Steady-state Rate Research Articles

Особенности системы гемостаза при истинной полицитемии у детей

Patients with polycythemia vera (PV) are at an increased risk for thrombosis. Abnormalities in coagulation parameters and global hemostasis tests can help with hypercoagulation recognition in PV. The purpose of this research was to analyze the features of changes in laboratory parameters of the hemostasis system in pediatric patients with PV. Materials and methods used: a single-center retrospective cohort study of clinical records of 32 (11 (35%) girls/21 (65%) boys aged 11.5 [0.8; 17.5] y/o) pediatric (all under the age of 18 y/o) PV patients who were admitted at the National Scientific and Practical Center for Pediatric Hematology, Oncology and Immunology named after Dmitry Rogachev (Moscow, Russia) in Jan. 2012-June 2024 was conducted. Laboratory parameters were determined prior to the beginning of the antiplatelet and cytoreductive therapy. Results: in 20 (62.5%) and 4 (12.5%) patients, mutations in the JAK2V617F and JAK2 ex 12 genes were detected, respectively, the remaining 8 (25%) children were JAK2-negative. In total, there were 8 (72%) JAK2-positive girls and 15 (71%) boys; gender did not statistically significantly affect the presence of a driver mutation (p=0.939). Both the median and the mean values of the main parameters of the blood coagulation system were within the reference values. The thromboelastography parameters did not deviate from the reference values for the parameters. According to the results of the thrombodynamics study, the average value of the initial clot growth rate among all patients was increased and amounted to 58.3±5.07 μm/min, the steady-state velocity also increased among all patients to 29.5±4.3 μm/min, the median and the mean values of the remaining parameters were within the reference intervals. Conclusion: the parameters of standard coagulogram and thromboelastography tests in pediatric PV patients had no deviations. The average values of thrombodynamics (initial and steady-state clot growth rate) were increased, which potentially indicates the hypercoagulation.

Sustainable Synthesis of Diamond-like Carbon and Giant Carbon Allotropes from Hyperbaric Methanol–Water Mixtures Through the Critical Point

Freeform carbon fibres were 3D-printed from CH3OH:H2O mixtures using hyperbaric-pressure laser chemical vapour deposition (HP-LCVD). The experiment overlapped a region of known diamond growth, with the objective of depositing diamond-like carbon without the use of plasmas or hot filaments. A high-pressure regime was investigated for the first time through the precursor’s critical point. Seventy-two C-fibres were grown from 13 different CH3OH:H2O mixtures at total pressures between 7.8 and 180 bar. Maximum steady-state axial growth rates of 14 µm/s were observed. Growth near the critical point was suppressed, ostensibly due to thermal diffusion and selective etching. In addition to nanostructured graphite, various carbon allotropes were synthesised at/within the outer surface of the fibres, including diamond-like carbon, graphite polyhedral crystal, and tubular graphite cones. Several allotropes were oversized compared to structures previously reported. Raman spectral pressure–temperature (P-T) maps and a pictorial P-T phase diagram were compiled over a broad range of process conditions. Trends in the Raman ID/IG and I2D/IG intensity ratios were observed and regions of optimal growth for specific allotropes were identified. It is intended that this work provide a basis for others in optimising the growth of specific carbon allotropes from methanol using HP-LCVD and similar CVD processes.

Fluorotelomer Alcohol (FTOH) Emission Rates from New and Old Rain Jackets to Air Determined by Iodide High-Resolution Chemical Ionization Mass Spectrometry

Per- and polyfluoroalkyl substances (PFAS), which include fluorotelomer alcohols (FTOHs), are synthetic chemicals used in consumer products because of their water-, stain-, and grease-repellent properties; thus, PFAS are commonly found in functional clothing such as rain jackets. To date, emissions of PFAS from products to indoor air have not been well characterized, although many PFAS-containing products are used and stored indoors. We used a test chamber connected to a high-resolution time-of-flight chemical ionization mass spectrometer equipped with iodide as a reagent ion (I-HR-ToF-CIMS) to measure emission rates for four FTOHs from 10 rain jackets and one backpack cover. The materials were categorized as old/used, new, or “PFAS-free”, and they were tested under two different scenarios, i.e., immediately out of package and after airing out. We observed real-time FTOH emissions from all materials. Under the out-of-package scenario, emissions of 6:2, 8:2 and 10:2 FTOH showed characteristics that indicate mass transfer is limited by internal diffusion, with a high initial peak followed by a lower steady-state emission rate. Peak emission rates correlated well with material-phase concentrations determined by an offline extractive gas chromatography-mass spectrometry (GC-MS) method. Our results further suggest that the old, used jackets had, on average, higher peak emission rates and higher material-phase concentrations than the new jackets, largely driven by 8:2 FTOH. “PFAS-free” materials had the overall lowest emission rates and material-phase concentrations. After airing out, emission rates were on average an order of magnitude lower than peak emission rates. Our findings emphasize the importance of considering consumer products like rain jackets as sources of indoor exposure to PFAS.

Relaxation-exchange magnetic resonance imaging (REXI): a non-invasive imaging method for evaluating trans-barrier water exchange in the choroid plexus.

The choroid plexus (CP) plays a crucial role in cerebrospinal fluid (CSF) production and brain homeostasis. However, non-invasive imaging techniques to assess its function remain limited. This study was conducted to develop a novel, contrast-agent-free MRI technique, termed relaxation-exchange magnetic resonance imaging (REXI), for evaluating CP-CSF water transport, a potential biomarker of CP function. REXI utilizes the inherent and large difference in magnetic resonance transverse relaxation times (T2s) between CP tissue (e.g., blood vessels and epithelial cells) and CSF. It uses a filter block to remove most CP tissue magnetization (shorter T2), a mixing block for CP-CSF water exchange with mixing time tm, and a detection block with multi-echo acquisition to determine the CP/CSF component fraction after exchange. The REXI pulse sequence was implemented on a 9.4 T preclinical MRI scanner. For validation of REXI's ability to measure exchange, we conducted preliminary tests on urea-water proton-exchange phantoms with various pH levels. We measured the steady-state water efflux rate from CP to CSF in rats and tested the sensitivity of REXI in detecting CP dysfunction induced by the carbonic anhydrase inhibitor acetazolamide. REXI pulse sequence successfully captured changes in the proton exchange rate (from short-T2 component to long-T2 component [i.e., ksl]) of urea-water phantoms at varying pH, demonstrating its sensitivity to exchange processes. In rat CP, REXI significantly suppressed the CP tissue signal, reducing the short-T2 fraction (fshort) from 0.44 to 0.23 (p < 0.0001), with significant recovery to 0.28 after a mixing time of 400 ms (p = 0.014). The changes in fshort at various mixing times can be accurately described by a two-site exchange model, yielding a steady-state water efflux rate from CP to CSF (i.e., kbc) of 0.49 s-1. A scan-rescan experiment demonstrated that REXI had excellent reproducibility in measuring kbc (intraclass correlation coefficient = 0.90). Notably, acetazolamide-induced CSF reduction resulted in a 66% decrease in kbc within rat CP. This proof-of-concept study demonstrates the feasibility of REXI for measuring trans-barrier water exchange in the CP, offering a promising biomarker for future assessments of CP function.

Effect of Time and Stress on Creep Damage Characteristics of Cement-Based Materials

In the realm of daily life, ensuring the safety of building structures and civil engineering projects remains a paramount research focus. The creep properties of materials significantly influence their long-term loading process. Specifically, creep load and creep time are pivotal factors that impact material creep damage, thereby playing a crucial role in assessing the safety of engineering endeavors and estimating aspects such as housing construction. This study undertakes creep damage tests on cement-based materials, subjecting them to varying creep loads and creep times, and subsequently conducts uniaxial compression tests on the specimens post-creep damage. The refined Nishihara model is employed for data fitting, facilitating the construction of a creep damage time-stress model. Concurrently, a Neural Network model is utilized to validate the experimental data. The findings indicate that both steady-state creep strain and steady-state creep rate exhibit discernible trends relative to creep load and creep time, effectively mirroring the alterations in creep damage experienced by the specimens. The refined Nishihara model proves adept at predicting and equating creep damage under diverse creep loads and creep times. Similarly, the trained Neural Network model demonstrates capability in measuring and estimating various creep damages. The study successfully explored the correlation between creep time and creep load, enabling the simulation of long-term creep damage within a shorter creep time and facilitating an analysis of its physical and mechanical properties, which is pivotal in predicting the safety of large-scale engineering projects. Concurrently, it advances research on material damage equivalence, offering insights and theoretical groundwork for developing a system to assess material damage equivalence under various damage conditions.

Experimental study on creep characteristics of cemented coal gangue backfill under uniaxial compression

ABSTRACT The uniaxial compression creep test is used to study the cemented coal gangue backfill body specimens with different cement-sand ratios (1:4,1:6,1:8, respectively). Through the processing and analysis of the creep curve, we discussed the influence of different cement-sand ratios, stress load and loading time on the strain, creep rate and long-term strength of the backfill body. These studies have revealed the creep law of the backfill body and obtained accurate conclusions. The results show that: (1) Different proportions of cemented coal gangue backfill body under the action of the set step by step axial loading stress, the strain is positively correlated with the change of loading stress. (2) With the increase of axial stress, the instantaneous deformation of cemented coal gangue backfill with three kinds of cement–sand ratio increases with the decrease of cement–sand ratio under the same axial stress. (3) With the increase of the axial stress of the three kinds of cement–sand ratio cemented coal gangue backfill body, the strain rate of the deceleration creep speed and the constant creep stage increases, and the duration of the deceleration creep stage increases. The average creep strain rate of the three kinds of cement–sand ratio cemented coal gangue backfill materials before entering the accelerated creep stage is determined. (4) Using an improved steady-state creep rate inflection point method, the long-term strength of three kinds of cement–sand ratio of cemented coal gangue backfill is determined, and it is concluded that the long-term strength decreases with the decrease of cement–sand ratio, which is positively correlated.

Mechanistic Study and Active Sites Investigation of Hydrogen Production from Methane and H2O Steady-State and Transient Reactivity with Ir/GDC Catalyst

Catalytic activity, mechanisms, and active sites were determined for methane steam reforming (MSR) over gadolinium-doped ceria (GDC) supported iridium (0.1 wt%) prepared by impregnation of GDC with iridium acetylacetonate. Isothermal steady-state rate measurements followed by micro-gas chromatography analysis were performed at 660 and 760 °C over Ir/GDC samples pretreated in N2 or H2 at 900 °C. Transient responses to CH4 or H2O step changes in isothermal conditions were carried out at 750 °C over Ir/GDC pretreated in He or H2 using online quadrupole mass spectrometry. In the proposed mechanism, Ir/GDC proceeds through a dual-type active site associating, as follows: (i) Ir metallic particles surface as active sites for the cracking of CH4 into reactive C species, and (ii) reducible (Ce4+) sites at GDC surface responsible for a redox mechanism involving Ce4+/Ce3+ sites, being reduced by reaction with reactive C into CO (or CO2) depending on the oxidation state of GDC and re-oxidized by H2O. Full reduction of reducible oxygen species is possible with CH4 after He treatment, whereas only 80% is reached in CH4 after H2 treatment.

Nondispersive ultraviolet monitoring of pulsed H2S gas delivery

This article describes time-resolved optical measurements of H2S partial pressure and mass flow in a pulsed gas delivery system approximating injection conditions encountered during atomic layer deposition. A high-speed nondispersive ultraviolet (NDUV) gas analyzer design is employed for in-line H2S detection in a gas delivery line with flowing carrier gas. An in-place analyzer calibration performed in a reference cell yields an H2S detection limit of ≈1.4 Pa (at 22 °C) at a sampling rate of 1 kHz. Flow measurements performed on the delivery line are used to evaluate the effects of adjustable delivery parameters on the time-dependent injection system output. Short pulse widths exhibit partial pressure transients attributed to flow development within the different volumes of the delivery system. After ≈1.0 s of injection, steady-state flow is established across flow elements. A partial pressure of H2S in the delivery line is found to vary linearly with upstream H2S pressure, consistent with choked flow. A stronger scaling of partial pressure is evident when the flow coefficient of the downstream metering valve is adjusted. Estimated steady-state H2S flow rates in the range of 0.05–0.21 mg/s are observed within a limited range of valve flow coefficients. However, further increases in the flow coefficient do not result in increased flow, likely due to conductance limitations in downstream flow system components. The utility of NDUV absorption measurements for high-pressure pulsed gas delivery systems is discussed.

Eco-friendly synthesis and surface modification of ZnO nanoparticles using Pueraria montana root extract: enhanced photocatalytic performance with trisodium pyrophosphate

ABSTRACT The synthesis of zinc oxide (ZnO) nanoparticles using Pueraria montana (kudzu) plant extracts highlights advancements in green nanotechnology. This study explores the use of Pueraria montana roots, rich in phytochemicals such as phenols, terpenoids and flavonoids, which serve as natural reducing and stabilizing agents for nanoparticle synthesis. The eco-friendly production and surface modification of ZnO nanoparticles were achieved using these plant extracts, enhancing their photocatalytic performance with trisodium pyrophosphate (TSPP).Characterization techniques, including XRD, TEM, and FE-SEM, confirmed the nanoparticles’ crystalline structure, with a BET surface area of 14.01 m²/g and a type II adsorption isotherm. The synthesized nanoparticles exhibited exceptional dye degradation capabilities, achieving 99.9% removal of malachite green (MG) and 97.78% for aniline blue (AB). Kinetic analysis revealed a steady-state rate constant (k) of 2 × 10⁻⁴ min⁻¹ for MG where as the response rate constant(k) for the photocatalytic degradation of AB using modified ZnO nanostructures was 3.0 × 10−3 min−1 allowing near-total dye removal within 600 minutes for MG and 350 min for AB . Adsorption studies were well described by Langmuir and Freundlich isotherms, indicating maximum adsorption capacities of 59.7 mg/g for MG and 61.2 mg/g for AB. Surface modification with TSPP improved charge carrier separation and enhanced the generation of reactive oxygen species under UV exposure, further increasing dye degradation efficiency.Statistical analysis indicated high reproducibility, with close mean adsorption values of 99.125 for MG and 97.3125 for AB, supported by small standard deviations. The findings affirm the potential of using Pueraria montana in synthesizing efficient photocatalysts, providing a sustainable and cost-effective approach for water treatment applications. Overall, this research underscores the effectiveness of plant-based materials in advancing eco-friendly nanotechnology solutions.

Contribution of transient heat transfer to overpressure protection in a passive Boiling Water Reactor

The BWRX-300 reactor is a small modular reactor with 300 MW nominal electric power output. As the abbreviation indicates, the reactor is a boiling type reactor using water as the coolant. The main operating principle of the reactor model is the use of natural circulation of the coolant for both steady-state operation and emergency cooling of the reactor. Isolation Condenser Systems (ICS) have been used in early BWRs and were reintroduced in the 1990s to implement passive safety.Modern technologies enable effective simulation of objects of various complexity. In this study, the thermal-hydraulic system code TRACE v.5 is used to simulate BWRX-300 reactor plant operation. The software enables calculation of a system consisting of the reactor pressure vessel and ICS in both steady-state and transient operation.The ICS is an emergency cooling system borrowed from the previous generation of GE Hitachi BWRs, the ESBWRs, and it consists of a vertical tube bundle heat exchanger immersed in a water tank. Although this system design remains unchanged, its purpose is different. The BWRX-300 design completely eliminates safety and relief valves. This is why the ICS must perform both overpressure protection and long term heat dissipation functions.Three reactor plant operation states were simulated: normal operation with nominal parameters; reactor isolation; and the transient process into the cooling down mode by reactor shutdown and ICS activation. The results demonstrate that the ICS is capable to mitigate overpressure transients. Upon ICS startup, its metallic structures absorb heat well in excess of its nominal steady-state rating. Initial thermal inertia of the system is important for overpressure mitigation in transients.

Testing a biexponential kinetic model for the heterogeneous isotopic exchange of phosphate ions on several types of soil

In this study, a new kinetic equation was applied for the heterogeneous isotopic exchange of phosphate ions on soil. Phosphate sorption on chernozem, marshy meadow and meadow soil was studied by P-32 heterogeneous isotopic exchange in steady-state. The soil samples were incubated with 5 different amounts of KH2PO4 for 1, 3, 13, 10, 12 and 22 weeks. Then they were equilibrated with destilled water, and after the equilibrium was reached, H332PO4 radiotracer was added to the soil solution. At different times samples were taken from the soil solution, and radioactivities were determined by liquid scintillation (LSC) technique. The concentration of phosphate ions was determined by photometry. The relative radioactivity of soil vs time could be fitted well by the biexponential kinetic equation, which assumes two types of weakly bonded phosphate. From the fitting parameters of the biexponential equation and the phosphate concentration determined by photometry the amounts of the two types of weakly bonded phosphate and their steady-state rates were determined. The amounts of weakly bonded phosphate were plotted vs phosphate concentration – data points could be fitted by a Langmuir-like representation or the S-shape sorption isotherms. The rate orders of the desorption proved to be 1 or 2; rate constants were determined. It can be concluded that in some cases cooperative sorption can occure, which can be due to hydrogen bonding between the hydrogenphosphate ions on the surface.

Effect of pulse current on the creep ageing behavior of pre-strained 2195 Al-Li alloy

Pre-strained aluminum lithium (Al-Li) alloy plates have ultra-high strength and comprehensive performance after aging treatments, and are widely used in the aerospace industry. The initial increase in dislocation density caused by these pre-strains will significantly affect the evolution of deformation, microstructure, and mechanical properties during the pulse current assisted creep ageing forming process. Therefore, the effect of pulse current on the creep ageing behavior of 2195 Al-Li alloy with different pre-strains (0 %, 4 %, and 8 %) was investigated. As the pulse current increases within the first 1h creep aging process of the various pre-strain samples, the 1h creep strain significantly increases and the subsequent steady-state creep rate slightly reduce. Moreover, the larger the pre-strain, the higher the total creep strain. Pulse current promotes the movement and recovery of initial dislocations, and promotes the fine formation of T1 phase and suppresses the nucleation of θ′ and δ′ phase, thereby improving mechanical properties. Compared with the conventional creep ageing process, the pulse current acting on pre-strained 2195 Al-Li alloy significantly increased the peak aged strengthen and shorten the peak aging time. Meanwhile, the peak time platform period has also been significantly extended. It is evident that the application of pulse current assisted creep ageing forming process to pre-strained 2195 Al-Li alloy plates can significantly improve formability and mechanical properties, enlarges the forming process window and realize collaborative manufacturing of Al-Li alloy component shape and performance.

Random fractional kinematic wave equations of overland flow: The HPM solutions and applications

This paper presents new findings from analyses of a random fractional kinematic wave equation (rfKWE) for overland flow. The rfKWE is featured with orders of temporal and spatial fractional derivatives and with the roughness parameter, the effective rainfall intensity and infiltration rate as random variables. The new solutions are derived with the aid of a numerical method named the homotopy perturbation method (HPM) and approximate solutions are presented for different situations. The solutions are evaluated with data from overland flow flumes with simulated rainfall in the laboratory. The results suggest that on an infiltrating surface the temporal nonlocality of overland flow represented by the temporal order of fractional derivatives diminishes over time while the spatial nonlocality manifested by the spatial order of fractional derivatives continue if there is overland flow. It shows that the widely used unit discharge-height relationship is a special case of the solution of the rfKWE. Procedures are demonstrated for determining the fractional roughness coefficient, nf, the order of spatial fractional derivatives, ρ, and the steady-state infiltration rate during the overland flow, As. The analyses of the data show that the mean spatial order of fractional derivatives is ρ=1.25, the mean flow pattern parameter m=1.50, and the mean fractional roughness coefficient is nf=0.002 which is smaller than the conventional roughness coefficient, n=0.108. With these average values of the parameters and their standard deviations, simulations were performed to demonstrate the use of the methods, which is also a comparison of the classic KWE and rfKWE models.

Response of growth and chlorophyll fluorescence parameters of mulberry seedlings to waterlogging stress

This study aimed to investigate the adaptive mechanisms of mulberry (Morus alba) to waterlogged conditions, with a specific focus on the development of adventitious roots (ARs), alteration of growth strategies, and adjustment of chlorophyll fluorescence parameters. To achieve this goal, 4-year-old potted mulberry plants were selected for research, and a waterlogging simulation method was implemented. Four treatments were established to investigate the effects of varying water conditions on leaf waterlogging damage, the number of ARs, plant height, chlorophyll fluorescence parameters, and proton motive force (pmf) parameters in mulberry plants. These treatments included the control group (CK), shallow submerged group (SS), half-submerged group (HS) and deep submerged group (DS). Our results showed that (1) The number of ARs in each group increased with increasing waterlogging time. (2) Waterlogging stress inhibited the height growth of mulberry, and the changes in plant height in the HS and DS groups were significantly lower than those in the CK and SS groups. (3) The maximum photochemical quantum yield (Fv/Fm) in the HS and DS groups decreased significantly under waterlogging stress. The nonphotochemical quenching (NPQt) of mulberry leaves in the submergence group increased significantly in the early stage of waterlogging stress, and the NPQt in the submergence group increased continuously with increasing waterlogging time. (4) Thylakoid conductivity to protons (gH+) in the leaves of mulberry decreased significantly under waterlogging stress, whereas the steady-state rate of proton flux (vH+) and total electrochromic shift (ECSt) increased significantly. The morphological, physiological, and ecological responses of mulberry plants to waterlogging stress include the timely generation of ARs at the stem base, the adjustment of plant growth strategies, and the repair of photosynthetic response centers in leaves through heat dissipation and thylakoid acidification mechanisms.

Characterize the high-temperature steady-state rheological behavior and Arrhenius activation of PEEK via strain rate jump tensile tests

Polyetheretherketone (PEEK) is a high-performance thermoplastic polymer with diverse industrial applications, such as aerospace, automotive, electronics, and medical devices. However, systematic research on its high-temperature rheological characteristics is inadequate. In this study, strain rate jump tensile tests were introduced to examine the steady-state rheology phenomena and strain rate sensitivity of PEEK at four different temperatures and nine different strain rates. Theoretical analysis based on the free volume theory and the Arrhenius law was also carried out to further analyze the transition of PEEK from Newtonian flow to non-Newtonian flow. Results indicate that PEEK materials exhibit a transition from Newtonian flow to non-Newtonian flow similar to metal materials at high temperatures. The transition point from Newtonian flow to non-Newtonian flow is marked by the emergence of steady-state rheology and its characteristic stress. Theoretical analysis demonstrates that the transition of PEEK is in accordance with the Arrhenius low. Moreover, its apparent activation energy (1.42 eV) is significantly lower than that of metal materials (5.28 eV), indicating a lower energy barrier and an easier transition. The strain rate sensitivity index correlates negatively with rising temperatures, especially at lower rates. This study enhances understanding of PEEK's rheological characteristics at high temperatures, aiding the development and application of high-performance thermoplastic materials.

Phosphate-Driven Interfacial Self-Assembly of Silk Fibroin for Continuous Noncovalent Growth of Nanothin Defect-Free Coatings.

Silk fibroin is a fiber-forming protein derived from the thread of Bombyx mori silkworm cocoons. This biocompatible protein, under the kosmotropic influence of potassium phosphate, can undergo supramolecular self-assembly driven by a random coil to β-sheet secondary structure transition. By leveraging concurrent nonspecific adsorption and self-assembly of silk fibroin, we demonstrate an interfacial phenomenon that yields adherent, defect-free nanothin protein coatings that grow continuously in time, without observable saturation in mass deposition. This noncovalent growth of silk fibroin coatings is a departure from traditionally studied protein adsorption phenomena, which generally yield adsorbed layers that saturate in mass with time and often do not completely cover the surface. Here, we explore the fundamental mechanisms of coating growth by examining the effects of coating solution parameters that promote or inhibit silk fibroin self-assembly. Results show a strong dependence of coating kinetics and structure on solution pH, salt species, and salt concentration. Moreover, coating growth was observed to occur in two stages: an early stage driven by protein-surface interactions and a late stage driven by protein-protein interactions. To describe this phenomenon, we developed a kinetic adsorption model with Langmuir-like behavior at early times and a constant steady-state growth rate at later times. Structural analysis by FTIR and photoinduced force microscopy show that small β-sheet-rich structures serve as anchoring sites for absorbing protein nanoaggregates, which is critical for coating formation. Additionally, β-sheets are preferentially located at the interface between protein nanoaggregates in the coating, suggesting their role in forming stable, robust coatings.

Power dissipation and entropy production rate of high-dimensional optical matter systems.

Entropy production is an essential aspect of creating and maintaining nonequilibrium systems. Despite their ubiquity, calculation of entropy production rates is challenging for high-dimensional systems, so it has only been reported for simple (i.e., l-particle) systems. Moreover, there is a dearth of nontrivial experimental systems where precise measurements of entropy production rate and characterization of the nonequilibrium steady state (NESS) are simultaneously possible. We report an approach to calculate the entropy production rate of overdamped, nonconservative, N-body systems and demonstrate this on a six-particle triangle optical matter (OM) system as a nontrivial example. OM systems consist of (nano-)particles organized into ordered arrays that are bound by electrodynamic interactions associated with the scattering and interference of light, and the associated induced-polarizations in and among the particles in coherent optical beams. The flux of laser light in OM systems in a solution environment necessitates that they dissipate energy, produce entropy, and relax to a NESS. The NESS may have several ordered particle configurations (i.e., isomers) that can interchange by barrier crossing processes. Understanding the power dissipation and entropy production rate of a NESS in an OM system along different (collective) modes of motion can advance understanding of the relative stability of the NESSs as well as inform design and control of OM structures. Therefore, we compute the components of the entropy production rate and power dissipation along the collective coordinates of the 6 Ag nanoparticle triangle OM system from OM NESS trajectory data and verify the Seifert relation [U. Seifert, Rep. Prog. Phys. 75, 126001 (2012)10.1088/0034-4885/75/12/126001] for these complex systems with a nuanced interpretation.

Initial stomatal conductance increases photosynthetic induction of trees leaves more from sunlit than from shaded environments: a meta-analysis.

It has long been held that tree species/leaves from shaded environments show faster rate of photosynthetic induction than species/leaves from sunlit environments, but the evidence so far is conflicting and the underlying mechanisms are still under debate. To address the debate, we compiled a dataset for 87 tree species and compared the initial increasing slope during the first 2-min induction (SA) and stomatal and biochemical characteristics between sun and shade species from the same study, and those between sun and shade leaves within the same species. In 77% of between-species comparisons, the species with high steady-state photosynthetic rate in the high light (Af) exhibited a larger SA than the species with low Af. In 67% within-species comparisons, the sun leaves exhibited a larger SA than the shade leaves. However, in only a few instances did the sun species/leaves more rapidly achieve 50% of full induction, with an even smaller SA, than the shade species/leaves. At both the species and leaf level, SA increased with increasing initial stomatal conductance before induction (gsi). Despite exhibiting reduced intrinsic water-use efficiency in low light, a large SA proportionally enhances photosynthetic carbon gain during the first 2-min induction in the sun species and leaves. Thus, in terms of the increase in absolute rate of photosynthesis, tree species/leaves from sunlit environments display faster photosynthetic induction responses than those from shaded environments. Our results call for re-consideration of contrasting photosynthetic strategies in photosynthetic adaption/acclimation to dynamic light environments across species.

SN 2021adxl: A luminous nearby interacting supernova in an extremely low-metallicity environment

SN 2021adxl is a slowly evolving, luminous, Type IIn supernova with asymmetric emission line profiles, similar to the well-studied SN 2010jl. We present extensive optical, near-ultraviolet, and near-infrared photometry and spectroscopy covering ∼1.5 years post discovery. SN 2021adxl occurred in an unusual environment, atop a vigorously star-forming region that is offset from its host galaxy core. The appearance of Lyα and O II, as well as the compact core, would classify the host of SN 2021adxl as a “Blueberry” galaxy, analogous to higher redshift, low-metallicity, star-forming dwarf “Green Pea” galaxies. Using several abundance indicators, we find a metallicity of the explosion environment of only ∼0.1 Z⊙, the lowest reported metallicity for a Type IIn SN environment. SN 2021adxl reaches a peak magnitude of Mr ≈ −20.2 mag and since discovery, SN 2021adxl has faded by only ∼4 magnitudes in the r band with a cumulative radiated energy of ∼1.5 × 1050 erg over 18 months. SN 2021adxl shows strong signs of interaction with a complex circumstellar medium, seen by the detection of X-rays, revealed by the detection of coronal emission lines, and through multi-component hydrogen and helium profiles. In order to further understand this interaction, we model the Hα profile using a Monte Carlo electron scattering code. The blueshifted high-velocity component is consistent with emission from a radially thin spherical shell resulting in the broad emission components due to electron scattering. Using the velocity evolution of this emitting shell, we find that the SN ejecta collide with circumstellar material of at least ∼5 M⊙ assuming a steady-state mass-loss rate of ∼4 − 6 × 10−3 M⊙ yr−1 for the first ∼200 days of evolution. SN 2021adxl was last observed to be slowly declining at ∼0.01 mag d−1, and if this trend continues, SN 2021adxl will remain observable after its current solar conjunction. Continuing the observations of SN 2021adxl may reveal signatures of dust formation or an infrared excess, similar to that seen for SN 2010jl.

Radiation Hydrodynamic Simulations of Massive Stars in Gas-rich Environments: Accretion of AGN Stars Suppressed by Thermal Feedback

Massive stars may form in or be captured into active galactic nuclei (AGN) disks. Recent 1D studies employing stellar-evolution codes have demonstrated the potential for rapid growth of such stars through accretion up to a few hundred solar masses. We perform 3D radiation hydrodynamic simulations of moderately massive stars’ envelopes in order to determine the rate and critical radius R crit of their accretion process in an isotropic gas-rich environment in the absence of luminosity-driven mass loss. We find that in the “fast-diffusion” regime where characteristic radiative diffusion speed c/τ is faster than the gas sound speed c s , the accretion rate is suppressed by feedback from gravitational and radiative advection energy flux, in addition to the stellar luminosity. Alternatively, in the “slow-diffusion” regime where c/τ < c s , due to adiabatic accretion, the stellar envelope expands quickly to become hydrostatic and further net accretion occurs on thermal timescales in the absence of self-gravity. When the radiation entropy of the medium is less than that of the star, however, this hydrostatic envelope can become more massive than the star itself. Within this subregime, the self-gravity of the envelope excites runaway growth. Applying our results to realistic environments, moderately massive stars (≲100M ⊙) embedded in AGN disks typically accrete in the fast-diffusion regime, leading to a reduction of steady-state accretion rate 1–2 orders of magnitudes lower than expected by previous 1D calculations and R crit smaller than the disk scale height, except in the opacity window at temperature T ∼ 2000 K. Accretion in slow diffusion regime occurs in regions with very high density ρ ≳ 10−9 g cm−3, and needs to be treated with caution in 1D long-term calculations.