Stabilization Process Research Articles

The Use of Spectroscopic Methods to Study Organic Matter in Virgin and Arable Soils: A Scoping Review

The use of modern spectroscopic methods of analysis, which provide extensive information on the chemical nature of substances, significantly expands our understanding of the molecular composition and properties of soil organic matter (SOM) and its transformation and stabilization processes in various ecosystems and geochemical conditions. The aim of this review is to identify and analyze studies related to the application of nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR) spectroscopy techniques to study the molecular composition and transformation of organic matter in virgin and arable soils. This article is mainly based on three research questions: (1) Which NMR spectroscopy techniques are used to study SOM, and what are their disadvantages and advantages? (2) How is the NMR spectroscopy technique used to study the molecular structure of different pools of SOM? (3) How is ESR spectroscopy used in SOM chemistry, and what are its advantages and limitations? Relevant studies published between 1996 and 2024 were searched in four databases: eLIBRARY, MDPI, ScienceDirect and Springer. We excluded non-English-language articles, review articles, non-peer-reviewed articles and other non-article publications, as well as publications that were not available according to the search protocols. Exclusion criteria for articles were studies that used NMR and EPR techniques to study non-SOM and where these techniques were not the primary methods. Our scoping review found that both solid-state and solution-state NMR spectroscopy are commonly used to study the structure of soil organic matter (SOM). Solution-phase NMR is particularly useful for studying soluble SOM components of a low molecular weight, whereas solid-phase NMR offers advantages such as higher 13C atom concentration for stronger signals and faster analysis time. However, solution-phase NMR has limitations including sample insolubility, potential signal aggregation and reduced sensitivity and resolution. Solid-state NMR is better at detecting non-protonated carbon atoms and identifying heterogeneous regions within structures. EPR spectroscopy, on the other hand, offers significant advantages in experimental biochemistry due to its high sensitivity and ability to provide detailed information about substances containing free radicals (FRs), aiding in the assessment of their reactivity and transformations. Understanding the FR structure in biopolymers can help to study the formation and transformation of SOM. The integration of two- and three-dimensional NMR spectroscopy with other analytical methods, such as chromatography, mass spectrometry, etc., provides a more comprehensive approach to deciphering the complex composition of SOM than one-dimensional techniques alone.

Bright solitons and interaction in the higher-order Gross-Pitaevskii equation investigated with Hirota's bilinear method

In this paper, we investigate bright solitons and their interactions in trapless Bose-Einstein condensate described by a one-dimensional Gross-Pitaevskii equation in the presence of higher-order nonlinearity. By constructing appropriate Hirota bilinear form of the problem, we derive the one- and two-bright soliton solutions where the effects of the higher-order interaction term are discussed in details. The profile of different solutions obtained clearly presents the phenomenon of soliton interaction that embodies the properties of soliton. It also highlights the impact of higher-order interactions that plays the role of wave amplification/compression resulting from the condensate. The theoretical results confirm that Hirota bilinear method is an efficient and interesting tool for the analysis of nonlinearity in physical science. In addition, the higher-order interactions have significant effects on the stabilization process of Bose-Einstein condensates.

Lignin-based carbon fibres: Effect of bio-polyamide on oxidative thermal stabilisation of lignin

Carbon fibres have been produced from hydroxypropyl-modified lignin (TcC)/bio-based polyamide 1010 (PA1010) blended filaments. Two grades of PA1010, with different molecular weights and rheological properties, were used for blending with TcC. An oxidative thermal stabilisation step was used prior to carbonisation in an inert atmosphere to prevent the fusion of the filaments during the latter step. Thermal stabilisation was not possible using a one-step stabilisation process reported in the literature for lignin and other lignin/synthetic polymer blends. As a consequence, a cyclic process involving an additional isothermal phase at a lower temperature than the precursor filaments’ melting point, was introduced to increase the cross-linking reactions between the lignin and polyamide. Thermally stabilised filaments were characterised by DSC, TGA, TGA-FTIR, ATR, and SEM techniques. Polymer rheology and heating rate used during thermal stabilisation influenced the thermal stabilisation process and mechanical properties of the derived filaments. Thermally stabilised filaments using optimised conditions (heating in the air atmosphere at 0.25 °C/min to 180 °C; isothermal for 1 h, cooling back down to ambient at 5 °C/min; heating to 250 °C at 0.25 °C/min, isothermal for 2 h) could be successfully carbonised. Carbon fibres produced had void-free morphologies and mechanical properties comparable to similarly thermally stabilised and carbonised polyacrylonitrile (PAN) filaments.

A drug–drug cocrystal strategy to regulate stability and solubility: A case study of temozolomide/caffeic acid

Temozolomide (TMZ) is a common clinical drug widely used to treat glioblastoma multiforme and gradual astrocytoma. Despite its widespread use in cancer treatment, issues remain with the solubility and stability of TMZ, which can be addressed by synthesizing novel pharmaceutical cocrystals. This study sought to enhance the physiochemical properties of TMZ. To this end, a pioneering pharmaceutical cocrystal of TMZ and caffeic acid (CAF), 2TMZ–CAF·0·5H2O (2:1:0.5) was synthesized and characterized using a solution method. The cocrystal structure was analyzed by molecular surface electrostatic potential (MESP), Hirshfeld surface analysis, and 2D fingerprinting. They were further characterized by single crystal X-ray diffraction, power X-ray diffraction, proton nuclear magnetic resonance, thermogravimetry-differential scanning calorimetry, dynamic vapor sorption, and Fourier transform infrared spectroscopy. Furthermore, the hygroscopicity, stability, and solubility of the TMZ–CAF cocrystal were investigated to evaluate their pharmaceutical applicability. In the asymmetric unit of the novel synthesized cocrystal, two complementary molecules of TMZ and CAF were found, forming planar hydrogen bonding pairs such as O–H···O, N–H···O, and O–H···N. Moreover, the cocrystals exhibited excellent stability compared to TMZ alone and regulated solubility during accelerated stabilization and dissolution processes. Hence, the cocrystals boast characteristics that can circumvent the rapid release of TMZ. In conclusion, the newly synthesized 2TMZ–CAF·0·5H2O cocrystals demonstrate enhanced physiochemical properties, including improved stability and solubility, compared to pure TMZ. This suggests potential utility in drug delivery systems. Additionally, the findings underscore the growing importance of pharmaceutical cocrystals in drug development, with implications for advancing cancer treatment and drug formulation strategies.

Stabilization of micaceous residual soil with industrial and agricultural byproducts: Perspectives from hydrophobicity, water stability, and durability enhancement

Micaceous residual soil is prevalent in the tropical regions of southern China. However, it is generally deemed unsuitable as a construction material in earthen structures due to its inferior engineering properties. Despite previous research into stabilizing micaceous soils, there remains an urgent demand for sustainable alternatives to traditional stabilizers to achieve circularity. Furthermore, uncertainties regarding the long-term performance of stabilized soils under hydraulic conditions complicated their use in flood-susceptible areas. To provide a sustainable and low-cost solution for creating stabilized soil for earthen structures in waterlogged regions, this study explores the impact of coir fiber and fly ash, agricultural and industrial byproducts, on the hydrophobicity, durability, and water stability of micaceous residual soil from Hainan, China. The study commenced with the preliminary mechanical tests to ascertain the optimal dosage of coir fiber and fly ash, which were determined to be 1% and 15%, respectively. Then, hydrophobicity, durability, and disintegration tests are conducted on fiber-reinforced fly-ash-treated soil under various stabilization conditions. The microstructural evolution of the soil fabric in response to the stabilization process was meticulously traced using scanning electron microscopy and energy-dispersive spectroscopy. Results indicated that the addition of fly ash could impart severe and persistent water repellency to the studied soil, with the contact angle improving from 16.7° to 102.9°, and the water drop penetration time significantly extending from 3.6 s to approximately 600 s. While incorporating coir fibers into the cemented soil presented negligible improvement on soil hydrophobicity, it markedly enhanced the soil’s durability, mitigated moisture-related deterioration and decelerated disintegration. Notably, the strength residual ratio of fiber-reinforced cemented sample maintained higher than 90% even after 20-day water immersion, and the disintegration rate decreased by 57% compared to unreinforced sample. Microstructural analysis revealed that bonding, friction, and interlocking among fibers, hydration products, and soil particles are the main contributors to the stable and robust matrix, ensuring improved mechanical behavior and longevity of micaceous residual soil. This study provides an innovative method for utilizing waste byproducts in stabilizing micaceous residual soil, as a viable option for earthworks in rain-soaked or flood-prone areas.

Dynamic exploration of laser linewidth compression in resonant feedback external-cavity laser

An external-cavity laser with resonant optical feedback is a common and mature method to achieve narrow linewidth lasers. Since the proposal of optical feedback in 1964, a series of studies on resonant optical feedback have been reported. Although longer feedback length leads to narrower linewidth, it also introduces coupling of environmental noise and causes instability in the laser cavity, which is detrimental to high-speed tuning of the laser wavelength. With such a challenge, current research on resonant optical feedback primarily focuses on the static results of laser linewidth compression. In order to obtain narrow linewidth high-speed tuned external-cavity lasers, further research on the laser dynamics is required to obtain dynamic tuning of narrow linewidth external-cavity lasers. In this work, we construct an external-cavity laser based on resonant optical feedback, and utilize a coherent detection method to measure the dynamic process of laser linewidth compression and wavelength tuning. Based on resonant optical feedback from the external cavity, the linewidth of the main-cavity laser can be compressed from near 100 kHz to the 100 Hz level, with the frequency noise compressed from the order of 104 to the 102 Hz2/Hz level. Since the wavelength switching process includes frequency shift process, linewidth compression process, and frequency stabilization process, etc., we first conduct a research on laser linewidth compression dynamics. In the results of linewidth compression dynamics, we discover that using a shorter fiber ring results in shorter linewidth compression time, which is advantageous for laser dynamic tuning. We subsequently carry out the laser wavelength switching process with a main-cavity switching time in milliseconds. In the wavelength switching process, while undergoing the frequency shift process of fast tuning transient laser frequency, the laser first undergoes the linewidth broadening process, then enters the main-cavity laser frequency stabilization process and undergoes the linewidth compression process at the same time. The experimental results show that the 100 m feedback fiber ring will not significantly increase the external-cavity laser wavelength switching time under the condition that linewidth compression is faster than main-cavity laser switching, while a longer fiber ring will introduce a strong noise. Our work experimentally demonstrates that shorter feedback ring lengths lead to faster compression, which provides valuable insights for the development of high-speed and high-precision tunable narrow linewidth external-cavity lasers.

Co-composting of green waste and biogas waste: physical, chemical parameters and quality of ripe compound.

The impact of adding biogas waste (BW) to green waste (GW) composting to increase nitrogen supplementation and improve mature compost quality was investigated. Conducted over 90days using static windrows, the experiment compared treatments with GW alone (T1) and GW supplemented with BW (T2 and T3). The results showed that the addition of BW increased temperatures, improved the C/N ratio, and expedited the stabilization process compared to T1. Furthermore, the addition of BW led to significant degradation of hemicellulose (up to 39.98%) and cellulose (up to 27.63%) compared to GW alone. Analysis of Fourier-transform infrared (FTIR) spectra revealed the presence of aromatic, phenolic, aliphatic, and polysaccharide structures in the compost, with BW supplementation enhancing these characteristics. Importantly, the germination index (GI) assessment indicated that the compounds produced were not toxic and instead exhibited stimulatory effects on seed germination. Overall, the findings suggest that supplementing GW composting with BW can enhance the quality and efficacy of the composting process, resulting in compost with desirable properties for agricultural use.

Adaptive PMSM Control of Ship Electric Propulsion with Energy-Saving Features

Electric ship propulsion is considered one of the most promising alternatives to conventional combustion systems. Its goal is to reduce the carbon footprint and increase a ship’s maneuverability, operational safety, and reliability. The high requirements for ship propulsion make permanent magnet synchronous motors (PMSMs) an attractive solution due to their characteristics. This paper discusses the control problem of a PMSM based on the input–output feedback linearization method combined with the optimal and adaptive control techniques. The method presented here integrates the parameter tuning process with the optimal design of the baseline controller. Since the load disturbances are treated as an additional unknown parameter, there is no need to introduce an integral action to deal with the resulting steady-state error. An important feature of the designed controller is the so-called energetic optimization of the system; i.e., in addition to the aforementioned adaptive and optimal controller, it has a feature of ensuring zero reactive power consumed by the system. The performed simulations of the machine speed stabilization process confirmed the high efficiency of the proposed controller despite the assumed uncertainty of the system parameters and environmental (load) disturbances. Besides achieving high-quality control, an essential feature of this approach is the elimination of the tuning problem.

Soft Clay Modified with Municipal Solid Waste and Stabilized with Nano-MgO for Pavement Subgrade and Embankment Fill Applications

Municipal solid waste (MSW) is the largest group of non-hazardous waste. Four percentages of MSW replacement (15 %, 25 %, 35 %, and 45 % by weight) were used for chemical modification of soft clay at 1, 14, and 28 days of curing. The MSW replacement at optimum (15 % and 25 %) to the clay enhanced unconfined compressive strength (UCS) and California bearing ratio (CBR) by 1.28 and 3.34 times, respectively. Also, the nanomagnesium (Nano-MgO) was used as an additive at small contents i.e., 0.25, 0.5, 0.75, and 1 % to improve the mechanical properties of MSW-soft clay blends. The optimum MSW replacement ratios with 1 % Nano-MgO significantly improves UCS and CBR of the soft clay when compared to clay stabilized with 1 % Nano-MgO. The UCS and CBR improvement mechanism was investigated via microstructural analysis of the MSW-soft clay stabilized with Nano-MgO. The improved structure of stabilized specimens was found to be due to flocculation, cation exchange, and cementation bond formation with brucite mineral. However, the X-ray diffraction tets results indicated the presence of the Palygorskite mineral in the specimen containing very high MSW replacement ratio, which retarded the Nano-MgO stabilization process. At optimum MSW replacement ratio (15 % and 25 %), Nano-MgO could effectively improve mechanical properties of soft clay for sustainable road construction.

Contemporary Views of the Extraction, Health Benefits, and Industrial Integration of Rice Bran Oil: A Prominent Ingredient for Holistic Human Health.

Globally, 50% of people consume rice (Oryza sativa), which is among the most abundant and extensively ingested cereal grains. Rice bran is a by-product of the cereal industry and is also considered a beneficial waste product of the rice processing industry. Rice bran oil (RBO) is created from rice bran (20-25 wt% in rice bran), which is the outermost layer of the rice kernel; has a lipid content of up to 25%; and is a considerable source of a plethora of bioactive components. The main components of RBO include high levels of fiber and phytochemicals, including vitamins, oryzanols, fatty acids, and phenolic compounds, which are beneficial to human health and well-being. This article summarizes the stabilization and extraction processes of rice bran oil from rice bran using different techniques (including solvent extraction, microwaving, ohmic heating, supercritical fluid extraction, and ultrasonication). Some studies have elaborated the various biological activities linked with RBO, such as antioxidant, anti-platelet, analgesic, anti-inflammatory, anti-thrombotic, anti-mutagenic, aphrodisiac, anti-depressant, anti-emetic, fibrinolytic, and cytotoxic activities. Due to the broad spectrum of biological activities and economic benefits of RBO, the current review article focuses on the extraction process of RBO, its bioactive components, and the potential health benefits of RBO. Furthermore, the limitations of existing studies are highlighted, and suggestions are provided for future applications of RBO as a functional food ingredient.

Enhanced Soil Carbon Stability through Alterations in Components of Particulate and Mineral-Associated Organic Matter in Reclaimed Saline–Alkali Drainage Ditches

Soil carbon content and stability are primarily influenced by the stabilization of particulate organic matter (POM) and mineral-associated organic matter (MAOM). Despite extensive research on the stabilization processes of POM and MAOM carbon components under various land-use types, the investigation into stabilization processes of soil carbon remains limited in saline–alkali soils. Therefore, we collected soil samples from different positions of saline–alkali drainage ditches at four reclamation times (the first, seventh, fifteenth, and thirtieth year) to determine their carbon content and physicochemical properties. Moreover, POM and MAOM fractions were separated from soil samples, and Fourier transform infrared spectra (FTIR) were used to investigate changes in their chemical composition. The results showed that with increasing reclamation time, the soil total carbon and soil organic carbon (SOC) contents significantly increased from 14 to 15 and 2.9 to 5.5 g kg−1, respectively. In contrast, soil inorganic carbon content significantly decreased from 11 to 9.6 g kg−1. Notably, the changes in soil carbon components following the increasing reclamation time were primarily observed in the furrow sole at a depth of 20–40 cm. While the SOC content of the POM fraction (SOCPOM) decreased significantly, the SOC content of the MAOM fraction (SOCMAOM) increased significantly. These alterations were largely dominated by drainage processes after reclamation instead of a possible conversion from SOCPOM to SOCMAOM. FTIR results revealed that MAOM was greatly influenced by the reclamation time more than POM was, but the change in both POM and MAOM contributed to an increase in soil carbon stability. Our findings will deepen the comprehension of soil carbon stabilization processes in saline–alkali drainage ditches after reclamation and offer a research framework to investigate the stability processes of soil carbon components via alterations in POM and MAOM fractions.

Utilization of waste rubber tyre in soil stabilization

This paper explores the feasibility and benefits of utilizing waste rubber tyre for soil stabilization purpose.With the growing environmental concern surrounding waste tyre disposal, repurposing them for soil stabilization presents a sustainable solution. Added amount of rubber tyre had been varied in proportions of 10%, 15%, 20% and 25%.Waste rubber tyre helps in improving the desired properties of soil and minimizes the amount of waste to be deposited in environment causing environmental pollution. Rubber tyres are cost effective and is quite easily available, due to day by day increase in cost of stabilizers like cement, lime and other admixtures;use of shredded rubber tyre can result in project completion optimally. The soil sample used is clay, thus being highly plastic it is required to be strengthened by using varying proportion of shredded rubber tyre. The effect of shredded rubber tyre on soil is analysed by conducting various tests that governs the basic properties of soil and the obtained result shows that increasing the percentage of shredded rubber tyre results in enhancement in desired soil properties.Increase specific gravity, increase liquid limit, and decrease plastic limit are achieved through the incorporation of appropriate additives in soil stabilization processes. Key Word: Waste rubber tyre, Soil stabilization, Tyre recycling, shredded rubber tyre, Engineering properties, clay soil.

Engineering ZIF-67 loaded nanofibrous membrane with thermal stabilization treatment for efficient photocatalytic CO2 reduction

The photocatalytic Metal-organic frameworks (MOFs) membrane addresses challenges faced by MOF powders in practical applications such as aggregation and difficult recovery, but its current application is mainly confined to wastewater treatment. Expanding the application of MOFs membranes to CO2 reduction could unleash their greater potential in energy conversion and storage field. In this study, ZIF-67 was deposited on polyacrylonitrile (PAN) nanofiber membranes (NFMs) using an in-situ growth technique, followed by thermal stabilization to produce SZIF-67/PAN NFMs for photocatalytic CO2 reduction. ZIF-67 was uniformly and densely distributed on the NFMs, with a mass loading of up to 8 wt%. The thermal stabilization process significantly enhanced the photothermal conversion capability and solvent resistance of the NFMs, enabling SZIF-67/PAN NFMs to exhibit outstanding photocatalytic activity even under mild environmental conditions, with a remarkable CO generation rate of 39,250 μmol g−1h−1. Furthermore, the performance remained at 70 % even after five consecutive tests. This study presents a novel and effective method for preparing MOF NFMs with excellent photocatalytic CO2 reduction performance, offering valuable insights for advancing the practical application of MOF materials.

SIMULATION OF TRANSIENT PROCESSES IN THE STABILIZATION SYSTEM OF DARRIEUS WIND TURBINE ROTOR ROTATIONS

In the work, the simulation of transient processes of the rotor speed system stabilization of vertical-axis wind turbines, controlled by changes of the blade length, is carried out. It is proved that real roots of the characteristic equation of a closed system with the proportional-integral law of feedback leads to a significantly longer length of transient processes than with complex-connected roots.

Statistical reanalysis of Archean zircon paleointensities: No evidence for stagnant-lid tectonics

The initiation of mobile-lid plate tectonics on Earth represented a critical transition towards a more familiar world in terms of surface temperature stabilization, biogeochemical cycling, topography creation, and other processes. Zircon-based estimates of the geomagnetic field intensity have recently been cited as providing evidence for the lack of mobile-lid motion between 3.9 and 3.4 billion years ago (Ga). We reanalyze the published dataset of 91 zircon paleointensities from the Jack Hills (Australia) and Green Sandstone Bed (GSB; South Africa) localities within this time interval and, using both analytical and bootstrap resampling approaches, show that the small number of samples result in large uncertainties in implied paleolatitude. Specifically, in more likely scenarios that do not assume coherent motion for both localities, all latitudinal displacements on Earth are permitted within the 95 % confidence interval. We also examine the less likely scenario that the two landmasses shared a motion history, which increases the data density and presents the best-case scenario for constraining latitudinal motion. In this case, the 95 % confidence interval of the zircon paleointensity data is compatible with the displacements of between 35 % and 52 % of modern continental localities, all of which experience mobile-lid tectonics. Finally, generating expected paleointensity time series for modern continents undergoing mobile-lid motion shows that about two-thirds of these motions would not be resolved by zircon paleointensities, even in the best-case scenario of combining Jack Hills and GSB datasets. All of these analyses assume that these zircons retain a primary paleomagnetic signal, an assertion which is opposed by a number of published zircon magnetism studies. We conclude that Archean zircon paleointensities do not provide evidence for or against mobile-lid plate tectonics prior to 3.4 Ga. Future paleomagnetic investigation of tectonic regime on the early Earth should therefore focus on magnetization directions in well-preserved, oriented whole rocks.

Effects of contact/stabilization time ratio on organic carbon-methane conversion in high-rate contact stabilization system

The high-rate contact stabilization (HRCS) process is a promising technique for recovering carbon from wastewater. However, its practical application faces challenges due to its low chemical oxygen demand (COD) removal efficiency, which requires further optimization. The objective of this study was to investigate the optimal process conditions for enhancing COD removal efficiency and carbon recovery rate (CRR) in the HRCS process. To achieve this, a sequencing batch reactor (SBR) was utilized to maximize the feast-famine regime. Although the HRCS process exhibited a lower COD removal efficiency compared to the high-rate activated sludge (HRAS) process in SBR mode, it demonstrated a 16.3 % higher CRR. The influence of the contact time to stabilization time (tc/ts ratio) on both COD removal efficiency and CRR was investigated. The optimum condition was achieved at a tc/ts ratio of 0.18, which resulted in a COD removal efficiency of 60.2 ± 3.0 % and a CRR of 0.417 ± 0.041 g-CODCH4/g-CODinf (CODCH4: produced methane as COD, CODinf: influent COD). The microbial communities in HRAS and HRCS exhibited simplification compared to conventional activated sludge. Distinct shifts were observed in response to changes in solids retention time and tc/ts ratio. Under harsher operating conditions, Lactococcus spp. became the predominant species, achieving the greatest dominance at a tc/ts ratio of 0.18. This is because they produce more extracellular polymeric substances and polyhydroxyalkanoates, which improve organic capture. The operating conditions identified in this study are anticipated to make a significant contribution to practical applications aimed at enhancing carbon recovery.

МАТЕМАТИЧНЕ МОДЕЛЮВАННЯ ПЕРЕХІДНИХ ПРОЦЕСІВ В ІЄРАРХІЧНИХ СТРУКТУРАХ ДЕРЖАВНОГО УПРАВЛІННЯ З НЕЛІНІЙНИМИ ХАРАКТЕРИСТИКАМИ

The last decades are characterized by a large number of studies of state and public figures, which can be called an era of deep (fundamental) and rapid changes. Society is experiencing qualitative changes and serious challenges, therefore there is a kind of paradox when the imperatives of a new era force the development of a theoretical basis in the semantic field of common sense, which is associated with permanence and qualitative changes in political, economic and social life [1, 2, 3] . In state administration and local self-government bodies, relations between people, rapid unpredictable changes in the situation in the country and in regions (political, economic, social, etc.) are non-linear management systems. Moreover, any physical system when examined in more detail is always nonlinear. The effectiveness of managing a nonlinear system, taking into account disturbing factors, depends on the accuracy of forecasting the dynamics of changes in individual elements of such a system. This is a multifaceted problem [15]. A characteristic feature of non-linear hierarchical structures (NIS) in the public service (state administration - DU and local self-government - MS) is a continuous and discrete change in the processes of development of events, which distinguishes them from other internal and external influences, such as those that cause the transformation of linear communication into non-linear, which ultimately leads to new changes. This is the first thing. Second, subject-object relationships can have uncoordinated actions caused by real-world circumstances. Such uncoordinated actions can occur even more in transitional processes of society (for example, the speed of their flow) due to the inertia of individual elements or the social system itself as a whole. As a result of these phenomena, the linear relationship between discrete changes is broken and the previous hierarchical structure changes, which leads to non-linear information relationships in the state administration (SU) and local self-government bodies (MS). For example, G. Pocheptsov and other scientists associate this nonlinearity with chaos, the growing complexity of social processes, globalization, with a threat to state security, with the manifestation of unpredictability and instability [1-5]. Strict requirements are imposed on the management process in the new state of DU and MS: - resilience of the management system; - the system should be described as continuous-discrete (its dynamics); - the management process must ensure the necessary accuracy of matching the indicators of the new state of the system with the previous one. A number of problems appear in newly formed non-linear hierarchical structures (NIS) in DU and MS: - lack of a priori information about processes with non-linear connections; - inaccuracy of structural identification; - inaccuracy in the choice of criteria for assessing the situation; - restructuring processes; - wrong choice of states of nature; - incorrect determination of the importance of the selected criteria according to the scale of importance; - incorrectly chosen dependence of alternatives on the criterion; - insufficient degree of awareness of the complexity of the situation. Solving the above problems requires experimental research. If the process of stabilization of the NIS in the DU is considered as an object of regulation, then it is enough to establish the dependence of this stability on the control action and the main disturbance, and all other actions are considered as disturbances on the object of study. Such a description will reflect the main dynamic characteristics of such a process and will be sufficient for the synthesis and development of an optimal regulation system with the aim of achieving stable (stable) processes in such systems (including DU and MS). In the future, we will approach the DU as a non-linear hierarchical system (NHS) and depict the NIS as a multidimensional continuous system, in which the state of nature is the regulated quantity, and the input is the action of managers in the DU and MS (management decisions made by them - PUR) regarding regulation , coordination and perturbations acting on the system.

Investigating geotechnical properties of silty clay stabilized using wheat straw ash and lime.

The change of soil conditions by either physical or chemical methods to improve the soil’s capability for engineering is known as soil stabilization. The primary goals of soil stabilization are to strengthen the soil’s carrying capacity, its resistance to degradation, and its ability to absorb water. Any building project’s durability is dependent on the stability of the base soils. For this reason, soil stabilization processes must be used to ensure the soil’s strength so that it is capable of supporting the load of the superstructure, particularly within the case of soil that is highly active. It also saves an important amount of time as well as funds when compared to the method of removing and replacing the unstable soil. The subject matter addresses the full inspection of how wheat straw ash and lime can be used to enhance soil qualities and stabilize it.

FINANCIAL AND ECONOMIC STABILITY OF FUNCTIONING OF ENTERPRISES AS AN IMPORTANT ASPECT OF SUSTAINABLE DEVELOPMENT OF UKRAINE

Goal. To analyze the organizational and economic category of economic and financial stability of functioning of enterprises in the context of sustainable development of Ukraine. Method. To achieve a certain goal, the study used a method of studying and generalizing information, system analysis. Results. The article investigates the organizational, technical and economic components of stabilization processes, the reasons for the inhibition of economic development at the present stage, the analysis of the organizational and economic category of economic and financial stability of functioning of enterprises, as a complex concept, which is influenced, the causes and factors that change the level of economic and financial stability with their division into tactical and strategic, internal and external. The goals of sustainable development of the state are determined: social justice, economic prosperity, high quality environment, rational resource use, demographic stability and employment, international cooperation. There are three directions of reducing energy costs are proposed: rationalization of fuel and energy use; changing the rate of development of energy, intensive and less energy-intensive industries; introduction of energy-saving technologies, processes, apparatus and equipment in the most energy-intensive industries. Scientific novelty. The study proposes ways and stages of increasing financial and economic stability of enterprises in Ukraine. Practical significance. The research and conclusions made in this article can be used by the heads of organizations in determining stabilization economic factors in making management decisions.

Coping with External and Internal Disintegration Forces: Qāḍī ʿIyāḍ and the Stabilization of Mālikīsm in the Maghrib

Abstract This article approaches Qāḍī ʿIyāḍ b. Mūsā’s contribution to the stabilization of Mālikīsm in the Islamic West through his characterization of three important Andalusī figures of the school: Ibn ʿAbd al-Barr, Abū l-Walīd al-Bāǧī and Abū Bakr al-Ṭurṭūšī. ʿIyāḍ’s biographies of these scholars in two of his works, Tartīb al-madārik and al-Ġunya, are compared with those of Ibn Farḥūn (d. 799/1397) in his al-Dībāǧ al-mudhab. These biographical dictionaries, Tartīb and Dibāǧ, are the two main sources for the pre-modern history of Mālikīsm. The results of this comparison go beyond an analysis of Iyāḍ’s contribution to the stabilization of the Mālikī school in the Maghrib. The strong dependence of the Dībāǧ on the Tartīb reveals Ibn Farḥūn’s vision of his great Maghribī predecessor which in turn forms an interesting intra-history of Mālikīsm worth preserving. Using Ibn Farḥūn’s Dībāǧ as a point of comparison also helps us to observe how the circumstances projected by the Tartīb evolved over time and space thus contributing to a better understanding of the process of doctrinal stabilization and social normalization of the Mālikī madhab West but also East. After introducing ʿIyāḍ’s facet as a historian and a biographer in Section 1, I present his biographies of the three selected scholars. In Section 3, I discuss the main differences in the way ʿIyāḍ and Ibn Farḥūn approached each of their contributions to Mālikīsm to wrap up the significance of these differences in the conclusions.