Stress Relaxation Analysis Research Articles

Robust Self-Healing Adhesives Based on Dynamic Urethane Exchange Reactions.

Thermoset polyurethanes (PUs) have been successfully reprocessed as covalent adaptable networks (CANs) by catalyzing carbamate exchange. Here we extend bond exchange beyond the internal network cross-links to create a dynamic urethane adhesive. Interfacing PU CANs to substrates with nucleophilic functional groups creates adhesives capable of reversible transcarbamoylation with the substrate, which has not been demonstrated previously by CAN adhesives. Two types of thermoset PU films were synthesized, one containing the green carbamate exchange catalyst Zr(tmhd)4 and the other containing no catalyst. Although otherwise identical in chemical and network properties, as indicated by FT-IR spectroscopy and dynamic mechanical thermal analysis (DMTA), the film containing catalyst showed dynamic bond exchange behavior through stress relaxation analysis. When evaluated as an adhesive, the CAN film exhibited self-healing properties and retained its adhesive strength for five cycles, which is attributed to reversible covalent bonding to the glass substrate. This work expands industrially relevant CANs to structural adhesives and demonstrates their potential value in an application that presently employs PUs as single-use materials.

Room temperature self-healing and reprocessing elastomer with dynamic bonds for flexible wearable sensor

The production of room-temperature (RT) self-healing elastomers with good mechanical properties is significant for application in soft electronics, yet remains a challenge in material design. Herein, we present an effective and feasible approach to create RT self-healing cross-linked elastomers (CEs) through photo-initiated copolymerization. A key feature is the incorporation of 2,7-dihydroxynaphthalene and alicyclic diisocyanate into the polymer backbone as hard domains, along with the rational optimization of the soft segments. In addition, urethane-based H-bonding interactions, acting as sacrificial bond, contribute to the high toughness of the CEs. The resulting CEs exhibit desirable mechanical performances, including a tensile strength of 12.9 MPa, an elongation at break of approximately 1243 %, and a high toughness of 68.64 MJ m–3. Furthermore, by integrating a flexible PTMEG-based polymeric chain and hindered urea bonds into the backbone, the chain mobility and dynamic nature of the CEs are improved. The CEs are capable of reprocessing and self-healing at RT within 30 min upon scratching, with a self-healing efficiency in toughness reaching 99.64 %. The dynamic networks are evidenced by rheological test, stress relaxation analysis, as well as creep and recovery experiments. These CEs, characterized by their superior properties, hold promise for applications in flexible wearable electronics.

Cause analysis of the compression spring stress relaxation of circuit breaker operating mechanism in a 220 kV Substation

Cause analysis of the compression spring stress relaxation of circuit breaker operating mechanism in a 220 kV Substation

Crustal stress buildup/relaxation and pore pressure in preparation and sequential brittle-shear fault rupture — Implications for a general theory of earthquake nucleation

Compelling geoscience evidence has heightened the appreciation of abnormal (suprahydrostatic, sub/quasi/supralithostatic) pore pressure and multimode (brittle-shear) fault rupture leading to seismicity. However, preparation and rupture nucleation are yet to be adequately constrained and quantitatively modeled. This challenges crucial schemes, notably physics-based earthquake forecasting/prediction. In this multidisciplinary study, the transitions and associated critical points linking the preexisting fluid overpressure in the fault patches, temporal crustal stress, and sequential brittle-shear fault failure were considered. In preparation, tectonic loading was accompanied by processes such as off-fault yielding, permeability enhancement, and foreshocks that facilitate local/regional stress relaxation. Subsequent equalization of stress and the preexisting local overpressure triggers hydraulic fracturing that destabilizes major asperities. Almost instant shear failure follows with the spatially varying rupture velocity/intensity of the frictional slip because of localized asperity stress and syn-slip fluid-/melt-driven fracturing/dilation and lubrication. Based on the aforementioned critical points, quantitative modeling associated stress drop with the evolution of the stress and pore pressure. Equations for the time to onset of stress relaxation and time to rupture were derived using fluid flow and viscoelastic models. The seismic moment was estimated with classical seismological relations after modifications accounting for the smaller surface area during frictional slip. For retrospective testing, two cases of induced seismicity (2016 Fairview, Oklahoma, USA, and 2017 Pohang, South Korea) and multiple cases of natural seismicity (including the 2024 Noto Peninsula earthquake, Japan) were considered. The replication of triggering mechanisms, source properties, and time to rupture suggested that stress temporal relaxation and triggered anomalies (STRATA) encompass fundamental hydromechanical processes in seismogenesis. The setting and scale invariance of STRATA suggest it might be a general theory of earthquake nucleation. Based on the identified preparatory processes/retrospective validations, a physics-based earthquake forecasting/prediction scheme was developed. The nurseries/hypocenters of impending earthquakes are identified through the simultaneous consideration of locally preexisting fluid overpressure and spatiotemporal analysis of stress relaxation. Event size and rupture timing are estimated with the derived relations herein.

Adaptable Polyurethane Networks Containing Tertiary Amines as Intrinsic Bond Exchange Catalyst

AbstractVitrimers exhibit unique properties, such as thermal recyclability akin to thermoplastics, while structurally mirroring thermosets in terms of strength, durability, and chemical resistance. However, a significant limitation of these materials is their dependence on an external catalyst. Consequently, this research aims to develop vitrimer materials that incorporate an intrinsic catalyst, thus maintaining excellent thermomechanical properties and recyclability. Polyaddition polymerization is employed to synthesize the desired polymer, incorporating a self‐synthesized tertiary amine unit, (bis(2‐hydroxyethyl)‐3,3′‐((2‐(dimethylamino)ethyl)azanediyl)dipropanoate) (N‐diol), as an internal catalyst for transcarbamoylation and potential transesterification reactions. The resulting polymer, with a gel content of 97% and a glass transition temperature of 29 °C, is fabricated into test samples for comprehensive thermal and mechanical evaluations. The material demonstrates an initial Young's modulus of 555 MPa, retaining 81% of this value after two recycling processes. Additionally, using stress relaxation analysis (SRA), a topology freezing temperature of 82 °C, indicative of the characteristic Arrhenius‐like relaxation behavior, is identified with a bond exchange activation energy of 163 kJ mol−1.

Dynamic imidazole-urea bonds for designing recyclable and crosslinked poly(imidazole-urea)

Covalent adaptable network (CAN) with the ability of structural rearrangement has attracted great attentions in recent years because it breaks the limitations in reprocessability and recyclability of traditional thermosetting polymers. Developing catalyst-free dynamic chemistry that proceeded in mild condition would make significant advances in the field of CAN and hold great promise for real applications. Here, we report a new class of highly dynamic imidazole-urea bonds for developing dynamically crosslinked poly (imidazole-urea) (PIU). The reversible reaction and the reaction kinetics between different imidazoles and isocyanate were first studied by model compounds. PIUs with varied crosslinking structures were then constructed from biobased histamine and commercially available isocyanates. Rheological and stress relaxation analysis revealed the rearrangement ability of PIUs at elevated temperature, while thermogravimetric and tensile tests showed their good thermal stability and mechanical properties. The reprocessed PIUs also demonstrated high recovery efficiency of mechanical properties after several cycles of reprocessing. It is expected that this study could broaden the scope of imidazole compounds for novel dynamic polymers.

Biomass- and Carbon Dioxide-Derived Polyurethane Networks for Thermal Interface Material Applications.

Recent environmental concerns have increased demand for renewable polymers and sustainable green resource usage, such as biomass-derived components and carbon dioxide (CO2). Herein, we present crosslinked polyurethanes (CPUs) fabricated from CO2- and biomass-derived monomers via a facile solvent-free ball milling process. Furan-containing bis(cyclic carbonate)s were synthesized through CO2 fixation and further transformed to tetraols, denoted FCTs, by aminolysis and utilized in CPU synthesis. Highly dispersed polyurethane-based hybrid composites (CPU-Ag) were also manufactured using a similar ball milling process. Due to the malleability of the CPU matrix, enabled by transcarbamoylation (dynamic covalent chemistry), CPU-based composites are expected to present very low interfacial thermal resistance between the heat sink and heat source. The characteristics of the dynamic covalent bond (i.e., urethane exchange reaction) were confirmed by the results of dynamic mechanical thermal analysis and stress relaxation analysis. Importantly, the high thermal conductivity of the CPU-based hybrid material was confirmed using laser flash analysis (up to 51.1 W/m·K). Our mechanochemical approach enables the facile preparation of sustainable polymers and hybrid composites for functional application.

Analysis of the tensile stress relaxation of weft-knitted medical compression fabrics in view of the fabric structure

Stress relaxation will create interference in the performance of textiles in applications such as compression garments, pressure bandages, and varicose stockings in which keeping a definite level of pressure on the scar area is vital. Therefore, considering the effectual parameters on the stress relaxation of the fabrics will help to produce appropriate functional clothes. In this research, rib-knitted fabrics with different numbers of tuck stitches in successive wales have been fabricated and their stress relaxation has been surveyed. According to the findings, in all fabric structures, stress relaxation is higher in the wale direction compared to the course direction. In both directions, the stress relaxation linearly changes with the number of tuck stitches in the fabric structure. By increasing the number of tuck stitches, the stress relaxation of the fabric increases from 43% to 81% in the course direction whilst decreasing from 47% to 82% in the wale direction. Consequently, utilization of the tuck stitch in the structure of pressure bandages enhances their functionality, whilst diminishing the performance of compression garments and varicose stockings. Therefore, the use of knitted fabric consisting of tuck stitches is not recommended for pressure garments and varicose stockings.

A numerical model for stress relaxation analysis of sealing systems in nonbonded pipe end fittings

Nonbonded flexible pipes consist of polymer materials that experience stress relaxation at high temperatures, which ultimately affects the sealing performance of end sealing systems. To assess stress relaxation curves under varying temperatures and pre-strains, this paper conducts both tensile and stress relaxation tests on PVDF materials. To describe the stress relaxation characteristics of these materials, the Prony series is utilized. In order to identify the parameters of the series, the paper employs the Levenberg-Marquardt method of nonlinear regression. A finite element model is established to verify the accuracy of the parameter identification method. Subsequently, the paper establishes a two-dimensional axisymmetric finite element model of the sealing system in the end fitting, while taking into account fluid pressure inside the pipeline using a pressure penetration method. The impact of stress relaxation on the sealing performance is then discussed. Finally, the paper alters the coefficients of the Prony series to explore their significance on the sealing performance of the sealing system.

Investigating the Static Recrystallization Behavior of 22MnB5 Manganese–Boron Steel through Stress Relaxation Analysis

A constitutive model was developed to characterize the static recrystallization (SRX) and evolution of the grain size of the industrially relevant press-hardening steel, 22MnB5, subsequent to the hot forming of sheet metal. Isothermal stress relaxation tests were conducted using the BAEHR 805 A/D thermomechanical simulator, encompassing a temperature range of 950 to 1050 °C, prestrain levels ranging from 0.01 to 0.1, and strain rates spanning from 0.01 to 0.8 s−1. The results obtained from the isothermal stress relaxation tests facilitated the formulation of an Avrami equation-based model, which aptly describes the kinetics of SRX in relation to the temperature, prestrain, and strain rate. Notably, an increase in temperature led to accelerated recrystallization kinetics, signifying temperature-dependent behavior. When the temperature increased from 950 to 1050 °C, the recrystallization time was reduced to approximately one-third. Additionally, the prestrain exhibited a positive influence on the acceleration of SRX kinetics. A quintupling of the prestrain from 0.01 to 0.05 resulted in a reduction of the static recrystallization duration to approximately one-fifth. Among the parameters studied, the strain rate had the least impact on the SRX kinetics, as doubling the strain rate from 0.01 to 0.8 only resulted in a halving of the recrystallization duration. Moreover, an analysis of the microstructural evolution in response to the forming parameters was undertaken. While the grain-size investigation post-isothermal stress relaxation tests provided results in line with the SRX kinetics calculations, the observed effects were comparatively subdued. Furthermore, a comprehensive examination was conducted using electron backscatter diffraction (EBSD) analysis, aiming to explore the effects of specific stress relaxation states on the morphology of martensite. The findings reveal fully recrystallized globulitic microstructures, characterized by relatively minor differences among them.

Room temperature deformation mechanisms of a Fe–Mn–Al–C steel

This study aims to investigate the deformation mechanisms of an austenite-based duplex Fe–Mn–Al–C steel at room-temperature through uniaxial tensile tests, strain rate sensitivity and stress relaxation analysis. Through numerical analysis and microstructural studies, this investigation reveals that increasing strain leads to the formation of low-angle boundaries (LABs) at the vicinity of grain boundaries. Consequently, these LABs play a facilitating role in the stress-assisted diffusion of carbon atoms, thereby triggering the dynamic strain aging (DSA) phenomenon. The evidence for this is substantiated by the strain rate sensitivity coefficient and stress relaxation results obtained from numerical analysis during uniaxial tensile tests. As deformation progresses, the misorientation of LABs increases, influencing the strain hardening behavior. The intensified DSA contributes to enhanced work hardening, while substructure development results in softening, creating a trade-off between these contrasting effects.

Stress relaxation and thermal management in highly filled flexible styrene butadiene styrene copolymer‐tungsten composites for high‐energy radiation attenuation

AbstractA high loading of high‐density and high‐atomic‐number fillers are necessary to obtain desirable X‐ray attenuation characteristics from radiation shields. However, at high filler loadings, the mechanical and viscoelastic properties of polymers are severely impaired, posing a long‐term threat to the mechanical integrity and radiation protection, and the radiation shield temperature may increase after prolonged exposure to ionizing radiation, accelerating the aging of the polymer matrix. In addition, inadequate thermal conduction can make the user uncomfortable while using radiation shields for personal protection. Unfortunately, little attention has been paid to the viscoelastic, stress relaxation, and thermal conductivity‐related features of these densely loaded systems, despite the significant effect of these parameters on long‐term applications and user compliance. In the present work, two different styrene butadiene styrene (SBS) copolymers were used to develop SBS‐tungsten (W) composites. At 500 phr W loading, significant attenuation of X‐rays was achieved along with good tensile strength and elongation at break. The results indicate that the concentration of styrene in the SBS and W loading substantially affected the attenuation, mechanical and rheological properties, and tensile stress relaxation rates. The thermal conductivity increased by >100%, and after gamma irradiation, faster cooling was observed in the W‐loaded composites beyond 300 phr of W loading. The 40% styrene composite demonstrated superior heat transfer at high W loadings owing to the better dispersion and distribution of the W filler in the SBS matrix. Rheological results showed that SBS‐W composites with 30% styrene had a more pronounced Payne effect than those with 40% styrene. Stress relaxation and morphological analyses also revealed changes in the W dispersion in the SBS matrix depending on the styrene content.

The effect of maturation conditions on physicochemical and viscoelastic properties of Kashkaval cheese

Abstract The equilibrium stress, decay stress, relaxation time, viscosity, modulus of elasticity, and decay modulus are major characteristics of viscoelastic food materials and therefore a modified mechanical model was used in this current research for the viscoelastic properties’ evaluation of Kashkaval cheese. Also, the chemical composition (fat content, moisture, protein content, water activity, salt, and acidity), and inside-outside color of the Kashkaval cheese were studied. From the analysis of stress relaxation curves the analyzed cheese samples fall into the category of viscoelastic solids with equilibrium stress greater than 0. The decay stress and decay modulus of the maturated unpacked samples showed the highest values of 36.31 kPa and 121.05 kPa, while the relaxation time of cheese samples was greater than 112.35 s. To evaluate the fit of the applied mechanical model to the experimental data the determination coefficient (R2 > 0.937) and the absolute average deviation coefficient were calculated (AAD < 10.324) and the evaluated cheeses’ parameters with the modified Maxwell model were at statistically appropriate levels.

Physical and thermo-mechanical properties of PCL/PEG based shape memory polyurethane for orthodontic ligature application

Thermoplastic elastomer polyurethanes (TEPUs) were synthesized for orthodontic ligature application and the relationship between various properties and structure of the synthesized TEPUs were studied. Polyethylene glycol and 1,4-butanediol were utilized in various weight ratios as chain extender. Fourier-transform infrared spectroscopy, differential scanning calorimetry, and X-ray diffraction were used to study the chemical and physical properties and also, tensile, stress relaxation, and elasticity analysis were performed to evaluate the mechanical properties of the prepared samples. Shape memory and stress relaxation analysis with temperature variation showed that the samples could recover the relaxed force due to the shape memory capability.

Analysis of Stress Relaxation in Bulk and Porous Ultra-High Molecular Weight Polyethylene (UHMWPE).

The reported study was devoted to the investigation of viscoelastic behavior for solid and porous ultra-high molecular weight polyethylene (UHMWPE) under compression. The obtained experimental stress curves were interpreted using a two-term Prony series to represent the superposition of two coexisting activation processes corresponding to long molecular (~160 s) and short structural (~20 s) time scales, respectively, leading to good statistical correlation with the observations. In the case of porous polymer, the internal strain redistribution during relaxation was quantified using digital image correlation (DIC) analysis. The strongly inhomogeneous deformation of the porous polymer was found not to affect the relaxation times. To illustrate the possibility of generalizing the results to three dimensions, X-ray tomography was used to examine the porous structure relaxation at the macro- and micro-scale levels. DIC analysis revealed positive correlation between the applied force and relative density. The apparent stiffness variation for UHMWPE foams with mixed open and closed cells was described using a newly proposed three-term expression. Furthermore, in situ tensile loading and X-ray scattering study was applied for isotropic solid UHMWPE specimens to investigate the evolution of internal structure and orientation during drawing and stress relaxation in another loading mode.

Neighboring Group Participation in Ionic Covalent Adaptable Networks

Covalent adaptable networks (CANs) typically require external catalysts for efficient cross-linker exchange, which can limit network reprocessability due to catalyst leaching and degradation. In this study, catalysts were avoided by using a bicyclo[3.3.1]nonane bis-alkyl halide cross-linker with sulfur-atom neighboring group participation (NGP) to increase the rate of bond exchange. Stress relaxation analyses demonstrate that the resultant pyridine-based network has an Arrhenius dependence on viscous flow at elevated temperatures (130–170 °C), which arises from SN1 transalkylation exchange. This thermally mediated cross-link interchange and associated flow behavior enabled reprocessing of the ionic networks over multiple damage and repair cycles. Additionally, these NGP-based CANs are chemically recyclable, allowing for recovery of the pyridyl-based polymer starting material, which comprises >90 wt % of the parent network. The dual thermal and chemical recycling potential of this catalyst-free CAN platform addresses key criteria for designing thermosets with extended lifecycles.

Thermo-healing and recyclable epoxy thermosets based on dynamic phenol-carbamate bonds

In recent years, the reversible addition reaction of isocyanates and active hydrogen compounds has aroused wide concern. The synthesis of a novel dynamic covalent system based on phenol-carbamate bonds (PCBs) and its application in the preparation of thermo-healing and recycled epoxy resins have become a research hotspot. Herein, a compound with a phenolic hydroxyl group was designed and synthesized, which was used to react with isocyanate to obtain the dynamic covalent system of PCBs. Based on PCBs, a cross-linked polyurethane curing agent and the epoxy thermosetting resin with recyclability and thermo-healing ability were prepared. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), thermogravimetric analysis (TGA), stress relaxation analysis and tensile test were carried out on the synthesized epoxy resins based on PCBs (PCBs-EP). The results showed that the dynamic PCBs endow epoxy thermosets with outstanding reprocessability, thermo-healing, welding, recycling and shape memory properties. Based on the reversible dynamic phenol-carbamate bonds, PCBs-EP can be thermally healed within 2 h under 100 °C, and the thermo-healing effect is obvious. More surprisingly, the tensile strength of PCBs-EP reaches 95.89 (±1.06) MPa, and its tensile strength still maintains 74.13% of the original after healed and 70.6% of the original after welded. Therefore, the strategies for incorporating dynamic covalent PCBs into thermosetting epoxy resins provide a feasible strategy for preparing cross-linked epoxy thermosets with high thermo-healing efficiency and high mechanical strength in a cost-effective manner.

Fabrication and Evaluation of Gellan Gum/Hyaluronic Acid Hydrogel for Retinal Tissue Engineering Biomaterial and the Influence of Substrate Stress Relaxation on Retinal Pigment Epithelial Cells.

Cell therapies for age-related macular degeneration (AMD) treatment have been developed by integrating hydrogel-based biomaterials. Until now, cell activity has been observed only in terms of the modulus of the hydrogel. In addition, cell behavior has only been observed in the 2D environment of the hydrogel and the 3D matrix. As time-dependent stress relaxation is considered a significant mechanical cue for the control of cellular activities, it is important to optimize hydrogels for retinal tissue engineering (TE) by applying this viewpoint. Herein, a gellan Gum (GG)/Hyaluronic acid (HA) hydrogel was fabricated using a facile physical crosslinking method. The physicochemical and mechanical properties were controlled by forming a different composition of GG and HA. The characterization was performed by conducting a mass swelling study, a sol fraction study, a weight loss test, a viscosity test, an injection force study, a compression test, and a stress relaxation analysis. The biological activity of the cells encapsulated in 3D constructs was evaluated by conducting a morphological study, a proliferation test, a live/dead analysis, histology, immunofluorescence staining, and a gene expression study to determine the most appropriate material for retinal TE biomaterial. Hydrogels with moderate amounts of HA showed improved physicochemical and mechanical properties suitable for injection into the retina. Moreover, the time-dependent stress relaxation property of the GG/HA hydrogel was enhanced when the appropriate amount of HA was loaded. In addition, the cellular compatibility of the GG/HA hydrogel in in vitro experiments was significantly improved in the fast-relaxing hydrogel. Overall, these results demonstrate the remarkable potential of GG/HA hydrogel as an injectable hydrogel for retinal TE and the importance of the stress relaxation property when designing retinal TE hydrogels. Therefore, we believe that GG/HA hydrogel is a prospective candidate for retinal TE biomaterial.

Achieving excellent corrosion resistance properties of 7075 Al alloy via ultrasonic surface rolling treatment

The corrosion resistance of 7075 aluminum (Al) alloy treated by ultrasonic surface rolling process (USRP) in a chloride environment was studied in this work. The effects of different USRP passes on the surface state (surface roughness and residual stress), surface microstructure, and corrosion resistance of this alloy were investigated through microstructural characterization, stress relaxation, immersion testing and electrochemical measurement. The results revealed that all USRP-treated samples demonstrated significantly improved corrosion resistance. However, the main factors that led to this performance enhancement were not the same. After 3 USRP treatment passes, the reduction in surface roughness and the increase in surface compressive residual stress improved the corrosion resistance of the 7075 Al alloy. After 7 USRP passes, the larger number of grain boundaries caused by surface grain nanocrystallization led to the rapid enrichment of passive elements, which formed a dense passive film on the alloy surface. At the same time, the dissolution of precipitates and the disappearance of precipitation-free zones (PFZ) reduced the corrosion caused by anodic dissolution. Meanwhile, the primary mechanism that controlled the corrosion rate was transformed from the surface state to the surface microstructure, which further improved the corrosion resistance of the 7075 Al alloy. • In our work, the surface state and surface microstructure of 7075 aluminum alloy are tailored by changing the ultrasonic rolling passes. • The corrosion resistance of 7075 Al alloy is significantly improved by ultrasonic surface rolling process (USRP) in this study. • The effects of surface roughness, residual stress, surface nanocrystalline and precipitates on the corrosion resistance of 7075 Al alloy after USRP are studied by stress relaxation and surface roughness analysis.

Effects of type 2 diabetes on the viscoelastic behavior of human trabecular bone

SummaryType 2 diabetes (T2D) is a well-known disease that impaired bone mechanical properties and increases the risk of fragility fracture. The bone tissue is a viscoelastic material that means the loading rate determines its mechanical properties. This study investigates the impact of T2D on the viscoelastic properties of human bone and its association with microstructure and biochemical properties. IntroductionViscoelasticity is an important mechanical property of bone and for this the interaction of individual constituents of bone plays an important role. The viscoelastic nature of bone can be affected by aging and diseases, which can further influence its deformation and damage behavior. MethodsThe present study investigated the effects of T2D on the viscoelastic behavior of trabecular bone. The femoral heads of T2D (n = 26) and non-T2D (n = 40) individuals with hip fragility fractures were collected for this investigation. Following the micro-CT scanning of all bone samples, the stress relaxation and dynamic mechanical analysis (DMA) tests were performed to quantify the viscoelasticity of bone. Further, a correlation analysis was performed to investigate the effects of alteration in bone microstructural and biochemical parameters on viscoelasticity. ResultsThe stress relaxation and frequency sweep responses of T2D and non-T2D trabecular bone specimens were not found significantly different. However, the storage modulus, initial stiffness, and initial stress were found lower in T2D bone. The significant correlation of percentage stress relaxed is obtained between the mineral content (r= - 0.52, p-value = 0.003), organic content (r = 0.40, p-value = 0.02), and mineral-to-matrix ratio (r = - 0.43, p-value = 0.009). Further, storage and loss modulus were correlated with bone volume fraction (BV/TV) for both groups. The stress relaxation and frequency sweep characteristics were not found significantly connected with the other chemical, structural, or clinical parameters. ConclusionThis study suggests that T2D does not affect the time-dependent response of human femoral trabecular bone. The viscoelastic properties are positively correlated with organic content and negatively correlated with mineral content.