Metastable high-entropy alloys (HEAs) with strong transformation-induced plasticity (TRIP) effects are quite desirable from the standpoint of mechanical performance. This can be achieved through ε (HCP) and α΄ (BCC) martensitic transformations during deformation, for which their importance and effectiveness should be systematically evaluated. Accordingly, in the present work, by adjusting the chemical composition of the FeCoCrNiMnV system, the formation of ε and α′-martensite was tailored. Vanadium alloying resulted in a single FCC phase, and increasing Fe at the expense of Co promoted the formation of α′-martensite over ε-martensite. The V-free Fe45Co30Cr15Ni5Mn5 HEA exhibited high strength but low ductility. However, the V-containing Fe40Co30Cr15Ni5Mn5V5, Fe45Co25Cr15Ni5Mn5V5, and Fe50Co20Cr15Ni5Mn5V5 HEAs showed much better tensile properties at room and cryogenic temperatures. The last HEA with the highest Fe content showed a remarkable room-temperature strength-ductility synergy with an ultimate tensile strength (UTS) of 826 MPa, a total elongation of 88 %, and tensile toughness of 604 MJ m−3, ascribed to the remarkable TRIP effect by the α′-martensite formation. At cryogenic temperatures, this effect resulted in a superior strength-ductility balance with a UTS of 1511 MPa, a total elongation of 68.9 %, and a tensile toughness of 814 MJ m−3. The results showed that α′-martensite formation is more important for overcoming the strength-ductility trade-off compared to ε-martensite formation in HEAs.
Read full abstract