Recently, there has been a growing recognition that the generic values of runoff coefficient (C) and curve number (CN) from standard lookup tables in the literature may not accurately capture the specific characteristics of a given catchment. This study aims to estimate and compare the event C and CN of two contrasting urban catchments in Ljubljana, Slovenia using observed rainfall-runoff data. Estimated parameter values were compared to the tabulated values from the literature (i.e., ASCE, 1992; USDA-NRCS, 2004). Seasonal changes of C and CN, along with diurnal streamflow patterns, were also analyzed to understand the eco-hydrological processes in the urban forest. The results demonstrated that the urban mixed forest exhibited high variability of Cs across all rainfall events with a mean and median of 0.11 and 0.062, respectively. Most of the C values observed in the urban area are clustered around the central tendency with a mean and median of 0.60. These mean C values in both catchments were lower than the tabulated values in the ASCE (1992) design manual. Mean and median CN values in the urban area were 95.45 and 96.81, respectively, lower than the urban mixed forest’s CN values of 82.69 and 83.95. An asymptotic CN∞ of 90.69 was found for the urban area and 71.71 for the urban mixed forest. Central tendency-derived CN values tend to be slightly higher than the tabulated values from USDA-NRCS (2004) and gridded values from GCN250 (Jaafar et al., 2019), while asymptotic CN∞ values were lower. Using central tendency measures as the single lumped value of C and CN may provide a reasonable representation of the runoff behavior in the studied urban area. However, this may present certain challenges in the urban forest catchment. Additionally, pre-event soil moisture conditions and specific storm characteristics contributed to the observed variations in C and CN. Bi-monthly analysis showed that C and CN were high during the autumn and winter months. Diurnal streamflow pattern is most prevalent during low-flow and precipitation-free periods while exhibiting seasonal structures in terms of the shape and timing of maxima and minima. Local estimation of C and CN allows for a more tailored representation of the catchment’s hydrological behavior.