In recent years, the impacts of climate change have variably affected the global ecological environment, exacerbating water scarcity and related issues. Meantime, as part of soil evapotranspiration and plant transpiration in water resources, green water is of great significance in stabilizing the global water cycle and promoting the sustainable development of agriculture. Therefore, the green water coefficient in this study calculates the conversion rate of precipitation to green water, which is important for the balance between blue and green water and the stability of the ecological environment. Based on trend analysis methods and Geodetector, this study analyses the spatial and temporal characteristics and driving mechanisms of the green water coefficient on the globe and on each land-use type from 1992 to 2020. The findings revealed that: (1) The global green water coefficient is clearly spatially differentiated, showing certain latitudinal distribution differences, with the lowest near the equator. The areas with higher green water coefficients are mainly in northern and southern Africa, central Asia, Oceania and northern and western North America, while the areas with lower green water coefficients are concentrated in northern South America and Southeast Asia. (2) The global average value of green water coefficient decreases before increasing. Except for water, the green water coefficient of other land use types (crop land, forest land, grassland, urban land, unused land) changes significantly and there are fewer abrupt change points. Areas where the green water coefficient is too low and changes drastically are not suitable for rainfed agriculture. (3) Different influential factors act on the green water coefficients of different land use types, and there is a two-factor enhancement and non-linear enhancement relationship between them, with a combination of factors affecting the green water coefficient. By studying the characteristics of the green water coefficient globally and across different land use types, we quantified the influence of climate factors such as precipitation, temperature, wind speed, evapotranspiration, radiation, etc., on the green water coefficient, thereby providing some information for future global rain-fed agriculture and water resources management.