This work demonstrates that a core-shell compound droplet can undergo separation into two different phase droplets or be transformed into a reverse-encapsulation droplet under the influence of thermocapillary effects. This study comprehensively investigates the thermocapillary effects on the migration, reverse-encapsulation, and core-release dynamics of compound droplets, with particular emphasis on the interactions among key dimensionless parameters, including the Marangoni number, Reynolds number, and the radius ratio of the inner to the middle fluid of a core-shell compound droplet. Using a reduction-consistent phase field model for incompressible N-phase flows, this research provides an in-depth analysis of the reverse-encapsulation and core-release processes of a compound droplet. The reverse-encapsulation process is characterized by three distinct stages: The initial acceleration stage, the encapsulation stage, and the post-transformation stage. Similarly, the core-release process also has three stages: The initial acceleration stage, the middle fluid contraction stage, and the independent movement stage. The results indicate that the Marangoni number has little influence on the migration velocity, while the tangential surface force (thermocapillary force) is the cause of these processes. The Reynolds number has a significant effect on the encapsulation dynamics, with higher values leading to slower and more turbulent processes. In addition, the radius ratio plays a critical role in determining the reverse-encapsulation and core-release processes, as well as migration behaviors. These findings advance our understanding of multiphase fluid dynamics and have significant implications for applications in microfluidics, targeted drug delivery, and advanced materials synthesis.
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