Stable Ring Research Articles

Resonances, black hole mimickers, and the greenhouse effect: Consequences for gravitational-wave physics

Ultracompact objects with photonspheres are known to mimic many observational features of black holes. It has been suggested that anomalous tidal heating or the presence of resonances in gravitational wave signals would be a clear imprint of a surface or absence of a horizon. Such claims and studies are all based on a frequency-domain analysis, assuming stationarity. Here we show that the object needs to first "fuel-up" until it reaches the stationary regime. The presence of a stable light ring and large light-travel times inside the object may in fact delay enormously the "charging-up" and effectively contribute to the effacement of structure. In other words, black hole mimickers behave as black holes more efficiently than previously thought. Our results have implications for other resonant systems with sharp resonances, including "floating orbits" around spinning black holes. A proper accounting of the self-force for such systems seems to be both mandatory, and would have important applications for tests of horizon physics.

The water vapor self-continuum absorption at room temperature in the 1.25 µm window

The water vapor self-continuum is newly measured at room temperature in the high energy edge of the 1.25 µm window by using highly stable and sensitive cavity ring down spectroscopy (CRDS). Self-continuum cross-sections, CS, are derived between 8290 and 8620 cm−1 at 29 selected spectral points by using pressure ramps (up to 15 Torr) of pure water vapor. Purely quadratic pressure dependence is obtained for the absorption coefficient at each measurement point. Although the spectral measurement points were chosen to minimize the contribution of resonance line absorption, the latter represents between 30 and 70% of the measured absorption in the studied region. The measurements are found consistent with a previous study of the low frequency edge of the 1.25 µm windows and (Campargue et al. J Geophys Res Atmos 2016;121:13,180 – 13,203. doi:10.1002/2016JD025531). The frequency dependence of the retrieved CS values shows an overall good agreement with the MT_CKD values, although an additional broad absorption feature is observed with a center near 8455 cm−1. It is tentatively interpreted as a possible impact of the uncertainties on the resonance line contribution on the derived CS values or as a possible evidence of a band of the bound dimers, (H2O)2.

Two case reports of ring lateral meniscus - A rare anatomical variant

IntroductionThe ring-shaped meniscus is an infrequent anatomical aberration with very few previous reports. Comparatively, these are reported more commonly in the lateral meniscus than the medial meniscus. Most often they are quiescent and rarely cause any symptom unless for an associated tear or parameniscal cyst. Thorough history taking, proper examination, adequate imaging along with arthroscopic evaluation is essential for diagnosing and treating these anomalies appropriately. Case reportsWe report two cases of asymptomatic ring lateral meniscus. The first patient was a 15-year-old girl with ACL insufficiency and the second patient was a 38-year-old doctor with medial meniscus bucket handle tear, three years post anterior cruciate ligament reconstruction. Arthroscopy revealed a stable ring lateral meniscus in both patients. Since these were incidental findings with no correlation to the patient's presenting complaints, it was decided not to touch them. ConclusionAberrations of lateral meniscus are many and the ring-shaped meniscus is one amongst the rarest. Knowledge of these malformation is essential to identify and initiate appropriate intervention as needed.

Seipin forms a flexible cage at lipid droplet formation sites

Lipid droplets (LDs) form in the endoplasmic reticulum by phase separation of neutral lipids. This process is facilitated by the seipin protein complex, which consists of a ring of seipin monomers, with a yet unclear function. Here, we report a structure of S. cerevisiae seipin based on cryogenic-electron microscopy and structural modeling data. Seipin forms a decameric, cage-like structure with the lumenal domains forming a stable ring at the cage floor and transmembrane segments forming the cage sides and top. The transmembrane segments interact with adjacent monomers in two distinct, alternating conformations. These conformations result from changes in switch regions, located between the lumenal domains and the transmembrane segments, that are required for seipin function. Our data indicate a model for LD formation in which a closed seipin cage enables triacylglycerol phase separation and subsequently switches to an open conformation to allow LD growth and budding.

Controlled, Sunlight-Driven Reversible Cycloaddition of Multiple Singlet Oxygen Molecules to Anthracene-Containing Trianglimine Macrocycles.

Controlled release of singlet oxygen is of interest not only to chemists, but also to biologists and medics involved in cancer therapy. Two chiral polyaza macrocyclic compounds and their corresponding endoperoxides have been synthesized. These peroxides exhibit high temperature stability, up to 80 °C. Detailed studies on their structure, including X-ray analysis as well as NMR, UV-VIS ECD spectroscopy and theoretical calculations, combined with photochemical measurements indicate that their high stability is related to the arrangement of oxygen atoms in a conformationally stable macrocyclic ring. Despite the change of carbon hybridization from sp2 to sp3 at the 9 and 10 positions of the anthracene units, the macrocyclic skeleton of the obtained compounds does not change its conformation. The obtained endoperoxides can be formed and release singlet oxygen by irradiation with UV light of 365 and 275 nm, respectively. Release of the oxygen does not degrade the macrocyclic structure.

Highly efficient poly(6-acryloylamino-N-hydroxyhexanamide) resin for adsorption of heavy metal ions

Heavy metal wastewater pollution has become an ecological challenge worldwide. This study reports the development of a novel poly (6-acryloylamino-N-hydroxyhexanamide) (PAHHA) resin for effective adsorption of heavy metal ions, including Cu2+, Pb2+ and Ni2+. The chelating resin was synthesized by the grafting reaction between 6-amino-N-hydroxyhexanamide and polyacrylic resin, thus containing the hydroxamate and acylamino groups. The batch adsorption experiments revealed that the PAHHA resin exhibited an excellent adsorption performance for Cu2+, Pb2+ and Ni2+. The maximum adsorption capacities of Cu2+, Pb2+ and Ni2+ were determined to be 238.59, 232.48 and 115.77 mg·g−1, respectively. Based on the adsorption kinetics, the pseudo-second-order kinetic model was noted to fit well for all metal ions. The metal ion concentration as a function of the equilibrium adsorption capacity fitted well with the Langmuir isotherm, thus indicating the single layer adsorption process. The adsorption mechanism was investigated by using Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), density functional theory (DFT) calculations, X-ray photoelectron spectroscopy (XPS) and adsorption isotherms. It was revealed that the PAHHA resin possessed multiple active sites, including –CONHOH, –CONH– and –COOH, which could strongly adsorb the metal ions. Specifically, the –CONHOH group displayed a high affinity by forming a stable five-membered ring with heavy metal ions. Overall, the developed resin exhibits advantages such as simple synthesis, inexpensive raw material and good recyclability, along with high adsorption ability, thus providing a new approach for efficiently treating wastewater contaminated with heavy metal ions.

Stable set rings which are Gorenstein on the punctured spectrum

The non-Gorenstein locus of stable set rings of finite simple perfect graphs is studied. We describe combinatorially those perfect graphs whose stable set rings are Gorenstein on the punctured spectrum. In addition, we show that, in general, for Cohen–Macaulay graded algebras, their Cohen–Macaulay type and residue are largely independent.

ОБРОБКА ВОДНОГО РОЗЧИНУ МЕТИЛЕНОВОЇ СИНІ В КРАПЛИНО- ПЛІВКОВОМУ СТАНІ ІМПУЛЬСНИМ БАР’ЄРНИМ РОЗРЯДОМ

The influence of various factors that can affect the efficiency of pulsed barrier discharge treatment in the air of atmospheric pressure of a model sample of contaminated water in the droplet-film state was investigated. The impurity in the water was an organic dye (methylene blue) with an initial concentration of 50 mg / l. Water consumption was 2–4 l / min, the characteristic diameter of the droplets was 1.7 mm, and the film thickness at the electrodes was about 0.15 mm. The water was treated in a flat discharge chamber with gas gaps of 3.36 mm and glass dielectric barriers, and in addition in an ozonation chamber, which used ozone that had not previously been useful. The discharge was excited by short ~ 100 ns pulses from voltage up to 21 kV, which provided the current density amplitude up to 1.7 A / cm2 and their energy up to 140 mJ. The decomposition time of the impurity and the energy efficiency of the discharge depending on the pulse repetition frequency of 25–300 Hz were studied. The discharge had the highest energy efficiency at frequencies of 25-50 Hz, at which the energy yield, which corresponds to 50% decomposition of the impurity, reaches ≈270 g / kWh, and for 90% decomposition − 60 g / kWh. As the pulse energy increases, the transparency of the solution for ultraviolet light increases, which is associated with the splitting of stable benzene rings that is part of the impurity molecule. No noticeable effect of water and gas consumption (0.36-1.5 l / min) on the research results was found. References 16, figures 8.

The flagellar motor protein FliL forms a scaffold of circumferentially positioned rings required for stator activation

The flagellar motor stator is an ion channel nanomachine that assembles as a ring of the MotA5MotB2 units at the flagellar base. The role of accessory proteins required for stator assembly and activation remains largely enigmatic. Here, we show that one such assembly factor, the conserved protein FliL, forms an integral part of the Helicobacter pylori flagellar motor in a position that colocalizes with the stator. Cryogenic electron tomography reconstructions of the intact motor in whole wild-type cells and cells lacking FliL revealed that the periplasmic domain of FliL (FliL-C) forms 18 circumferentially positioned rings integrated with the 18 MotAB units. FliL-C formed partial rings in the crystal, and the crystal structure-based full ring model was consistent with the shape of the rings observed in situ. Our data suggest that each FliL ring is coaxially sandwiched between the MotA ring and the dimeric periplasmic MotB moiety of the stator unit and that the central hole of the FliL ring has density that is consistent with the plug/linker region of MotB in its extended, active conformation. Significant structural similarities were found between FliL-C and stomatin/prohibitin/flotillin/HflK/C domains of scaffolding proteins, suggesting that FliL acts as a scaffold. The binding energy released upon association of FliL with the stator units could be used to power the release of the plug helices. The finding that isolated FliL-C forms stable partial rings provides an insight into the putative mechanism by which the FliL rings assemble around the stator units.

Homocysteine-specific fluorescence detection and quantification for evaluating S-adenosylhomocysteine hydrolase activity.

Studies have shown that homocysteine (Hcy) levels are closely related to cardiovascular and cerebrovascular diseases. In this work, we have developed and synthesized three copper complexes, F542-Cu2+, F508-Cu2+, and F465-Cu2+ for Hcy detection. The different binding constants (Ks) of the copper complexes endow them with dramatic reactivity toward biothiols. The pyridine-containing tetraazacycle was employed in the construction of F542-Cu2+, which renders the medium Ks value for the copper complex compared with cyclen and TACN and effectively prevented the disintegration of the complexes. Pyridine-containing tetraazacycle provided the basis and possibility for the hypothesis for the reduction of Cu2+ by biothiols to shape into a stable six-membered ring structure. The obtained results verified that F542-Cu2+ could be utilized to specifically probe Hcy in a switched-on fluorescence mode. F542-Cu2+ exhibited excellent environmental stability, superior sensitivity, and outstanding selectivity toward Hcy under physiological conditions. The mechanism of Hcy specificity was confirmed to be related to the generation of Hcy-induced six-membered ring by fluorescence imaging, time-dependent fluorescence spectra, ESI-MS, and electron paramagnetic resonance (EPR) analyses. Furthermore, we exploited the application of F542-Cu2+ and developed a strategy for evaluating the activity of S-adenosylhomocysteine hydrolase (AHCY) in vitro by fluorescence analysis. More importantly, real-time in vivo evaluation of the enzymatic activity of AHCY was realized and assisted by our probe, providing the possibility of opening up a new avenue for enzymatic reaction assessment.

Synthesis and Primary Biological Evaluation of Triazole‐Modified Picroside II Compounds

AbstractPicroside II, an iridoid glycoside, has anti‐cancer, anti‐virus, anti‐apoptotic, nervous and myocardial protection effects and so on. However, the oral bioavailability of Picroside II is low, and the half‐life in vivo is short, so it is limited to use in clinic. Triazole is a highly stable heterocyclic ring, which can be interacted with various enzymes or receptors in the organism through non‐covalent interactions, and many of its good pharmacological activities in vitro and in vivo have been reported. Based on the advantages of triazole and Picroside II, a series of triazole‐modified Picroside II derivatives (5 a–5 i) were synthesized by using drug combination principles for the first time. The structures were confirmed by different spectroscopic techniques including 1H NMR, 13C NMR and HRMS, and the primary biological evaluation of anti‐breast cancer, anti‐colorectal cancer, the effect on SARS‐CoV‐2 3CLpro inhibitor, and CD47‐SIRPα protein were screened as well. Compound 5 e has anti‐breast cancer activity, and compounds 3 and 5 i have anti‐colorectal cancer activity.

Stable Cosmic Vortons in Bosonic Field Theory.

Stable ring solutions supported by the angular momentum caused by superconducting charge and current have been suggested to exist in the gauged U(1)×U(1) field theory. We construct potentially cosmologically relevant solutions using gradient flow for the first time and present the strongest evidence to date that they are stable to axial and, crucially, nonaxial perturbations. More importantly, we illustrate quantitative agreement with semianalytic predictions based on the thin string approximation, which validates world sheet action approaches to their formation and evolution.

Band structure tuning of g-C3N4 via sulfur doping for broadband near-infrared ultrafast photonic applications

Abstract Graphitic carbon nitride (g-C3N4) featuring a stable heptazine ring structure and high polymerization degree, was indexed as a high thermochemical stability material, attracting rising research enthusiasm for diverse applications. However, the poor near-infrared (NIR) optical absorption and resulting limited NIR applications were pronounced for g-C3N4 due to its large bandgap of 2.7 eV. In the present work, sulfur-doping was manifested by first-principles calculations to introduce impurity level and result in anisotropic spin splitting in g-C3N4 for enhancing broadband nonlinear optical characteristics in NIR regime. The modified sulfur-doped g-C3N4 (S-C3N4) exhibited the maximum effective nonlinear absorption coefficient to be −0.82 cm/GW. Pulse duration within hundred nanoseconds was realized with high modulation stability employing S-C3N4 as saturable absorber in Q-switching operations. Moreover, broadband ultrafast photonics properties were successfully demonstrated in constructed ytterbium-doped and erbium-doped fiber lasers, generating highly stable dissipative soliton and traditional soliton mode-locking pulses. The presented S-C3N4 nanomaterial with remarkable nonlinear optical performances might explicitly boost the development and application of g-C3N4 materials in advanced optoelectronic and ultrafast photonic devices.

Structure and Energetics of GTP- and GDP-Tubulin Isodesmic Self-Association.

Tubulin self-association is a critical process in microtubule dynamics. The early intermediate structures, energetics, and their regulation by fluxes of chemical energy, associated with guanosine triphosphate (GTP) hydrolysis, are poorly understood. We reconstituted an in vitro minimal model system, mimicking the key elements of the nontemplated tubulin assembly. To resolve the distribution of GTP- and guanosine diphosphate (GDP)-tubulin structures, at low temperatures (∼10 °C) and below the critical concentration for the microtubule assembly, we analyzed in-line size-exclusion chromatography-small-angle X-ray scattering (SEC-SAXS) chromatograms of GTP- and GDP-tubulin solutions. Both solutions rapidly attained steady state. The SEC-SAXS data were consistent with an isodesmic thermodynamic model of longitudinal tubulin self-association into 1D oligomers, terminated by the formation of tubulin single rings. The analysis showed that free dimers coexisted with tetramers and hexamers. Tubulin monomers and lateral association between dimers were not detected. The dimer-dimer longitudinal self-association standard Helmholtz free energies were -14.2 ± 0.4 kBT (-8.0 ± 0.2 kcal mol-1) and -13.1 ± 0.5 kBT (-7.4 ± 0.3 kcal mol-1) for GDP- and GTP-tubulin, respectively. We then determined the mass fractions of dimers, tetramers, and hexamers as a function of the total tubulin concentration. A small fraction of stable tubulin single rings, with a radius of 19.2 ± 0.2 nm, was detected in the GDP-tubulin solution. In the GTP-tubulin solution, this fraction was significantly lower. Cryo-TEM images and SEC-multiangle light-scattering analysis corroborated these findings. Our analyses provide an accurate structure-stability description of cold tubulin solutions.

Kerr black hole shadows in Melvin magnetic field with stable photon orbits

We have studied the spacetime of a Kerr black hole immersed in Melvin magnetic field, and found not only unstable light rings could exist, but also stable light rings could exist. Both the prograde and retrograde unstable light rings radiuses increase with the magnetic field parameter $B$, but it is the opposite for stable light rings. The existence of unstable, stable light rings depend on both the rotation parameter $a$ and the magnetic field parameter $B$. For a certain $a$, there are both the prograde and retroprade unstable (stable) light rings when $B$ is less than a critical value $B_{c}$ of retrograde light ring. In this case, the shadows of Melvin-Kerr black hole have two gray regions on both sides of the middle main shadow, which correspond to the prograde and retrograde stable photon orbits. The photons in stable orbits are always moving around Melvin-Kerr black hole, they can't enter the black hole or escape to infinity. As $B$ continues to increase, there is only the prograde unstable (stable) light ring. In this case, the gray region only emerges in the life of the main shadow, which corresponds to the prograde stable photon orbits. The absence of the retrograde unstable (stable) light rings makes the Melvin-Kerr black hole shadow an half-panoramic (equatorial) shadow. When $B$ is bigger than $B_{C}$ of prograde light ring, neither prograde nor retroprade unstable (stable) light rings exist. In this case, the shadow of Melvin-Kerr black hole has no gray region for stable photon orbits, and becomes a panoramic (equatorial) shadow. In addition, there also exist some self-similar fractal structures in the shadow of Melvin-Kerr black hole arising from the chaotic motion of photon.

Pd Doped on TCH@SBA-15 Nanocomposites: Fabrication and Application as a New Organometallic Catalyst in the Three-Component Synthesis of N-Benzo-imidazo- or -thiazole-1,3-thiazolidinones.

In this study, Pd(II)/TCH@SBA-15 nanocomposites were synthesized by the grafting of 3-chloropropyltriethoxysilane and thiocarbohydrazide on SBA-15 and subsequent deposition of palladium acetates through the ligand–metal coordination method. The structure and morphology of this nanoporous nanocomposite was thoroughly identified by Fourier transform infrared spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, thermogravimetric analysis, atomic absorption spectroscopy, and Brunauer–Emmett–Teller instrumental analyses. Furthermore, the catalytic activity of this nanocomposite was investigated in the three-component synthesis of 3-benzimidazolyl or benzothiazoleyl-1,3-thiazolidin-4-ones via a reaction of 2-aminobenzimidazole or 2-aminobenzothiazole, aromatic aldehydes, and thioglycolic acid in an acetone–H2O mixture under green conditions. The Pd/TCH@SBA-15 nanocatalyst is demonstrated to exhibit a high catalyzing activity in the three-component reaction of the synthesis of N-heterocyclic thiazolidinones with good to excellent yields. One of the advantages of the suggested method is the direct application of the thiocarbohydrazide ligand to stabilize Pd nanoparticles through formation of a stable ring complex without creating an additional Schiff base step. Moreover, this organometallic nanocatalyst can be recycled several times with no notable leaching or loss of performance.

Circular RNA hsa_circ_0007507 May Serve as a Biomarker for the Diagnosis and Prognosis of Gastric Cancer.

PurposeThe morbidity and mortality of gastric cancer (GC) remain high worldwide. In recent years, circular RNAs (circRNAs) have attracted widespread attention among cancer researchers due to the stable ring structure. The present work aims to find serum circRNA biomarkers that can be used in clinical applications and effective diagnosis.MethodsHsa_circ_0007507 was extracted through circRNA sequencing. Exonuclease digestion assay, actinomycin D, agarose gel electrophoresis (AGE), and Sanger sequencing verified the potential of hsa_circ_0007507 as a biomarker. Besides, a real-time fluorescent quantitative polymerase chain reaction (RT-qPCR) was established to detect the level of expression of hsa_circ_0007507. Twenty cases of GC and the paired adjacent tissues were collected to verify its overexpression. Then, serum samples from 30 cases of colorectal cancer, 30 cases of thyroid cancer, and 30 cases of breast cancer were collected to verify their organ specificity. Additionally, serum samples from 80 healthy people, 62 gastritis patients, 31 intestinal metaplasia patients, and 100 GC patients were collected, and the diagnostic efficacy was evaluated through analysis of the receiver operating characteristic (ROC) curve. Furthermore, 16 post-operative GC samples, samples of 65 relapsed patients and 36 non-relapsed patients were collected to evaluate the prognosis of GC.ResultsThe level of expression of hsa_circ_0007507 in GC tissues was up-regulated (p = 0.0121), which was consistent with the results of circRNA sequencing. Exonuclease digestion assay and actinomycin D confirmed that hsa_circ_0007507 had a stable structure and a longer half-life. In the analysis of organ specificity experiments, serum hsa_circ_0007507 did not have specificity for patients with colorectal cancer (p = 0.5319), thyroid cancer (p = 0.5422), or breast cancer (p = 0.5178). Analysis of diagnostic efficacy indicated that the expression of hsa_circ_0007507 was significantly higher than that of normal people (p <0.0001); the area under the ROC (AUC) was 0.832 (95% CI: 0.771-0.892); the diagnostic power of hsa_circ_0007507 was higher than that of CEA (AUC = 0.765, 95% CI: 0.697-0.833) and CA199 (AUC = 0.587, 95% CI: 0.504-0.67). Through diagnosis using a combination of the three, GC patients could be distinguished from normal people (AUC = 0.849), and higher diagnostic efficiency could be achieved. The expression of serum hsa_circ_0007507 in GC patients significantly decreased after surgery (p = 0.001). Besides, the expression of serum hsa_circ_0007507 in patients with post-operative recurrence was significantly up-regulated again (p = 0.0139).ConclusionsSerum hsa_circ_0007507 is differentially expressed in GC patients, post-operative GC patients, gastritis patients, intestinal metaplasia patients and relapsed patients, suggesting that serum hsa_circ_0007507 can be used as a new diagnostic and dynamic monitoring biomarker for GC.

Switched pseudo-current mirror inverter for low-power, thermally stable and robust ring oscillator

This paper proposes a low-power inverter in 65 nm CMOS technology, which utilizes a switched pseudo-current mirror to control the pull-up network and to reduce the short-circuit current during the transition. This inverter saves 75% power per cycle, while its power-delay product is almost half of the CMOS inverter. The proposed inverter constructs a low-power ring oscillator with improved thermal stability and aging robustness. The proposed structure of a 1.2GHz ring oscillator consumes 0.66mW, while its CMOS counterpart dissipates 4.46mW. The immunity against supply voltage fluctuations is also improved. On the other side, the proposed inverter consumes twice the silicon area and doubles the propagation delay, limiting its usage in high-performance and high-density VLSI applications. These results indicate that the proposed inverter is a viable candidate for special applications, such as ring oscillators used in physically unclonable functions and true random number generators.

Rapid enrichment detection of patulin and alternariol in apple using surface enhanced Raman spectroscopy with coffee-ring effect

Patulin (PAT) and alternariol (AOH) are the main mycotoxin contaminants in fruits and their products, which have great toxic effects on human body due to their teratogenicity and carcinogenicity. This study proposed a surface enhanced Raman spectroscopy (SERS) technology combining chemometrics and coffee-ring effect to build high-throughput label-free detection models for PAT and AOH. A stable coffee ring structure was built by optimizing the drying temperature and droplet volume. Comparing the partial least squares (PLS) models grounded on variables selection method, the best performance was obtained by using synergy interval (Si) and genetic algorithm (GA) for PAT (Rc = 0.9905, Rp = 0.9759) and AOH (Rc = 0.9829, Rp = 0.9808), respectively. The limits of detection (LOD) for PAT and AOH were as low as 1 μg L−1, and the recovery rates were 92.80%–114.83% with relative standard deviation (RSD) ≤ 4.86 for PAT and 82.06%–108.13% with RSD ≤2.28% for AOH. The SERS technology combined with chemometrics and coffee-ring effect holds promise for high-throughput label-free detection of PAT and AOH in fruits and their products.

High-Voltage-Tolerant Covalent Organic Framework Electrolyte with Holistically Oriented Channels for Solid-State Lithium Metal Batteries with Nickel-Rich Cathodes.

By introducing lithiophilic groups and electrochemically stable quinolyl aromatic ring linkages, we prepared covalent organic frameworks (COFs) exhibiting a large band gap with an ultralow HOMO value (-6.2 eV under vacuum) and oxidative stability up to 5.6 V (versus Li+ /Li) as solid-state electrolytes (SSEs). The obtained flexible COF SSE thin films showed a holistically oriented arrangement along the (001) facet with remarkable ionic conductivity up to 1.5×10-4 S cm-1 at 60 °C and excellent mechanical strength with a high Young's modulus of 10.5 GPa. Molecular dynamic simulations showed that lithium ions are transmitted in this COF SSE by directional hopping paths with fast drift velocity. The COF SSE film was used to assemble all-solid-state lithium metal batteries with nickel-rich cathodes (NMC811). The batteries demonstrated stable cycling performance over 400 cycles, high coulombic efficiency (>99 %), and could also withstand abuse tests, such as folding.