Aluminium–lithium-base alloys are of considerable interest because of their low density and high modulus. However, they have been shown to have low ductility and poor fracture toughness. This has been attributed to a variety of factors, including intense shear band formation, segregation to grain boundaries, and weakened grain boundaries due to precipitation and precipitate-free zones. The authors have investigated the deformation structures observed in binary and more complex commercial alloys. As would be expected, considering the microstructure of the alloys, extensive strain localization and shear band formation occurs in these alloys. However, it is shown that the commercial alloys are less sensitive to strain localization than the model binary alloy systems investigated. The stresss–train behaviour has been investigated. The alloys exhibit jerky flow, which is indicative of negative strain rate sensitivity, and strain rate change tests showed this to be the case. This is consistent with the deformation structures observed. The effect of weakened grain boundaries due to precipitation and precipitate-free zones has been studied by comparing the fracture characteristics of aged and unaged material. It is shown that the mode of failure is identical under appropriate conditions. It is concluded that segregation to grain boundaries is the major cause of the lower ductility and toughness of Al–Li alloys. This possibility has been investigated using in situ fracture surface analysis techniques. Results are presented on grain boundary segregation, and methods of reducing its influence on fracture behaviour are indicated.MST/570