Nuclear structure of 27Al nucleus has been investigated using shell model with self-consistent Hartree–Fock calculations. Shell model calculations are performed with full sd model space for positive parity states. For all selected excited states, Skyrme interactions are adopted to generate from them a one-body potential in Hartrre-Fock theory to calculate the single-particle matrix elements and compared with those of the harmonic oscillator. The deduced results are discussed for the longitudinal and transverse form factors and compared with the available experimental data. It has been found that the core-polarization effects are essential in obtaining a reasonable description of the data.