AbstractNonchemical high-pressure steam treatments have been intensively researched and commercialized to produce chemical-free wood products with enhanced properties. However, the utilization of high-pressure steam involves vapor-phase reactions using high-temperature steam generated at the expense of high energy input. In this research, influences of reaction media (steam and hot-compressed water) and temperature (100°C and 140°C) during thermal treatment on physical properties and drying behavior of yellow-poplar (Liriodendron tulipifera) heartwood were compared. The length, width, and thickness of the samples were 22.53 mm, 17.18 mm, and 16.72 mm, respectively. After the treatment, the samples were dried under an isothermal temperature condition of 105°C. Data on moisture content and time of drying from drying experiments were fitted with unsteady-state molecular transport equations to calculate overall liquid diffusion coefficients. Dimensions, weight, and true volume of samples were measured for green, thermally treated, and dried samples and the values were used to calculate selected physical characteristics. Additionally, selected mechanical properties were evaluated for samples conditioned to 13 percent moisture content. Results showed that intensified hot-compressed water-treated and control samples had the highest and lowest saturated moisture contents (101% and 44%), respectively, immediately after treatments. Intensified steam-treated and control samples had the highest and lowest total porosity (95% and 82%), respectively. Furthermore, mild hot-compressed water-treated samples showed the greatest compression strength (47.8 MPa) at 13 percent moisture content. Except for steam treatment at 140°C, other treatments significantly decreased the diffusion coefficient. Collectively, samples treated with hot-compressed water at 100°C showed the most improved mechanical properties.