Reference State Research Articles

Luminol tautomers and their interaction with zinc cation – A DFT treatment

Luminol is a chemiluminescent material having variety of applications. In the present study, its 1,3-proton tautomers have been considered within the restrictions of density functional theory at the level of B3LYP/6-31++G(d,p) and B3LYP/6-311++G(d,p) levels. Also, interaction of luminol tautomers with zinc dication at the level of B3LYP/6-31++G(d,p) is considered. All the structures considered presently are thermally favored and electronically stable at the standard states. The effect of zinc dication on the tautomers of luminol is not drastic but causes some conformational changes and enhancing the hydrogen bond formation in some cases. Some electron population has been transferred from the organic partner of the composite to the zinc cation, thereby lowering the initial formal charge of the cation. Various structural and quantum chemical data have been collected and discussed, including IR and UV-VIS spectra. Also the NICS (0) data have been obtained for the tautomers.

Pyrolytic conversion of glucose into hydroxymethylfurfural and furfural: Benchmark quantum-chemical calculations.

Quantum chemical methods have been intensively applied to study the pyrolytic conversion of glucose into hydroxymethylfurfural (HMF) and furfural (FF). Herein, we collect the most relevant mechanistic proposals from the recent literature and organize them into a single reaction network. All the transition structures (TSs) and intermediates are characterized using highly accurate ab initio methods and the possible reaction pathways are assessed in terms of the Gibbs energies of the TSs and intermediates with respect to β-glucopyranose, selecting a 2D ideal-gas standard state at 773 K to represent the pyrolysis conditions. Several pathways can lead to the formation of both HMF and FF passing through rate-determining TSs that have ΔG‡ values of ~49-50 kcal/mol. Both water-assisted mechanisms and nonspecific environmental effects have a minor impact on the Gibbs energy profiles. We find that the HMF → FF + CH2O fragmentation has a small ΔrxnG value and an accessible ΔG‡ barrier. Our computational results, which are in consonance with the kinetic parameters derived from lumped models, the results of isotopic labeling experiments and the reported HMF/FF molecular ratios, could be useful for modeling studies including on nonequilibrium kinetic effects that may render more information about product yields and the relevance of the various pathways.

Signatures of light new particles in B→K(*)Emiss

The recent Belle II observation of B→KEmiss challenges theoretical interpretations in terms of Standard Model neutrino final states. Instead, we consider new physics scenarios where up to two new light-invisible particles of spin 0 up to 3/2 are present in the final state. We identify viable scenarios by reconstructing the (binned) likelihoods of the relevant B→K(*)Emiss and also Bs→Emiss experimental analyses and present preferred regions of couplings and masses. In particular, we find that the current data prefer two-body decay kinematics involving the emission of a single massive scalar or a vector particle or, alternatively, three-body decays involving pairs of massive scalars or spin 1/2 fermions. When applicable, we compare our findings with existing literature and briefly discuss some model-building implications. Published by the American Physical Society 2024

Model predictive control based integrated fault tolerant controller for autonomous vehicles with four-wheel independent steering, driving and braking systems

This paper presents a fault-tolerant control algorithm for path and velocity tracking of an autonomous vehicle based on four-wheel independent steering, driving, and braking systems. The proposed algorithm is designed to distribute the control effort to normal actuators in the occurrence of faults. The proposed algorithm consists of three modules. The reference velocity and yaw rate to track the reference path are determined by the reference state decision module. The model predictive control (MPC)-based fault-tolerant controller determines the optimal inputs to compensate for the effect of the faulty actuator and maintain the tracking performance. A faulty-factor estimator is proposed based on a recursive covariance estimator to evaluate the performance degradation due to the failure of each actuator. The estimated faulty factors are applied to the objective function of the MPC such that the control input is distributed based on the level of the fault. The performance of the proposed algorithm was verified via performing simulations using MATLAB/Simulink and CarSim. The simulations proved that the proposed controller maintained the control performance of the normal case even in multiple actuator failures.

Search for dark mesons decaying to top and bottom quarks in proton-proton collisions at s\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\sqrt{\ extrm{s}} $$\\end{document} = 13 TeV with the ATLAS detector

A search for dark mesons originating from strongly-coupled, SU(2) dark flavor symmetry conserving models and decaying gaugephobically to pure Standard Model final states containing top and bottom quarks is presented. The search targets fully hadronic final states and final states with exactly one electron or muon and multiple jets. The analyzed data sample corresponds to an integrated luminosity of 140 fb−1 of proton-proton collisions collected at s\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\sqrt{s} $$\\end{document} = 13 TeV with the ATLAS detector at the Large Hadron Collider. No significant excess over the Standard Model background expectation is observed and the results are used to set the first direct constraints on this type of model. The two-dimensional signal space of dark pion masses mπD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\pi_D} $$\\end{document} and dark rho-meson masses mρD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\rho_D} $$\\end{document} is scanned. For mπD/mρD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\pi_D}/{m}_{\\rho_D} $$\\end{document} = 0.45, dark pions with masses mπD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\pi_D} $$\\end{document}< 940 GeV are excluded at the 95% CL, while for mπD/mρD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\pi_D}/{m}_{\\rho_D} $$\\end{document} = 0.25 masses mπD\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ {m}_{\\pi_D} $$\\end{document}< 740 GeV are excluded.

The association between selenium status and global and attention-specific cognition in very old adults in the Newcastle 85+ Study: cross-sectional and longitudinal analyses

BackgroundSelenium has potential safeguarding properties against cognitive decline, because of its role in protecting DNA, proteins, and lipids in the brain from oxidative damage. However, acute and chronic overexposure to selenium can be neurotoxic. ObjectiveThe aim of this analysis was to explore the association between selenium status [serum selenium and selenoprotein P (SELENOP) concentrations and glutathione peroxidase 3 (GPx3) activity] and cognitive function in 85-y olds living in Northeast England at baseline and ≤5 y of follow-up. MethodsGlobal cognitive performance was assessed in 755 participants from the Newcastle 85+ study using the standardized Mini-Mental State Examination and attention-specific cognition was assessed using composite scores derived from the Cognitive Drug Research System. Serum selenium, SELENOP, and GPx3 activity were measured at baseline by total reflection X-ray fluorescence, enzyme-linked immunosorbent assay, and coupled-enzyme reaction, respectively. Regression analyses explored linear and nonlinear associations between continuous values and tertiles of selenium status biomarkers, respectively, and cognitive function at baseline. Generalized linear mixed models explored associations between continuous values and tertiles of selenium status biomarkers, and global cognitive decline over 5 y, and attention-specific cognitive decline over 3 y. ResultsOver 3 and 5 y, none of the selenium biomarkers were associated with the rate of cognitive decline. At baseline, in fully adjusted models, higher serum selenium was nonlinearly associated with global cognition (β = 0.05 ± 0.01, P = 0.387 linear, β = 0.04 ± 0.01, P = 0.002 nonlinear). SELENOP and GPx3 activity were not associated with any cognitive outcomes. ConclusionsThere were no associations between selenium status and cognitive decline. However, serum selenium, but not SELENOP or GPx3 activity, was positively associated nonlinearly with global cognition at baseline. Furthermore, these associations were not evident during follow-up, potentially because of residual confounding and reverse causation.

Thermodynamic aspects of WO3 tungsten oxide reduction by carbon, silicon, aluminum and titanium

The development and research of new materials for machine parts of the mining and metallurgical complex by the method of surfacing with flux cored wire has a lot of attention nowadays. Flux cored wires are widely used for surfacing of steels with high wear resistance, in which reduced tungsten in the form of ferroalloys, ligatures and metal powder of various degrees of purity are used as fillers. However, due to the scarcity and high cost of tungsten, its rational use is an urgent task. For practical application, the technology of surfacing with tungsten-containing flux cored wire is of interest; using it the maximum extraction of tungsten into the deposited layer is achieved due to reduction processes in the arc. In order to increase the beneficial use of tungsten, the technologies of indirect alloying with tungsten during surfacing under the flux of flux cored wires, in which tungsten oxide is used as a filler on the one hand, and reducing agent – on the other, deserve consideration. It can be expected that during arc discharge, tungsten and (or) chemical compounds of tungsten with reducing agents can be formed during the surfacing process. This paper presents the results of a comparative analysis of the thermodynamic processes of tungsten oxide reduction by carbon, silicon, aluminum and titanium during arc discharge occurring during surfacing with flux cored wires under a layer of flux. The thermodynamic analysis of 41 reactions in standard states showed that the presence of reducing agents (carbon, silicon, aluminum, titanium) in the flux cored wire used for surfacing will contribute to the formation of silicides and tungsten carbides, and, possibly, tungsten itself. It was determined that the best state for the participation of tungsten oxide in reactions in the arc is WO3(g) gaseous state.

Solid-liquid phase boundary of oxide solid solutions using neural network potentials

We propose a cost-effective computational approach for predicting the phase boundary of oxide solid solutions, i.e., melting point, by identifying the point where the free energies of the solid and liquid phases are equivalent. To evaluate the melting point, we computed the temperature-dependent free energies of both phases using the thermodynamic integration (TI) method. This was combined with the reverse-scaling technique, employing the Einstein model for the solid and the scaled Uhlenbeck–Ford model for the liquid as the reference systems. The change in free energy between the real and reference states in the present TI method was calculated as the ensemble average of the configurations sampled from molecular dynamics (MD) simulations using neural network potentials (NNPs) trained on first-principles density functional theory (DFT) data. Initially, we benchmarked copper (Cu) as a typical metal. Tungsten (W) and magnesium oxide (MgO) were then tested as typical high melting-point metals and oxides, respectively, achieving good agreement with both ab initio MD (AIMD) results and experimental data. We then applied our established approach to a BaO–CaO oxide solid solution, observing that the computed phase boundary aligns well with Calphad predictions from previous studies. The integration of NNPs into phase boundary prediction is essential for reducing computational costs while ensuring accuracy, compared with AIMD-based approaches.

Fourth-Order Algebraic Diagrammatic Construction for Electron Detachment and Attachment: The IP- and EA-ADC(4) Methods.

We present a non-Dyson fourth-order algebraic diagrammatic construction formulation of the electron propagator, featuring the distinct IP- and EA-ADC(4) schemes for the treatment of ionization and electron attachment processes. The algebraic expressions have been derived automatically using the intermediate state representation approach and implemented in the Q-Chem quantum-chemical program package. The performance of the novel methods is assessed with respect to high-level reference data for ionization potentials and electron affinities of closed- and open-shell systems. While only minor improvements over the corresponding third-order methods are observed for one-hole ionization and one-particle electron attachment processes from closed-shell systems (MAEIP-ADC(4) = 0.27 eV and MAEEA-ADC(4) = 0.05 eV), a significantly enhanced performance is found in case of open-shell reference states (MAEIP-ADC(4) = 0.11 eV and MAEEA-ADC(4) = 0.02 eV). A particularly appealing feature of the novel methods is their accurate treatment of satellite transitions. For closed-shell reference states, we obtain accuracies of MAEIP-ADC(4) = 0.81 eV and MAEEA-ADC(4) = 0.27 eV, while in case of open-shell reference states, mean absolute errors of MAEIP-ADC(4) = 0.15 eV and MAEEA-ADC(4) = 0.27 eV are found.

Theory and experiment on distributed output formation tracking of unmanned aerial and ground vehicle swarm systems over jointly connected digraphs

This paper studies the distributed output formation tracking control problem of the unmanned aerial vehicle (UAV) and unmanned ground vehicle (UGV) swarm systems, where the UAV swarm cooperatively tracks the output trajectory of the UGV in a formation under directed jointly connected communication networks. A three-layer formation tracking protocol is proposed. Firstly, a novel distributed observer using neighbor interactions is designed for each UAV to estimate the states of the UGV with parameterized inputs over periodic jointly connected digraphs. Next, based on the observation result and output regulation theory, a virtual reference system that tracks the trajectory of the UGV in the desired formation is constructed to generate reference states for each UAV. Then based on the differential flatness of UAVs, a geometric controller is utilized for UAVs to track the reference states and form the formation. An algorithm to determine the gain matrices of the protocol is also presented while the convergence of the system is analyzed. Finally, an experiment platform with three quadrotor UAVs and one UGV is built. The effectiveness of the proposed protocol is validated both by the simulation and experiment.

Quantum multi-anomaly detection

A source assumed to prepare a specified reference state sometimes prepares an anomalous one. We address the task of identifying these anomalous states in a series of n preparations with k anomalies. We analyze the minimum-error protocol and the zero-error (unambiguous) protocol and obtain closed expressions for the success probability when both reference and anomalous states are known to the observer and anomalies can appear equally likely in any position of the preparation series. We find the solution using results from association schemes theory, thus establishing a connection between graph theory and quantum hypothesis testing. In particular, we use the Johnson association scheme which arises naturally from the Gram matrix of this problem. We also study the regime of large n and obtain the expression of the success probability that is non-vanishing. Finally, we address the case in which the observer is blind to the reference and the anomalous states. This scenario requires a universal protocol for which we prove that in the asymptotic limit, the success probability corresponds to the average of the known state scenario.

Grassland restoration on linear landscape elements – comparing the effects of topsoil removal and topsoil transfer

Artificial linear landscape elements, including roads, pipelines, and drainage channels, are main sources of global habitat fragmentation. Restoration of natural habitats on unused linear landscape elements can increase habitat quality and connectivity without interfering with agricultural or industrial development. Despite that topsoil removal and transfer are widely applied methods in restoration projects, up to our knowledge these were previously not compared in the same study system. To address this knowledge gap, we compared spontaneous vegetation recovery after the elimination of positive (embankments) and negative landscape scars (drainage channels) in lowland alkaline landscapes in South Hungary. The novelty of our study is that we compared the fine-scale and landscape-scale results of both methods. At the fine scale, we monitored the spontaneous vegetation development on the created open surfaces in the first, second and fourth year after restoration in 160 permanent plots per year. For characterizing the habitat changes on the landscape scale, we prepared habitat maps and assigned naturalness scores to each patch before and after the restoration activities. Both restoration methods resulted in a rapid vegetation recovery at the fine scale, progressing toward the reference state. In the topsoil removal treatment, a large part of the soil seed bank was removed; therefore, the colonization of the bare surface was a slower process. Seeds of halophytes, including the endemic and protected Suaeda pannonica, were probably present in the deeper soil layers, and these species became established in the restored surfaces, despite being absent in the surrounding vegetation. For restoring vegetation cover, topsoil transfer was a more rapid option; however, vegetation closure and competition by generalist species and weeds hampered the establishment of target species. The removal of the landscape scars by both methods made the sites accessible for grazing. At the landscape scale, the two methods had different effects: there was a slight increase in the habitat naturalness in the topsoil removal site, and a slight decrease in the topsoil transfer site because of weed encroachment. Spreading an upper layer of nutrient-poor soil with low amounts of weed seeds, direct propagule transfer, and targeted grazing regimes could enhance restoration success.

Towards 2050: Evaluating the Role of Energy Transformation for Sustainable Energy Growth in Serbia

This paper aims to investigate the outlook of energy generation by means of transformation within the context of sustainable energy development. An analysis is conducted to assess the stability of energy systems so to implement cutting-edge energy production models at the national level, with a focus on a contemporary approach to energy modeling. Considering the energy transition and the existing constraints within the energy industry, the model assesses the feasibility of the practical advancement of renewable energy sources. The bottom-up energy model was used to determine how the components of energy development sustainability can be applied until the year 2050. To perform comparison testing with the reference state scenario, the LEAP energy model was used. This instrument was selected because of its ability to provide flexible and advanced options for selecting suitable parameters for energy transformation prediction. A progressive reduction in environmental pollution can be achieved by the deployment of current methods of energy generation by transformation until the year 2050 in Serbia, as indicated by the findings. The research highlights the significance of utilizing green energy sources for the continuing development of energy and the gradual reduction in environmental pollution through value co-creation.

Computation of rate coefficients in solutions based on transition state theory combined with a heuristically corrected polarizable continuum model: intermolecular Diels-Alder reactions as case studies.

Transition state theory (TST) based on activation parameters computed using quantum mechanics calculations combined with the polarizable continuum model (QM/PCM) is a fundamental tool for investigating reaction rates in the liquid phase. In conventional QM/PCM methods, thermodynamic data and partition functions for a solute are often derived from a quasi-ideal gas treatment (IGT) widely implemented in commercially available computation packages. This approach tends to overestimate entropy because calculations of thermodynamic parameters in the liquid phase ignore hindered translational and rotational modes in real solutions. The present work formulated partition functions for more realistic solutes hindered by surrounding solvent molecules in conjunction with the basic QM/PCM concept. In addition, a configuration partition function for solute molecules at a standard concentration of 1 mol dm-3 was incorporated using a simple lattice model. The canonical partition function and thermodynamic functions were derived based on statistical thermodynamics for localized systems. Expressions for rate coefficients within TST were also derived with a consistent formalism based on the standard state selected in partition function calculations. The performance of the proposed method was assessed by predicting rate coefficients for three different Diels-Alder reactions and comparing these with experimental results. QM/PCM calculations at the G4//ωB97X-D/6-311++G(d,p)/IEF-PCM level of theory with corrections for the dispersion and repulsion energies were performed to obtain the electronic structures of stationary points on potential energy surfaces as a means of finding activation enthalpy, entropy and Gibbs energy values based on revised partition functions as well as predicting rate coefficients. The activation Gibbs energies obtained from our proposed method were lower than those obtained from the IGT method due to reasonable entropy computations. The proposed method overestimated the rate coefficients by one to two orders of magnitude compared to the experimental values, whereas the IGT method underestimated them by the same amount. This discrepancy arises because the proposed method calculates the partition function from the viewpoint of a localized system, whereas the IGT method calculates it from the viewpoint of a non-localized system. Given that actual liquids exist in a state between non-localized and localized systems, it is essential to formulate the partition function in a way that more accurately represents the liquid state.

Electron Binding Energies of Open-Shell Species from Diagonal Electron-Propagator Self-Energies with Unrestricted Hartree-Fock Spin-Orbitals.

For closed-shell molecules, valence electron binding energies may be calculated accurately and efficiently with ab initio electron-propagator methods that have surpassed their predecessors. Advantageous combinations of accuracy and efficiency range from cubically scaling methods with mean errors of 0.2 eV to quintically scaling methods with mean errors of 0.1 eV or less. The diagonal self-energy approximation in the canonical Hartree-Fock basis is responsible for the enhanced efficiency of several methods. This work examines the predictive capabilities of diagonal self-energy approximations when they are generalized to the canonical spin-orbital basis of unrestricted Hartree-Fock (UHF) theory. Experimental data on atomic electron binding energies and high-level, correlated calculations in a fixed basis for a set of open-shell molecules constitute standards of comparison. A review of the underlying theory and analysis of numerical errors lead to several recommendations for the calculation of electron binding energies: (1) In calculations that employ the diagonal self-energy approximation, Koopmans's identity for UHF must be qualitatively correct. (2) Closed-shell reference states are preferable to open-shell reference states in calculations of molecular ionization energies and electron affinities. (3) For molecular electron binding energies between doublets and triplets, calculations of electron detachment energies are more accurate and efficient than calculations of electron attachment energies. When these recommendations are followed, mean absolute errors increase by approximately 0.05 eV with respect to their counterparts obtained with closed-shell reference orbitals.

Impact of temperature and relative humidity variations on coda waves in concrete

The microstructure of concrete can be affected by many factors, from non-destructive environmental factors through to destructive damage induced by transient stresses. Coda wave interferometry is a technique that is sensitive enough to detect weak changes within concrete by evaluating the ultrasonic signal perturbation compared to a reference state. As concrete microstructure is sensitive to many factors, it is important to separate their contributions to the observables. In this study, we characterize the relationships between the concrete elastic and inelastic properties, and temperature and relative humidity. We confirm previous theoretical studies that found a linear relationship between temperature changes and velocity variation of the ultrasonic waves for a given concrete mix, and provide scaling factors per Kelvin for multiple settings. We also confirm an anti-correlation with relative humidity using long-term conditioning. Furthermore, we explore beyond the existing studies to establish the relationship linking humidity and temperature changes to ultrasonic wave attenuation.

МУГАЛИМДЕРДИН КОММУНИКАТИВДИК КОМПЕТЕНТТҮҮЛҮГҮНҮН СОЦИАЛДЫК-ПСИХОЛОГИЯЛЫК АСПЕКТИЛЕРИ

In addition to instilling general and specialized knowledge on the basis of a competent attitude, along with the psychological aspects of professional competence required by state standards, the qualities necessary for the growth and development of society are developed (communication, initiative, independence, preparation at a creative level, responsibility, determination, ability to implement set goals, etc.). The reports of scientists on the problem of communicative skills, communicative abilities, and their formation, considered as components of the psychological aspects of communicative competence, are presented, and five different types of teacher activities and a scheme of socio-psychological competence of a teacher are presented. The processes taking place in the economic life of our country, Kyrgyzstan's entry into developed world cooperation create conditions for the development of the organization of new forms of production in the economy. This is a reduction in the cycle of technical updates, the widespread use of information technology, computer technology, complex electronic equipment.

Entanglement and Generalized Berry Geometrical Phases in Quantum Gravity

A new formalism is introduced that makes it possible to elucidate the physical and geometric content of quantum space–time. It is based on the Minimum Group Representation Principle (MGRP). Within this framework, new results for entanglement and geometrical/topological phases are found and implemented in cosmological and black hole space–times. Our main results here are as follows: (i) We find the Berry phases for inflation and for the cosmological perturbations and express them in terms of the observables, such as the spectral scalar and tensor indices, nS and nT, and the tensor-to-scalar ratio r. The Berry phase for de Sitter inflation is imaginary with the sign describing the exponential acceleration. (ii) The pure entangled states in the minimum group (metaplectic) Mp(n) representation for quantum de Sitter space–time and black holes are found. (iii) For entanglement, the relation between the Schmidt type representation and the physical states of the Mp(n) group is found: This is a new non-diagonal coherent state representation complementary to the known Sudarshan diagonal one. (iv) Mean value generators of Mp(2) are related to the adiabatic invariant and topological charge of the space–time, (matrix element of the transition −∞&lt;t&lt;∞). (v) The basic even and odd n-sectors of the Hilbert space are intrinsic to the quantum space–time and its discrete levels (in particular, continuum for n→∞), they do not require any extrinsic generation process such as the standard Schrodinger cat states, and are entangled. (vi) The gravity or cosmological on one side and another of the Planck scale are entangled. Examples: The quantum primordial trans-Planckian de Sitter vacuum and the classical late de Sitter vacuum today; the central quantum gravity region and the external classical gravity region of black holes. The classical and quantum dual gravity regions of the space–time are entangled. (vii) The general classical-quantum gravity duality is associated with the Metaplectic Mp(n) group symmetry which provides the complete full covering of the phase space and of the quantum space–time mapped from it.

The effects of heat treatment on the mechanical properties of 450 HB wear resistant steel

The effects of heat treatment on the mechanical properties of 450 HB wear resistant steel produced by Usiminas steelworks in the form of heavy plates were investigated. The results showed that when tempering temperature is lower than 200°C, there are no significant changes in hardness, tensile properties and absorbed energy in Charpy V-notch test. With further increase in temperature up to 400°C, hardness, tensile strength, total elongation and impact toughness exhibited a slight downward trend. For heating carried out from 400°C to 600°C, a very significant drop in hardness and tensile strength and an increase in total elongation and absorbed energy values were observed. The abrasive wear resistance, evaluated by dry-sand rubber wheel test, increased with the heating up to 500°C. With the additional rise in temperature to 600°C, the abrasive wear resistance decreased, reaching a similar level to the reference state (steel in as-delivered condition).

Применение конопляного урбеча и нутовой муки в составе комбинированных творожных десертов

Purpose. Determination of the functional and technological compatibility of whipped food systems of combined curd desserts with neoprotein ingredients. Materials and Мethods. Experimental research and development of samples were carried out in the conditions of the Department of Food Production Technologies of Volgograd State Technical University and Complex Analytical Laboratory of VRIMMP (Volgograd). The object of the study was combined curd desserts with neoprotein ingredients: urbech from peeled hemp seeds in the curd part and chickpea flour in the biscuit part. All studies within the framework of this work were carried out in accordance with regulatory documents of state standards of the Russian Federation: assessment of organoleptic indicators – according to GOST R ISO 22935-2-2011 and GOST 31986-2012; whipped of the curd part was determined according to GOST R 52175-2003, mass fraction of moisture – according to GOST 3626-73, titratable acidity – titrimetrically (GOST 3624-92), mass fraction of moisture in the biscuit – according to GOST 5900-2014. Results. Sample of curd part No. 2 with the addition of 6% urbech from purified hemp kernels and sample of biscuit No. 2 using chickpea flour after frying demonstrated the best organoleptic characteristics. The results of physicochemical and rheological tests showed that the addition of urbech increases whipped of the curd part by 2 times, reduces acidity by 11.1% and increases mass fraction of moisture by 5.5%, and frying chickpea flour helps to increase the mass fraction of moisture in the biscuit, which slows down staling. The use of neoprotein components enriches the combined whipped curd product with plant protein, dietary fiber, macro- and microelements. Conclusion. Production of combined whipped curd products using neoprotein components - hemp urbech and fried chickpea flour, is advisable due to the improvement of the organoleptic, physico-chemical and rheological properties of both the curd and biscuit parts of the product, as well as increasing their nutritional and biological value.