Terms Of Stability Research Articles

APPROACHES TO ASSESSING THE MINIMUM SUFFICIENT LEVEL OF FINANCIAL INDEPENDENCE OF THE ORGANIZATION

The coefficient of financial independence is an important indicator characterizing the level of financial stability of the organization. It reflects the level of use of own funds by the company to carry out its activities. This indicator is also an important analytical tool for investors, creditors and management personnel, as it helps to assess the level of risk associated with the company's financial policies and its ability to ensure financial stability in the long term. The article proposes a new approach to assessing the minimum necessary amount of equity capital for the organization and the sufficient (smallest) level of the coefficient of financial independence based on it.

Phenophases of Species of the Salix Genus in the Conditions of Osh City

The study of the phenology of urban trees and shrubs has increased dramatically worldwide in recent years, as changes in plant phenology may indicate the impacts of climate change at different scales. The aim of the study is to determine the patterns of the seasonal rhythm of individual species belonging to the Salixgenus in Osh. The studies were conducted in the period 2019-2023 at the Department of Biology, Chemistry and Nature Management of Osh State Pedagogical University. The subject of the study is 4 species of the genus Salix: Salix babylonica L., Salix turanica Nasarow, Salix wilhelmsiana M. Bieb. and Salix tenuijulis Ledeb. Phenological observations were carried out for 5 years using generally accepted phenological methods. The results of phenological observations in 2019-2023 show that the duration of the growing season in urban conditions is 240-245 days, and this indicator varies depending on climatic conditions. The observed species have differences in the flowering sequence, the beginning and duration of flowering. The total duration of flowering in the studied species is 25-35 days. The seasonal type of growth and phenological development of plants of the genus Salix is characterized by an early onset and late end of vegetation, stability of average phenological terms. Such a phenological rhythm of the studied species of the genus Salix makes it possible to consider cultivation for decorative and environmental purposes in urban conditions promising.

Asymmetric impact of climate change on banking system stability in selected sub-Saharan economies

This study is an empirical examination of the asymmetric impact of climate change on banking system stability in selected sub-Saharan economies. The study leverages a quantitative research approach through a panel non-linear ARDL framework and data from 29 selected economies, which spans 1996-2017. Findings from the study reveal that in the long term, partial sums of temperature have an insignificant relationship with banking system stability. Further, partial sums of precipitation are negatively related to banking system stability in the long term. The finding indicates that both positive and negative precipitation do harm banking system stability in the selected sub-Saharan economies. Moreover, we find that partial sums of greenhouse gas emissions had an insignificant relationship with banking system stability. In addition, we conclude that greenhouse gases (positive and negative) do not impair banking system stability in selected sub-Saharan economies in the long term. We surmise from the findings that both positive and negative climate change indexes are harmful to banking system stability. On the short-term asymmetric impact, we discover that partial sums of temperature, precipitation, and climate change index do not harm banking system stability. However, negative greenhouse gas emissions are pernicious to the banking system’s stability in the short term. Conversely, positive greenhouse gas levels were statistically insignificant. The study recommends that central banks and monetary authorities in Sub-Saharan Africa design green banking policies to push the climate change agenda in the banking sector.

Synergistic Cationic Shielding and Anionic Chemistry of Potassium Hydrogen Phthalate for Ultrastable Zn─I2 Full Batteries.

Electrolyte additives are investigated to resolve dendrite growth, hydrogen evolution reaction, and corrosion of Zn metal. In particular, the electrostatic shielding cationic strategy is considered an effective method to regulate deposition morphology. However, it is very difficult for such a simple cationic modification to avoid competitive hydrogen evolution reactions, corrosion, and interfacial pH fluctuations. Herein, multifunctional additives of potassium hydrogen phthalate (KHP) based on the synergistic design of cationic shielding and anionic chemistry for ultrastable Zn||I2 full batteries are demonstrated. K cations, acting as electrostatic shielding cations, constructed the smooth deposition morphology. HP anions can enter the first solvation shell of Zn2+ for the reduced activities of H2O, while they remain in the primary solvation shell and are finally involved in the formation of SEI, thus accelerating the charge transfer kinetics. Furthermore, by in situ monitoring the near-surface pH of the Zn electrode, the KHP additives can effectively inhibit the accumulation of OH- and the formation of by-products. Consequently, the symmetric cells achieve a high stripping-plating reversibility of over 4500 and 2600 h at 1.0 and 5mA cm-2, respectively. The Zn||I2 full cells deliver an ultralong term stability of over 1400 cycles with a high-capacity retention of 78.5%.

Long-Term Reproducibility of BMD-Measurements with Clinical QCT Using Simultaneous and Asynchronous Calibration Methods and Different Measurement and Reconstruction Protocols.

Osteoporosis is underdiagnosed and undertreated. To improve timely fracture risk assessment optimized densitometry methods are required such as opportunistic spinal quantitative computed tomography (QCT). However, it is unclear how to best calibrate these scans and correct for potential scanner drift of QCT when used for monitoring bone mineral density (BMD) changes. We compared gold standard simultaneous calibration with asynchronous calibration methods, assessing mid-term (12weeks) and long-term (1.5years) reproducibility of BMD measurements. Cortical and trabecular compartments of the European Spine Phantom were studied with ten different protocols including low dose and high resolution (HR)-modes. Based on weekly phantom data, we compared simultaneous calibration to asynchronous single (termed global) or monthly calibration. The accuracy was better for trabecular measurements than for cortical measurements for all calibration methods. Reproducibility was excellent for all methods and slightly better for asynchronous than for simultaneous calibration both for trabecular and cortical bone. For HR protocols, reproducibility was better than for low dose measurements. In trabecular compartments averaged HR-BMD remained stable for global (- 0.1%/year, ns) but not for simultaneous calibration (- 1.5%/year, p < 0.001). No significant drifts could be detected for averaged low dose BMD (- 0.9 to + 0.8%/year) for either calibration method. Our data suggest that with regard to precision and accuracy measurements with asynchronous calibration are suitable for vertebral BMD assessment (no contrast agents) in clinical practice. Regular (e.g., monthly) stability tests using a calibration phantom could assure long term stability of at least 1year.

Implementation Of Indonesia's Defence Economy Through The Defence Budget Sector

The implementation of military spending through the Indonesian defense industry has shown gradual positive development, driven by efforts to establish an independent defense sector. This study examines the role of Indonesia's defense budget in supporting national security and fostering economic growth, focusing on the collaboration between state-owned enterprises (BUMN) and private companies (BUMS). The defense budget is applied progressively to balance the country's limited resources and the relatively low level of external threats. Using a qualitative research method, this study analyzes data from relevant literature, reports, and policies to evaluate the impact of the defense budget on the Indonesian economy. The research explores key aspects such as the gradual development of defense equipment, the role of research and development (R&amp;D) in driving innovation, and the partnership between public and private sectors to strengthen the local defense industry. The results indicate that Indonesia's defense budget has steadily increased over the past decade, contributing to economic growth, particularly in the manufacturing and technology sectors. However, the overall impact on the economy remains mixed due to challenges such as bureaucratic inefficiencies and dependence on imported materials. The discussion highlights the potential for defense R&amp;D investments to generate spillover effects into civilian industries and recommends strategies to enhance the efficiency of defense spending. In conclusion, the implementation of defense economic policies has laid a strong foundation for the development of an independent defense industry in Indonesia. The study suggests that a gradual increase in defense spending, combined with strategic partnerships and innovation, can support both national security and economic stability in the long term

Evaluation of imidazole blocking layers for perovskite stability

The prevention of AgI formation is critical for ensuring long term stability of perovskite solar cells. While sputtered metal oxide films are known for uniform dense film formation, solution phase nanoparticle coatings of metal oxides are prone to pinholes through which free iodide can migrate leading to AgI formation at the back contact. Iodide migration can be prevented through the addition of passivator or blocking layers at the perovskite/charge transport or charge transport/Ag interfaces. In this paper we evaluated a series of imidazoles as interfacial layers to prevent iodide migration from the perovskite to the Ag back contact through solution phase deposited Y:SnO2. We identified structural features of the imidazoles that contribute to an effective blocking layer. Specifically, it was found that imidazoles with conjugated planer systems and hydrogen bonding heteroatoms were able to prevent ion migration while retaining device performance. Of the materials evaluated 4-(Imidazol-1-yl)phenol had the best performance with a 60 % increase in stability verse the control under illumination at short circuit conditions.

A-163 Stability of apixaban in Li-heparin plasma stored refrigerated over mint green-top tube separator gel

Abstract Background Apixaban is a factor Xa inhibitor used as a direct oral anticoagulant (DOAC). The laboratory was asked to provide measurements of plasma apixaban in the context of studies regarding interaction of apixaban with other therapeutic drugs. One study involved isolation of plasma from to-be-discarded specimens, where such specimens were those originally collected in mint green-top tubes (Li-heparin tubes containing plasma separator gel), and that had been centrifuged and stored refrigerated for 5 days. Whereas apixaban concentration is known to be stable in refrigerated plasma specimens for up to two weeks, stability of apixaban concentration in plasma stored refrigerated for prolonged periods over plasma separator gel was unknown. Our objective was to examine stability of apixaban in plasma stored refrigerated for 5 days over plasma separator gel. Methods Pharmacy records were reviewed to identify inpatients who were prescribed apixaban, and for whom a mint green-top tube specimen (Becton-Dickinson BD Vacutainer PST Gel and Lithium Heparin, #367961) had been drawn for routine chemistry tests. From such specimens, 500 uL aliquots of plasma were obtained on day 1 (A) and day 5 (B) of storage under refrigeration (4 °C). Apixaban concentrations for A and B were measured by LC-MS/MS and compared. Additionally, short term (1 day) stability of apixaban was examined by comparison of replicate measurements of apixaban in a single spiked pooled purple-top plasma specimen (Becton-Dickinson BD Vacutainer K2 EDTA, #367856), with (C) or without (D) exposure to mint green-top tube separator gel for a 24h refrigeration period. Data analyses were conducted using R (version 4.0.5). Results A total of 21 specimen pairs (A, B) were examined. [Apixaban] ranged from 30-1000 ng/mL. The ratio B/A was 1.007 ± 0.034, consistent with no effect on plasma [apixaban] of refrigerated storage over separator gel between day 1 and day 5 (by paired t-test: p&amp;gt;0.8). Experiments for replicates of (C, D) specimens (n = 4, average [apixaban] = 410 ng/mL) gave D/C ratio of 1.009 ± 0.019, consistent with no effect on plasma [apixaban] of short term (1 day) refrigerated storage of plasma over separator gel (by paired t-test: p&amp;gt;0.4). Conclusions For plasma specimens collected and centrifuged in mint-green plasma separator tubes, there was no effect on plasma [apixaban] of refrigerated storage over separator gel for periods of 0-5 days.

NiO/MWCNT incorporated methyl ammonium lead iodide for an efficient perovskite solar cells

The perovskite solar cells (PSCs) reveal the impressive performance due to the extraordinary characteristic features of perovskite material and its fabrication methods. The complex deposition process and hygroscopic nature of hole transport materials are biggest obstacles for attaining high power conversion efficiency (PCE) with long term stability in PSC. In this study, NiO/MWCNT nanocomposites have been synthesized by hydrothermal method and are incorporated in CH3NH3PbI3 to increase the performance of PSCs with stability. The incorporation has been carried out to improve the properties of CH3NH3PbI3 such as formation of large grain size/grain boundaries, reduce the defects that enhance the charge generation/collection and reduction in recombination. The fabricated PSCs with NiO/MWCNT revealed a PCE of 14.93 % with moderate hysteresis, which is significantly higher PCE than that of pristine PSC. The enhanced recombination resistance was observed by electrochemical impedance spectroscopy, which evinces the remarkable PCE of NiO/MWCNT incorporated PSC. The strong PL quenching and red shift of PL spectrum confirms the low recombination and larger grains in the NiO/MWCNT-CH3NH3PbI3 layer. Moreover, the NiO/MWCNT incorporated PSC retains 94 % of its initial PCE after 600 h of aging under atmospheric condition whereas the PCE of pristine PSC shows 87 % of its initial PCE value. The carbon back electrode also supports to lift up PCE and stability of PSCs.

Computationally Optimized Graphene-Based Electrochemical Sensor with Enhanced Signal Stability for the Determination of the Antimicrobial Agent 9-aminoacridine

A hydrophobic aryl diazonium salt has been synthesized from 3,5-bis(trifluoromethyl)aniline and utilized to covalently modify graphene nanoplatelets and carbon nanotubes. The modified nanomaterials were applied on a screen-printed electrode/ion sensing membrane interface resulting in reduced potential drift to 100 μV h−1 compared to control sensors. Characterization was achieved through X-ray photoelectron spectroscopy. The electrode’s response was optimized using response surface methodology and then utilized for determination of 9-Aminoacridine (9-AA) in pharmaceutical gel dosage form and spiked human plasma without prior extraction steps. 9-AA is a fluorescent dye with antimicrobial activity that eradicates a range of microorganisms that can cause oral sores or broken skin and it has been recently used as anticancer among other uses as fluorescent dye and pH indicator. Accurate determination of 9-AA could help in adjusting dosages for each application. The optimized sensor was validated per IUPAC guidelines and obtained a wide linearity range from 1.0 × 10–7 M to 1.0 × 10–2 M, correlation coefficient of 0.9997, improved Nernstian slope 59.72, long term stability, and lower limit of detection (9.0 × 10–8 M). Furthermore, Analytical Eco-scale and AGREE methods were utilized to evaluate the presented method’s greenness.

2-AG-loaded and bone marrow-targeted PCL nanoparticles as nanoplatforms for hematopoietic cell line mobilization

BackgroundThe use of mobilizing agents for hematopoietic stem cell (HSC) transplantation is insufficient for an increasing number of patients. We previously reported lipid made endocannabinoid (eCB) ligands act on the human bone marrow (hBM) HSC migration in vitro, lacking long term stability to be therapeutic candidate. In this study, we hypothesized if a novel 2-AG-loaded polycaprolactone (PCL)-based nanoparticle delivery system that actively targets BM via phosphatidylserine (Ps) can be generated and validated.MethodsPCL nanoparticles were prepared by using the emulsion evaporation method and characterized by Zetasizer and scanning electron microscopy (SEM). The encapsulation efficiency and release profile of 2-AG were determined by liquid chromatography-tandem mass spectrometry (LC-MS/MS). The presence of cannabinoid receptors (CBRs) in HSCs and monocytes was detected by flow cytometry. Cell morphology and viability were assessed using transmission electron microscopy (TEM), SEM, and the WST-1 viability assay. The migration efficacy of the 2-AG and 2-AG-loaded nanoparticle delivery system on HSCs and HPSCs (TF-1a and TF-1) and monocytes (THP-1) was evaluated using a transwell migration assay.ResultsThe 140–225 nm PCL nanoparticles exhibited an increasing polydispersity index (PDI) after the addition of Ps and 2-AG, with a surface charge ranging from − 25 to -50 mV. The nanoparticles released up to 36% of 2-AG within the first 8 h. The 2-AG-Ps-PCL did not affect cellular viability compared to control on days 5 and 10. The HSCs and monocytes expressed CB1R and CB2R and revealed increased migration to media containing 1 µM 2-AG-Ps-PCL compared to control. The migration rate of the HSCs toward monocytes incubated with 1 µM 2-AG-Ps-PCL was higher than that of the monocytes of control. The 2-AG-Ps-PCL formulation provided a real time mobilization efficacy at 1 µM dose and 8 h time window via a specific CBR agonism.ConclusionThe newly generated and validated 2-AG-loaded PCL nanoparticle delivery system can serve as a stable, long lasting, targeted mobilization agent for HSCs and as a candidate therapeutic to be included in HSC transplantation (HSCT) protocols following scale-up in vivo preclinical and subsequent clinical trials.Graphical

Thermodynamic stability and component heterogeneity of CO2/N2 mixed hydrates: Implications for hydrate-based CO2 capture and sequestration

Injecting CO2/N2 into marine sediments to form gas hydrates for CO2 storage is an emerging Carbon Capture and Storage (CCS) technology, holding the potential to significantly reduce the costs of CCS while simultaneously enhancing environmental persistence. However, there is currently a lack of comprehensive investigation into the critical parameters and stability evaluations of CO2/N2 mixed hydrates (Mix-H) formation. This study delves into the impact of gas–liquid ratios, pressure–temperature gradients, and hydrate formation degree on the phase equilibrium, formation kinetics, and thermodynamic stability of Mix-H. Experimental findings elucidate the excess water significantly enhances CO2 dissolution, increasing the thermodynamic barrier for Mix-H formation. Consequently, this leads to weakened kinetics and reduced total CO2 composition within the Mix-H (54.2%–96.4%). Raman spectroscopy confirmed varying heterogeneous compositions and thermodynamic stability of hydrate crystals within the bulk Mix-H. The heterogeneity is quantitatively assessed using a novel test – stepwise depressurization, which revealed increased heterogeneity with decreasing initial pressure–temperature as well as increasing gas–liquid ratios and hydrate formation degree. The heterogeneity of Mix-H significantly impacts the CO2 capture efficiency and long–term stability of CO2 sequestration under environmental disturbances. The results also pave the way for evaluating the performance of mixed hydrate application in hydrate–based chemical engineering and CCS technology.

Dynamic protein hydration water mediates the aggregation kinetics of amyloid β peptides at interfaces

Protein hydration water is essential for protein misfolding and amyloid formation, but how it directs the course of amyloid formation has yet to be elucidated. Here, we experimentally demonstrated that femtosecond sum frequency generation vibrational spectroscopy (SFG–VS) and the femtosecond IR pump–SFG probe technique can serve as powerful tools for addressing this issue. Using amyloid β(1–42) peptide as a model, we determined the transient misfolding intermediates by probing the amide band spectral features and the local hydration water changes by measuring the ultrafast vibrational dynamics of the amide I band. For the first time, we established a correlation between the dynamic change in protein hydration water and aggregation propensity. The aggregation propensity depends on the dynamic change in the hydration water, rather than the static hydration water content of the initial protein state. Water expulsion enhances the aggregation propensity and promotes amyloid formation, while protein hydration attenuates the aggregation propensity and inhibits amyloid formation. The suppression of water expulsion and protein hydration can prevent protein aggregation and stabilize proteins. These findings contribute to a better understanding of the underlying effect of hydration water on amyloid formation and protein structural stability and provide a strategy for maintaining long–term stabilization of biomolecules.

Modernisation of the personnel management system of the Armed Forces of Ukraine in the context of the ongoing military conflict with Russia

Considering the ongoing military conflict with the Russian Federation, the modernisation of the personnel management system of the Armed Forces of Ukraine is of utmost significance. Effective training of new officers is becoming a strategic task to strengthen the country’s defence capability and ensure its national security. The purpose of this research is to thoroughly analyse and justify ways to modernise the personnel management system of the Armed Forces of Ukraine in the context of the current military conflict, with a focus on improving the education and training of the new generation of officers. The research is based on a statistical analysis of data obtained through expert analysis and a survey of highly qualified professionals. The analysis demonstrated that the existing personnel management system of the Armed Forces of Ukraine requires significant modifications to respond to the current challenges of military operations. In particular, there is a need to introduce advanced teaching methods and use modern technologies in the training of officers. In addition, it is essential to improve the organisational structures that provide training for officers. It includes revision of programmes, adaptation to modern conflicts and implementation of international standards of military training. In addition, the psychological and social aspects of the design and development of the officer corps should be considered to ensure its stability and productivity in the long term. A special emphasis is placed on the need to introduce international experience and cooperation with partner countries, which may include the exchange of experience, and joint exercises and training programmes. The results obtained are essential for the development and implementation of strategic plans for the modernisation of the personnel management system of the Armed Forces of Ukraine, which will help to increase the effectiveness of military activities and strengthen the country’s defence capabilities in the face of ever-growing security threats.

Effects of AI-Generated Misinformation and Disinformation on the Economy

This study investigates the potential consequences of AI-driven misinformation/disinformation on the economy, which the World Economic Forum has identified as the most significant threat to global stability in the near term. To determine the effects of false and/or fake information on the economy, qualitative research method which involves collecting and analyzing information that is rich in detail, context, and meaning was preferred within the framework of this study, and the following inferences and conclusions were drawn regarding the potential implications and consequences of AI-generated mis/disinformation. Mis/disinformation can severely damage consumer trust, leading to reduced revenue and tarnished reputations for businesses. Fake news and reviews can harm consumers by influencing their decisions and can damage brands, resulting in crisis management efforts and decreased consumer loyalty. In financial markets, dis/misinformation can create divergent opinions among investors, leading to market volatility. Within supply chains, the spread of false information can disrupt operations and have significant economic consequences. AI-driven disinformation can pose additional risks, potentially affecting political stability and economic policies. As AI technology advances, countries are implementing stricter regulations, such as the EU AI Act, which may increase compliance costs, particularly for smaller businesses. This study can be considered important as it aims to contribute to a growing awareness of the complex and multifaceted nature of the impact of AI on the economy by investigating the potential negative effects of AI.

Gabapentin: An impurity profiling approach with hydrogen peroxide induced thermal oxidation in autoclave

Predicting unconventional pathways in long term stability studies can be very challenging, especially in solid state degradation. This is of vital importance for enhancement in the level of degradation and to further enable the isolation of unknown degradation products. Predicting the mechanism or pathway also help in designing control strategies to minimise the potential chances of impurity formation. In this context, the lagtime of most oxidative degradation mechanisms is extremely important, which allows enough requisite of free radicals etc., one of the unconventional pathways. This is difficult to replicate in degradation studies involving usual solution form. In this investigation, we demonstrate that employing autoclave degradation with hydrogen peroxide conditions provide an enhanced level of an unknown degradation product, which was found to be futile in traditional forced degradation studies. The conditions used probably bypass the lag time. This impurity has been isolated using preparative liquid chromatography (Prep-HPLC) method and spectroscopic techniques like high-resolution mass spectrometry (HRMS) and nuclear magnetic resonance NMR (1H, 13C, DEPT-135, NOESY, APT) for elucidation of the molecular structure. The impurity was identified as a dimer of gabapentin impurity-A (impurity (2,2′-diaza[l,2′-bispiro[4.5]decane]-3,3′-dione) and named it as impurity-U. A plausible mechanism for the formation of isolated impurity is proposed. HPLC methods have been developed and reported for the determination of gabapentin and its related substances using UV detection.

Fabrication of nickel oxide decorated CNTs/GO nanohybrid: A multifunctional electrocatalyst for overall electrochemical water splitting

Hydrogen production from water as renewable energy resource is vital to fulfil the huge energy demands without any hazardous environmental impact. Pursuing the efficient, durable and economical electrocatalyst other than benchmark expensive materials such as Pt, Ru, and Ir, for water electrolysis is a big challenge to produce the hydrogen as clean fuels. Here, we have successfully decorated nickel oxides nanoparticles over the carbon nanotubes covered by the graphene oxide layers (GO/NiO@CNTs/GO) using a facile hydrothermal method and utilized as electrocatalyst for electrochemical water splitting. The surface morphology and structure was assessed using a variety of analytical techniques, including scanning electron microscopy (SEM), energy dispersive X-rays spectroscopy (EDX) and X-ray diffraction (XRD). As prepared nanohybrid (GO/NiO@CNTs/GO) was utilized as multifunctional electrocatalyst to investigate the water electrolysis potential via different electrochemical techniques including linear sweep voltammetry (LSV), and cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and chronoamperometry. The fabricated electrode exhibited a lower overpotential of 236 mV and 208 mV at the standard current density of 10 mAcm−2 under alkaline and acidic conditions, respectively. Enhanced double layer capacitance (Cdl) and reduced charge transfer resistance (Rct) also showed the boosted performance for the hybrid materials with long term stability. The carbon based nanohybrid (GO/NiO@CNTs/GO) showed the promising potential having multifunctional characteristics including oxygen and hydrogen evolution reactions along with overall electrochemical water splitting.

Short segment linear "flaps" of the abdominal aorta: proposed mechanism of origin and evaluation of natural history via retrospective imaging review.

Luminal linear findings (LLF) of the abdominal aorta are often called aortic "flaps," triggering concern for acute aortic syndrome. However, these "flaps" are unlikely to represent intimomedial dissection given isolation to the abdominal aorta, short length, and incidental discovery. We aim to characterize the etiology and stability of LLF. CT reports finalized January 2021-December 2022 were queried for terms "focal dissection," "dissection flap," "linear filling defect," and "linear flap." Patients were excluded for thoracoabdominal dissection, LLF in non-aortic vessel, no prior contrast-enhanced imaging, and less than 6months between exams. Index exam reviewed for presence of LLF, atherosclerosis, and aortic caliber at LLF site. Prior exam assessed for aortic caliber and aortic findings at subsequent LLF site. Patients with unchanged LLF between exams were categorized "Stable" and patients with interval change "Dynamic." Seven hundred and two cases identified. After exclusions, imaging from 70 patients reviewed; 1 excluded for no LLF. Stable Cohort of 39 patients had median follow-up 31months (range 6-284 months). 87% of aortas were moderately/severely atherosclerotic (n = 16 moderate, n = 18 severe), while 69% were ectatic/aneurysmal (n = 27). Dynamic Cohort of 20 patients had median follow-up of 70months (range 14-244months). All were atherosclerotic and 80% were ectatic/aneurysmal compared to 25% ectatic/aneurysmal at prior imaging. Mural thrombus was present at the site of the future LLF in 17 of 20, thrombosed PAU in 1, and no focal findings in 2. Short-segment LLFs within the abdominal aorta arise from prior mural thrombus and demonstrate long term stability. Clinically and radiographically indolent, LLFs should not be called dissection flaps.

A virtual reconstruction method for corridor gable buildings based on the knowledge of structural dynamics: taking Leiyin Cave as an example

Virtual reconstruction of ancient buildings often has incomplete records of the original design and construction details, and can only be reconstructed based on limited data, drawings and photography, which is different from the actual conditions. The unique overhanging structure of the corridor gable building makes it vulnerable to damage in extreme weather conditions. In order to ensure that the virtual reconstruction results can not only reproduce the original appearance of history, but also ensure that the reconstructed model maintains structural stability in the long term. This paper proposes a reconstruction method of the original appearance of the corridor gable building remains based on structural dynamics analysis. This method comprehensively uses three-dimensional reconstruction, structural engineering, dynamic analysis, and computer simulation technology to ensure the structural accuracy and historical authenticity of the virtually reconstructed corridor gable building. First, through data collection and analysis, combined with ancient architectural construction techniques, a preliminary three-dimensional model was created, which included all structural elements and details. Several groups of reconstruction schemes are determined based on material properties. Then, using finite element analysis software, perform dynamic analysis on the three-dimensional model. Evaluate the stability of the reconstructed structure and optimize the material selection plan to ensure the feasibility and accuracy of the virtual reconstruction. Taking the virtual reconstruction of the eaves in front of Leiyin Cave as an example, it shows that this method is effective and feasible to achieve the virtual reconstruction of corridor gable buildings. It provides new ideas for virtual reconstruction of ancient buildings and has important practical application value.

Elevating Oxygen Evolution using Iron Phthalocyanine Infused Vanillic acid Electrocatalyst.

Oxygen evolution reaction (OER) is the bottle neck step in water splitting reaction towards the realization of hydrogen based clean energy production and storage. Metal air batteries and polymer electrolyte membrane fuel cells (PEMFC) are the alternative green energy systems that utilise O2 and H2 in the production of continuous and high energy output without the utilization of carbon based fuels which are the major sources of pollution. Transition metal based N4 organics are explored extensively as oxygen electrocatalysts i. e., OER and oxygen reduction reaction (ORR) catalysts because of their ease of synthesis, tuneable properties, low cost and high performance with long term stability. Here, vanillic acid functionalized iron phthalocyanine (FeVAPc) was synthesised and characterised by various spectroscopic techniques. The novel FeVAPc exhibited good thermal stability and was coated on Ni foam for OER studies. The scanning electron microscopy images showed net-work like surface morphology and the X-ray photoelectron spectroscopy indicated the presence of Fe in +3 oxidation state. The Ni/FeVAPc demonstrated excellent electrocatalytic activity for OER with overpotential of 312 mV at 10 mA.cm-2 current density in 1.0 M KOH electrolyte. The designed organic based catalyst exhibited lesser Tafel slope value which is nearer to the benchmark catalyst, IrO2. The proposed catalyst exhibited good stability as phthalocyanines are highly stable and do not undergo decomposition even in strong acidic and basic corrosive media. Integration of FeVAPc onto the Ni foam resulted in higher mass activity, lower charge transfer resistance, high active surface area leading to enhanced conductivity and activity. The fabricated Ni/FeVAPc is an appropriate cost-effective, efficient and stable catalyst for OER towards industrial applications.