Stability Properties Research Articles

Insight into ion dynamics in a NaClO4-doped polycaprolactone solid polymer electrolyte for solid state batteries.

Employing low Tg polymers has fundamental limitations in providing the desirable ionic conductivity at ambient temperature due to the freezing of chain dynamics. The stiffening of polymer chains and the formation of highly ordered systems due to the crosslinks have influenced the ionic conductivity. Ionic conductivity of 1.02 × 10-5 S cm-1 was attained for the system that presented a quantum mechanical tunnelling mode of ion transport. A Na-ion transference number of 0.31 was achieved for 30 wt% of NaClO4 salt in a polycaprolactone (PCL) matrix with an electrochemical stability window of 3.6 V at 25 °C. High crystallinity and limited availability of free Na+ ions in the electrolyte have resulted in lower ionic conductivity. PCL-NaClO4 exhibited brilliant thermal stability and mechanical properties. The influence of cathode materials MnO2, V2O5 and I2 on the discharge characteristics of an electrochemical cell in the configuration cathode |(70 wt%)PCL-NaClO4(30 wt%)|Na has been studied.

Flexible Crossbar Molecular Devices with Patterned EGaIn Top Electrodes for Integrated All-Molecule-Circuit Implementation.

Here, a unique crossbar architecture is designed and fabricated, incorporating vertically integrated self-assembled monolayers in electronic devices. This architecture is used to showcase 100 individual vertical molecular junctions on a single chip with a high yield of working junctions and high device uniformity. The study introduces a transfer approach for patterned liquid-metal eutectic alloy of gallium and indium top electrodes, enabling the creation of fully flexible molecular devices with electrical functionalities. The devices exhibit excellent charge transport performance, sustain a high rectification ratio (>103), and stable endurance and retention properties, even when the devices are significantly bent. Furthermore, Boolean logic gates, including OR and AND gates, as well as half-wave and full-wave rectifying circuits, are successfully implemented. The unique design of the flexible molecular device represents a significant step in harnessing the potential of molecular devices for high-density integration and possible molecule-based computing.

Sustainable poly(imide‐imide) vitrimer based on multiple dynamic covalent bonds

AbstractPolyimide materials with high mechanical strength are widely used in various fields, but pose certain challenges in achieving sustainable material utilization. A poly(imide‐imide) vitrimer material (ADTA) based on multiple dynamic covalent bonds (imide, imine, and disulfide bonds) was constructed by preparing vanillin difunctionalized derivatives (DVA) for aldolamine condensation reactions with bis‐amine monomers (ATFA) and tris(2‐aminoethyl) amines (TAEA) with imide structures. The ADTA material has good 5% thermal stability Td5% (278.87°C), high energy storage modulus E (2421.26 MPa), and fast relaxation time (36.39 s). The thermal stability and mechanical properties of the material are enhanced by the more stable alicyclic structure of the imide structure. The material also demonstrated excellent solvent resistance and self‐healing properties. This study provides a new option for the development of sustainable utilization of polyimide materials.

Hydrothermal Carbonization of Biomass for Electrochemical Energy Storage: Parameters, Mechanisms, Electrochemical Performance, and the Incorporation of Transition Metal Dichalcogenide Nanoparticles

Given the pressing climate and sustainability challenges, shifting industrial processes towards environmentally friendly practices is imperative. Among various strategies, the generation of green, flexible materials combined with efficient reutilization of biomass stands out. This review provides a comprehensive analysis of the hydrothermal carbonization (HTC) process as a sustainable approach for developing carbonaceous materials from biomass. Key parameters influencing hydrochar preparation are examined, along with the mechanisms governing hydrochar formation and pore development. Then, this review explores the application of hydrochars in supercapacitors, offering a novel comparative analysis of the electrochemical performance of various biomass-based electrodes, considering parameters such as capacitance, stability, and textural properties. Biomass-based hydrochars emerge as a promising alternative to traditional carbonaceous materials, with potential for further enhancement through the incorporation of extrinsic nanoparticles like graphene, carbon nanotubes, nanodiamonds and metal oxides. Of particular interest is the relatively unexplored use of transition metal dichalcogenides (TMDCs), with preliminary findings demonstrating highly competitive capacitances of up to 360 F/g when combined with hydrochars. This exceptional electrochemical performance, coupled with unique material properties, positions these biomass-based hydrochars interesting candidates to advance the energy industry towards a greener and more sustainable future.

Unraveling the Stability and Magnetic Properties of Bis-Hydrated Mn(II) Complexes via Tailored Ligand Design.

Exploring the electronic structure and dynamic behavior of Mn(II) complexes reveals fascinating magnetic properties and prospective biomedical applications. In this study, we investigate the solvent phase dynamics of heptacoordinated Mn(II) complexes through ab initio molecular dynamics simulations and density functional theory (DFT) calculations with effectively varying temperatures. We observed that the complex with high stability ([Mn(pmpa)(H2O)2]) remains relatively rigid as the temperature increases to 90 °C, with only a minor change in its radial distribution functions (RDFs), compared to the RDF peaks at 25 °C. To elucidate the impact of halogens on the magnetic anisotropy of seven-coordinated Mn(II) complexes, we performed both DFT and multireference calculations. This shows that the zero-field splitting (ZFS) parameter D follows the order D(I)> D(Br)> D(Cl). We observed a significant increase in the D-value following the substitution of soft Se-donors in the equatorial position and heavier halogens in the axial position. The D-value of halogen derivatives of Se-analogues varies in the order of D(Cl) < D(I) < D(Br), deviating from the regular spectrochemical series with the discrepancy between the covalency of the Mn(II)-Se bond and the ligand field strength. We anticipate that this study will enhance our understanding of the solvent phase dynamics and structural aspects of ZFS in various Mn(II) complexes with different electronic environments.

Evaluation of dimensional stability, setting time, tensile strength, and rheological properties of kaolin clay incorporated alginate impression material

This study aims to determine and compare the dimensional stability, setting time, tensile strength, and rheological properties of kaolin clay powder-modified and unmodified alginate impression material. Commercially available alginate-based impression material was considered as a control (C) while experimental groups E-1, E-2, and E-3 were fabricated by adding 2%, 4%, and 8% of kaolin clay powder in the control, respectively. Analytical techniques were used for the characterization of the samples. A tensile strength, rheological property, dimensional stability, and setting time were recorded for control and experimental groups. FTIR analysis confirmed the presence of kaolin clay powder in all experimental groups. SEM showed a round solid structure and irregular shape particle appearance in all experimental groups as well as a control group. The dimensional stability was improved by the addition of kaolin clay powder to the alginate impression material. The percentage dimensional change at 5 min, 6, and 12 h was increased for E3 adding (8% kaolin clay powder) and decreased for the control group. The mean value of tensile strength was highest for E3 followed by E2, E1, and least in control groups. Higher Young’s Modulus and lower deformation values were measured for E3. The mean value of setting time was highest for E3 and the least was in the control group. The results for both setting time and tensile strength were very highly statistically significant (p < 0.001). The mean values of viscoelasticity, flow, and drip test were increased statistically by adding various concentrations of kaolin clay powder to the alginate impression material.

An eco-friendly strategy of cell wall stapling: In situ crosslinking of acrylic acid emulsion impregnated in thermally treated poplar wood

Traditional wood modification methods often result in the release of harmful substances and energy wastage. This study proposes an efficient and environmentally friendly modification strategy for fast-growing poplar wood. The approach involves polymerizing organic linear molecules within the cell wall to form stitches, thereby enhancing the dimensional stability and mechanical properties of wood and increasing its ability to withstand various environments. Poplar wood specimens were treated via a method that combines heat treatment with acrylic emulsion impregnation. The research findings indicated an improvement in the mechanical properties of poplar wood following the combined treatment. Moreover, poplar wood subjected to this treatment approach exhibited a 35.24 % lower water absorption rate after a 7-day water immersion test, and tangential and radial swelling rates of the wood were reduced by 29.66 % and 45.68 %, respectively. Scanning electron microscopy revealed excellent penetration of acrylic emulsion into wood cells; the emulsion infiltrated the wood and adhered to the cell walls, forming a crosslinked network structure. Analysis of the modification mechanism through X-ray diffraction, Fourier-transform infrared spectroscopy, and X-ray photoelectron spectroscopy showed that the successful infusion of acrylic emulsion compensated for the lower mechanical properties of thermally treated wood, thus improving the utilization value of poplar. The acrylic emulsion is an environmentally friendly and harmless modifier, making the modified wood suitable for various applications, including indoor furniture, logistics, and outdoor facilities. This modification strategy enables efficient resource utilization and provides valuable insights for the sustainable development of the timber industry.

Fabrication, Characterization, and Performance Evaluation of Thermally Stable [5,6]-Fused Bicyclic Energetic Materials.

In recent decades, there has been considerable interest in investigating advanced energetic materials characterized by high stability and favorable energetic properties. Nevertheless, reconciling the conflicting balance between high energy and the insensitivity of such materials through traditional approaches, which involve integrating fuel frameworks and oxidizing groups into an organic molecule, presents significant challenges. In this study, we employed a promising method to fabricate high-energy-density materials (HEDMs) through the intermolecular assembly of variously substituted purines with a high-energy oxidant. Purines are abundant in nature and are readily available. A series of advanced energetic materials with a good balance between energy and sensitivity were prepared by the simple and effective self-assembly of purines with high-energy oxidants. Notably, these compounds exhibit incredibly improved crystal densities (1.80-2.00 g·cm-3) and good detonation performance (D: 7072-8358 m·s-1; P: 19.82-34.56 GPa). In comparison to RDX, these self-assembled energetic materials exhibit reduced mechanical sensitivities and enhanced thermal stabilities. Compounds 1-5 demonstrate both high energy and low sensitivity, indicating that self-assembly represents a straightforward and effective approach for developing advanced energetic materials with a balanced combination of energy and safety. Moreover, this study offers an avenue for synthesizing energetic materials based on naturally occurring compounds assembled through intermolecular attractions, thereby achieving a balance between energy and sensitivity along with versatile functionality.

Large-energy operation of an Er-doped fiber laser with ZrGeTe4 saturable absorber

ZrGeTe4 as a layered semiconductor material with good stability and optoelectronic properties, and excellent saturable absorption characteristics, but its application in fiber lasers is still insufficient. In order to explore its application in fiber lasers, we prepared ZrGeTe4-PVA thin film by liquid phase exfoliation and performed a series of characterizations. A modulation depth of 13.15 %, a non-saturated loss of 6.4 %, and a saturation intensity of 5.5 MW/cm2 were obtained. Then used the ZrGeTe4-PVA thin film as the saturable absorber (SA) in an Er-doped fiber laser (EDFL), the large-energy operation could be realized. In the case of a cavity length of 234 m, when the pump power was increased to 1229 mW, a maximum single pulse energy of about 32.72 nJ was achieved, with a repetition frequency of 859 kHz. To the best of our knowledge, this is the highest single-pulse energy achieved in an EDFL based on ZrGeTe4-SA. This experiment shows that the ZrGeTe4 is a promising two-dimensional (2D) material with good nonlinear absorption properties, proving that it is a promising pulse modulation of SA and laying a foundation for its subsequent study in fiber lasers.

Enhanced stability and catalytic performance of immobilized phospholipase D on chitosan-encapsulated magnetic nanoparticles using oxidized dextran and glutaraldehyde as cross-linkers

Phospholipase D (PLD) is essential for the bioconversion of phosphatidylcholine (PC) to phosphatidylserine (PS), a process valuable in functional food and medicine. This study explores the stability and catalytic properties of PLD immobilized on chitosan-encapsulated magnetic nanoparticles (CMNPs), utilizing oxidized dextran (DX) and glutaraldehyde (Glu) as cross-linkers. The cross-linker concentration and immobilization time were optimized to assess their effects on PLD catalytic performance. PLD immobilized on CMNPs with DX (DX-CMNPs-PLD) exhibited optimal activity at pH 8.0 and 30 °C, retaining over 40 % activity after 14 cycles, while Glu-cross-linked PLD (Glu-CMNPs-PLD) retained approximately 65 %. DX-CMNPs-PLD demonstrated superior pH, temperature, and operational stability compared to free PLD. Additionally, the immobilized PLD was characterized using transmission electron microscopy, X-ray diffraction, and Fourier-transform infrared spectroscopy. Kinetics parameters (Vmax and Km) of the immobilized PLD were also studied with free PLD serving as a control. Conformational analyses indicated a significant change in PLD's secondary structure, particularly in β-sheet content, which likely contributed to the enhanced stability and activity. These findings suggest a promising approach for PLD immobilization on CMNPs, with notable implications for biotechnological applications.

Polymeric silk fibroin hydrogel as a conductive and multifunctional adhesive for durable skin and epidermal electronics

AbstractSilk fibroin (SF)‐based hydrogels are promising multifunctional adhesive candidates for real‐world applications in tissue engineering, implantable bioelectronics, artificial muscles, and artificial skin. However, developing conductive SF‐based hydrogels that are suitable for the micro‐physiological environment and maintain their physical and chemical properties over long periods of use remains challenging. Herein, we developed an ion‐conductive SF hydrogel composed of glycidyl methacrylate silk fibroin (SilMA) and bioionic liquid choline acylate (ChoA) polymer chains, together with the modification of acrylated thymine (ThyA) and adenine (AdeA) functional groups. The resulting polymeric ion‐conductive SF composite hydrogel demonstrated high bioactivity, strong adhesion strength, good mechanical compliance, and stretchability. The formed hydrogel network of ChoA chains can coordinate with the ionic strength in the micro‐physiological environment while maintaining the adaptive coefficient of expansion and stable mechanical properties. These features help to form a stable ion‐conducting channel for the hydrogel. Additionally, the hydrogel network modified with AdeA and ThyA, can provide a strong adhesion to the surface of a variety of substrates, including wet tissue through abundant hydrogen bonding. The biocompatible and ionic conductive SF composite hydrogels can be easily prepared and incorporated into flexible skin or epidermal sensing devices. Therefore, our polymeric SF‐based hydrogel has great potential and wide application to be an important component of many flexible electronic devices for personalized healthcare.

Cosymplectic Geometry, Reductions, and Energy-Momentum Methods with Applications

Classical energy-momentum methods study the existence and stability properties of solutions of t-dependent Hamilton equations on symplectic manifolds whose evolution is given by their Hamiltonian Lie symmetries. The points of such solutions are called relative equilibrium points. This work devises a new cosymplectic energy-momentum method providing a new and more general framework to study t-dependent Hamilton equations. In fact, cosymplectic geometry allows for using more types of distinguished Lie symmetries (given by Hamiltonian, gradient, or evolution vector fields), relative equilibrium points, and reduction methods, than symplectic techniques. To make our work more self-contained and to fill some gaps in the literature, a review of the cosymplectic formalism and the cosymplectic Marsden–Weinstein reduction is included. Known and new types of relative equilibrium points are characterised and studied. Our methods remove technical conditions used in previous energy-momentum methods, like the Ad∗\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ extrm{Ad}^*$$\\end{document}-equivariance of momentum maps. Eigenfunctions of t-dependent Schrödinger equations are interpreted in terms of relative equilibrium points in cosymplectic manifolds. A new cosymplectic-to-symplectic reduction is developed and a new associated type of relative equilibrium points, the so-called gradient relative equilibrium points, are introduced and applied to study the Lagrange points and Hill spheres of a restricted circular three-body system by means of a not Hamiltonian Lie symmetry of the system.

Influence of Metal Ions on the Structural Complexity of Mixed-Ligand Divalent Coordination Polymers

The reactions of the angular ligand 4,4′-oxybis(N-(pyridin-3-yl)benzamide) (L1) and 1,4-naphthalenedicarboxylic acid (1,4-H2NDC) with divalent metal salts yielded three distinct coordination polymers (CPs): {[Zn2(L1)(1,4-NDC)2]·MeOH}n, 1, {[Cu(L1)(1,4-NDC)(H2O)]·3H2O}n, 2, and {[Cd(L1)(1,4-NDC)]·2H2O}n, 3. Complex 1 features a 2-fold interpenetrated 3D framework with the (412·63)-pcu topology, while complex 2 reveals a 1D triple-strained helical chain and complex 3 displays a 3-fold interpenetrated 3D framework with (66)-dia topology. Additionally, the reactions of the flexible ligand N,N′-bis(3-methylpyridyl) adipoamide (L2) afforded {[Co4(L2)0.5(1,4-NDC)3(H2O)3(µ3-OH)2]·EtOH·2H2O}n, 4, {[Zn2(L2)(1,4-NDC)2]·2CH3OH}n, 5, and [Cd(L2)(adipic)(H2O)]n (H2adipic = adipic acid), 6, exhibiting a self-catenated 3D framework with the (420·68)-8T32 topology, a 2D layer with the (413·62) − (4,4)IIb topology, and a 2D layer with the (44·62)-sql topology, respectively. The structural diversity observed in complexes 1–6 highlights the pivotal influence of the metal center on the degree of entanglement in CPs within mixed-ligand systems. The thermal stability and luminescent properties of complexes 1–3, 4, and 6 are also discussed.

Lead-Free Perovskite With Efficient Tellurium Ion Activation for Multifunctional Applications.

Lead-free perovskite materials have received extensive attention due to their non-toxicity, super environmental stability and adjustable photoelectric properties. However, the inherent problems of low luminous efficiency and low photoluminescence quantum yields (PLQYs) limit its development in multifunctional applications. Here, Te4+ doped Cs2ZrCl6 with high luminous efficiency and stability for multifunctional applications are developed. Te4+ ions are used as emission centers to improve the optical properties of Cs2ZrCl6 to make efficient and stable single-component white light-emitting diodes (WLEDs), and can be used as scintillator materials to improve scintillation performance to achieve high-resolution and low-dose X-ray imaging detection. In addition, it is found for the first time that Te4+ ions can be introduced into the trap center, so that the Cs2ZrCl6:Te4+ perovskite material exhibits excellent persistent luminescence (PersL) and mechanoluminescence (ML) after X-ray radiation, which has potential applications in the fields of delayed imaging and stress sensing. This work provides a method for designing lead-free perovskites with high optical performance and scintillating properties, as well as developing multifunctional applications.

Structural and physical properties of the MAX phases RE2SX (RE = La ∼ Lu; X=B, C, N) via first-principles calculations

MAX phase layered compounds have high temperature stability, excellent mechanical properties, good thermal conductivity and electronic properties. In order to provide a certain theoretical basis for further experimental exploration of the MAX phase with rare-earth (RE) element, a detailed study of the RE2SX (RE = La∼Lu, X = B, C, N) MAX phase has been performed by using first-principles calculations. The study comprehensively examines the mechanical properties, elastic anisotropy, dynamical stability and thermal properties of the RE2SX phase, and the results demonstrate that 37 RE2SX phases satisfied the thermodynamical, mechanical and dynamical stabilities among the 45 compounds. The mechanical properties of the 37 stable phases were systematically analyzed, including bulk modulus, shear modulus, Young's modulus and hardness. Among these phases, La2SN, Ce2SB/N, Pr2SB/N, Nd2SB/N, Pm2SB, Sm2SB, Eu2SB, and Gd2SB were identified as exhibiting promising ductility potential. In the RE2SX carbides, the occupied states on the Fermi level of the RE2SC phase are very small, with the conduction band is mainly occupied by the valence electrons of the RE and S atoms, suggesting that these carbides exhibit notable electronic characteristics. These results can enhance our understanding of RE2SX phases and provide valuable guidance for future experimental research.

The thermoelectric properties of the two-dimensional Nowotny-Juza material NaBeX (X = P, As, and Sb)

The two-dimensional β-type Nowotny-Juza phase-filled tetrahedral compound has excellent electrical conductivity, low thermal conductivity and outstanding thermoelectric properties. This study investigated the stability and electronic properties of NaBeX (X = P, As, and Sb) through first-principles calculations. The results demonstrate that these materials are structurally stable and are direct bandgap semiconductors with bandgaps of 0.6542 eV, 0.6549 eV, and 0.6686 eV, respectively. The electrical and thermal transport properties of NaBeX are investigated by combining the deformation potential theory and Boltzmann transport theory. Subsequently, the thermoelectric properties of NaBeX are evaluated at temperatures ranging from 400 to 800 K. The n-type NaBeX materials exhibit large ZT values of 2.48, 2.62, and 1.72. The results of the present study indicate that n-type NaBeX has the potential to be used as a thermoelectric candidate material at temperatures ranging from 400 to 800 K.

Insights into effects of Fe doping on phase stability, martensitic transformation, and magnetic properties in Ni-Mn-Ti-Fe all-d-metal Heusler alloys

In this work, the effects of Fe doping on phase stability, martensitic transformation, and magnetic properties of Ni50Mn37.5-xTi12.5Fex (x = 3.125, 6.25, 9.375) all-d-metal Heusler alloys were systematically investigated by first-principles calculations. The results indicate a tendency for doped Fe atoms to aggregate within the Ni50Mn37.5-xTi12.5Fex alloys. As Fe concentration increases, a gradual reduction in both lattice constants and phase stability of austenite and martensite is observed. In the absence or presence of minimal Fe doping, both austenite and martensite exhibit antiferromagnetic behavior. However, at x = 9.375, a transition to a ferromagnetic state is observed in the austenite phase. This transition is attributed to the activation of the ferromagnetic coupling effect in the austenite phase induced by Fe doping in the Ni-Mn-Ti alloy. In contrast, the martensite phase maintains its antiferromagnetic characteristics throughout the doping range. A comprehensive analysis of the electronic structure elucidates the underlying physical mechanisms responsible for the martensitic transformation and magnetic property changes.

Preparation and Characterization of Fluorinated Acrylate and Epoxy Co-Modified Waterborne Polyurethane

Conventional waterborne polyurethane (WPU) has poor water resistance and poor overall performance, which limits its application in outdoor coatings. A solution to this problem is urgently needed. The introduction of fluorine-containing groups can effectively improve the water resistance of WPU. In this study, a new fluorinated chain extender (HFBMA-HPA) synthesized by free radical copolymerization and epoxy resin (E-44) were used to co-modify WPU, and five waterborne fluorinated polyurethane (WFPU) emulsions with different fluorine contents were prepared by the self-emulsification method. The effects of HFBMA-HPA content on the emulsion particle properties, coating surface properties, mechanical properties, water resistance, thermal stability, and corrosion resistance were investigated. The results showed that the WFPU coating had excellent thermal stability, corrosion resistance, and mechanical properties. As the content of HFBMA-HPA increased from 0 wt% to 14 wt%, the water resistance of the WFPU coating gradually increased, the water contact angle (WCA) increased from 73° to 98°, the water absorption decreased from 7.847% to 3.062%, and the surface energy decreased from 32.8 mN/m to 22.6 mN/m. The coatings also showed impressive performances in the adhesion and flexibility tests in extreme conditions. This study provides a waterborne fluorinated polyurethane material with excellent comprehensive performance that has potential application value in the field of outdoor waterproof and anticorrosion coatings.

Anti-counterfeiting labels with controllable and anti-interference coding information based on core–shell Ag@SiO2 nanomaterials for ink printing

The core–shell structured Ag@SiO2 nanomaterial integrated with surface-enhanced Raman scattering (SERS) spectroscopy promises a critical application in anti-counterfeiting. Security labels have been fabricated based on Ag@SiO2 embedded with Raman reporters. The Ag@SiO2 nanomaterial shows good stability and excellent anti-interference property for anti-counterfeiting. Multiple kinds of Raman probe molecules have been anchored in the Ag@SiO2 labels to provide specific and abundant encoding information. The flexible encoding security information could be controlled conveniently by adjusting probe molecules, which not only enrich the SERS information but also improve the level of anti-counterfeiting. Furthermore, the Ag@SiO2 shown excellent stability in organic solvent, and successfully used in ink for the anti-counterfeiting application.

Anomalous hybridized excitons induced by combined effects of Van der Waals coupling and Rashba spin–orbit coupling

As a typical transition-metal dichalcogenide, MoS2has drawn wide attention due to its good stability and excellent physicochemical properties, making it suitable for visible-region optoelectronic devices. To expand its application, bandgap engineering via heterostructure, thus far, was conventionally employed to tune the band gap. However, this strategy has the disadvantage that energy levels of bands do not show obvious changes compared to the isolated components, limiting the range of applications. Here, we achieve hybridized excitons induced by combined effects of Van der Waals (vdW) coupling and Rashba spin-orbit coupling (SOC), with a small exciton energy of 0.65 eV. For this purpose, we design a MoS2/MoWC heterostructure, where a built-in field (due to the absence of mirror symmetry) induces the Rashba SOC and contributes to the anomalous hybridized states, combined with the vdW coupling. An effective model is proposed to demonstrate the anomalous hybridized states for the heterostructure. Our approach reveals a novel mechanics model for hybridized excitons states, providing new physical ways to achieve infrared-region devices.