Stretchable Conductors Research Articles

A Guide to Printed Stretchable Conductors.

Printing of stretchable conductors enables the fabrication and rapid prototyping of stretchable electronic devices. For such applications, there are often specific process and material requirements such as print resolution, maximum strain, and electrical/ionic conductivity. This review highlights common printing methods and compatible inks that produce stretchable conductors. The review compares the capabilities, benefits, and limitations of each approach to help guide the selection of a suitable process and ink for an intended application. We also discuss methods to design and fabricate ink composites with the desired material properties (e.g., electrical conductance, viscosity, printability). This guide should help inform ongoing and future efforts to create soft, stretchable electronic devices for wearables, soft robots, e-skins, and sensors.

Room temperature synthesis and hydrophobic surface protection of silver dendrites for hydrogel stretchable sensors

Hydrogel stretchable sensors have gained increasing popularity as essential components for next-generation flexible electronics. Stringent standards have been placed on the cost, conductivity, stability, and sensitivity of composites. In this work, highly conductive silver dendrites with uniform morphology were successfully synthesized by galvanic displacement reaction. Due to the more complex three-dimensional structure of the silver dendrites, the percolation threshold of the conductive composites was reduced to approximately 45 wt%. By decorating the as-prepared silver dendrites with a dense and hydrophobic dodecanethiol layer, the issue of hygrothermal stability in the hydrogel matrix has been successfully addressed. Silver dendrites conductive composites exhibited excellent electrical conductivity (8.57×10−4Ω∙cm for 65 wt% silver dendrites) and sensing properties. The stretchable conductors exhibited high sensitivity and linearity with F= 9.48 and R2= 0.9967. Therefore, human-computer interaction was successfully carried out by monitoring the movement of fingers, wrists, elbows, and knees of the human body.

Highly stretchable conductor with elastomeric passivation sheath enabling applications in harsh conditions

The rapid development of robotics requires stretchable electrical conductors capable of large deformations and having high operational stability in terms of electrical and mechanical characteristics. Carbon nanotubes (CNT) have been considered as the primary component of stretchable conductors, and mechanically drawn CNT sheets have shown their functionality when combined with various elastomeric materials in the shape of yarns. Herein, an electrically passivated stretchable conductor with an elastomer sheath and a spandex–CNT coiled-yarn core structure is reported. Based on the proven performance of spandex–CNT coiled-yarn, the electrical insulation by the Ecoflex elastomer enhances its applicability in an actual situation without degrading the stretchable conductor functionality. The experimental results show a substantial working deformation range (up to 350%), high durability, and low resistance variation during repetitive stretch and release cycles. Additionally, its stability is confirmed over a wide temperature range (up to 150 °C) and even inside an acidic liquid environment where the elastomeric sheath protects the conducting core. The perfect cooperation between the Ecoflex sheath and spandex–CNT core opens the possibility of deploying this stretchable conductor technology under harsh conditions.

Recent advances in intrinsically stretchable electronic materials and devices

AbstractIntrinsically stretchable electronics have gained extensive interest recently, due to their promising application in wearable electronics, bio‐integrated electronics, and healthcare devices. All of the components of such stretchable electronics need to be stretchable and mechanically robust to accommodate complex movements. The design and fabrication of robust intrinsically stretchable electronic materials represent a critical challenge in this emerging field. In this review, we focus on the latest studies of intrinsically stretchable electronics, covering the strategies for achieving intrinsically stretchable electronic materials, the recent progresses in the key electronic materials including intrinsically stretchable conductors, semiconductors, dielectrics, and the devices produced by them. Finally, some suggestions and prospects for the future development of intrinsically stretchable electronics are proposed.

Hierarchical buckling of elastic fiber under transverse confinement

Hierarchical buckling is a novel phenomenon observed in elastic fibers subjected to transverse confinement; however, the deformation mechanisms and modal transitions of this unique phenomenon remain to be elucidated. This paper investigates the hierarchical buckling of elastic fibers with elliptical (circular) cross-sections under transverse confinement through analytical derivations and numerical simulations. Various magnitudes of hierarchical buckling of fibers are observed with the variation of the controlled elastic matrix stiffness. An analytical solution is first derived for the fiber’s buckling phenomenon, and the hierarchical buckling is accomplished through the superposition of buckling at various modes. The theoretical results are validated against the finite element simulations with good agreement. It is demonstrated from the parametric results that the hierarchical buckling phenomenon is primarily influenced by the stiffness of the external transverse confinement (matrix), which is defined as a dimensionless parameter. It is thus illustrated from the computational results that the buckling of elastic fibers within a solid or fluid matrix can be controlled and customized. The present work provides theoretical guidance for the application of elastic fibers in stretchable conductor fibers and flexible electronic devices.

A bio-based thermoplastic polyurethane with triple self-healing action for wearable technology and smart textiles

A bio-based thermoplastic elastomer with triple self-healing action is presented for use in stretchable conductors, wearable devices and e-skin.

A thin, intrinsically stretchable MXene-MWCNTs/polymer current collector for deformable aqueous Li-ion batteries

By integrating Ti3C2Tx with MWCNTs on an elastic SEBS film, a thin, intrinsically stretchable hybrid conductor was constructed and used to fabricate deformable aqueous Li-ion batteries.

Low hysteresis zwitterionic supramolecular polymer ion-conductive elastomers with anti-freezing properties, high stretchability, and self-adhesion for flexible electronic devices.

The fabrication of stretchable ionic conductors with low hysteresis and anti-freezing properties to enhance the durability and reliability of flexible electronics even at low temperatures remains an unmet challenge. Here, we report a facile strategy to fabricate low hysteresis, high stretchability, self-adhesion and anti-freezing zwitterionic supramolecular polymer ion-conductive elastomers (ICEs) by photoinitiated polymerization of aqueous precursor solutions containing a newly designed zwitterionic monomer carboxybetaine ureido acrylate (CBUIA) followed by solvent evaporation. The resultant poly(carboxybetaine ureido acrylate) (PCBUIA) ICEs are highly stretchable and self-adhesive owing to the presence of strong hydrogen bonds between ureido groups and dipole-dipole interactions of zwitterions. The zwitterion groups on the polymer side chains and loaded-lithium chloride endow PCBUIA ICEs with excellent anti-freezing properties, demonstrating mechanical flexibility and ionic transport properties even at a low temperature (-20 °C). Remarkably, the PCBUIA ICEs demonstrate a low hysteresis (≈10%) during cyclic mechanical loading-unloading (≤500%), and are successfully applied as wearable strain sensors and triboelectric nanogenerators (TENGs) for energy harvesting and human motion monitoring. In addition, the PCBUIA ICE-based TENG was used as a wireless sensing terminal for Internet of Things smart devices to enable wireless sensing of finger motion state detection.

Rubbery stretchable conductors based on 3D printed silver nanowires and their application in wearable optoelectronic devices

The facile and scalable manufacturing of rubbery stretchable conductors is realized based on 3D printed silver nanowires and their applications are demonstrated by constructing wearable photodetectors and transistors.

Versatile Stretchable Conductor with Exceptional Resilience and Rapid Rebound Capabilities: Toward Sustainable and Damage‐Resistant Soft Electronics

AbstractStretchable conductors (SCs) have garnered significant attention in both academia and industry, owing to their promising applications in flexible electronics. However, achieving a highly resilient and rapidly rebounding SC that enables prompt electrical response to applied strain, while also being fully recyclable and self‐healable, remains a challenge. Here, the design and preparation of a high‐performance SC based on a small bio‐molecule (α‐Lipoic acid) are reported, using a straightforward, cost‐effective, and scalable method. The engineered SC exhibits a ≈100% rebound ratio and fast rebound speed (≈0.4 s) under repeated high strains, along with outstanding electrical sensitivity to both deformation and temperature variation. This ensures that the SC possesses high precision and real‐time sensing attributes. Moreover, the SC features high optical transparency (>97%), robust reversible adhesion to diverse surfaces (up to 5.0 MPa), efficient room‐temperature self‐healing properties, and full recyclability. The superior properties of the SC are fundamentally attributed to the installed hierarchical dynamic bonding at the molecular level, which enables continuous energy dissipation and is analyzed through DFT calculations. The developed SC holds great potential for applications in soft electronics and human–machine interfaces.

Thionated stereoisomer enhance the mixed conduction, ambient stability and mechanical deformability for high-performance small molecular n-type organic electrochemical transistors

High performance stretchable organic mixed ionic-electronic conductors with highly stability are extremely demanding for flexible bioelectronics. However, very little is known about the correlation between the mixed conduction and both stability and mechanical deformability of n-type small molecular organic electrochemical transistors (OECTs). Herein, a stereoisomerism was reported as an effective platform to address these challenges by introducing a concept of coupling rigid tetrachloro perylene diimides (PDI) skeleton and amorphous thionation stereoisomer to afford the stereoisomerism of dithionated oligo(ethylene glycol) functionalized PDI (2S-gPDI). In further, for the first time we carried out proof-of-concept experiments to build the correlations between both chemical/microstructures and the thin/thick films’ ambient stability as well as mechanical deformability based on this novel small-molecule mixed conductors. Our results reveal that the thionation stereoisomerism render 2S-gPDI higher figure of merit μC* and ambient stability as well as higher mechanical deformability owing to the lower LUMO levels, porous film morphology and lower degree of film crystallinity, when compared with the parent unthionated gPDI-based mixed conductors. It is envisioned that the coupling rigid skeleton and amorphous stereoisomer concept will guide the next generation of high stable small-molecules stretchable OECTs.

A Soft, Adhesive Self-Healing Naked-Eye Strain/Stress Visualization Patch.

Learning about the strain/stress distribution in a material is essential to achieve its mechanical stability and proper functionality. Conventional techniques such as universal testing machines only apply to static samples with standardized geometry in laboratory environment. Soft mechanical sensors based on stretchable conductors, carbon-filled composites, or conductive gels possess better adaptability, but still face challenges from complicated fabrication process, dependence on extra readout device, and limited strain/stress mapping ability. Inspired by the camouflage mechanism of cuttlefish and chameleons, here an innovative responsive hydrogel containing light-scattering "mechano-iridophores" is developed. Force induced reversible phase separation manipulates the dynamic generation of mechano-iridophores, serving as optical indicators of local deformation. Patch-shaped mechanical sensors made from the responsive hydrogel feature fast response time (<0.4 s), high spatial resolution (≈100µm), and wide dynamic ranges (e.g., 10-150% strain). The intrinsic adhesiveness and self-healing material capability of sensing patches also ensure their excellent applicability and robustness. This combination of chemical and optical properties allows strain/stress distributions in target samples to be directly identified by naked eyes or smartphone apps, which is not yet achieved. The great advantages above are ideal for developing the next-generation mechanical sensors toward material studies, damage diagnosis, risk prediction, and smart devices.

Regulating the π–π interactions of copolymer gelators: Effective molecular design of highly stretchable and tough ionogels for wearable ionotronics

The emergence of stretchable ionic conductors has facilitated the development of wearable devices that can perceive changes in their surrounding environment and interpret external stimuli. An example of this is ionic skin, a form of artificial skin that is worn constantly for the real-time monitoring of temperature, pressure, and tension. However, ionic skins are vulnerable to physical damage and stress, which reduces their functionality, performance, and longevity. To obtain mechanically durable ionic skins, the toughness of their constituent ionogels must be improved by increasing their strength and/or stretchability. However, the molecular design and synthesis of these materials remain challenging due to the inherent trade-off between mechanical durability and ionic conductivity. In the present study, we introduced three styrene derivatives containing pendant groups of different sizes to copolymer gelators as ionic liquid (IL)-solvophobic components that form physically crosslinked domains and compared the mechanical and conductivity performance of the resulting ionogels. As the packing density of the styrene decreased, the IL-solvophobic domains became softer and more deformable due to the weaker physical crosslinking via π–π interactions. The optimal ionogel exhibited high stretchability (∼1200 %), excellent toughness (∼3.4 MJ·m−3), and high transparency (∼98 %). The successful use of the optimal ionogel in ionic skin sensors and deformable alternating-current electroluminescent displays demonstrated its broad range of practical applications.

Healable Ionic Conductors with Extremely Low-Hysteresis and High Mechanical Strength Enabled by Hydrophobic Domain-Locked Reversible Interactions.

Extremely low hysteresis, high mechanical strength, superior toughness, and excellent healability are essential for stretchable ionic conductors to enhance their reliability and meet for cutting-edge applications. However, the fabrication of stretchable ionic conductors with such mutually exclusive properties remains challenging. Herein, extremely low-hysteresis and healable ionic conductors with a tensile strength of ≈8.9MPa and toughness of ≈23.2MJ m-3 are fabricated through the complexation of 4-carboxybenzaldehyde (CBA) grafted poly(vinyl alcohol) (PVA) (denoted as PVA-CBA) and poly (allylamine hydrochloride) (PAH) followed by acidification and ion-loading steps. The acidification step generates the PVA-CBA/PAH ionic conductors with in situ formed dynamic hydrophobic domains that lock and stabilize noncovalent interactions. This significantly minimizes the energy dissipation of the ionic conductors during cyclic mechanical loading (≤200% strain), resulting in ionic conductors with extremely low hysteresis (≈5%). The fractured ionic conductors can be healed at 60°C to restore their original properties. Because of the extremely low hysteresis, the PVA-CBA/PAH ionic conductors show a highly stable and reproducible electrical response over 5000 uninterrupted loading-unloading cycles at a strain of 200%. The ionic conductor based sensors exhibit a high sensitivity to a wide range of strains (1-500%).

Printed sustainable elastomeric conductor for soft electronics

The widespread adoption of renewable and sustainable elastomers in stretchable electronics has been impeded by challenges in their fabrication and lacklustre performance. Here, we realize a printed sustainable stretchable conductor with superior electrical performance by synthesizing sustainable and recyclable vegetable oil polyurethane (VegPU) elastomeric binder and developing a solution sintering method for their composites with Ag flakes. The binder impedes the propagation of cracks through its porous network, while the solution sintering reaction reduces the resistance increment upon stretching, resulting in high stretchability (350%), superior conductivity (12833 S cm−1), and low hysteresis (0.333) after 100% cyclic stretching. The sustainable conductor was used to print durable and stretchable impedance sensors for non-obstructive detection of fruit maturity in food sensing technology. The combination of sustainable materials and strategies for realizing high-performance stretchable conductors provides a roadmap for the development of sustainable stretchable electronics.

Mechanically Rupturing Liquid Metal Oxide Induces Electrochemical Energy

AbstractLiquid metals, such as Gallium‐based alloys, have unique mechanical and electrical properties because they behave like liquid at room temperature. These properties make liquid metals favorable for soft electronics and stretchable conductors. In addition, these metals spontaneously form a thin oxide layer on their surface. Applications made possible by this delicate oxide skin include shape reconfigurable electronics, 3D‐printed structures, and unconventional actuators. This paper introduces a new approach where liquid metal oxide serves as an electrochemical energy source. By mechanically rupturing their surface oxide, liquid metals form a galvanic cell and convert their chemical energy to electrical energy. When dispersing liquid metals into an ionically‐conductive liquid to form emulsions, this composite material can provide ∼500 mV of open‐circuit voltage and up to ∼4 μW of power. Protected by the naturally occurring oxide skin, the passivating oxide layer of the liquid metal shields it from self‐discharge over time. The device is also stable in harsh environments, such as high temperature or aquatic conditions. Future applications of this device are demonstrated by designing a strain‐activated stretchable battery and a pressure‐sensitive self‐powered keypad. These findings may unlock new pathways to design stretchable batteries and harness their inherent energy for self‐powered robust devices.

3D Highly Stretchable Liquid Metal/Elastomer Composites with Strain‐Enhanced Conductivity

AbstractCurrent stretchable conductors, often composed of elastomeric composites infused with rigid conductive fillers, suffer from limited stretchability and durability, and declined conductivity with stretching. These limitations hinder their potential applications as essential components such as interconnects, sensors, and actuators in stretchable electronics and soft machines. In this context, an innovative elastomeric composite that incorporates a 3D network of liquid metal (LM), offering exceptional stretchability, durability, and conductivity, is introduced. The mechanics model elucidates how the interconnected 3DLM architecture imparts softness and stretchability to the composites, allowing them to withstand tensile strains of up to 500% without rupture. The relatively low surface‐to‐volume ratio of the 3DLM network limits the reforming of the oxide layer during cyclic stretch, thereby contributing to low permanent strain and enhanced durability. Additionally, the 3D architecture facilitates crack blunting and stress delocalization, elevating fracture resistance, while simultaneously establishing continuous conductive pathways that result in high conductivity. Notably, the conductivity of the 3DLM composite increases with strain during substantial stretching, highlighting its strain‐enhanced conductivity. In comparison to other LM‐based composites featuring 0D LM droplets, the 3DLM composite stands out with superior properties.

Divide and Conquer: Design of Gallium‐Based Liquid Metal Particles for Soft and Stretchable Electronics

AbstractGallium‐based liquid metal (LM) has attracted considerable attention as a promising material for stretchable conductors due to its remarkable combination of deformability and metallic conductivity. However, LM inherently faces challenges such as high surface tension, resistance increase, electrical failure due to leakage, and limited mechanical stability. Recently, researchers have explored the concept of “dividing” bulk LM into microparticles (LMP) as a means of addressing these limitations. Nonetheless, the fabrication of LMP results in inherent electrical insulation, requiring additional activation steps to enable their use as stretchable conductors. In this review, the potential of LMP is discussed as an alternative to bulk LM and explore various methods to generate stable LMP‐based conductors and electrically activate LMP for their implementation in soft and stretchable electronics.

Photothermal Lithography for Realizing a Stretchable Multilayer Electronic Circuit Using a Laser.

Photolithography is a well-established fabrication method for realizing multilayer electronic circuits. However, it is challenging to adopt photolithography to fabricate intrinsically stretchable multilayer electronic circuits fully composed of an elastomeric matrix, due to the opacity of thick stretchable nanocomposite conductors. Here, we present photothermal lithography that can pattern elastomeric conductors and via holes using pulsed lasers. The photothermal-patterned stretchable nanocomposite conductor exhibits 3 times higher conductivity (5940 S cm-1) and 5 orders of magnitude lower resistance change (R/R0 = 40) under a 30% strained 5000th cyclic stretch, compared to those of a screen-printed conductor, based on the percolation network formed by spatial heating of the laser. In addition, a 50 μm sized stretchable via holes can be patterned on the passivation without material ablation and electrical degradation of the bottom conductor. By repeatedly patterning the conductor and via holes, highly conductive and durable multilayer circuits can be stacked with layer-by-layer material integration. Finally, a stretchable wireless pressure sensor and passive matrix LED array are demonstrated, thus showing the potential for a stretchable multilayer electronic circuit with durability, high density, and multifunctionality.

A highly stretchable and sintering-free liquid metal composite conductor enabled by ferrofluid

Stretchable and highly conductive elastomers with intrinsically deformable liquid metal (LM) fillers exhibit promising potential in soft electronics, wearables, human-machine interfaces, and soft robotics. However, conventional LM-elastomer (LME) conductors require a high loading ratio of LM and the post-sintering to rupture LM particles to achieve electric conductivity, which results in high LM consumption and process complexity. In this work, we presented a straightforward and post-sintering-free method that utilizes magnetic aggregation to fabricate stretchable LME conductors. This was achieved by dispersing LM ferrofluid into the elastomer precursor, followed by applying the magnetic field to induce the aggregation and interconnection of the LM ferrofluid particles to form conductive pathways. This method not only simplifies the preparation of initially conductive LME but also reduces the LM loading ratio. The resulting conductive LME composites show high stretchability (up to 650% strain), high conductance stability, and magnetic responsiveness. The stretchable LME conductors were demonstrated in various applications, including the creation of flexible microcircuits, a magnetically controlled soft switch, and a soft hydrogel actuator for grasping tasks. We believe the stretchable LME conductors may find wide applications in electronic skins, soft sensors, and soft machines.