Tungsten is generally too brittle to serve a robust structural function. Here, we explore the fracture toughness of 90 to 97%W (by wt.) liquid phase sintered tungsten heavy alloys (WHAs). The room temperature (RT) maximum load fracture toughness (KIc or KJm ≈ 38 to 107 MPa√m) of WHA, containing only 3 to 10 wt.% of a NiFe-based ductile phase (DP), is ≈ 5 to 13 times higher than KIc typical of monolithic W (≈ 8 MPa√m). RT tests for a range of precracked bend bar sizes generally show extensive stable ductile tearing (DT), except in the case of the 97 wt.%W alloy, where elastic fracture occurs in all but the smallest specimen tests. Nevertheless, even in this case the KIc = 38 ± 4 MPa√m, which is still almost 5 times higher than that for monolithic W. Tests with the smallest specimens down to -196°C, to partially emulate irradiation hardening, show decreasing toughness and a transition to elastic fracture at a temperature of -150°C for 90W to -25oC for 97W. However, even at -196°C, the 97W KIc is ≈ 3 times that of monolithic W at RT. In contrast to classical ductile phase toughening by macrocrack bridging, WHA toughening mainly involves new mechanisms associated with arrest, blunting and bridging of numerous dilatationally shielding process zone microcracks.
Read full abstract