This paper presents a mixed-mode I/II fracture criterion to investigate the crack initiation in orthotropic materials in which the crack is directed along fibers. The minimum strain energy density criterion is extended to investigate the cracked orthotropic materials. The reinforced isotropic solid model based on collinear crack propagation along fibers is proposed as an advantageous model to study the fracture behavior of composites. This model introduces fibers as reinforcements of the isotropic matrix in orthotropic materials in which their effects are qualified by defining reinforcement factors at tension and shear modes. The proposed criterion can predict the crack initiation phenomenon. Therefore, in this study a new concept of linear fracture toughness for orthotropic materials is proposed. Experimental data are used to validate the output of the proposed criterion. The coincidence of fracture limit curves and experimental data indicates the ability of the new criterion to predict crack initiation in orthotropic materials.