ABSTRACT Use of traditional catchment characteristics and lack of effective separation of catchment characteristics from rainfall characteristics limits the adequate understanding of the actual influences of catchment characteristics on stormwater quality. In this context, this study adopted a pattern-based separation approach to identifying common events from three rainfall clusters of study catchments, where rainfall characteristics for identified common 8, 9 and 36 events are similar, but catchment characteristics are different. This study identified that the locations of pervious surfaces and urban forms are also important catchment characteristics. The contribution of the pervious area to runoff is significant for long durational (cluster 1) and high-intensity (cluster 3) rainfall events associated with low antecedent dry days and initiated at around 35 mm rainfall depth. A catchment having a large impervious area and pervious area located at far distances from the drainage system can contribute more pollutant load at first 10% runoff volume. High socio-economic developed urban form can contribute a high fraction wash-off corresponding to 10–70% runoff volume due to traffic-related behaviour and various anthropogenic activities. The developed knowledge will overcome the shortcomings of lumped characteristics-based treatment design and improve the efficiency of current stormwater treatment system design practices.