The order of singularity near the vertex of bonded joints is one of the main factors responsible for debonding of electronic device under mechanical or electrical loading. The distribution of singularity field near the vertex of bonded joints is very important to maintain the reliability of smart electronic structure. Piezoelectric material, due to its characteristic direct-converse piezoelectric effect, has naturally received considerable attentions. Piezoelectric materials have been extensively used as transducers and sensors due to their piezoelectric effects that take place between electric fields and mechanical deformation. The order of singularity at a vertex and at a point on singularity line in 3D transversely isotropic piezoelectric joints is analyzed. Eigen analysis based on FEM is used for stress singularity field analysis of piezoelectric bimaterial joints. The eigen equation is used for calculating the order of stress singularity and the angular function of elastic displacement, electric potential, stress and electric displacement. The numerical result shows that the angular functions have large value near the interface edge than the inner portion of the joint. Therefore, there is a possibility to debond and delamination occurs at interface edge of the piezoelectric bimaterial joints, due to the higher stress and electric displacement concentration at the free edge.