Stratospheric Water Vapor Research Articles

Role of Southern Hemisphere sudden stratospheric warming in altering the intensity of Brewer-Dobson circulation and its impact on stratospheric ozone and water vapor

The changes in the intensity of Brewer-Dobson circulation (BDC) in the record-breaking Southern Hemisphere sudden stratospheric warming (SH SSW) event in 2019 are investigated in the present study. Wave driving was observed to be at its highest in 2019 SH SSW, despite the event being classified as a minor warming event. The Eliassen-Palm flux divergence, indicative of wave driving, was observed to be increasing before the SSW, and subsiding afterwards. The stratospheric circulation followed the wave driving and intensified along the warming episode. The resulting stratospheric distribution from Aura Microwave Limb Sounder showed a negative ozone anomaly (∼20%) in the tropical lower stratosphere and a downward propagating positive anomaly in the Southern Hemisphere polar stratosphere around the central dates. The water vapor mixing ratio showed an increase of more than 25% in the polar lower stratosphere and 10% in the tropical upper stratosphere. A cooling of about 5 K was observed in the tropical middle stratosphere. The results indicate that SH SSW can change the intensity of the stratospheric circulation which in turn affects the ozone and water vapor transport from the tropics to the pole.

Multi-decadal variability controls short-term stratospheric water vapor trends

Stratospheric water vapor increases are expected in response to greenhouse gas-forced climate warming, and these changes act as a positive feedback to surface climate. Previous efforts at inferring trends from the 3–4 decade-long observational stratospheric water vapor record have yielded conflicting results. Here we show that a robust multi-decadal variation of water vapor concentrations exists in most parts of the stratosphere based on satellite observations and atmospheric model simulations, which clearly divides the past 40 years into two wet decades (1986–1997; 2010–2020) and one dry decade (1998–2009). This multi-decadal variation, especially pronounced in the lower to middle stratosphere and in the northern hemisphere, is associated with decadal temperature anomalies (±0.2 K) at the cold point tropopause and a hemispheric asymmetry in changes of the Brewer-Dobson circulation modulating methane oxidation. Multi-decadal variability must be taken into account when evaluating stratospheric water vapor trends over recent decades.

Climatology, sources, and transport characteristics of observed water vapor extrema in the lower stratosphere

Abstract. Stratospheric water vapor (H2O) is a substantial component of the global radiation budget and therefore important to variability in the climate system. Efforts to understand the distribution, transport, and sources of stratospheric water vapor have increased in recent years, with many studies utilizing long-term satellite observations. Previous work to examine stratospheric H2O extrema has typically focused on the stratospheric overworld (pressures ≤ 100 hPa) to ensure the observations used are truly stratospheric. However, this leads to the broad exclusion of the lowermost stratosphere, which can extend over depths of more than 5 km below the 100 hPa level in the midlatitudes and polar regions and has been shown to be the largest contributing layer to the stratospheric H2O feedback. Moreover, focusing on the overworld only can lead to a large underestimation of stratospheric H2O extrema occurrence. Therefore, we expand on previous work by examining 16 years of Microwave Limb Sounder (MLS) observations of water vapor extrema (≥ 8 ppmv) in both the stratospheric overworld and the lowermost stratosphere to create a new lower-stratosphere climatology. The resulting frequency of H2O extrema increases by more than 300 % globally compared to extrema frequencies within stratospheric overworld observations only, though the percentage increase varies substantially by region and season. Additional context is provided for this climatology through a backward isentropic trajectory analysis to identify potential sources of the extrema. We show that, in general, tropopause-overshooting convection presents itself as a likely source of H2O extrema in much of the world, while meridional isentropic transport of air from the tropical upper troposphere to the extratropical lower stratosphere is also possible.

Atmospheric composition and climate impacts of a future hydrogen economy

Abstract. Hydrogen is expected to play a key role in the global energy transition to net zero emissions in many scenarios. However, fugitive emissions of hydrogen into the atmosphere during its production, storage, distribution and use could reduce the climate benefit and also have implications for air quality. Here, we explore the atmospheric composition and climate impacts of increases in atmospheric hydrogen abundance using the UK Earth System Model (UKESM1) chemistry–climate model. Increases in hydrogen result in increases in methane, tropospheric ozone and stratospheric water vapour, resulting in a positive radiative forcing. However, some of the impacts of hydrogen leakage are partially offset by potential reductions in emissions of methane, carbon monoxide, nitrogen oxides and volatile organic compounds from the consumption of fossil fuels. We derive a refined methodology for determining indirect global warming potentials (GWPs) from parameters derived from steady-state simulations, which is applicable to both shorter-lived species and those with intermediate and longer lifetimes, such as hydrogen. Using this methodology, we determine a 100-year global warming potential for hydrogen of 12 ± 6. Based on this GWP and hydrogen leakage rates of 1 % and 10 %, we find that hydrogen leakage offsets approximately 0.4 % and 4 % respectively of total equivalent CO2 emission reductions in our global hydrogen economy scenario. To maximise the benefit of hydrogen as an energy source, emissions associated with hydrogen leakage and emissions of the ozone precursor gases need to be minimised.

The dehydration carousel of stratospheric water vapor in the Asian summer monsoon anticyclone

Abstract. During the StratoClim Geophysica campaign, air with total water mixing ratios up to 200 ppmv and ozone up to 250 ppbv was observed within the Asian summer monsoon anticyclone up to 1.7 km above the local cold-point tropopause (CPT). To investigate the temporal evolution of enhanced water vapor being transported into the stratosphere, we conduct forward trajectory simulations using both a microphysical and an idealized freeze-drying model. The models are initialized at the measurement locations and the evolution of water vapor and ice is compared with satellite observations of MLS and CALIPSO. Our results show that these extremely high water vapor values observed above the CPT are very likely to undergo significant further freeze-drying due to experiencing extremely cold temperatures while circulating in the anticyclonic “dehydration carousel”. We also use the Lagrangian dry point (LDP) of the merged back-and-forward trajectories to reconstruct the water vapor fields. The results show that the extremely high water vapor mixed with the stratospheric air has a negligible impact on the overall water vapor budget. The LDP mixing ratios are a better proxy for the large-scale water vapor distributions in the stratosphere during this period.

The SPARC water vapour assessment II: biases and drifts of water vapour satellite data records with respect to frost point hygrometer records

Abstract. Satellite data records of stratospheric water vapour have been compared to balloon-borne frost point hygrometer (FP) profiles that are coincident in space and time. The satellite data records of 15 different instruments cover water vapour data available from January 2000 through December 2016. The hygrometer data are from 27 stations all over the world in the same period. For the comparison, real or constructed averaging kernels have been applied to the hygrometer profiles to adjust them to the measurement characteristics of the satellite instruments. For bias evaluation, we have compared satellite profiles averaged over the available temporal coverage to the means of coincident FP profiles for individual stations. For drift determinations, we analysed time series of relative differences between spatiotemporally coincident satellite and hygrometer profiles at individual stations. In a synopsis we have also calculated the mean biases and drifts (and their respective uncertainties) for each satellite record over all applicable hygrometer stations in three altitude ranges (10–30 hPa, 30–100 hPa, and 100 hPa to tropopause). Most of the satellite data have biases <10 % and average drifts <1 % yr−1 in at least one of the respective altitude ranges. Virtually all biases are significant in the sense that their uncertainty range in terms of twice the standard error of the mean does not include zero. Statistically significant drifts (95 % confidence) are detected for 35 % of the ≈ 1200 time series of relative differences between satellites and hygrometers.

The Influence of Internal Climate Variability on Stratospheric Water Vapor Increases After Large‐Magnitude Explosive Tropical Volcanic Eruptions

AbstractSubstantial and prolonged enhancements in stratospheric water vapor (SWV) have occurred after large‐magnitude explosive tropical volcanic eruptions, with modified tropopause entry caused by aerosol‐absorptive heating. Here, we analyze the timing and longevity of heating‐driven post‐eruption SWV changes within CMIP6‐VolMIP short‐term climate‐response experiments with the UK Earth System Model (UKESM1). We find aerosol‐absorptive heating causes peak SWV increases of 17% (∼1 ppmv) and 10% (0.5 ppmv) at 100 and 50 hPa, at ∼18 and ∼23 months after a Pinatubo‐like eruption, respectively. We track the temperature response in the tropical lower stratosphere and identify the main SWV increase occurs only after the descending aerosol heating reaches the tropopause, suggesting a key role for aerosol microphysical processes (sedimentation rate). We explore how El Niño–Southern Oscillation variability modulates this effect. Post‐eruption SWV increases are ∼80% stronger for the La Nina phase compared to the ensemble mean. Tropical upwelling strongly mediates this effect.

Extreme Altitudes of Stratospheric Hydration by Midlatitude Convection Observed During the DCOTSS Field Campaign

AbstractWater vapor's contribution to Earth's radiative forcing is most sensitive to changes in its lower stratosphere concentration. One recognized pathway for rapid increases in stratospheric water vapor is tropopause‐overshooting convection. Since this pathway has been rarely sampled, the NASA Dynamics and Chemistry of the Summer Stratosphere (DCOTSS) field project focused on obtaining in situ observations of stratospheric air recently affected by convection over the United States. This study reports on the extreme altitudes to which convective hydration was observed. The data show that the overworld stratosphere is routinely hydrated by convection and that past documented records of stratospheric heights of convective hydration were exceeded during several DCOTSS flights. The most extreme event sampled is highlighted, for which stratospheric water vapor was increased by up to 26% at an altitude of 19.25 km, a potential temperature of 463 K, and an ozone mixing ratio >1500 ppbv.

Technical note: On HALOE stratospheric water vapor variations and trends at Boulder, Colorado

Abstract. This study compares time series of stratospheric water vapor (SWV) data at 30 and 50 hPa from 1993 to 2005, based on sets of Halogen Occultation Experiment (HALOE) profiles above the region of Boulder, CO (40∘ N, 255∘ E), and on local frost-point hygrometer (FPH) measurements. Their differing trends herein agree with most of the previously published findings. FPH trends are presumed to be accurate within their data uncertainties, and there are no known measurement biases affecting the HALOE trends. However, the seasonal sampling from HALOE is deficient at 40∘ N from 2001 to 2005, especially during late winter and springtime, when HALOE SWV time series at 55∘ N clearly show a springtime maximum. This study finds that the SWV trends from HALOE and FPH measurements nearly agree within uncertainties at 30 hPa for the more limited time span of 1993 to 2002. Yet, HALOE SWV at 50 hPa has significant and perhaps uncertain corrections for interfering aerosols from 1992 to 1994. Northern Hemisphere time series and daily SWV plots near 30 hPa from the Limb Infrared Monitor of the Stratosphere (LIMS) experiment indicate that there is transport of filaments of high SWV from polar to middle latitudes during dynamically active winter and springtime periods. Although FPH measurements sense SWV variations at all scales, the HALOE time series do not resolve smaller-scale structures because its time series data are based on an average of four or more occultations within a finite latitude–longitude sector. It is concluded that the variations and trends of HALOE SWV are reasonable at 40∘ N and 30 hPa from 1993 to 2002 and in accord with the spatial scales of its measurements and sampling frequencies.

Strong Evidence of Heterogeneous Processing on Stratospheric Sulfate Aerosol in the Extrapolar Southern Hemisphere Following the 2022 Hunga Tonga‐Hunga Ha'apai Eruption

AbstractThe January 2022 eruption of Hunga Tonga‐Hunga Ha'apai (HT‐HH) caused the largest enhancement in stratospheric aerosol loading in decades and produced an unprecedented enhancement in stratospheric water vapor, leading to strong stratospheric cooling that in turn induced changes in the large‐scale circulation. Here we use satellite measurements of gas‐phase constituents together with aerosol extinction to investigate the extent to which the thick aerosol, excess moisture, and strong cooling enabled heterogeneous chemical processing. In the southern tropics, unambiguous signatures of substantial chlorine and nitrogen repartitioning appear over a broad vertical domain almost immediately after the eruption, with depletion of N2O5, NOx, and HCl accompanied by enhancement of HNO3, ClO, and ClONO2. After initially rising steeply, HNO3 and ClO plateau, maintaining fairly constant abundances for several months. These patterns are consistent with the saturation of N2O5 hydrolysis, suggesting that this reaction is the primary mechanism for the observed composition changes. The southern midlatitudes and subtropics show similar but weaker enhancements in ClO and ClONO2. In those regions, however, effects of anomalous transport dominate the evolution of HNO3 and HCl, obscuring the signs of heterogeneous processing. Perturbations in chlorine species are considerably weaker than those measured in the southern midlatitude stratosphere in 2020 following the Australian New Year's fires. The moderate HT‐HH‐induced enhancements in reactive chlorine seen throughout the southern middle and low‐latitude stratosphere, far smaller than those in typical winter polar vortices, do not lead to appreciable chemical ozone loss; rather, extrapolar lower‐stratospheric ozone remains primarily controlled by dynamical processes.

Impact of Hunga Tonga-Hunga Ha’apai Volcanic Eruption on Stratospheric Water Vapour, Temperature, and Ozone

Despite being rare, large volcanic eruptions can have a long-lasting impact on the chemistry, radiation, and dynamics of the stratosphere. This study attempts to quantify the changes in the stratospheric water vapour and its relationship to temperature and ozone observed from space-based Microwave Limb Sounder (MLS) observations during the submarine volcano eruption Hunga Tonga-Hunga Ha’apai that occurred on 15 January 2022. The most notable aspect of this eruption is the plumes, which are water vapour columns that reached higher altitudes (1 hPa (47.6 km)) than earlier eruptions. We discovered that the eruption injected a record amount of water vapour (6–8 ppmv) directly into the stratosphere from 38–10 hPa vertically, which is present even after one year. The majority of water vapour is confined to the Southern Hemisphere (SH) tropics, i.e., 30°S to 5°N, and gradually descends to the SH polar latitudes over time. The WV from the lower stratosphere reaches mesospheric altitudes during January 2023. We quantify the impact of increased water vapour on temperature and ozone as well. Temperatures begin to fall during the month of March in the regions where there is an increase in water vapour. A ~5 K cooling occurs in July and August as a result of the thermal adjustment to the extra water vapour IR cooling. Our analysis shows a decrease in ozone caused by an increase in water vapour. Significant variability is observed in all three parameters at 26 km compared to other levels. Further, we noticed that after one year of eruption, the water vapour, Temperature and Ozone did not reach the background values. It is possible that this unusual eruption produced a different atmospheric reaction than other significant volcanic eruptions that have been well investigated.

Weakening of the tropical tropopause layer cold trap with global warming

Abstract. Lagrangian trajectories have previously been used to reconstruct water vapor variability in the lower stratosphere, where the sensitivity of surface radiation to changes in the water vapor concentration is strongest, by obtaining temperature histories of air parcels that ascend from the troposphere to the stratosphere through the tropical tropopause layer (TTL). Models and theory predict an acceleration of the Brewer–Dobson circulation (BDC) and deceleration of the Walker circulation with surface warming, and both of these will drive future changes to transport across the TTL. Here, we examine the response of TTL transport during boreal winter to idealized changes in the BDC and Walker circulation by comparing the temperature histories of trajectories computed with ERA5 data to those calculated using the same data but with altered vertical and zonal wind velocities. We find that lower-stratospheric water vapor mixing ratios calculated from trajectories' cold point temperatures can increase by about 1.6 ppmv (about 50 %) when only zonal winds are slowed, while changes to vertical winds have a negligible impact on water vapor concentrations. This change follows from a decrease in zonal sampling of the temperature field by trajectories, which weakens the “cold trap” mechanism of dehydration as TTL transport evolves. As the zonal winds of the TTL decrease, the fraction of air that passes through the cold trap while ascending to the stratosphere will decrease and the coldest average temperature experienced by parcels will increase. Future changes to TTL temperatures can be applied as an offset to these temperature histories, including enhanced warming of the cold trap due to El Niño-like warming, which has a secondary impact on the fraction of air that is dehydrated by the cold trap. Some of the resultant moistening may be negated by a decreased rate of temperature change following the cold point, which will allow more ice to gravitationally settle before sublimating outside of the cold trap. This result presents a mechanism for a stratospheric water vapor feedback that can exist without changes to TTL temperatures.

Stratospheric water vapor affecting atmospheric circulation

Water vapor plays an important role in many aspects of the climate system, by affecting radiation, cloud formation, atmospheric chemistry and dynamics. Even the low stratospheric water vapor content provides an important climate feedback, but current climate models show a substantial moist bias in the lowermost stratosphere. Here we report crucial sensitivity of the atmospheric circulation in the stratosphere and troposphere to the abundance of water vapor in the lowermost stratosphere. We show from a mechanistic climate model experiment and inter-model variability that lowermost stratospheric water vapor decreases local temperatures, and thereby causes an upward and poleward shift of subtropical jets, a strengthening of the stratospheric circulation, a poleward shift of the tropospheric eddy-driven jet and regional climate impacts. The mechanistic model experiment in combination with atmospheric observations further shows that the prevailing moist bias in current models is likely caused by the transport scheme, and can be alleviated by employing a less diffusive Lagrangian scheme. The related effects on atmospheric circulation are of similar magnitude as climate change effects. Hence, lowermost stratospheric water vapor exerts a first order effect on atmospheric circulation and improving its representation in models offers promising prospects for future research.

Significant Stratospheric Moistening Following Extreme El Niño Events

The moistening impact of El Niño on the tropical lower stratosphere has been extensively studied, yet a long-standing challenge is its potential nonlinearities regarding the strength of El Niño. Extreme El Niño’s hydration in 2015/2016 was unprecedented in the satellite era, providing a great opportunity to distinguish the differential response of water vapor to extreme and moderate El Niño. Using ERA5 and MERRA-2 reanalysis data from 1979–2019, we compare the composite tropical lower stratospheric water vapor anomalies throughout all extreme and moderate El Niño episodes since the satellite era. We validate the variations in the lower stratospheric water vapor during the two distinct El Niño episodes using a three-dimensional chemistry transport model simulating the same period. The model reproduces the observed pattern in lower stratospheric water vapor. Both demonstrate that robust moistening during extreme El Niño events occurs throughout the tropical lower stratosphere. However, moderate El Niño events seem to have a weak effect on lower stratospheric water vapor. In comparison to moderate El Niño, the strong convective activities induced by extreme El Niño release large amounts of latent heat, causing extensive and intense warming in the tropical upper troposphere and lower stratosphere, thus greatly increasing the water vapor content in the tropical lower stratosphere. Additionally, moderate El Niño events have strong seasonality in their hydration effect in the tropics, whereas the intense moistening effect of extreme El Niño events prevails in all seasons during their episodes.

Natural short-lived halogens exert an indirect cooling effect on climate

Observational evidence shows the ubiquitous presence of ocean-emitted short-lived halogens in the global atmosphere1–3. Natural emissions of these chemical compounds have been anthropogenically amplified since pre-industrial times4–6, while, in addition, anthropogenic short-lived halocarbons are currently being emitted to the atmosphere7,8. Despite their widespread distribution in the atmosphere, the combined impact of these species on Earth’s radiative balance remains unknown. Here we show that short-lived halogens exert a substantial indirect cooling effect at present (−0.13 ± 0.03 watts per square metre) that arises from halogen-mediated radiative perturbations of ozone (−0.24 ± 0.02 watts per square metre), compensated by those from methane (+0.09 ± 0.01 watts per square metre), aerosols (+0.03 ± 0.01 watts per square metre) and stratospheric water vapour (+0.011 ± 0.001 watts per square metre). Importantly, this substantial cooling effect has increased since 1750 by −0.05 ± 0.03 watts per square metre (61 per cent), driven by the anthropogenic amplification of natural halogen emissions, and is projected to change further (18–31 per cent by 2100) depending on climate warming projections and socioeconomic development. We conclude that the indirect radiative effect due to short-lived halogens should now be incorporated into climate models to provide a more realistic natural baseline of Earth’s climate system.

Response of stratospheric water vapour to warming constrained by satellite observations

Future increases in stratospheric water vapour risk amplifying climate change and slowing down the recovery of the ozone layer. However, state-of-the-art climate models strongly disagree on the magnitude of these increases under global warming. Uncertainty primarily arises from the complex processes leading to dehydration of air during its tropical ascent into the stratosphere. Here we derive an observational constraint on this longstanding uncertainty. We use a statistical-learning approach to infer historical co-variations between the atmospheric temperature structure and tropical lower stratospheric water vapour concentrations. For climate models, we demonstrate that these historically constrained relationships are highly predictive of the water vapour response to increased atmospheric carbon dioxide. We obtain an observationally constrained range for stratospheric water vapour changes per degree of global warming of 0.31 ± 0.39 ppmv K−1. Across 61 climate models, we find that a large fraction of future model projections are inconsistent with observational evidence. In particular, frequently projected strong increases (>1 ppmv K−1) are highly unlikely. Our constraint represents a 50% decrease in the 95th percentile of the climate model uncertainty distribution, which has implications for surface warming, ozone recovery and the tropospheric circulation response under climate change.

The Sensitivity of Moisture Flux Partitioning in the Cold‐Point Tropopause to External Forcing

AbstractThe dryness of the stratosphere is the result of air entering through the cold tropical tropopause layer (TTL). However, our understanding of the moisture flux partitioning into water vapor and frozen hydrometeors is incomplete. This raises concerns regarding the ability of General Circulation Models to accurately predict changes in stratospheric water vapor following perturbations in the radiative budget due to volcanic aerosol or stratospheric geoengineering. We present the first results using a global storm‐resolving model investigating the sensitivity of moisture fluxes within the TTL to an additional heating source. We address the question how the partitioning of moisture fluxes into water vapor and frozen hydrometeors changes under perturbations. The analysis reveals the resilience of the TTL, keeping the flux partitioning constant even at an average cold‐point warming exceeding 8 K. In the control and perturbed simulations, water vapor contributes around 80% of the moisture entering the stratosphere.

A multi-model assessment of the Global Warming Potential of hydrogen

With increasing global interest in molecular hydrogen to replace fossil fuels, more attention is being paid to potential leakages of hydrogen into the atmosphere and its environmental consequences. Hydrogen is not directly a greenhouse gas, but its chemical reactions change the abundances of the greenhouse gases methane, ozone, and stratospheric water vapor, as well as aerosols. Here, we use a model ensemble of five global atmospheric chemistry models to estimate the 100-year time-horizon Global Warming Potential (GWP100) of hydrogen. We estimate a hydrogen GWP100 of 11.6 ± 2.8 (one standard deviation). The uncertainty range covers soil uptake, photochemical production of hydrogen, the lifetimes of hydrogen and methane, and the hydroxyl radical feedback on methane and hydrogen. The hydrogen-induced changes are robust across the different models. It will be important to keep hydrogen leakages at a minimum to accomplish the benefits of switching to a hydrogen economy.

Measurements of Stratospheric Water Vapor at Mauna Loa and the Effect of the Hunga Tonga Eruption

AbstractThe eruption of Hunga Tonga in January 2022 injected an amount of water vapor into the stratosphere that is unprecedented in the satellite era. In the ensuing months Aura Microwave Limb Sounder measurements showed that this plume of water vapor spread from its original injection site at 20.5°S to Mauna Loa, Hawaii at 19.5°N, where an increase was observed in April by the ground‐based Water Vapor Millimeter‐wave Spectrometer instruments. Interannual variations in water vapor occur over Mauna Loa due to both dynamical variations in the tropical stratosphere and variations in the amount of water vapor crossing the tropical tropopause, and we place the observed stratospheric water vapor increase from Hunga Tonga into context of these other variations that have been observed since 2013.

Stratospheric Water Vapor from the Hunga Tonga–Hunga Ha’apai Volcanic Eruption Deduced from COSMIC-2 Radio Occultation

The eruption of the Hunga Tonga–Hunga Ha’apai (HTHH) volcano on 15 January 2022 injected large amounts of water vapor (H2O) directly into the stratosphere. While normal background levels of stratospheric H2O are not detectable in radio occultation (RO) measurements, effects of the HTHH eruption are clearly observed as anomalous refractivity profiles from COSMIC-2, suggesting the possibility of detecting the HTHH H2O signal. To separate temperature and H2O effects on refractivity, we use co-located temperature observations from the Microwave Limb Sounder (MLS) to constrain a simplified H2O retrieval. Our results show enhancements of H2O up to ~2500–3500 ppmv in the stratosphere (~29–33 km) in the days following the HTHH eruption, with propagating patterns that follow the dispersing volcanic plume. The stratospheric H2O profiles derived from RO are in reasonable agreement with limited radiosonde observations over Australia. The H2O profiles during the first few days after the eruption show descent of the plume at a rate of ~−1 km/day, likely due to strong radiative cooling (~−10 K/day) induced by high H2O concentrations; slower descent (~−200 m/day) is observed over the following week as the plume disperses. The total mass of H2O injected by HTHH is estimated as 110 ± 14 Tg from measurements in the early plumes during 16–18 January, which equates to approximately 8% of the background global mass of stratospheric H2O. These RO measurements provide novel quantification of the unprecedented H2O amounts and the plume evolution during the first week after the HTHH eruption.