The Mount Grace metamorphosed carbonatites (Late Devonian) outcrop as thin (0.5–4 m), laterally discontinuous, strata-bound mappable lenses within the Monashee complex of the southeastern Canadian Cordillera. The host stratigraphic sequence (Monashee cover gneiss) was metamorphosed and deformed in the Late Cretaceous to early Eocene followed immediately by exhumation of the Frenchman Cap and Thor Odin domes. We present seven stratigraphic logs for Mount Grace carbonatites including new and previously described outcroppings spanning ∼30 km. The Mount Grace carbonatite units were deposited regionally within or near the top of a shallow marine sedimentary sequence within miogeoclinal strata of the western margin of paleo-North America (Laurentia). The distribution of the Mount Grace carbonatite lithofacies and the preserved depositional structures and textures suggest that these are pyroclastic deposits resulting from phreatomagmatic eruptions. Our new data enhance the volcanological story with an eruption scenario involving phreatomagmatic reactions and deposition from pyroclastic density currents, sourced from multiple centers within a field of monogenetic maar volcanoes. The distribution of the Mount Grace carbonatites parallel to the western margin of the paleo-North American continent correlates well with regional Late Devonian alkaline magmatism associated with development of an extensional back-arc basin.