Pollution Status Of Heavy Metals Research Articles

Assessment of Heavy Metal Pollution Status in Surface Soil of a Nigerian University

The problem of urban soil contamination with heavy metals due to rapid urbanization and industrialization has been a major concern in recent years. A university can be considered as a product of industrialization and urbanization which is associated with different activities that may induce heavy metals pollution into the environment. Therefore, this research work assessed the contamination level of chromium (Cr), copper (Cu), lead (Pb), zinc (Zn) and manganese (Mn) in surface soils of Afe-Babalola university (ABUAD) using various indices. Soil samples were taken from ten (10) different functional sites in the university. These samples were taken to the laboratory and analyzed for chromium (Cr), copper (Cu), lead (Pb), zinc (Zn) and manganese (Mn) using standard method. The mean concentrations of copper (Cu), chromium (Cr) and lead (Pb) were up to 0.75, 0.66 and 0.36 mg/g respectively, while manganese (Mn) and zinc (Zn) were 1.37 and 0.49 mg/g respectively. The average concentration of manganese (Mn) was comparable to its corresponding natural background value, but the average concentration of chromium (Cr), copper (Cu), zinc (Zn) and lead (Pb) were higher. They were approximately of the ratio 1:7, 1:2, 1:3 and 1:2 respectively compared to their corresponding natural background value. The multivariate statistical analyses indicated that vehicles, power generating sets, petrol station, machine workshops, production plants and emissions from outdoor roasted food spots were the major sources of heavy metals contamination on the universitys’ soil. The results from contamination indices and assessment showed that the contamination level of soils within the university can generally be classified as moderately contaminated. Therefore, periodic assessment of the sources and associated ecological risks of the heavy metals is highly recommended. This is to enable decision-makers to effectively manage the environment in the manner that will preserve public and ecosystem health.

Accumulation Characteristics and Pollution Evaluation of Soil Heavy Metals in Different Land Use Types: Study on the Whole Region of Tianjin.

Heavy metal pollution in soil has received much attention in recent decades. Many studies have analyzed the interaction between specific soil quality and soil heavy metal pollution. However, there is little information about the pollution status, spatial distribution and pollution sources of heavy metals in the province of Tianjin. In this paper, the distribution characteristics and pollution sources of heavy metals in soil were studied by means of the surface soil of Tianjin, as the study area and object, conducted in combination with land use types, using multiple data analysis and multivariate statistics, while the pollution levels were evaluated by various indices. The results showed the mean contents of the seven heavy metals of the studied elements followed an increasing order of Cd (0.15 mg/kg) < As (11.9 mg/kg) < Cu (24.3 mg/kg) = Pb (24.3 mg/kg) < Ni (27.9 mg/kg) < Cr (70.7 mg/kg) < Zn (79.1 mg/kg). The median values of Cr and Ni were lower than the background values and did not exceed the screening values at the points, and the median values of Cu, Zn and Pb were close to the background values, while the median contents of As and Cd were higher than the background values. The highest accumulation of heavy metals was found in grassland, and the coefficient of variation of heavy metal contents were higher in garden land, industrial and mining storage land, residential land and transportation land, indicating that the soil heavy metal contents under these land use types were more significantly disturbed by human factors. The evaluation results of the ground accumulation index method showed that the soil in Tianjin was free of pollution, except for Cd, which was at the non-polluted to moderately polluted level. The Nemero integrated pollution index evaluation method and the pollution load index evaluation method together showed that the integrated pollution levels of heavy metals in Tianjin soils were both at no pollution level/safety level. Apart from Cd and As, which were not correlated, the other heavy metals were correlated with each other two by two. Cd, Pb and Zn were the main pollution contributors from traffic, industry and other anthropogenic factors, while Cr and Ni were the main pollution contributors from soil parent material, and Cu was the main pollution contributor from mining and metal smelting. In addition, As was presumed to be the main source of pollution contribution from agriculture and surface runoff.

Heavy Metal Pollution and Health Risk Assessment of Vegetable-Soil Systems of Facilities Irrigated with Wastewater in Northern China.

Soil pollution by heavy metals is a major concern in China and has received much attention in recent years. Aiming to investigate the status of heavy metal pollution and the safety of vegetables in the soil of wastewater-irrigated facilities, this study investigated the distribution and migration characteristics of heavy metals in vegetable–soil systems of facilities in a typical sewage irrigation area of the Xi River, Shenyang City, northern China. Health risks due to the fact of exposure to heavy metals in the vegetable soil of facilities and ingrown vegetables through different exposure pathways were evaluated. Spatial interpolation and a potential ecological risk assessment were applied to evaluate the soil quality. Bioaccumulation factors (BCFs) were used to analyze the absorption and transportation capacity of Cd, Cu, Pb, and Zn by different parts of different vegetables. The results showed that the average concentration of Cd exceeded the standard values by 1.82 times and accumulated by 11 times, suggesting that Cd poses the most severe pollution among the four metals in the soil of facilities in the Xi River sewage irrigation area. In the city, a significant accumulation of Cd in the soil was identified with different spatial distributions. Cd also contributed the most in terms of the estimated potential ecological risk index, while the impacts of the other three metals were relatively small. The concentrations of heavy metals were mostly lower than the limit set by the corresponding Chinese standards. Various BCFs were observed for the four metals in the order Cd > Zn > Cu > Pb. Vegetables also demonstrated different BCFs in the order of leaf vegetables > Rhizome vegetable > Solanaceae vegetable. The magnitude of the noncarcinogenic risk for all four heavy metals was less than one for all three exposure routes and did not cause significant noncarcinogenic health effects in humans. However, the carcinogenic risk of Cd from some vegetables via dietary intake was considered higher. Protection measures should be taken to implement better pollution control and land use planning.

A comprehensive review of heavy metal pollution in the coastal areas of Bangladesh: abundance, bioaccumulation, health implications, and challenges.

The coastal zone of Bangladesh, with a population density of 1278 people per square kilometer, is under serious threat due to heavy metal pollution. To date, many studies have been conducted on the heavy metal contamination in soils, water, aquatic animals, and plants in the coastal zone of Bangladesh; however, the available information is dispersed. In this study, previous findings on the contamination levels, distributions, risks, and sources of heavy metals in sediments and organisms were summarized for the first time to present the overall status of heavy metal pollution along coastal regions. Earlier research found that the concentrations of various heavy metals(HMs), particularly Co, Cd, Pb, Cu, Cr, Mn, Fe, and Ni in water, sediment, and fish in most coastal locations, were above their permissible limits. High concentrations of HMs were observed in sediments and water, like Cr of 55mg/kg and 86.93mg/l in the ship-breaking areas and Karnaphuli River, respectively, in coastal regions of Bangladesh. Heavy metals severely contaminated the Karnaphuli River estuary and ship-breaking area on the Sitakundu coast, where sediments were the ultimate sink of high concentrations of metals. Sedentary or bottom-dwelling organisms like gastropods and shrimp had higher levels of heavy metals than other organisms. As a result, the modified PRISMA review method was used to look at the critical research gap about heavy metal pollution in Bangladesh's coastal areas by analyzing the current research trends and bottlenecks.

Distribution, Assessment, and Source of Heavy Metals in Sediments of the Qinjiang River, China.

Heavy metals are toxic, persistent, and non-degradable. After sedimentation and adsorption, they accumulate in water sediments. The aim of this study was to assess the extent of heavy metal pollution of Qinjiang River sediments and its effects on the ecological environment and apportioning sources. The mean total concentrations of Mn, Zn, Cr, Cu, and Pb are 3.14, 2.33, 1.39, 5.79, and 1.33 times higher than the background values, respectively. Co, Ni, and Cd concentrations are lower than the background values. Fe, Co, Ni, Cd, Cr, Cu, and Pb are all primarily in the residual state, while Mn and Zn are primarily in the acid-soluble and oxidizable states, respectively. Igeo, RI, SQGs, and RAC together indicate that the pollution status and ecological risk of heavy metals in Qinjiang River sediments are generally moderate; among them, Fe, Co, Ni, Cd, Cr, and Pb are not harmful to the ecological environment of the Qinjiang River. Cu is not readily released because of its higher residual composition, suggesting that Cu is less harmful to the ecological environment. Mn and Zn, as the primary pollution factors of the Qinjiang River, are harmful to the ecological environment. This heavy metal pollution in surface sediments of the Qinjiang River primarily comes from manganese and zinc ore mining. Manganese carbonate and its weathered secondary manganese oxide are frequently associated with a significant amount of residual copper and Cd, as a higher pH is suitable for the deposition and enrichment of these heavy metals. Lead–zinc ore and its weathering products form organic compounds with residual Fe, Co, Cr, and Ni, and their content is related to salinity. The risk assessment results of heavy metals in sediments provide an important theoretical basis for the prevention and control of heavy metal pollution in Qinjiang River.

Variation Feature, Pollution Risk Assessment, and Source Analysis of Heavy Metals in Lanzhou City, Northwestern China

Lanzhou is located in the northwest of China and is famous for its petrochemical and heavy industries of China. The city has suffered long-term pollution of heavy metals in recent years. Significant efforts, such as tax subsidies for new energy vehicles and treating solid waste, have been launched by the Lanzhou municipal government to address the pollution of heavy metals since 2010. What is the current status of heavy metal pollution in Lanzhou? In this study, the concentrations of 12 heavy metals (V, Cr, Mn, Co, Ni, Cu, Zn, As, Mo, Cd, Sb, and Pb) were tested from 20 sediment samples. Mn, Zn, V, and Cr are the predominant heavy metals, with mean concentrations of 534.65, 65.85, 56.29, and 36.05 mg/kg; Ni, Cu, Pb, Co, and As are in moderate amounts, with mean concentrations of 25.2, 21.5, 16.7, 9.87, and 4.86 mg/kg; Mo and Cd have the lowest mean concentrations of 0.54 and 0.15 mg/kg. A low ecological risk is confirmed by two indices, the Hakanson potential ecological risk index ( R I ) and the geoaccumulation index ( I geo ). The R I index has lower E i r values (&lt;40) and R I values (&lt;150), which range from 18.11 to 37.95, with an average value of 25.61. Co, V, Cd, Cu, Zn, As, Cr, Ni, Pb, and Mn metals are classified as an uncontaminated environment (level 0) and a moderately to heavily contaminated environment (level 2-level 3) by I geo values. Seven heavy metals (Pb, Cd, Cr, As, Cu, Zn, and Ni) in Lanzhou are the relatively lowest amount in the 5 cities in China. The changing trends of heavy metal concentrations firstly increase and then decrease gradually from 2005 to 2022. The time turning point of concentration shrinking occurred in approximately 2014, which is in response to the increased efforts of addressing the pollution launched by the Lanzhou municipal government since 2010. Source analysis by Pearson’s correlation and principal component analysis revealed that the accumulation of Mo metal was caused by the enrichment of MnO2 in the oxidic condition; the accumulations of Cu, Co, Ni, Mn, Cr, Zn, Cd, and Pb metals are influenced by natural sources and human activities (vehicle exhaust and industrial pollution), respectively.

Heavy Metal Pollution and Health Risk Assessment of Mine Soil in Yangtze River Economic Belt

The study of heavy metal pollution in mine soil of the Yangtze River Economic Belt is important for promoting the ecological restoration of mines and the construction of green mines in the Yangtze River Economic Belt. For this study, we collected the relevant research on the pollution of heavy metals in the mine soil of the Yangtze River Economic Belt from 2006 to 2020 and studied the pollution status, distribution law, and health risk of heavy metals by using the land accumulation index method, Kriging interpolation method, and health risk assessment method. The results showed that the average contents of Pb, Cd, Cr, Hg, As, Zn, Ni, and Cu in mine soil far exceeded the background value in China, and the accumulation degree of Cd and Hg was significant. The pollution evaluation results showed that the pollution degree of the eight heavy metals was Cd>Hg>Pb>Zn>Cu>As>Ni>Cr, the pollution degree of Cd and Hg was the highest, and more than 60% of the sample points were at medium pollution. The pollution evaluation showed that the soil pollution of tin and lead-zinc mines was more prominent than that of other minerals. The health risk assessment indicated that oral intake was the main intake route for non-carcinogenic and carcinogenic risks, the total non-carcinogenic and carcinogenic risk index was within the unacceptable range, and the non-carcinogenic and carcinogenic risk of mine soil in the middle and upper reaches of the Yangtze River Economic Belt was significantly higher than that in the lower reaches.

Quantitative Assessment of Pollution Status of Heavy Metals in the Water from Mairua Dam, Faskari LGA, Katsina State, Northwestern Nigeria

Pollution of surface water by toxic metals has received considerable attention due to its risk to human health and ecology. Consequently, the present study focused on the assessment of the heavy metal concentrations in the water from Mairua dam. This research reveals the concentrations of the selected toxic metals (Pb, Cd, Co, Cr and Ni) in water samples. The following trend was observed across the sampling points; Co&gt; Cr&gt; Cd&gt; Ni&gt; Pb. The concentrations of Pb across the sampling points were within the WHO (2011) permissible limits. However the Cd concentrations across the sampling points were within the WHO limits of 0.003 mg/kg with exemption of W1, W2, W3, W4, W5, W8 and W10 respectively. Similarly the concentrations of Co in the analyzed water samples were all above WHO (2011) tolerable limits of 0.01 mg/kg. The elevated level of cobalt in the water may be attributed to leachates from farmlands and domestic waste. The concentrations of Cr across the sampling points were within the WHO (2011) permissible limits of 0.005 mg/kg with exemption of samples W2, W3, W4, W7, W8, W10 and W11 respectively. However, the concentrations of Ni across the sampling points were higher than WHO (2011) permissible limits of 0.01 mg/kg. Nickel is introduced into the environment from both natural and man-made sources. The results obtained for Contamination Factors reveals low contamination (Cf&lt;1) with an exemption of Cd in points W1 and W2. PLI denotes no pollution and Hazard quotient values also showed that the analyzed water has no potential health effects with exemption to Cd. The results also shows that there was no significant difference in the analyzed samples at p&lt;0.005 across the sampling sites. Pollution of the water by Cd may be as a result of anthropogenic activities that are released into the dam. It is recommended to periodically monitor the water.

Spatial-Heterogeneity Analysis of the Heavy Metals Cd and Pb in Road Dust in the Main Urban Area of Harbin

To provide a scientific basis for pollution prevention and control of the urban environment, the current status of heavy-metal pollution in road dust in Harbin was studied. In total, 63 road dust samples in the main urban area of Harbin were collected, and the contents of Cd and Pb, two representative heavy metals, were detected. Using the Moran Index coupled with semi-variable function and geostatistical methods, the spatial correlation, variation structure, and distribution pattern were analyzed, and the estimated probability of the heavy metals exceeding the safety standard was determined. The study showed that: The mean concentrations of Cd and Pb were higher than the background values in Heilongjiang province, and both exhibited moderate variability, while the coefficient of variation of Cd was larger than that of Pb; Cd was weakly correlated in space and randomly distributed, Pb was moderately correlated in space and exhibited good spatial structure, and both were spatially aggregated. The optimal model for fitting the variance function showed that Cd was a spherical model, and Pb was an exponential model. The variation of Cd was mainly influenced by human factors, and the variation of Pb was influenced by both structural and random factors. The optimized interpolation results of the variance function had high accuracy, and the spatial distribution of Cd was elliptical, whereas the distribution of Pb was stripe-shaped, Cd was mainly influenced by traffic factors, such as industrial enterprise distribution and road painting, while Pb was influenced by natural factors such as river sediment or the study area belonging to a geologically high background area, in addition to the above factors. The estimated probabilities indicate a higher potential risk of Cd in the northeastern part of the study area.

Characteristics and Health Risk Assessment of Heavy Metal Pollution in Haikou Bay and Adjacent Seas.

Heavy metal contamination in coastal waters may pose a serious threat to aquatic products and human health. This study aimed to gain a better understanding of the pollution-induced by heavy metals in Haikou Bay and adjacent seas and assessed the potential ecological risk. The spatial distributions of heavy metals including Cu, Pb, Zn, Cd, Cr, Hg, and As were analyzed in the surface and bottom water, surface sediment, and five species of fish collected from Haikou Bay and adjacent seas. For seawater, the results showed that the horizontal distribution of the seven heavy metal elements in the study area had no uniform pattern due to the influence of complex factors, such as land-based runoff, port shipping, and ocean current movement. In contrast, the vertical distribution of these heavy metal elements, except for Zn and Cd, showed high concentrations in the surface water and low concentrations in the bottom water. Due to the symbiotic relationship between Zn and Cd, the distributions of these two elements were similar in the study areas. Different from the complex distribution of heavy metals in water, the highest concentrations of these elements in surface sediment all occurred at station 11 except for Pb. Our study revealed that organic carbon and sulfide are important factors affecting the heavy metal concentrations in the surface sediments. Heavy metals in waters and surface sediment were lower than the quality standard of class I according to the China National Standard for Seawater Quality and the sediment quality, except for Zn in water, suggesting that the seawater and surface sediment in Haikou Bay and adjacent seas has not been polluted by heavy metals. Additionally, the heavy metal As was the main element affecting the quality of fish in this study area, and attention should be paid in the future. The target hazard quotient (THQ) values of seven heavy metal elements in fish were all lower than 1.0, indicating that eating fish in this area will not pose a risk to human health. These results provide valuable information for further understanding the status of heavy metal pollution in Haikou Bay and adjacent seas and the development of targeted conversation measures for the environment and fish consumers.

Potential removal capacity and secondary pollution risk evaluation of heavy metals in Gracilaria lemaneiformis from a typical seaweed farming base

Seaweeds are significant primary producers in marine ecosystems and accumulate heavy metals from the environment during growth. However, seaweed litter is produced during the growth and harvest process and has become an important bottleneck that restricts the sustainable development of the seaweed cultivation industry. In this study, we investigated the risk assessment and potential removal of heavy metals in the Gracilaria lemaneiformis cultivation zone in a typical seaweed farming base and evaluated the secondary pollution risk of heavy metals in G. lemaneiformis litter. The results indicated that G. lemaneiformis was a good candidate for the removal and active absorption of heavy metals. A total of 60 thousand tons of harvestable G. lemaneiformis was estimated to remove 242.5 kg copper, 34.5 kg cadmium, 74 kg lead, and 2134.5 kg zinc from a typical seaweed farming base in 2018. Furthermore, the G. lemaneiformis did not pose a health risk to consumers. Variations in the heavy metal accumulation index between dead and fresh G. lemaneiformis litter differed significantly and provided evidence that metals could be either imported or exported from litter to the environment. It is suggested that G. lemaneiformis litter had a potential function in simultaneous heavy metal accumulation and release, and the function of metal accumulation was more effective during growth and decay. The results of this study contribute to the knowledge of heavy metal pollution status and risk assessment in the environment and in G. lemaneiformis, underscoring the strong capacity of heavy metal accumulation in G. lemaneiformis from the environment and the potential heavy metal removal by G. lemaneiformis cultivation and its utilization in a typical seaweed farming base.

Concentration Characteristics of Heavy Metals in Farmland-Sphagnum System and Ecological Risk Assessment

In order to study the current status of heavy metal pollution, the accumulation capacity of farmland Sphagnum for heavy metals and the source of heavy metal pollution in the soil near Gaozhai Reservoir in Maojian Tea Town, Duyun City, Guizhou Province were assessed. Sphagnum and topsoil near this area were selected as the research object to measure the content of heavy metals. Spatial analysis and multivariate statistical analysis methods were used to conduct pollution evaluation and source analysis of heavy metals. The results showed that the heavy metal content in topsoil and farmland Sphagnum were V>Zn>Cr>Pb>Cu>Ni>As>Cd>Hg and Zn>Cr>Ni>Cu>Pb>V>As>Cd>Hg, respectively. The dominant species of Sphagnum in the study area were Sphagnum palustre L. ssp. palustre and Sphagnum ovatum Hamp.C.Muell, both of which had a strong ability to accumulate soil Cd, Ni, Cu, and Zn; however, the S. ovatum enrichment capacity of soil heavy metals was generally higher than that of the latter. Both the single pollution index (Cf) and the geo-accumulation index (Igeo) indicated that the Cd and Hg content in soil were at the highest levels, and the average comprehensive pollution index RI was 87.75, which indicates a slight ecological risk. The sources of heavy metals in soil and Sphagnum included transportation, domestic sewage, agricultural activities, and natural soil-forming processes.

Human-induced sediment degradation of Burullus lagoon, Nile Delta, Egypt: Heavy metals pollution status and potential ecological risk

Heavy metals contamination level and their ecological risk of the Burullus lagoon were estimated using four cores and twelve surficial sediment samples. The distributions maps of Fe, Mn, Zn, Hg, Cu, and Pb indicate an increase toward drains areas, whereas Cd rises toward the Boughaz El-Burullus. The geoaccumulation index (Igeo) and contamination factor (CF) for heavy metal displayed the following order: Cd > Zn > Fe > Cu > Pb > Mn > Hg. The degree of contamination (Cd) indicates a considerable degree of contamination for 81.25% of the studied stations, and the pollution load index (PLI) suggested deterioration in 100% of sediments. Regarding the potential ecological risk (RI), the metals were arranged as: Cd > Hg > Cu > Pb > Zn, with considerable risk at the eastern part. According to sediment quality guidelines (SQGs), Zn concentrations suggest frequently adverse impacts on biota while Cu and Cd indicating an occasional adverse impact. Periodic monitoring of heavy metals in aquatic organisms is recommended to assess their toxic risk.

Preliminary Determination of Heavy Metals in Sediment, Water, and Some Macroinvertebrates in Tawi-Tawi Bay, Philippines

Determination of heavy metals is enormously important to determine the condition of the aquatic environment in terms of chemical pollution. In this study, a preliminary determination of heavy metal concentrations in sediment, water, and some macroinvertebrates in several sampling sites along Tawi-Tawi Bay, Philippines, was undertaken to have an initial status of heavy metal pollution in the area. Results revealed that the average concentration of heavy metals followed the order of Fe&amp;gt;Zn&amp;gt;Mn&amp;gt;Pb&amp;gt;Cu&amp;gt;Ni&amp;gt;Cd for sediment, Pb &amp;gt; Zn &amp;gt; Cu &amp;gt; Ni &amp;gt; Fe &amp;gt; Cd &amp;gt; Mn for seawater, Fe &amp;gt; Zn &amp;gt; Mn &amp;gt; Cu &amp;gt; Pb &amp;gt; Ni &amp;gt; Cd for spider conch (Lambis lambis Linnaeus, 1758), and Fe&amp;gt; Zn &amp;gt; Pb &amp;gt; Ni &amp;gt; Mn &amp;gt; Cu &amp;gt; Cd for sea cucumber (Holothuria scabra, Jaeger, 1833). However, all these determined heavy metals were within the safety limits set by WHO, US (EPA and FDA), and EMA. This study suggests that despite the anthropogenic activities in the coastal areas, heavy metal contamination in Tawi-Tawi Bay has not exceeded the safety limits.

Impact of acid mine drainage on groundwater hydrogeochemistry at a pyrite mine (South China): a study using stable isotopes and multivariate statistical analyses.

Combining environmental isotope analysis with principal component analysis can be an effective method to discriminate the inflows and sources of contamination in mining-affected watersheds. This paper presents a field-scale study conducted at an acid mine drainage (AMD)-contaminated site adjacent to a pyrite mine in South China. Samples of surface water and groundwater were collected to investigate transport in the vadose zone using stable isotopes of oxygen (δ18O) and hydrogen (δD) as environmental tracers. Principal component analysis of hydrogeochemical data was used to identify the probable sources of heavy metals in the AMD. The heavy metal pollution index (HPI) was applied to evaluate the pollution status of heavy metals in the groundwater. The groundwater associated with the Datai reservoir was recharged by atmospheric precipitation and surface water. On the side near the AMD pond, the groundwater was significantly affected by the soluble metals produced by pyrite oxidation. The concentrations of some metals (Al, Mn, and Pb) in all of the samples exceed the desirable limits prescribed by the World Health Organization (Guidelines for drinking-water quality, 4th edn. World Health Organization, Geneva, 2011). Among them, the concentration of Al is more than 30,000 times higher than the desirable limits prescribed by the World Health Organization (2011), and the concentration of Mn is more than 3000 times higher. The HPI values based on these heavy metal concentrations were found to be 10-1000 times higher than the critical pollution index value of 100. These findings provide a reference and guidance for research on the migration and evolution of heavy metals in vadose zone water in AMD-contaminated areas.

The Nutrient and Heavy Metal Contents in Water of Tidal Creek of the Yellow River Delta, China: Spatial Variations, Pollution Statuses, and Ecological Risks

In order to understand the spatial distribution, ecological risks, and pollution status of nutrients and heavy metals in the coastal tidal creek water of the Yellow River Delta (YRD), a total of 21 water samples were collected from 7 sample sites. The results indicated that along the coastline from northwest to southeast in the YRD, the concentrations of TN, TP, and NH4+-N in the water decreased and then increased; the Cu concentration increased, decreased, and then increased; and the Pb concentration decreased. The average TN/TP mass ratio indicated that the tidal creek water belonged to a potential phosphorus-restricted eutrophication state. The RI result indicated that Cu and Pb in the water were at low ecological risk, while the SSD and RQ results indicated that Cu in the water was at a high ecological risk level and had potential harm to aquatic organisms. Based on the single-factor method, the water quality of the tidal creek inside and outside the Yellow River Delta Nature Reserve belonged to Grade IV. Cu should be controlled to improve the water quality and reduce the ecological risk, especially in the Yellow River Delta Nature Reserve.

Heavy metal pollution status in soil for different land activities by contamination indices and ecological risk assessment

Heavy metal pollution status in soil for different land activities by contamination indices and ecological risk assessment

Pollution and Potential Ecological Risk Assessment of Heavy Metals in Surface Sediments of Tangxun Lake

In order to understand the pollution characteristics, spatial distribution, potential sources, and ecological risk of heavy metals in the sediments of Tangxun Lake, the contents of heavy metals (As, Hg, Cd, Cr, Cu, Pb, Zn, and Ni) in the surface sediments of Tangxun Lake were analyzed, and the pollution status and potential ecological risk degree of heavy metals in the sediments were evaluated using the geo-accumulation index and potential ecological risk index. The potential sources of heavy metal pollutants were analyzed by correlation and principal component analysis. The results showed that except for Cr, the contents of other heavy metals were higher than their background values. The contents of Hg, Cd, Zn, and Cu were higher in the southwest and northeast corners of the lake, which may come from the combined pollution of sewage discharge, fisheries, and surrounding industrial and agricultural activities. The geo-accumulation index and potential ecological risk showed that Hg and Cd were in moderate pollution; Cu, Pb, and Zn were in non-light pollution; and As, Cr, and Ni were in non-pollution. Except for Hg and Cd, there were serious and serious potential ecological risks, and the other elements were at a low risk level. The heavy metals in the surface sediments of Tangxun Lake showed a high ecological risk level.

Geo-accumulation Index Method to Optimize the Evaluation Method of Polymetallic Environment Quality: Taking Developed Agricultural Areas as an Example

An accurate and reasonable soil pollution assessment method is the premise of regional soil pollution assessment. Triangular fuzzy numbers were introduced into the geo-accumulation index method, combined with α-cut technology and the Latin hypercube sampling (LHS) stochastic simulation method, to evaluate the accumulation of heavy metals in five different soil types (moisture soil, aeolian sandy soil, cinnamon soil, loessal soil, and alluvial soil), with large differences in heavy metal (Cd, Hg, As, Pb, and Cr) content in the study area. This method can avoid the inaccuracy of the evaluation results caused by the traditional geological accumulation index method in the selection of background values and the great difference between local and whole heavy metal contents in the study area and can comprehensively and truly represent the regional soil heavy metal pollution status, thus providing a theoretical basis for scientific decision-making. The results showed that the improvement in the method will not affect the evaluation results when the heavy metal content difference is small, that is, when the evaluation results of the geological accumulation index at all points are within a certain interval level or when the evaluation results of the geological accumulation index at all points are less than 0. The traditional and geological cumulative index method based on the evaluation with triangular fuzzy numbers provides results for a certain level, which is determined by the heavy metal content in the study area average; conversely, differences in the heavy metal content of soil sampling points throughout the study area can result in a decrease or increase in the recorded heavy metal contents in larger areas, making the evaluation result inaccurate. Combined with the LHS sampling method, the possibility of changing the evaluation results into various pollution levels can greatly improve the limitations of traditional evaluation methods and make the evaluation results more reasonable and accurate. Combined with the geographic information system (GIS) method, the regional heavy metal pollution accumulation concentration can also be visualized.

Spatial Distribution and Source Analysis of Soil Heavy Metals in a Small Watershed in the Mountainous Area of Southern Ningxia Based on PMF Model

In order to ascertain the distribution characteristics of soil heavy metal pollution and main pollution sources in a small watershed in the southern mountainous area of Ningxia and to ensure the quality of the soil environment, the contents of heavy metals Pb, Ni, Zn, Mn, Cu, Cr, and Cd in 260 surface soil samples (0-20 cm) were collected and determined. Based on the soil background value in Ningxia, the soil heavy metal pollution status and potential ecological risk were evaluated through the single factor index, Nemera composite index, and potential ecological risk index, and the method of combining positive definite matrix factor analysis (PMF) and Kriging interpolation was used to analyze the soil heavy metal spatial distribution and source. The results showed that the average contents of ω(Pb), ω(Ni), ω(Zn), ω(Mn), ω(Cu), ω(Cr), and ω(Cd) were 31.42, 36.22, 62.89, 546.18, 22.26, 61.90, and 0.18 mg·kg-1, respectively. Except for Ni, the other elements were higher than the background value of Ningxia but lower than the background value of agricultural soil pollution risk selection criteria and green food environmental quality standards. The Nemera composite index showed that the proportions of mild, moderate, and severe heavy metal pollution were 71.92%, 19.23%, and 1.54%, respectively. The potential ecological risks were mainly minor risks, accounting for 98.85%. In addition, there were a very small number of samples with medium potential ecological risk levels, accounting for 1.15% of the total number of samples. Source analysis showed that the main sources of soil heavy metals in the small watershed in the mountainous area of southern Ningxia were mixed sources of fertilization and industrial emissions (12.6%), agricultural activity sources (23.5%), natural parent material sources (27.6%), mixed sources of pesticide use and mining development emissions (17.7%), and atmospheric deposition sources (18.6%).