Let $GP(q,d)$ be the $d$-Paley graph defined on the finite field $\mathbb{F}_q$. It is notoriously difficult to improve the trivial upper bound $\sqrt{q}$ on the clique number of $GP(q,d)$. In this paper, we investigate the connection between Gauss sums over a finite field and the maximum cliques of their corresponding generalized Paley graphs. We show that the trivial upper bound on the clique number of $GP(q,d)$ is tight if and only if $d \mid (\sqrt{q}+1)$, which strengthens the previous related results by Broere-D\"oman-Ridley and Schneider-Silva. We also obtain a new simple proof of Stickelberger's theorem on evaluating semi-primitive Gauss sums.
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