ABSTRACTBy using 4,4′-dihydroxydiphenylsulfone (BPS) and 4,4′-dihydroxydiphenylsulfide (BTS) react with amidinethiourea and tetrabutylammonium respectively, two isomorphs of inclusion compounds of (n-C4H9)4N+·C12H9O4S−·C2H4N4S (1) and (n-C4H9)4N+·C12H9O2S−·C2H4N4S (2) were prepared and characterized by Single crystal X-ray diffraction. Although two varied types of V-shaped molecules were selected to react in the actual experimental process, two isomorphs with similar packing modes were finally obtained. Interestingly, amidinothiourea molecule occurred in situ oxidation reaction to generate a new compound of 3,5-dimido-1,2,4,-thiadiazole during the experiments, and these two inclusion compounds here are the pioneer examples of thiadiazole and tetraalkylammonium and can be regarded as two isomorphs due to their similar crystallization modes. In these two isomorphs, thiadiazole molecules derived from amidinothiourea link with various V-type molecules to develop the similar dumbbell-type hydrogen-bonded ribbons by the alike hydrogen bonding modes, then the ribbons interpenetrate with tetrabutylammonium to result in two stable isomorphism structures.
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