Activated sludge models are increasingly being adopted to guide the operation of wastewater treatment plants. Chemical oxygen demand (COD) is an indispensable input for such models. To ensure that the activated sludge mathematical model can adapt to various water quality conditions and minimize prediction errors, it is essential to predict the parameters of the COD components in real-time based on the actual influent COD concentrations. However, conventional methods of determining the components' contributions are too intricate and time-consuming to be really useful. In this study, the chemical oxygen demand in the actual waste water treatment plant was disassembled and analyzed. The research involved determining the proportions of each COD component, assessing the reliability of the measurement parameters, and examining potential factors affecting measurement accuracy, including weather conditions, pipeline conditions, and residents' habits. Then, a backpropagation neural network was developed which can deliver real-time predictions for five important contributors to COD in real time. In addition, using the receiver operating characteristics curve and prediction accuracy to evaluate the performance of the prediction model. For all five components, which SS, XS, SI, XA, and XH, the prediction accuracy of model was more than 80 %. The maximum deviation values of these parameters fall within the range of the actual detected values, suggesting that the model's predictions align well with real-world observations, and demonstrated prediction performance adequate for practical application in wastewater treatment. This article can provide research basis for the engineering application of activated sludge model and help for the intelligent upgrading of waste water treatment plants.
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