Resonance Stabilization Research Articles

Design of a Compact Single-Layer Frequency Selective Surface With High Oblique Stability

In this article, a compact single layer band stop frequency selective surface (FSS) with superior resonant stability is presented. The proposed FSS unit comprises of a symmetrically modified square loop. The square loop has been modified in order to increase the perimeter. Moreover, modified square loop is arranged in C4 rotational symmetry to ensure the polarization independence. The designed FSS exhibits highly stable response for the incident angle variation from 0° to 86°. At the resonant frequency of 5.54 GHz, its miniaturized unit cell size is 0.09 <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">λ₀</i> × 0.09 <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">λ₀</i> and the thickness is only 0.007 <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">λ₀</i> . The operating phenomenon of this FSS is explicated by analyzing the equivalent circuit model, electric field and surface current distributions at resonant frequency. A test sample of the designed FSS has been constructed for the validation purpose. The transmission coefficients response of the proposed FSS has been measured and found to be congruent with the simulated responses. The salient features that distinguish the proposed FSS design over others are low complexity, low thickness, compact unit cell and excellent angular stability.

중추 조절의 회복이 뮤지컬 발성에 미치는 영향 연구 - 알렉산더 테크닉을 중심으로 -

The current study aims to examine the effectiveness of central control in the recovery and growth of vocal competencies through efficient vocal training of musical actors. Musica l actors cannot be free from neck strain while they play musical songs that require a wide range of vocal ranges and intense vocals. Based on the theoretical support of the Alexander Technique's primary control that neck-head-body coordination is significant not only for breathing but also for the operation of efficient vocal organs, the dynamic principles were applied to vocalization and the effectiveness was assessed by interviewing 10 university students majoring in musicals and analyzing voiceprint. The results are as follows: Signifi cant changes when the central control was restored were experienced first, as the head came to mind, the pressed larynx, stuffy breathing, and the sense of length, width, and depth of the pressed torso were restored. Second, during voice scale, the movement of the larynx became smooth and expanded, and the vocal range expanded. Third, during Hands-On on the back of the neck, the clearness and resonance of the tone were improved, and the sense of vibrati on was strengthened with a higher effort in the head. In addition, the stability and vibrati on of the body were strengthened, and the stability of pitch and resonance was also experien ced. The results of the study suggest the effectiveness of the Alexander Technique in vocal training as well as proposing basic data for more advanced vocal training programs in the future.

Detection of molecular transitions with nitrogen-vacancy centers and electron-spin labels

We present a protocol that detects molecular conformational changes with two nitroxide electron-spin labels and a nitrogen-vacancy (NV) center in diamond. More specifically, we demonstrate that the NV can detect energy shifts induced by the coupling between electron-spin labels. The protocol relies on the judicious application of microwave and radiofrequency pulses in a range of parameters that ensures stable nitroxide resonances. Furthermore, we demonstrate that our scheme is optimized by using nitroxides with distinct nitrogen isotopes. We develop a simple theoretical model that we combine with Bayesian inference techniques to demonstrate that our method enables the detection of conformational changes in ambient conditions including strong NV dephasing rates as a consequence of the diamond surface proximity and nitroxide thermalization mechanisms. Finally, we counter-intuitively show that with our method the small residual effect of random molecular tumbling becomes a resource that can be exploited to extract inter-label distances.

Impact of electrode conductivity on mass sensitivity of piezoelectric resonators at high temperatures

Abstract. High-temperature stable piezoelectric Ca3TaGa3Si2O14 and La3Ga5SiO14 resonators with keyhole-shaped Pt electrodes are coated with metal oxide films such as TiO2−δ and SnO2 that overlap the Pt electrodes. The resonators are exposed to reducing atmospheres in order to increase the electrical conductivity of the oxide film and then act as extended oxide electrodes. The resulting increase in the effective electrode radius causes an increase in the mass sensitivity of the resonators and, thereby, resonance frequency shifts. In other words, the effective mass of the Pt electrode becomes higher. An electrical circuit model is presented to describe the increase in the effective electrode radius of the resonator, which is used to calculate the related resonance frequency shift. Additionally, an electromechanical model is presented, which subdivides the resonator into two coupled oscillators. One is representing the resonator volume underneath the Pt electrode and the other underneath the oxide electrode at increased electrical conductivity. The model reflects how the oxide electrodes affect the resonance frequency. Furthermore, the impact of increasing oxide electrode conductivity on the resonance frequency is discussed with respect to the application of oxide electrodes and for gas sensing.

A simple and stable chemiluminescence resonance energy transfer system based on Ce(IV)-MOFs for detection of sulfite

Chemiluminescence (CL) is an effective way for designing sulfite (SO32-) sensors. However, the practical application of these sensors was hampered so far due to the poor selectivity or stability of the probes (e.g., KMnO4 and Ce4+). In this work, the Ce(IV)-MOF was fabricated through a simple and time-saving hydrothermal synthetic method. The special structure of Ce(IV)-MOF endowed it with high selectivity and stability in the CL reaction. Based on chemiluminescence resonance energy transfer (CRET) from the luminescent intermediate of the CL system to dyes (Nile blue, and rhodamine B), a simple, stable and sensitive CL sensing platform for SO32- was successfully established. The proposed CL sensing platform with the outstanding CL efficiency hold great potential for detecting SO32- in complex samples. This study not only broadened the application of MOF in CL field, but also provided a new clue for the design of stable CL system and CRET process.

High-resolution resonant portraits of a single-planet white dwarf system

ABSTRACT The dynamical excitation of asteroids due to mean motion resonant interactions with planets is enhanced when their parent star leaves the main sequence. However, numerical investigation of resonant outcomes within post-main-sequence simulations is computationally expensive, limiting the extent to which detailed resonant analyses have been performed. Here, we combine the use of a high-performance computer cluster and the general semi-analytical libration width formulation of Gallardo, Beaugé &amp; Giuppone in order to quantify resonant stability, strength, and variation instigated by stellar evolution for a single-planet system containing asteroids on both crossing and non-crossing orbits. We find that resonant instability can be accurately bound with only main-sequence values by computing a maximum libration width as a function of asteroid longitude of pericentre. We also quantify the relative efficiency of mean motion resonances of different orders to stabilize versus destabilize asteroid orbits during both the giant branch and white dwarf phases. The 4:1, 3:1, and 2:1 resonances represent efficient polluters of white dwarfs, and even when in the orbit-crossing regime, both the 4:3 and 3:2 resonances can retain small reservoirs of asteroids in stable orbits throughout giant branch and white dwarf evolution. This investigation represents a preliminary step in characterizing how simplified extrasolar Kirkwood gap structures evolve beyond the main sequence.

A stable and sensitive Au metal organic frameworks resonance Rayleigh scattering nanoprobe for detection of SO3 2- in food based on fuchsin addition reaction.

A stable Au metal organic frameworks (AuMOF) nanosol was prepared. It was characterized by electron microscopy and molecular spectral techniques. In pH 6.8 PBS buffer solution, AuMOF nanoprobes exhibit a strong resonance Rayleigh scattering (RRS) peak at 330 nm. After basic fuchsin (BF) adsorbing on the surface of AuMOF, the RRS energy of the nanoprobe donor can be transferred to BF receptor, resulting in a decrease in the RRS intensity at 330 nm. Both sulfite and BF taken place an addition reaction to form a colorless product (SBF) that exhibit weak RRS energy transfer (RRS-ET) between AuMOF and SBF, resulting in the enhancement of the RRS peak. As the concentration of SO3 2-increases, the RRS peak is linearly enhanced. Thus, a new and sensitive RRS-ET method for the detection of SO3 2- (0.160-5.00 μmol/L) was developed accordingly using AuMOF as nanoprobes, with a detection limit of 0.0800 μmol/L. This new RRS method was applied to determination of SO3 2- in food and SO2 in air samples. The recoveries of food and air samples were 97.1-106% and 92.9-106%, and the relative standard deviation (RSD) was 2.10-4.80% and 2.10-4.50%, respectively.

Long-Term Organ Function After HCT for SCD: A Report From the Sickle Cell Transplant Advocacy and Research Alliance

Hematopoietic cell transplantation (HCT) is an established cure for sickle cell disease (SCD) supported by long-term survival, but long-term organ function data are lacking. We sought to describe organ function and assess predictors for dysfunction in a retrospective cohort (n=247) through the Sickle cell Transplant Advocacy and Research alliance. Patients with <1-year follow-up or graft rejection/second HCT were excluded. Organ function data were collected from last follow-up. Primary measures were organ function, comparing pre- and post-HCT. Bivariable and multivariable analyses were performed for predictors of dysfunction. Median age at HCT was 9.4 years; the majority had HbSS (88.2%) and severe clinical phenotype (65.4%). Most received matched related (76.9%) bone marrow (83.3%) with myeloablative conditioning (MAC; 57.1%). Acute and chronic graft-versus-host disease (GVHD) developed in 24.0% and 24.8%. Thirteen patients (5.3%) died ≥1 year after HCT, primarily from GVHD or infection. More post-HCT patients had low ejection or shortening fractions than pre-HCT (0.6%→6.0%, P=.007 and 0%→4.6%, P=.003). The proportion with lung disease remained stable. Eight patients (3.2%) had overt stroke; most had normal (28.3%) or stable (50.3%) brain magnetic resonance imaging. On multivariable analysis, cardiac dysfunction was associated with MAC (odds ratio [OR]=2.71; 95% confidence interval [CI], 1.09-6.77; P=.033) and severe acute GVHD (OR=2.41; 95% CI, 1.04-5.62; P=.041). Neurologic events were associated with central nervous system indication (OR=2.88; 95% CI, 2.00-4.12; P < .001). Overall organ dysfunction was associated with age ≥16 years (OR=2.26; 95% CI, 1.35-3.78; P=.002) and clinically severe disease (OR=1.64; 95% CI, 1.02-2.63; P=.043). In conclusion, our results support consideration of HCT at younger age and use of less intense conditioning.

Stretchable three-dimensional tunable frequency selective fabric of U-shaped units and its electromagnetic response mechanism

Three-dimensional frequency selective fabric, based on textile or textile composite materials, is formed by adding another dimension in the longitude along the two-dimensional (2D) plane, and has the characteristics of miniaturization and multi-resonant frequency compared to the traditional 2D frequency selective fabric. In this paper, tunable three-dimensional frequency selective fabric (3D TFSF) forming a U-shaped array is proposed. The U-shaped unit is composed of two velvets and a dipole at the bottom. Through analysis of the physical samples, the geometric model of the 3D TFSF stretched along the x-axis and the y-axis during the stretching process was established. The velvets of the 3D TFSF were studied in both oblique and upright states during stretching. The 3D TFSF has good tunability, while the velvets remain upright when stretched, and it has the characteristics of stable resonance frequency under small strain and adjustable resonance frequency under large strain. By stretching, because the shape and size of the U-shaped conductive units can be changed, the equivalent inductance ( L) and capacitance ( C) of 3D TFSF can change during stretching to realize the tuning of resonant frequency. The 3D TFSF offers more design freedom and possibilities. Significant effects of wave absorption or selective filtering by the periodic structure can be achieved by regulating the structural parameters and material parameters together.

Design of miniaturize flexible wideband frequency selective surface for electromagnetic shielding application

In this paper, a flexible, ultra-thin, miniaturized broadband frequency selective surface (FSS) is demonstrated for wideband electromagnetic shielding application. The unit cell of the proposed FSS structure consists of cross dipoles loaded with the metallic circular strip. The proposed miniaturized FSS structure has an extremely low profile with a thickness of and a unit cell size of . This FSS structure provides wideband shielding of more than 20 dB from 1.1 to 2.6 GHz frequency region. Besides this wide stopband, the FSS structure acts as a transparent window in the frequency band which can be used for the 5G communication purpose. Moreover, by comprehending the interaction between the incident electromagnetic wave and unit cell, a conceptual equivalent circuit model is developed that helps to interpret the mechanism of the miniaturization as well as the broadband response of FSS structure. We also compared the proposed FSS with other recently reported structures and observed more than 55% improvement in size reduction with several other miniaturized flexible FSS structure. Furthermore, this FSS structure exhibits 20 dB attenuation over a wide frequency region with a fractional bandwidth of 111%. Moreover, excellent resonant stability is achieved in regards to different polarization and incident angle up to .

Unmanned airborne miniaturized pulsed CO2 laser with wavelength automatic tuning

This paper presents a miniaturized mechanically Q-switched pulsed CO2 laser with wavelength automatic tuning, which could be used in unmanned airborne lidar system. A three-mirror cavity structure with real focus in the cavity is designed to provide a stable resonator, which has short beam transit time for mechanically Q-switched laser. The matching relationship between the beam in the resonant cavity and the aperture of the optical chopper is experimentally studied, the CO2 laser pulse output with good waveform is obtained, and the wavelength automatic tuning is realized. The CO2 laser produces a maximum output peak power of 3.7 kW at 10.59 μm for pulse width of 350 ns, corresponding beam quality M2 of 1.75, and the laser weight is about 18 kg.

The COVID-19 pandemic as a consequence of sustainable changes in the planet’s biosphere

The pandemic caused by the SARS-CoV-2 virus has demonstrated the development of new global biological, biophysical and epidemiological processes able to change human environment and cause signifi cant demographic, social and economic consequences. The explanation of the pandemic as caused by accidental transmission of the virus from animal to human does not seem convincing and does not correspond to the scale of the planetary biological shifts that have occurred as a result of the pandemic. The authors of the article develop a hypothesis that links the causes of the COVID-19 pandemic with global environmental problems and damages of the biocoenosis of large ecosystems on the planet. The disastrous reduction of forest areas throughout the continents has led to a growing disproportion of the plant kingdom, animals and the expansion of viruses in biosphere. The mechanism of viral infections propagation has changed under conditions of violation of the stability of the biocoenosis and the fi lling of large ecosystems with viruses. Along with the traditional methods of infection transmission from person to person, the physical features of viruses and their correlations to the nanoworld have become signifi cantly important. Literature data and the results of our own research suggest that viruses have wave properties and are capable of creating stable resonance systems and an electromagnetic fi eld. Presumably, the energy of the electromagnetic fi eld determines the mechanism for filling ecosystems with viruses, “competitive relations” with other representatives of the microcosm, and the process of self-limitation of viral expansion. The article for the first time touches upon the issues of the interaction of viruses within the framework of viral and viral-bacterial microbiocenosis, the persistence of viruses in the human body and the development of chronic diseases. The study of the mechanisms of virus expansion, the patterns of emergence and contagion suggests newopportunities for understanding the nature of new viral infections and the development of methods to resist them.

Dearomative Aminocarbonylation of Arenes via Bifunctional Coordination to Chromium.

Amides are ubiquitous in physical and life sciences. Given the significant abundance of arenes, dearomative aminocarbonylation of arenes would lead to a large and underexplored chemical space for amide discovery. However, such reactions are challenging due to the high degree of resonance stabilization and selectivity issues. Herein, we disclose an unprecedented dearomative trifluoromethylative aminocarbonylation of arenes via bifunctional coordination to chromium, providing a modular platform for the construction of amides possessing trifluoromethyl (CF3 ) groups and three-dimensional rings. Its versatility further enabled a switchable difluoromethylation or trifluoromethylation aminocarbonylation of arene C-H bonds. A possible mechanism was proposed based on control experiments. Finally, the synthetic utility was well demonstrated by diverse applications in the total synthesis of CF3 -functionalized amide-type drugs, including praziquantel, nateglinide, maraviroc and alloyohimbane.

Dearomative Aminocarbonylation of Arenes via Bifunctional Coordination to Chromium

AbstractAmides are ubiquitous in physical and life sciences. Given the significant abundance of arenes, dearomative aminocarbonylation of arenes would lead to a large and underexplored chemical space for amide discovery. However, such reactions are challenging due to the high degree of resonance stabilization and selectivity issues. Herein, we disclose an unprecedented dearomative trifluoromethylative aminocarbonylation of arenes via bifunctional coordination to chromium, providing a modular platform for the construction of amides possessing trifluoromethyl (CF3) groups and three‐dimensional rings. Its versatility further enabled a switchable difluoromethylation or trifluoromethylation aminocarbonylation of arene C−H bonds. A possible mechanism was proposed based on control experiments. Finally, the synthetic utility was well demonstrated by diverse applications in the total synthesis of CF3‐functionalized amide‐type drugs, including praziquantel, nateglinide, maraviroc and alloyohimbane.

Dynamic characteristics analysis of magnetorheological semi-active vibration isolator with high-static-low-dynamic stiffness

High static and low dynamic stiffness vibration isolators have the advantages of high load-bearing capacity and small static displacement, but their negative stiffness components will cause a jump phenomenon at the resonance frequency. A semi-active vibration isolator with high-static-low-dynamic stiffness based on magnetorheological (MR) damper is proposed. The equivalent dynamic model of the MR semi-active vibration isolator is established, and the main resonance steady solution and stability conditions of the vibration isolation system are obtained using the average method. The influences of the basic excitation amplitude, excitation frequency, coulomb force, viscous damping coefficient, load-bearing mass, nonlinear elastic force coefficient and linear elastic force coefficient on the stability and performance of vibration isolation systems are analyzed. The results will provide a certain theoretical basis for the design of semi-active control strategies.

Bubble Templated Flexible Ceramic Nanofiber Aerogels with Cascaded Resonant Cavities for High-Temperature Noise Absorption.

Aviation noise pollution has become a significant public health problem, especially with the endless improvement of flight speed and loading capacity. Existing aviation noise absorbers have fatal defects of large weight, weak high-temperature stability, and difficulty to achieve both good low-frequency (<1000 Hz) and high-frequency (up to 6000 Hz) noise absorption simultaneously. Herein, we report a robust strategy to create flexible ceramic nanofiber aerogels with cascaded resonant cavities by the air bubbles-assisted freeze-casting technology. The stable hinged resonance cavity structures coassembled by flexible ceramic nanofibers, soft montmorillonite nanosheets, and silica sol glue endow the aerogels with temperature-invariant compressibility (from -196 to 1100 °C) and bendability. Moreover, the comprehensive advantages of cascaded resonance cavities and interconnected fibrous networks enable flexible ceramic nanofiber aerogels to have temperature-invariant full-frequency noise absorption performance (noise reduction coefficient up to 0.66 in 63-6300 Hz). The synthesis of this flexible ceramic nanofiber aerogel provides a versatile platform for the design of high-efficiency noise-absorbing material for various fields.

A criterion for the stability of planets in chains of resonances

Uncovering the formation process that reproduces the distinct properties of compact super-Earth exoplanet systems is a major goal of planet formation theory. The most successful model argues that non-resonant systems begin as resonant chains of planets that later experience a dynamical instability. However, both the boundary of stability in resonant chains and the mechanism of the instability itself are poorly understood. Previous work postulated that a secondary resonance between the fastest libration frequency and a difference in synodic frequencies destabilizes the system. Here, we use that hypothesis to produce a simple and general criterion for resonant chain stability that depends only on planet orbital periods and masses. We show that the criterion accurately predicts the maximum mass of planets in synthetic resonant chains up to six planets. More complicated resonant chains produced in population synthesis simulations are found to be less stable than expected, although our criterion remains useful and superior to machine learning models.

Design, synthesis, in silico ADME/T profiling of pseudo-pyrimidine derivatives and anticancer activity evaluation

Pyrimidines are aromatic heterocyclic nitrogenous bases predominantly present as integral building blocks of DNA and RNA. The alternating single and double bonds connecting the C and N atoms in these 6-membered heterocyclic rings confer them to resonance, aromaticity and exceptional stability. The prevalence of pyrimidine derivatives in nucleic acids, vitamins, amino acids, antibiotics, alkaloids and several reported bioactive compounds promoted investigation of their novel biological roles which eventually demonstrated a plethora of medicinal advantages of the pyrimidine scaffold by virtue of its synthetic versatility. In this research work, we aim to explore the anticancer activity of various substituent derivatives of thiopyrimidines and present them as a novel, potential anti-cancer strategy. A series of novel disubstituted derivatives of thiopyrimidine were designed and synthesized [Fig. 1]. Further, the promising results of in vitro biological assays conclusively indicate their anti-cancer potential.

Synthesis and preclinical application of a Prussian blue-based dual fluorescent and magnetic contrast agent (CA).

The aim of this study was to develop and characterize a Prussian Blue based biocompatible and chemically stable T1 magnetic resonance imaging (MRI) contrast agent with near infrared (NIR) optical contrast for preclinical application. The physical properties of the Prussian blue nanoparticles (PBNPs) (iron (II); iron (III);octadecacyanide) were characterized with dynamic light scattering (DLS), zeta potential measurement, atomic force microscopy (AFM), and transmission electron microscopy (TEM). In vitro contrast enhancement properties of PBNPs were determined by MRI. In vivo T1-weighted contrast of the prepared PBNPs was investigated by MRI and optical imaging modality after intravenous administration into NMRI-Foxn1 nu/nu mice. The biodistribution studies showed the presence of PBNPs predominantly in the cardiovascular system. Briefly, in this paper we show a novel approach for the synthesis of PBNPs with enhanced iron content for T1 MRI contrast. This newly synthetized PBNP platform could lead to a new diagnostic agent, replacing the currently used Gadolinium based substances.

Green photoreduction synthesis of dispersible gold nanoparticles and their direct in situ assembling in multidimensional substrates for SERS detection.

Gold nanoparticles (AuNPs) and their composites have been applied in surface-enhanced Raman scattering (SERS) detection methods, owing to their stable and excellent surface plasmon resonance. Unfortunately, methods for synthesizing AuNPs often require harsh conditions and complicated external steps. Additionally, removing residual surfactants or unreacted reductants is critical for improving the sensitivity of SERS detection, especially when employing AuNPs-assembled multidimensional substrates. In this study, we propose a simple and green method for AuNPs synthesis via photoreduction, which does not require external surfactant additives or stabilizers. All the processes were completed within 20min. Along this way, only methanol was employed as the electron acceptor. Based on this photoreduction synthesis strategy, AuNPs can be directly and circularly assembled in situ in multidimensional substrates for SERS detection. The removal of residual methanol was easy because of its low boiling point. This strategy was employed for the preparation of three different dimensional SERS substrates: filter paper@AuNPs, g-C3N4@AuNPs, and MIL-101(Cr)@AuNPs. The limit of detection of filter paper@AuNPs for thiabendazole SERS detection was 1.0 × 10-7mol/L, while the limits of detection of g-C3N4@AuNPs and MIL-101(Cr)@AuNPs for malachite green SERS detection were both 5.0 × 10-11mol/L. This strategy presents potential in AuNP doping materials and SERS detection.