Steep Temperature Research Articles

A controllable and byproduct-free synthesis method of carbon-coated silicon nanoparticles by induction thermal plasma for lithium ion battery

Carbon coated silicon nanoparticle is regarded as a promising anode material for the next generation of lithium ion batteries, while the development of a cost-effective and environmental-friendly preparation method is still difficult and hinders the practical implementation. In this research, a controllable and byproduct-free synthesis method is proposed for the preparation of silicon nanoparticles with amorphous hydrogenated carbon coating. The current apparatus is operated based on the application of induction thermal plasma. Plasma properties are tunable by adjusting the ratio of tangential and radial gas flow rates (T/R), which compose the plasma sheath gas. Obtained results reveal the plasma shape is shrunk with higher T/R values, which will lead to a steeper temperature gradient and lower temperature distributions in reaction chamber. Consequently, the compositions and properties of synthesized particles can be modified with T/R values. The formation of SiC, which was an intractable issue before, can be vanished at higher tangential gas flow rates in current research and the capacity of silicon anode for batteries will be improved in predict. This research is significant for a deep understanding of plasma synthesis processing and design of batteries with excellent performance.

Predictions of Conjugate Heat Transfer in Turbulent Channel Flow Using Advanced Wall-Modeled Large Eddy Simulation Techniques.

In this paper, advanced wall-modeled large eddy simulation (LES) techniques are used to predict conjugate heat transfer processes in turbulent channel flow. Thereby, the thermal energy transfer process involves an interaction of conduction within a solid body and convection from the solid surface by fluid motion. The approaches comprise a two-layer RANS–LES approach (zonal LES), a hybrid RANS–LES representative, the so-called improved delayed detached eddy simulation method (IDDES) and a non-equilibrium wall function model (WFLES), respectively. The results obtained are evaluated in comparison with direct numerical simulation (DNS) data and wall-resolved LES including thermal cases of large Reynolds numbers where DNS data are not available in the literature. It turns out that zonal LES, IDDES and WFLES are able to predict heat and fluid flow statistics along with wall shear stresses and Nusselt numbers accurately and that are physically consistent. Furthermore, it is found that IDDES, WFLES and zonal LES exhibit significantly lower computational costs than wall-resolved LES. Since IDDES and especially zonal LES require considerable extra work to generate numerical grids, this study indicates in particular that WFLES offers a promising near-wall modeling strategy for LES of conjugated heat transfer problems. Finally, an entropy generation analysis using the various models showed that the viscous entropy production is zero inside the solid region, peaks at the solid–fluid interface and decreases rapidly with increasing wall distance within the fluid region. Except inside the solid region, where steep temperature gradients lead to high (thermal) entropy generation rates, a similar behavior is monitored for the entropy generation by heat transfer process.

Influence of hydrodynamic interactions among multiple bubbles on convective heat transfer in nucleate boiling

To clear the effects of the hydrodynamic interactions among neighboring vapor bubbles on the saturated pool boiling heat transfer, artificial nucleation sites with several cavity arrangements were manufactured on the substrate surface and measured liquid temperatures near heated substrate by a miniature thermocouple probe with 10 kHz. The surface temperature of heated substrate was measured by an infrared camera with 1 kHz and bubble dynamics were simultaneously visualized by a high-speed video camera with 5 kHz and 10 kHz, respectively. The liquid temperature fluctuations, measured with micro thermocouple 100 μm and 10 μm above the substrate surface, were compared among each other and with the transient temperature fields obtained through IR measurements. Results showed that the hydrodynamic interaction among neighboring bubbles causes the liquid convection, that was only detected 100 µm above the boiling surface. Generally, the degree of liquid temperature fluctuations at 10 μm height and different arrangements of nucleation sites was under 1 K. Here the superheated sublayer in the vicinity of the boiling surface was generally not affected by the convection. Only when the coalescence from two neighboring nucleation sites occurred and the liquid-vapor interface nearly reached the substrate, a steep temperature drop over 2 K was detected. It was concluded that the viscous sublayer stably exists during boiling of water in lower heat flux conditions. To enhance the convective heat transfer in nucleate boiling, coalesced bubble needs to peel off the viscous sublayer during its deformation. Based on the measurements in this study, this peel-off effect only happens when the coalescence point is less than 1 mm above the heated surface.

Modelling picosecond and nanosecond laser ablation for prediction of induced damage on textured SiNx/Si surfaces of Si solar cells

AbstractThis study investigated the laser‐induced damage arising from 266 and 532 nm laser ablation of SiNx films on alkaline textured Si surfaces with nanosecond and picosecond pulse durations using a combination of optical‐thermal simulations and measurements of carrier recombination current density. Simulations predict that the melting depth is limited to within 150 nm of the SiNx/Si surface after 266 nm ps laser irradiation due to the greater absorption in both the SiNx and Si resulting in more direct ablation, while temperatures exceeding the melting temperature of Si are predicted to extend up to 1000 nm into the Si substrate with 532 nm ps pulses leading primarily to spallation. Ablation of the SiNx by 266 nm ps irradiation is predicted to be more homogeneous on smaller sized pyramids due to the increased absorption of double‐bounce reflected light on the pyramid faces. This finding has implications for applications requiring uniform ablation of dielectrics on textured Si surfaces. Ablation of SiNx by the longer wavelength 532 nm ps pulses also increases carrier recombination compared to that incurred with 266 nm ps pulses due to the increased melting depth. Longer ns pulses result in less steep temperature gradients and, for 266 nm pulses, an increased melting depth compared to ps pulses. Consequently, shorter ps UV pulses are preferred for SiNx ablation on Si surfaces due to their reduced laser damage penetration, whereas the less steep temperature gradients resulting from ns 532 nm pulses are beneficial for laser doping to form selective emitters.

Mixed convection in sinusoidal lid driven cavity with non-uniform temperature distribution on the wall utilizing nanofluid

Mixed convection heat transfer of Cu-water nanofluid in an arc cavity with non-uniform heating has been numerically studied. The top flat moving wall is isothermally cooled at Tc and moved with a constant velocity. While the heated arc stationary wall of the cavity is maintained at a hot temperature Th. FORTRAN code is used to solve the mass, momentum, and energy equations in dimensionless form with suitable boundary conditions. In this study, the Reynolds number changed from 1 to 2000, and the Rayleigh number changed from 0 to 107. Also, the range of nanoparticles volume fraction extends from ϕ = 0 to 0.07. Stream vorticity method selected for the discretization of flow and energy equations. The present results are compared with the previous results for the validation part, where the results found a good agreement with the others works. The isotherms are regulated near the arc-shape wall causing a steep temperature gradient at these regions and the local and average heat transfer rate increases with increased volume fraction or Reynolds number or Rayleigh number. Finally, Correlation equations of the average Nusselt number from numerical results are presented.

Studies on the effect of thermal shock on crack resistance of 20MnMoNi55 steel using compact tension specimens

One of the major factors affecting the life span of a Reactor Pressure Vessel (RPV) is the Pressurised Thermal Shock (PTS). PTS is a thermo-mechanical load on the RPV wall due to steep temperature gradients and structural load created by internal pressure of the fluid within the RPV. Safe operating life of a nuclear power plant is ensured by carrying out fracture analysis of the RPV against thermal shock. Carrying out fracture tests on RPV/large scale components is not always feasible. Hence, studies on laboratory level specimens are necessary to validate and supplement the prototype results. This paper aims to study the fracture behaviour of standard Compact Tension [C(T)] specimens, made of RPV steel 20MnMoNi55, subjected to thermal shock through experimental and numerical investigations. Fracture tests have been carried out on the C(T) specimens subjected to thermal transient load and tensile load to quantify the effect of thermal shock. Crack resistance curves are obtained from the fracture tests as per ASTM E1820 and compared with those obtained numerically using XFEM and a good agreement was found. A quantitative study on the crack tip plastic zone, computed using cohesive segment approach, from the numerical analyses justified the experimental crack initiation toughness.

Joining of Nanostructured Ferritic 14YWT Alloys by Spark Plasma Technique

Spark plasma joining of nanostructured ferritic 14YWT alloys has been carried out at 800°C, 1020 °C and 1030 °C in vacuum. The characteristics of joining as a function of temperatures were investigated using bulk density, nanoindentation and electron backscattered diffraction techniques. Joining performed at 1020 °C and 1030 °C shows a complete, uniform bonding of the samples, whereas the samples joined at 800 °C showed a visible crack that runs along the entire sample length. Bulk density measurements indicate that the reduction in density of samples joined at 800 °C is due to the presence of voids at the interface. The presence of columnar grains only close to the interface at 800 °C suggests the possibility of a steep temperature rise locally at the interface that is attributed to high electrical contact resistance at the interface.

Study of mixed convection in two layers of saturated porous medium and nanofluid with rotating circular cylinder

In this study, a numerical investigation of mixed convective heat transfer in a square enclosure partitioned in two layers with a rotating circular cylinder at the middle of the cavity has been carried out. The experiments are performed with Al2O3–water nanofluid (upper layer) and superposed porous medium (lower layer). The upper and lower horizontal walls are assumed to be insulated, while the left and right walls are kept at high and low temperature respectively. Galerkin finite element method has been used to solve the dimensionless governing equations. This study is focused to investigate the effect of Darcy number (10−2≤ Da ≤10−5), Rayleigh number (103≤ Ra≤106), dimensionless angular rotational velocity (−6000≤ W ≤ 6000), solid volume fraction (0≤ ɸ ≤0.06), and the radius of the inner circular cylinder (R = 0.1, 0.2 and 0.3) on the heat transfer, fluid flow, and the physical characteristics thermal of the thermal fields. The results show that the intensity of the flow, steep temperature gradient, and the average Nusselt number (Nu) increase with increasing the value of Darcy number, Rayleigh number, and solid volume fractions at any cylinder radius. Moreover, the recirculation and isotherm distribution lines of the fluid at low Darcy numbers are high when the cylinder rotates counter-clockwise compering with clockwise. The findings also revealed that when W = 0, the maximum Nu is at R = 0.1 and decreases as the cylinder radius increases. Moreover, at high Darcy number, the highest local Nusselt number is found at the porous layer region in case of clockwise rotation while at the nanofluid layer region in case of anti-clockwise rotation.

Microstructure and mechanical properties of 9Cr-0.5Mo-1.8W–VNb (P92) steel weld joints processed by fusion welding

Abstract Grade P92 steel is used for making steam generator components of thermal and nuclear power plants at temperatures up to 923 K. Microstructures, mechanical properties and the service life of the welded components are influenced by the welding process employed. In the present investigation, the effect of Tungsten Inert Gas (TIG) and Activated TIG (A-TIG) welding processes on the microstructure and mechanical properties of P92 steel weld joints are studied. Optical microscope, SEM and TEM were used for characterizing the microstructures. Application of the activated flux on the joint area during A-TIG welding significantly increases the depth of penetration. Due to high current density peak temperature is higher in the weld pool and steep temperature gradient is observed across the joint interface. Therefore, the microstructure is relatively coarse in the A-TIG weld metal. TEM investigations have confirmed that the precipitates present at the grain and lath boundaries are carbides of the form M23C6 and the precipitates seen within the matrix of the lath are niobium and vanadium rich carbides and nitrides of type MX. The tensile strength of the A-TIG weld joint both at room temperature and at 923 K is higher than that of the TIG weld joint. In comparison to the base metal and TIG weld joint, a decrease in the Charpy impact toughness is observed in the A-TIG weld joint due to the formation of δ-ferrite along the fusion interface. However, in contrast to the TIG weld metal, tensile residual stresses at the A-TIG weld are very low.

Microphysical Features of Unprecedented Hailstorms Over Central Region of India During February – March 2014

The central region of India was battered by prolonged, widespread and severe hailstorm events during the period of 15 February 2014 to 15 March 2014. The events were unprecedented not only in terms of time of occurrence, duration and frequency of hailstorms but also size of hailstones. In the present study, we have proposed a hypothesis which governs the mechanism for the development of severe hailstorms based on atmospheric instability, cloud microphysics and its feedback to large scale dynamics. The steep temperature lapse rate owing to warm (i.e. moist) south easterlies in the lower troposphere and cold (i.e. dry) westerlies in upper troposphere as a result of anomalous southward penetration of mid-latitude westerlies in the form of westerly trough fostered convective instability build up. The updraft associated with convectively unstable atmosphere invigorated growth of ice crystals by rapid collection of supercooled water droplets. This ultimately led to formation of graupel/hailstones through the microphysical mechanisms (e.g., riming process). The hypothesis is further tested with high resolution numerical model. The experiment pinpoints that mixed-phase hydrometeors were predominant in mid and upper troposphere and had bearing on the release of latent heat, further stronger the deep convective clouds (i.e., instability). Time evolution of cloud microphysical processes indicate dominant presence of graupel/hail which is consistent with formation of rain water, cloud ice and snow. The results underpin the interplay between large scale dynamical and cloud microphysical processes in the formation of anomalously widespread and persistent severe hailstorm events.

Observation of inverse magnetocaloric effect in magnetic-field-induced austenite phase of Heusler alloys Ni50−xCoxMn31.5Ga18.5 (x=9 and 9.7)

Magnetocaloric effect (MCE), magnetization, specific heat, and magnetostriction measurements were performed in both pulsed and steady high magnetic fields to investigate the magnetocaloric properties of Heusler alloys Ni50-xCoxMn31.5Ga18.5 (x = 9 and 9.7). From direct MCE measurements for Ni41Co9Mn31.5Ga18.5 up to 56 T, a steep temperature drop was observed for magnetic-field-induced martensitic transformation (MFIMT), designated as inverse MCE. Remarkably, this inverse MCE is apparent not only with MFIMT, but also in the magnetic-field-induced austenite phase. Specific heat measurements under steady high magnetic fields revealed that the magnetic field variation of the electronic entropy plays a dominant role in the unconventional magnetocaloric properties of these materials. First-principles based calculations performed for Ni41Co9Mn31.5Ga18.5 and Ni45Co5Mn36.7In13.3 revealed that the magnetic-field-induced austenite phase of Ni41Co9Mn31.5Ga18.5 is more unstable than that of Ni45Co5Mn36.7In13.3 and that it is sensitive to slight tetragonal distortion. We conclude that the inverse MCE in the magnetic-field-induced austenite phase is realized by marked change in the electronic entropy through tetragonal distortion induced by the externally applied magnetic field.

An extreme climate gradient-induced ecological regionalization in the Upper Cretaceous Western Interior Basin of North America

Abstract The Upper Cretaceous Western Interior Basin of North America provides a unique laboratory for constraining the effects of spatial climate patterns on the macroevolution and spatiotemporal distribution of biological communities across geologic timescales. Previous studies suggested that Western Interior Basin terrestrial ecosystems were divided into distinct southern and northern communities, and that this provincialism was maintained by a putative climate barrier at ∼50°N paleolatitude; however, this climate barrier hypothesis has yet to be tested. We present mean annual temperature (MAT) spatial interpolations for the Western Interior Basin that confirm the presence of a distinct terrestrial climate barrier in the form of a MAT transition zone between 48°N and 58°N paleolatitude during the final 15 m.y. of the Cretaceous. This transition zone was characterized by steep latitudinal temperature gradients and divided the Western Interior Basin into warm southern and cool northern biomes. Similarity analyses of new compilations of fossil pollen and leaf records from the Western Interior Basin suggest that the biogeographical distribution of primary producers in the Western Interior Basin was heavily influenced by the presence of this temperature transition zone, which in turn may have impacted the distribution of the entire trophic system across western North America.

Thermal modulation of epicardial Ca2+ dynamics uncovers molecular mechanisms of Ca2+ alternans.

Ca2+ alternans (Ca-Alts) are alternating beat-to-beat changes in the amplitude of Ca2+ transients that frequently occur during tachycardia, ischemia, or hypothermia that can lead to sudden cardiac death. Ca-Alts appear to result from a variation in the amount of Ca2+ released from the sarcoplasmic reticulum (SR) between two consecutive heartbeats. This variable Ca2+ release has been attributed to the alternation of the action potential duration, delay in the recovery from inactivation of RYR Ca2+ release channel (RYR2), or an incomplete Ca2+ refilling of the SR. In all three cases, the RYR2 mobilizes less Ca2+ from the SR in an alternating manner, thereby generating an alternating profile of the Ca2+ transients. We used a new experimental approach, fluorescence local field optical mapping (FLOM), to record at the epicardial layer of an intact heart with subcellular resolution. In conjunction with a local cold finger, a series of images were recorded within an area where the local cooling induced a temperature gradient. Ca-Alts were larger in colder regions and occurred without changes in action potential duration. Analysis of the change in the enthalpy and Q10 of several kinetic processes defining intracellular Ca2+ dynamics indicated that the effects of temperature change on the relaxation of intracellular Ca2+ transients involved both passive and active mechanisms. The steep temperature dependency of Ca-Alts during tachycardia suggests Ca-Alts are generated by insufficient SERCA-mediated Ca2+ uptake into the SR. We found that Ca-Alts are heavily dependent on intra-SR Ca2+ and can be promoted through partial pharmacologic inhibition of SERCA2a. Finally, the FLOM experimental approach has the potential to help us understand how arrhythmogenesis correlates with the spatial distribution of metabolically impaired myocytes along the myocardium.

A comparative study of aromatic characterization of Yingde Black Tea infusions in different steeping temperatures

Black tea, known for its unique aroma, is one of the most popular non-alcoholic beverages. Because of complex aroma composition, studying black tea aroma has attracted widespread attention. The aim of this study was to evaluate the effect of different steeping temperatures (60 °C, 70 °C, 80 °C, and 95 °C) on the aroma composition of Yingde black tea for the first time. A total of 157 volatile compounds were identified by gas chromatography-mass spectrometry (GC-MS). These compounds can be divided into 11 categories, including alcohols, esters, ketones, aldehydes, terpenes and sulfides. The types of different volatile compounds and contents in tea infusion samples show a positive correlation with steeping temperature. A total of 16 main aromatic compounds were identified though the comparison analysis of gas chromatography-olfactometry (GC-O FD ≥ 32) data and odor activity value (OAV value ≥ 1), including β-damascone, β-ionone, linalool, ethyl hexanoate, dimethyl sulfide, dimethyl trisulfide, nonanal, methyl salicylate, 3-hexenyl isovalerate, cedrol, and longifolene. A correlation of characteristic aroma data with descriptive sensory analysis (DSA) data clearly established that different steeping temperatures result in different overall aroma qualities of the black tea, indicating that steeping temperature is a key parameter affecting the aroma composition.

Dropstones in the Mar del Plata Canyon Area (SW Atlantic): Evidence for Provenance, Transport, Distribution, and Oceanographic Implications

AbstractA variety of gravel‐ to cobble‐sized rocks, recovered from the Mar del Plata (MdP) Canyon area (Western South Atlantic at 38°S) and interpreted as ice‐rafted debris, represent the first evidence that large icebergs have floated in the Falkland (Malvinas) Current from the southern polar high latitudes far northward. Detailed petrographic analyses identified the Antarctic Peninsula, sub‐Antarctic islands in the Scotia Sea, and Tierra del Fuego as plausible source areas. The drift process could have started as early as at the beginning of the last deglaciation, according to an age obtained from a cold‐water coral fragment associated with one of the dropstones. At the end of the Last Glacial Maximum, large icebergs have been supplied to the Antarctic Circumpolar Current, captured by those ocean current branches that circumvent the Falkland (Malvinas) Islands and entered the Argentine Margin. When the iceberg fleets approached the Brazil‐Falkland (Malvinas) Confluence Zone with its steep latitudinal temperature gradient, the icebergs got oceanographically trapped and melted off rapidly. The sediment load sinking down to the seafloor formed a dropstone blanket particularly where the MdP Canyon had incised into the continental slope. Here, mass‐flow processes, induced by local slope instability, and along‐slope sediment resorting, due to the erosional effects of strong and persistent contouritic bottom currents, favored local enrichment in dropstones in the form of a loose, coarse sediment drape inside morphological depressions. The bottom current velocity would be locally strong enough to rework this sediment, leaving coarse rafted debris as a lag deposit.

Sediment acidification and temperature increase in an artificial CO2 vent

We investigated the effect of an artificial CO2 vent (0.0015−0.037 mol s−1), simulating a leak from a reservoir for carbon capture and storage (CCS), on the sediment geochemistry. CO2 was injected 3 m deep into the seafloor at 120 m depth. With increasing mass flow an increasing number of vents were observed, distributed over an area of approximately 3 m. In situ profiling with microsensors for pH, T, O2 and ORP showed the geochemical effects are localized in a small area around the vents and highly variable. In measurements remote from the vent, the pH reached a value of 7.6 at a depth of 0.06 m. In a CO2 venting channel, pH reduced to below 5. Steep temperature profiles were indicative of a heat source inside the sediment. Elevated total alkalinity and Ca2+ levels showed calcite dissolution. Venting decreased sulfate reduction rates, but not aerobic respiration. A transport-reaction model confirmed that a large fraction of the injected CO2 is transported laterally into the sediment and that the reactions between CO2 and sediment generate enough heat to elevate the temperature significantly. A CO2 leak will have only local consequences for sediment biogeochemistry, and only a small fraction of the escaped CO2 will reach the sediment surface.

Comparative transcriptomics of spotted seatrout (Cynoscion nebulosus) populations to cold and heat stress.

Resilience to climate change depends on a species' adaptive potential and phenotypic plasticity. The latter can enhance survival of individual organisms during short periods of extreme environmental perturbations, allowing genetic adaptation to take place over generations. Along the U.S. East Coast, estuarine‐dependent spotted seatrout (Cynoscion nebulosus) populations span a steep temperature gradient that provides an ideal opportunity to explore the molecular basis of phenotypic plasticity. Genetically distinct spotted seatrout sampled from a northern and a southern population were exposed to acute cold and heat stress (5 biological replicates in each treatment and control group), and their transcriptomic responses were compared using RNA‐sequencing (RNA‐seq). The southern population showed a larger transcriptomic response to acute cold stress, whereas the northern population showed a larger transcriptomic response to acute heat stress compared with their respective population controls. Shared transcripts showing significant differences in expression levels were predominantly enriched in pathways that included metabolism, transcriptional regulation, and immune response. In response to heat stress, only the northern population significantly upregulated genes in the apoptosis pathway, which could suggest greater vulnerability to future heat waves in this population as compared to the southern population. Genes showing population‐specific patterns of expression, including hpt, acot, hspa5, and hsc71, are candidates for future studies aiming to monitor intraspecific differences in temperature stress responses in spotted seatrout. Our findings contribute to the current understanding of phenotypic plasticity and provide a basis for predicting the response of a eurythermal fish species to future extreme temperatures.

Upper Bathyal Pacific Ocean biogeographic provinces from octocoral distributions

Biogeographical classification schemes such as the Marine Ecoregions of the World (MEOW) have been developed for continental shelf depths. The lack of faunal data in the deep sea has led to the development of biogeographical units based on oceanographic characteristics. The aim of this study was to propose biogeographical schemes for the Upper Bathyal (200–1000 m) across the Pacific Ocean using octocoral distributions. We retrieved over 200 000 octocoral data records from the Deep Sea Coral Data Portal (DSCDP), Ocean Biogeographic Information System (OBIS), Tropical Deep-Sea Benthos program (French National Museum of Natural History), Queensland Museum from the CIDARIS expeditions, and records retrieved from the Siboga expedition reports. We used cluster analysis to examine octocoral distributions against four different biogeographical classification schemes. The classification schemes produced mostly concordant patterns with three major faunal distribution barriers: the North Pacific Current isolates the subarctic units by creating a steep temperature gradient; the Subantarctic Front separates the Subantarctic from the rest of the Pacific; and the East Pacific Barrier separates the East Pacific from the Central and West Pacific. Two other smaller but distinct provinces are the Indo-Pacific where Lower Bathyal genera are found in the Upper Bathyal, and Torres Strait/Coral Sea characterised by mesophotic genera. We propose 12 biogeographic provinces across the Pacific Ocean Upper Bathyal region from 200 to 1000 m depth based on octocoral distributions. The main driver for these units seems to be temperature, a defining feature of water masses. These units could potentially be subdivided into smaller regions based on habitat. Additionally, the clustering of Ecological Marine Units (EMUs) provides evidence that the Upper Bathyal should in certain regions be divided vertically into two depth zones based on water masses.

Analytical Modeling of Residual Stress in Laser Powder Bed Fusion Considering Volume Conservation in Plastic Deformation

Residual stress (RS) is the most challenging problem in metal additive manufacturing (AM) since the build-up of high tensile RS may influence the fatigue life, corrosion resistance, crack initiation, and failure of the additively manufactured components. While tensile RS is inherent in all the AM processes, fast and accurate prediction of the stress state within the part is extremely valuable and results in optimization of the process parameters to achieve a desired RS and control of the build process. This paper proposes a physics-based analytical model to rapidly and accurately predict the RS within the additively manufactured part. In this model, a transient moving point heat source (HS) is utilized to determine the temperature field. Due to the high temperature gradient within the proximity of the melt pool area, the material experiences high thermal stress. Thermal stress is calculated by combining three sources of stresses known as stresses due to the body forces, normal tension, and hydrostatic stress in a homogeneous semi-infinite medium. The thermal stress determines the RS state within the part. Consequently, by taking the thermal stress history as an input, both the in-plane and out of plane RS distributions are found from the incremental plasticity and kinematic hardening behavior of the metal by considering volume conservation in plastic deformation in coupling with the equilibrium and compatibility conditions. In this modeling, material properties are temperature-sensitive since the steep temperature gradient varies the properties significantly. Moreover, the energy needed for the solid-state phase transition is reflected by modifying the specific heat employing the latent heat of fusion. Furthermore, the multi-layer and multi-scan aspects of metal AM are considered by including the temperature history from previous layers and scans. Results from the analytical RS model presented excellent agreement with XRD measurements employed to determine the RS in the Ti-6Al-4V specimens.

Resolidification of a mushy-zone and directional solidification: a method for efficient alloy development demonstrated using the example of Cu\u2013Ga\u2013Sn

An experimental method for alloy development that allows to systematically scan multicomponent alloy systems is presented using the Cu–Ga–Sn system as an example. Rods with homogeneous concentration distribution of different initial compositions are annealed in a steep temperature gradient with temperatures in the range from above liquidus to below solidus temperature. During resolidification of the initially formed mushy-zone, a continuously varying composition over the length of the rods develops. Further concentration gradients of the alloying elements are generated during subsequent directional solidification. The graded samples are evaluated for different properties. Vickers hardness as a function of composition was measured along the length of the samples to get first information on the mechanical behavior of bulk samples. The melting range of selected compositions (cylindrical disks of 1 mm thickness cut out of the rods) was determined by differential scanning calorimetry and compared to liquidus temperatures extrapolated from the binary systems with a fitting method and the Calphad method. With the procedure introduced here, it is possible to determine several alloy properties over an extended composition range of a multicomponent system with significantly reduced experimental effort.