials.

Dehydroxylative radical N-glycosylation of heterocycles with 1-hydroxycarbohydrates enabled by copper metallaphotoredox catalysis

N-Glycosylated heterocycles play important roles in biological systems and drug development. The synthesis of these compounds heavily relies on ionic N-glycosylation, which is usually constrained by factors such as labile glycosyl donors, precious metal catalysts, and stringent conditions. Herein, we report a dehydroxylative radical method for synthesizing N-glycosides by leveraging copper metallaphotoredox catalysis, in which stable and readily available 1-hydroxy carbohydrates are activated for direct N-glycosylation. Our method employs inexpensive photo- and copper- catalysts and can tolerate some extent of water. The reaction exhibits a broad substrate scope, encompassing 76 examples, and demonstrates high stereoselectivity, favoring 1,2-trans selectivity for furanoses and α-selectivity for pyranoses. It also exhibits high site-selectivity for substrates containing multiple N-atoms. The synthetic utility is showcased through the late-stage functionalization of bioactive compounds and pharmaceuticals like Olaparib, Axitinib, and Metaxalone. Mechanistic studies prove the presence of glycosyl radicals and the importance of copper metallaphotoredox catalysis.

Proton-triggered topological transformation in superbase-mediated selective polymerization enables access to ultrahigh-molar-mass cyclic polymers.

The selective synthesis of ultrahigh-molar-mass (UHMM, >2 million Da) cyclic polymers is challenging as an exceptional degree of spatiotemporal control is required to overcome the possible undesired reactions that can compete with the desired intramolecular cyclization. Here we present a counterintuitive synthetic methodology for cyclic polymers, represented here by polythioesters, which proceeds via superbase-mediated ring-opening polymerization of gem-dimethylated thiopropiolactone, followed by macromolecular cyclization triggered by protic quenching. This proton-triggered linear-to-cyclic topological transformation enables selective, linear polymer-like access to desired cyclic polythioesters, including those with UHMM surpassing 2 MDa. In addition, this method eliminates the need for stringent conditions such as high dilution to prevent or suppress linear polymer contaminants and presents the opposite scenario in which protic-free conditions are required to prevent cyclic polymer formation, which is capitalized to produce cyclic polymers on demand. Furthermore, such UHMM cyclic polythioester exhibits not only much enhanced thermostability and mechanical toughness, but it can also be quantitatively recycled back to monomer under mild conditions due to its gem-disubstitution.

An inertial‐like Tseng's extragradient method for solving pseudomonotone variational inequalities in reflexive Banach spaces

A survey of the existing results in the literature shows that several of the results on variational inequality problem were established under some stringent conditions and employed some form of linesearch technique even in the framework of Hilbert spaces. However, due to the loop nature of the linesearch technique, the implementation of such algorithms might be economically nonviable. In this article, we study the pseudomonotone variational inequality problem. We propose a new inertial‐like Tseng's extragradient method with non‐monotonic self‐adaptive step size that does not involve any linesearch technique for finding the solution of the problem in reflexive Banach spaces. Under some mild conditions, we prove a strong convergence result for the proposed method without the sequentially weakly continuity condition often assumed by authors to guarantee convergence when studying the pseudomonotone variational inequality problems. Moreover, we apply our result to study a constrained convex minimization problem. Finally, we present several theoretical and real applications to optimal control numerical experiments to illustrate and show the performance of our method in comparison with related methods in the literature.

Interface-Targeting Carrier-Catalytic Integrated Design Contributing to Lithium Dihalide-Rich SEI toward High Interface Stability for Long-Life Solid-State Lithium-Metal Batteries.

The generation of solid electrolyte interphase (SEI) largely determines the comprehensive performance of all-solid-state batteries. Herein, a novel "carrier-catalytic" integrated design is strategically exploited to in situ construct a stable LiF-LiBr rich SEI by improving the electron transfer kinetics to accelerate the bond-breaking dynamics. Specifically, the high electron transport capacity of Br-TPOM skeleton increases the polarity of C-Br, thus promoting the generation of LiBr. Then, the enhancement of electron transfer kinetics further promotes the fracture of C-F from TFSI- to form LiF. Finally, the stable and homogeneous artificial-SEI with enriched lithium dihalide is constructed through the in situ co-growth mechanism of LiF and LiBr, which facilitatse the Li-ion transport kinetics and regulates the lithium deposition behavior. Impressively, the PEO-Br-TPOM paired with LiFePO4 delivers ultra-long cycling stability over 1000 cycles with 81 % capacity retention at 1 C while the pouch cells possess 88 % superior capacity retention after 550 cycles with initial discharge capacity of 145 mAh g-1at 0.2 C in the absence of external pressure. Even under stringent conditions, the practical pouch cells possess the practical capacity with stable electric quantities plateau in 30 cycles demonstrates its application potential in energy storage field.

Interface‐Targeting Carrier‐Catalytic Integrated Design Contributing to Lithium Dihalide‐Rich SEI toward High Interface Stability for Long‐Life Solid‐State Lithium‐Metal Batteries

AbstractThe generation of solid electrolyte interphase (SEI) largely determines the comprehensive performance of all‐solid‐state batteries. Herein, a novel “carrier‐catalytic” integrated design is strategically exploited to in situ construct a stable LiF‐LiBr rich SEI by improving the electron transfer kinetics to accelerate the bond‐breaking dynamics. Specifically, the high electron transport capacity of Br‐TPOM skeleton increases the polarity of C−Br, thus promoting the generation of LiBr. Then, the enhancement of electron transfer kinetics further promotes the fracture of C−F from TFSI− to form LiF. Finally, the stable and homogeneous artificial‐SEI with enriched lithium dihalide is constructed through the in situ co‐growth mechanism of LiF and LiBr, which facilitatse the Li‐ion transport kinetics and regulates the lithium deposition behavior. Impressively, the PEO‐Br‐TPOM paired with LiFePO4 delivers ultra‐long cycling stability over 1000 cycles with 81 % capacity retention at 1 C while the pouch cells possess 88 % superior capacity retention after 550 cycles with initial discharge capacity of 145 mAh g−1at 0.2 C in the absence of external pressure. Even under stringent conditions, the practical pouch cells possess the practical capacity with stable electric quantities plateau in 30 cycles demonstrates its application potential in energy storage field.

Bioinspired bimetallic metal–organic framework nanozyme with laccase-mimicking activity for detection and removal of phenolic contaminants

Laccase, despite its eco-friendly nature, faces constraints due to cost and inherent vulnerability, restricting its widespread application. Therefore, pursuing the development of a robust laccase mimetic displaying exceptional activity remains an ongoing endeavor. This research synthesized a bimetallic metal–organic framework nanozyme (Cu-Mn MOF) with enhanced laccase-mimicking activity via a one-step solvothermal method. The diverse Cu redox valence state of the nanozyme mimics the multi-copper active center of laccase, which endows Cu-Mn MOF with laccase-mimicking activity. Incorporating Mn introduces a novel metal center into the MOF, creating a catalytic microenvironment. Bimetallic Cu-Mn synergistic interplay accelerates the electron transfer rate, resulting in enhanced laccase-mimicking activity. The Michaelis constant of Cu-Mn MOF for 2,4-dichlorophenol (2,4-DP) registers at 0.080 mM, displaying remarkable stability and recyclability even under stringent conditions, thereby achieving a comprehensive surpass of laccase. Accordingly, Cu-Mn MOF was utilized to degrade phenolic compounds and design a smartphone sensing platform to facilitate portable and visual detection of phenol. Utilizing the occurrence of Cu-S coordination, which accelerates the electron transfer rate, a thiourea-enhanced Cu-Mn MOF was designed to improve the degradation rate. The limit of detection (LOD) for smartphone platform is 0.159 μM, with a linear detection range of 1–40 μM. The detection method was applied to determine the phenol in spiked samples with the spiked recoveries rate of 96.05–104.30 % and the relative standard deviations less than ± 4 %. The outcomes of these applications reveal the vast application potential of Cu-Mn MOF in environmental engineering.

ASSESSMENT OF ANCHOR BORROWER PROGRAM AMONG MAIZE FARMERS IN KAURU LOCAL GOVERNMENT AREA OF KADUNA STATE, NIGERIA

The study assessed Anchor Borrower Program (ABP) among maize farmers in Kauru Local Government Area of Kaduna State, Nigeria. Multi-stage sampling techniques consisting purposive and random sampling was used in selection of 157 farmers for the study. Data were collected using structured questionnaire and analysed using both descriptive and inferential statistics. The results revealed that maize farmers were age range of 30-39 with an average age of 41 years. It also revealed that (74.2%) of the farmers were male. The result further shows that majority (73.5%) of the farmers were married with an average of 22 years of farming experience. The result further reveals that majority (87.4%) of the farmers took farming as a major occupation. It also showed that 34.4% maize farmers had attended tertiary education as their level of education. Majority (89.56%) of the farmers acquired their land through inheritance, while majority (64.9%) of the farmers had farm size of 2.5 to 4 hectares with an average farm size of 2.5 hectares. Result further shows that 31.4% of the farmers acquired their loan through uptakers and 29.6% of them acquired their input through Bank of Agriculture. The results also revealed that majority (87.4%) of maize farmers had increase in income after using the loan. The results of regression analysis revealed that R2 was 0.365 meaning that 36.5% of the variation in the dependent variable was explained by the independent or explanatory variables included in the model. The coefficient of age and marital status has a negative and significant at a P<0.01 level of probability, farm size and land tenure had a positive coefficient and highly significant at P<0.01. The major constraints affecting farmers in anchor borrower programme were fluctuating of price, cumbersome process or stringent process, distance from financial institution, high Family expenditure and low productivity due to harsh weather condition. The study concluded that ABP enhanced the output and income of maize farmers in study area. Based on the finding, it is recommended that, all stringent conditions attached to access to loan for agricultural production should be removed, ABP facilitators should ensure timely disbursement of funds and input before planting commences.

Wavelength-tuned transformation between photonic skyrmion and meron spin textures

Topological spin textures, among which skyrmions and merons are typical examples, have with their swirling vectorial structures triggered enormous interest in physical systems including elementary particles and magnetic materials. Manipulating their symmetry and topology is important for understanding the mechanisms that underlie their topological phase transformation as well as offering tunable degrees of freedom to encode information, which has already been demonstrated in magnetic materials. Recently, the photonic counterparts of skyrmions and merons were constructed in a 2D wave system with deep-subwavelength features promising for optical sensing, imaging, and information decoding. However, their experimental realization relied on stringent excitation conditions that only support a single spin texture type on a specific structure. Here, we demonstrate for the first time the transformation between photonic skyrmion and meron spin lattices on the same metallic meta-surface having a well-designed structural period. We show experimentally the wavelength-tuned symmetry transformation of the photonic spin lattices, which are also found to be robust against disorder in the structure to a certain degree. This work provides new insights into controlling the electromagnetic field symmetry and topology, as well as in developing applications in spin optics and topological photonics.