Various isotopes have different levels of significance or limiting parameters of health hazard. Methods of radioactivity measurement vary, frequently from one laboratory to another, even to the extent that the measurements are often only roughly comparable. All radioactivity measurements at the Illinois State Water Survey, Urbana, Illinois, made since May 1957 have been of samples of well waters, streams, and rivers. These measurements have been limited to gross alpha and beta activities by proportional counting of the nonvolatile residue remaining after evaporation of the water carrier. Such residues do not contain tritium, which will, therefore, not be discussed and which, furthermore, has a very low level of energy with a half‐life of 12 years. It is of interest, however, as shown by Libby, that the beta activity of tritium in the Mississippi River was 5‐20 μμc/l; in Lake Michigan, 5 μμc/l; and in rainfall in the Midwest, approximately 20 μμc/l. For low levels of activity, an error of approximately 50 per cent was estimated. Therefore, any appreciable confidence in results cannot be extended to activities of less than about 3 μμc/l (relative to 20‐min counting in duplicate for 250‐ml samples). For 5O per cent confidence at an acti‐ vity of 3 μμc/l, a 2‐hr counting period would be required. Favorable limitations of the counting procedures are further degraded by the absence of specific information on the self‐absorption that results from the deposition of neutral mineral salts from the samples containing nuclides responsible for radioactivity. The physiologic significance of gross activity and specific radioactive isotopes, and the optimum and standard procedures for the determination of gross and specific activities, are not discussed. Consideration is given to: the radioactivity of groundwaters, which have been used as public supplies for more than four generations and which, for all practical purposes, contain only those isotopes of long half‐lives; excerpts from, and interpretations of, data on Ra226 by Lucas and Ilcewicz of Argonne National Laboratories, Lemont, Illinois; and, data on gross activity of surface waters, with particular emphasis on measurements of gross dissolved beta radioactivity, with reference to the natural activity of Illinois water resources.
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