Different micelles orients in a way to increase their overall electrochemical and ionic stability. In this work, we report on a reverse micellization approach to prepare uncarbonized starch and poly (1,4-butylene succinate) hybrids with exceptional charge storage performance. Uncarbonized starch was activated through protonation, hybridized with poly (1,4-butylene succinate), configured into conductive reverse micelles, and incorporated with magnetite nanoparticles. The succesful design of the supercapacitive micelles was confirmed through diminished O-H and stronger C=O bands in FTIR, fine C-C resolutions in Raman, and d-spacing values in XRD. A conductivity value as high as 84.97 Scm-1 at 373 K, and surface tension as low as 50.23 Nm-1 implies they are conductive and favourable for electrolytic interactions. In the three electrodes system, before magnetite incorporation, the maximum specific capacitance (Csp), energy density (Ed), power density (Pd) and retention capacity (%) of the reverse micelles were estimated to be 584 Fg-1, 143 WhKg-1, 2356 WKg and 97.5%. After magnetite incorporation, we achieved maximum supercapacitive performance of 631 Fg-1, 204 WhKg-1, 4371 WKg-1 and 98%. In the two electrodes system, the reverse micelle nanohybrids showed up to 92% of the supercapacitive performances achieved in the three electrodes system. The incorporated magnetite nanoparticles are free to move within the micelles, and they align perpendicularly to the current collector electric field. This reduces the diffusion paths and increase the overall kinetics of active ions on the electrode surface. This work demonstrate that different micelles show different ionic and electronic properties, leading to different capacitance, and the overall research offers new route to the design of natural and uncarbonized biopolymer nanohybrids, in energy storage application. We demonstrate that the use of magnetite incorporated St-PBS reverse micelles minimizes the contact resistance between two supercapacitor electrodes, and achieved high charge storage capacity. Keywords: Supercapacitor, energy storage, starch biopolymers, sustainable energy, magnetite nanohybrids. Figure 1